{"id":56494,"date":"2016-12-23T06:30:34","date_gmt":"2016-12-22T22:30:34","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=56494"},"modified":"2016-12-21T22:34:59","modified_gmt":"2016-12-21T14:34:59","slug":"jacs%ef%bc%9a%e9%ab%98%e6%95%88%e8%b6%85%e5%88%86%e5%ad%90%e5%82%ac%e5%8c%96%e5%89%82-%e5%8d%95%e5%a3%81%e9%87%91%e5%b1%9e%e8%9e%ba%e6%97%8b%e7%ba%b3%e7%b1%b3%e7%ae%a1%ef%bc%88m-hn%ef%bc%89","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=56494","title":{"rendered":"JACS\uff1a\u9ad8\u6548\u8d85\u5206\u5b50\u50ac\u5316\u5242  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M-HN<\/strong><strong>\u50ac\u5316\u5242\u7684\u6982\u5ff5\u548c\u5236\u5907\u8fc7\u7a0b<\/strong><\/p>\n<p><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/\u56fe1-1.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-57813\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/\u56fe1-1.png\" alt=\"\" width=\"600\" height=\"351\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/\u56fe1-1.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/\u56fe1-1-300x176.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/a><\/p>\n<p>(a,b)\u5355\u58c1\u91d1\u5c5e\u87ba\u65cb\u7eb3\u7c73\u7ba1\u7684\u5236\u5907\u793a\u610f\u56fe\u3002<\/p>\n<p>(c)\u50ac\u5316\u5242Bi(III)-HN\u5bf9Mukaiyama Aldol\u53cd\u5e94\u7684\u50ac\u5316\u793a\u610f\u56fe\u3002\u53ea\u97001.2 mol %\u7684\u7528\u91cf\uff0c\u8be5\u50ac\u5316\u5242\u4fbf\u80fd\u8fbe\u5230\u9ad8\u8fbe97%\u7684\u5bf9\u6620\u9009\u62e9\u6027\u3002<\/p>\n<p>(d)\u50ac\u5316\u5242Cu(II)-HN\u5bf9Diels\u2212Alder\u53cd\u5e94\u7684\u50ac\u5316\u793a\u610f\u56fe\u3002\u53ea\u97000.1 mol %\u7684\u7528\u91cf\uff0c\u8be5\u50ac\u5316\u5242\u4fbf\u80fd\u8fbe\u5230\u9ad8\u8fbe91%\u7684\u5bf9\u6620\u9009\u62e9\u6027\u3002<\/p>\n<p><strong>\u56fe\u4e8c<\/strong><strong> M-HN<\/strong><strong>\u50ac\u5316\u5242\u7684\u8868\u5f81<\/strong><\/p>\n<p><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/\u56fe2.jpeg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-57814\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/\u56fe2.jpeg\" alt=\"\" width=\"600\" height=\"511\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/\u56fe2.jpeg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/\u56fe2-300x256.jpeg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/a><\/p>\n<p>(a)\u8d85\u5206\u5b50\u81ea\u7ec4\u88c5\u5f62\u6210\u7684\u87ba\u65cb\u5355\u58c1\u7eb3\u7c73\u7ba1\u7684AFM\u56fe\u50cf\u3002<\/p>\n<p>(b)\u8d1f\u8f7d1\/50 mol Bi<sup>3+<\/sup>\u79bb\u5b50\u7684Bi(III)-HN\u50ac\u5316\u5242\u7684AFM\u56fe\u50cf\u3002<\/p>\n<p>(c)\u8d1f\u8f7d1\/50 mol Bi<sup>3+<\/sup>\u79bb\u5b50\u7684Bi(III)-HN\u50ac\u5316\u5242\u7684TEM\u56fe\u50cf\u3002<\/p>\n<p>(d)\u8d1f\u8f7d1\/50 mol Bi<sup>3+<\/sup>\u79bb\u5b50\u7684Bi(III)-HN\u50ac\u5316\u5242\u7279\u5b9a\u533a\u57df\u7684\u5143\u7d20\u56fe\u50cf\u3002<\/p>\n<p><strong>\u56fe\u4e09<\/strong> <strong>\u50ac\u5316\u5242<\/strong><strong>Bi(III)-HN<\/strong><strong>\u5bf9<\/strong><strong>Mukaiyama Aldol<\/strong><strong>\u53cd\u5e94\u7684\u50ac\u5316<\/strong><\/p>\n<p><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/\u56fe3.jpeg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-57815\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/\u56fe3.jpeg\" alt=\"\" width=\"600\" height=\"658\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/\u56fe3.jpeg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/\u56fe3-274x300.jpeg 274w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/a><\/p>\n<p>\u50ac\u5316\u5242Bi(III)-HN\u5bf9Mukaiyama