{"id":57455,"date":"2016-12-28T14:00:31","date_gmt":"2016-12-28T06:00:31","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=57455"},"modified":"2016-12-30T11:25:37","modified_gmt":"2016-12-30T03:25:37","slug":"chem-rev-%ef%bc%9a%e7%a9%ba%e5%bf%83%e5%be%ae%e7%ba%b3%e7%b1%b3%e5%82%ac%e5%8c%96%e5%89%82","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=57455","title":{"rendered":"Chem. Rev.\uff1a\u7a7a\u5fc3\u5fae\/\u7eb3\u7c73\u50ac\u5316\u5242"},"content":{"rendered":"<p>&nbsp;<\/p>\n<p>\u5317\u4eac\u65f6\u95f410\u67087\u53f7\uff0c\u7f8e\u56fd\u5316\u5b66\u4f1a\u65d7\u4e0b\u9876\u5c16\u7684\u7efc\u8ff0\u7c7b\u671f\u520aChemical Reviews\uff08IF= 44.509\uff0cJCR2014\uff09\u53d1\u8868\u4e86Ferdi Schu\u0308th\u6559\u6388\u4f5c\u4e3a\u901a\u8baf\u4f5c\u8005\uff0c\u9898\u4e3a\uff1a\u7a7a\u5fc3\u5fae\/\u7eb3\u7c73\u50ac\u5316\u5242\uff08Hollow Nano- and Microstructures as Catalysts\uff09\u7684\u7efc\u8ff0\u6587\u7ae0<sup>1<\/sup>\u3002<strong><span style=\"color: #0000ff;\">Ferdi Schu\u0308th<\/span><\/strong>\u6559\u6388\u4f5c\u4e3a\u5fb7\u56fd\u9a6c\u666e\u7164\u7814\u7a76\u6240\u6240\u957f\uff08Max-Planck-Institut f\u00fcr Kohlenforschung, M\u00fclheim\uff09\u3001\u9a6c\u514b\u65af-\u666e\u6717\u514b\u5b66\u4f1a\u526f\u4f1a\u957f\uff08Max-Planck-Society\uff09\uff0c\u662f\u50ac\u5316\u53ca\u6750\u6599\u7814\u7a76\u9886\u57df\u77e5\u540d\u7684\u79d1\u5b66\u5bb6\uff0c\u5177\u4f53\u4ecb\u7ecd\u89c1\u6587\u672b\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58102 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/in1-1.jpg\" alt=\"\" width=\"680\" height=\"402\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/in1-1.jpg 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/in1-1-300x177.jpg 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p><span style=\"color: #0000ff;\"><strong>\u3010\u524d\u8a00\u3011<\/strong><\/span><\/p>\n<p>\u7535\u5b50\u663e\u5fae\u955c\u7684\u53d1\u5c55\uff0c\u4f7f\u5f97\u7a7a\u5fc3\u6750\u6599\u7684\u8868\u5f81\u548c\u5236\u5907\u6210\u4e3a\u53ef\u80fd\u3002\u7ecf\u8fc730\u591a\u5e74\u7684\u53d1\u5c55\uff0c\u5c06\u7a7a\u5fc3\u6750\u6599\u5e94\u7528\u4e8e\u50ac\u5316\uff0c\u5f97\u5230\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\uff0c\u4e0e\u7a7a\u5fc3\u7ed3\u6784\u50ac\u5316\u6709\u5173\u7684\u51fa\u7248\u7269\u6570\u91cf\u5448\u6307\u6570\u589e\u957f\uff08\u56fe1\uff09\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>1 <\/strong><strong>\u7a7a\u5fc3\u7ed3\u6784\u76f8\u5173\u7684\u6587\u732e\u53d1\u8868\u91cf\u53d8\u5316\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58103 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/1-51.jpg\" alt=\"\" width=\"680\" height=\"694\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/1-51.jpg 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/1-51-294x300.jpg 294w\" sizes=\"(max-width: 680px) 100vw, 680px\" 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height=\"465\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/3-34.jpg 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/3-34-300x205.jpg 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\u5982\u4eca\uff0c\u5bf9\u751f\u4ea7\u8f83\u5927\u91cf\u7684\u6837\u54c1\uff0c\u63d0\u51fa\u4e86\u91cd\u5927\u7684\u6311\u6218\uff0c\u5e94\u9488\u5bf9\u8fd9\u4e2a\u8bdd\u9898\uff0c\u8bbe\u60f3\u51fa\u53ef\u884c\u7684\u6a21\u578b\uff0c\u5e76\u6269\u5927\u53ef\u91cd\u590d\u6027\u5de5\u4f5c\u7684\u5e94\u7528\u548c\u63a8\u5e7f\u3002<\/p>\n<p><strong><span style=\"color: #0000ff;\">\u4e00\u3001\u6e7f\u5316\u5b66\u6cd5\u5236\u5907\u7a7a\u5fc3\u6750\u6599<\/span><\/strong><\/p>\n<p>\u6e7f\u5316\u5b66\u5408\u6210\u7a7a\u5fc3\u6750\u6599\uff0c\u4e3b\u8981\u5728\u6db2\u4f53\u4ecb\u8d28\u4e2d\u8fdb\u884c\uff0c\u5982\u6db2\u4f53\u4e2d\u4e73\u6db2\u6216\u56fa\u4f53\u60ac\u6d6e\u6db2\u3002\u8be5\u65b9\u6cd5\u5bf9\u5408\u6210\u53c2\u6570\u7684\u63a7\u5236\u8981\u6c42\u8f83\u9ad8\uff0c\u56e0\u6b64\u5408\u6210\u7684\u6700\u7ec8\u7ed3\u6784\u6bd4\u8f83\u7279\u6b8a\u3002\u7136\u800c\uff0c\u4e3b\u8981\u7684\u7f3a\u70b9\u662f\u901a\u5e38\u5728\u9ad8\u5ea6\u7a00\u91ca\u7684\uff08\u901a\u5e38\u662f\u80f6\u4f53\u7684\uff09\u4ecb\u8d28\u4e2d\u53cd\u5e94\uff0c\u56e0\u6b64\u53cd\u5e94\u6db2\u4f53\u79ef\u8f83\u5927\uff0c\u5e76\u4e14\u901a\u5e38\u5206\u6b65\u8fdb\u884c\u3002\u6545\u6e7f\u5316\u5b66\u5408\u6210\u7684\u76ee\u6807\u662f\u4ee5\u8fde\u7eed\u65b9\u5f0f\u64cd\u4f5c\u800c\u4e14\u4e0d\u964d\u4f4e\u4ea7\u54c1\u7684\u8d28\u91cf\u3002<\/p>\n<p>\u5728\u6db2\u4f53\u4ecb\u8d28\u4e2d\uff0c\u901a\u5e38\u65bd\u52a0\u6a21\u677f\u6750\u6599\u4ee5\u5f15\u5bfc\u5408\u6210\u7a7a\u5fc3\u6750\u6599\uff0c\u5e76\u51b3\u5b9a\u9897\u7c92\u5c3a\u5bf8\u548c\u5f62\u72b6\u3002 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src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/4-3.jpeg\" alt=\"\" width=\"680\" height=\"831\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/4-3.jpeg 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/4-3-245x300.jpeg 245w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\uff08a\uff09\u57fa\u4e8e\u5fae\u4e73\u6db2\u7684Au@SiO<sub>2<\/sub>\u86cb\u9ec4-\u86cb\u58f3\u7ed3\u6784\u7eb3\u7c73\u9897\u7c92\uff08Au@HSN\uff09\u5408\u6210\u7684\u65b9\u6848\u3002TEOS\uff1a\u539f\u7845\u9178\u56db\u4e59\u916f\uff1bAPTS\uff1a3\u6c28\u57fa\u4e19\u57fa\u4e09\u7532\u6c27\u57fa\u7845\u70f7\u3002<\/p>\n<p>\uff08b-d\uff09\u5404\u79cd\u91d1\u8d1f\u8f7d\u91cf\u7684Au@HSN\u7684TEM\u663e\u5fae\u7167\u7247\u3002<\/p>\n<p>\uff08e\uff09Fe<sub>3<\/sub>O<sub>4<\/sub>\u7cd6\u5316\u7eb3\u7c73\u9897\u7c92\u7684\u5408\u6210\u65b9\u6848\uff1a\u63ba\u5165\u9884\u5408\u6210\u7684Fe<sub>3<\/sub>O<sub>4<\/sub>\u80f6\u4f53\u7eb3\u7c73\u6676\u4f53\u6db2\u6ef4\u7684o\/w\u5fae\u4e73\u6db2\u3002<\/p>\n<p>\uff08f\uff09Fe<sub>3<\/sub>O<sub>4<\/sub>\u7684TEM\u663e\u5fae\u7167\u7247\u7eb3\u7c73\u6676\u4f53\u3002\uff08g\u548ch\uff09Fe<sub>3<\/sub>O<sub>4<\/sub>@\u805a\u5408\u7269\u7eb3\u7c73\u68d2\u7684\u660e\u573a\u548c\u6697\u573aHAADF\u7167\u7247\u3002\uff08i\uff09Fe<sub>3<\/sub>O<span