Aldol\u53cd\u5e94\u7684\u975e\u5bf9\u79f0\u50ac\u5316\u793a\u610f\u56fe\u53ca\u76f8\u5e94\u5e95\u7269\u8303\u56f4\u3002<\/p>\n<p><strong>\u56fe\u56db<\/strong> <strong>\u50ac\u5316\u5242<\/strong><strong>Cu(II)-HN<\/strong><strong>\u5bf9<\/strong><strong>Diels\u2212Alder<\/strong><strong>\u53cd\u5e94\u7684\u50ac\u5316<\/strong><\/p>\n<p><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/\u56fe4.jpeg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-57816\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/\u56fe4.jpeg\" alt=\"\" width=\"600\" height=\"500\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/\u56fe4.jpeg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/\u56fe4-300x250.jpeg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/a><\/p>\n<p>\u50ac\u5316\u5242Cu(II)-HN\u5bf9Diels\u2212Alder\u53cd\u5e94\u7684\u975e\u5bf9\u79f0\u50ac\u5316\u793a\u610f\u56fe\u53ca\u76f8\u5e94\u5e95\u7269\u8303\u56f4\u3002<\/p>\n<p><strong>\u56fe\u4e94<\/strong><strong> Cu(II)-HN<\/strong><strong>\u50ac\u5316\u5242\u5bf9<\/strong><strong>Diels\u2212Alder<\/strong><strong>\u53cd\u5e94\u7684\u50ac\u5316\u673a\u7406\u793a\u610f\u56fe\u00a0<\/strong><\/p>\n<p><strong><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/\u56fe5.jpeg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-57817\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/\u56fe5.jpeg\" alt=\"\" width=\"600\" height=\"524\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/\u56fe5.jpeg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/\u56fe5-300x262.jpeg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/a><\/strong><\/p>\n<p><strong>\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n<p>\u6587\u4e2d\u7740\u91cd\u4ecb\u7ecd\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u8d85\u5206\u5b50\u624b\u6027\u50ac\u5316\u5242\u2014\u2014\u91d1\u5c5e\u87ba\u65cb\u7eb3\u7c73\u7ba1\u7684\u5236\u5907\u53ca\u5176\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\uff0c\u5e76\u5bf9\u5176\u50ac\u5316\u673a\u7406\u8fdb\u884c\u4e86\u63a2\u8ba8\u3002\u540c\u65f6\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86\u4ee5\u81ea\u7ec4\u88c5\u7684\u624b\u6027\u5355\u58c1\u7eb3\u7c73\u7ba1\u4e3a\u50ac\u5316\u5242\u7684\u65b0\u6982\u5ff5\uff0c\u4e3a\u975e\u5bf9\u79f0\u5408\u6210\u50ac\u5316\u9886\u57df\u5f00\u8f9f\u4e86\u5e7f\u9614\u7684\u524d\u666f\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.6b08808\" target=\"_blank\">Self-Assembled Single-Walled Metal-Helical Nanotube (M\u2011HN): Creation of Efficient Supramolecular Catalysts for Asymmetric Reaction <\/a>\uff08J. Am. Chem. Soc., 2016\uff0cDOI: 10.1021\/jacs.6b08808\uff09<\/p>\n<p>\u8be5\u6587\u732e\u6c47\u603b\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u7eb3\u7c73\u5b66\u672f\u7ec4\u7ae0\u534e\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"http:\/\/www.cailiaoniu.com\/25127.html\" target=\"_blank\"><strong>\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/strong><\/a>\u3002<\/p>\n<p>\u6750\u6599\u4eba\u7f51\u5c0a\u91cd\u6240\u6709\u8fdb\u884c\u77e5\u8bc6\u4f20\u64ad\u7684\u5a92\u4f53\uff0c\u8f6c\u8f7d\u8bf7\u8054\u7cfbtougao@cailiaoren.com<\/p>\n<p><strong>\u00a0<b>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/b><a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\"><b>\u6d4b\u8bd5\u8c37<\/b><\/a><b>\uff01<\/b><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u624b\u6027\u50ac\u5316\u662f\u5236\u5907\u5355\u4e00\u7ed3\u6784\u624b\u6027\u5f02\u6784\u4f53\u7684\u91cd\u8981\u65b9\u6cd5\uff0c\u5728\u624b\u6027\u5316\u5408\u7269\u7684\u975e\u5bf9\u79f0\u5408\u6210\u53cd\u5e94\u4e2d\u6709\u7740\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\u3002\u4e00\u76f4\u4ee5\u6765\uff0c\u624b\u6027\u6709\u673a\u5c0f\u5206\u5b50\u50ac\u5316\u53d7\u5230\u5927\u5bb6\u7684\u5e7f\u6cdb\u5173\u6ce8\uff0c\u7136\u800c\u5176\u50ac&#8230;<\/p>\n","protected":false},"author":82,"featured_media":57817,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[116,33],"class_list":["post-56494","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-catalyst","tag-nano"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/56494"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/82"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=56494"}],"version-history":[{"count":6,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/56494\/revisions"}],"predecessor-version":[{"id":58178,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/56494\/revisions\/58178"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/57817"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=56494"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=56494"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=56494"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}