style=\"text-decoration: line-through;\"><sub>4<\/sub><\/span>@C\u7684\u78c1\u5b66\u6027\u80fd\u3002<\/p>\n<p><strong>\u56fe5 \u6e7f\u5316\u5b66\u6cd5\u4e4b\u4e73\u6db2\u540e\u5904\u7406\u5f97\u5230\u7684PtCo\u7a7a\u5fc3\u6750\u6599<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58108 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/5-2.jpeg\" alt=\"\" width=\"680\" height=\"664\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/5-2.jpeg 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/5-2-300x293.jpeg 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\uff08a\uff09\u5408\u6210PtCo@C\u62e8\u6d6a\u9f13\u578b\u7eb3\u7c73\u7c92\u5b50\uff08PtCo@HCS\uff09\u7684\u65b9\u6cd5\uff0c<\/p>\n<p>\uff08b\uff09SEM\u663e\u5fae\u7167\u7247\uff0c<\/p>\n<p>\uff08c\uff09HAADF-STEM\u663e\u5fae\u7167\u7247\u548c\uff08d\uff09PtCo@HCS\u7684EDX\u5143\u7d20\u5206\u5e03\u56fe\uff08Co\uff1a\u7eff\u8272\uff0cPt\uff1a\u7ea2\u8272\uff09\u3002<\/p>\n<p><strong>\u56fe6 \u6e7f\u5316\u5b66\u6cd5\u4e4b\u80f6\u675f\u6a21\u677f\u6cd5\u5236\u5907\u591a\u5b54SiO<sub>2<\/sub>\u7403<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58109 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/6-2.jpeg\" alt=\"\" width=\"680\" height=\"441\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/6-2.jpeg 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/6-2-300x195.jpeg 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\u901a\u8fc7\u4e24\u4e2a\u80f6\u675f\u7684\u76f8\u4e92\u4f5c\u7528\u5f62\u6210\u6a21\u677f\u5316\u7684\u4e2d\u7a7a\u4ecb\u5b54\u4e8c\u6c27\u5316\u7845\uff08HMS\uff09\u7eb3\u7c73\u9897\u7c92\u7684\u5f62\u6210\u65b9\u6848\u80f6\u675f\uff08\u9876\u90e8\uff09\u3002 HMS\u7eb3\u7c73\u9897\u7c92\u7684SEM\uff08a1\uff09\u548cTEM\uff08a2\uff0ca3\uff09\u663e\u5fae\u7167\u7247\u3002<\/p>\n<p><strong>\u56fe7 \u6e7f\u5316\u5b66\u6cd5\u4e4b\u56ca\u6ce1\u4f5c\u4e3a\u8f6f\u6a21\u677f\u5236\u5907\u4ecb\u5b54\u4e8c\u6c27\u5316\u7845\u7a7a\u5fc3\u7eb3\u7c73\u7403<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58110 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/7-2.jpeg\" alt=\"\" width=\"680\" height=\"1049\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/7-2.jpeg 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/7-2-194x300.jpeg 194w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/7-2-664x1024.jpeg 664w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>(a) \u591a\u58f3\u4ecb\u5b54\u4e8c\u6c27\u5316\u7845\u7a7a\u5fc3\u7eb3\u7c73\u7403\u7684\u591a\u58f3\u5f62\u6210\u793a\u610f\u56fe\u3002<\/p>\n<p>\uff08b\uff09SEM\u663e\u5fae\u7167\u7247\u3002<\/p>\n<p>\uff08c\uff09TEM\u663e\u5fae\u7167\u7247\u3002<\/p>\n<p><strong>\u56fe8 \u6e7f\u5316\u5b66\u6cd5\u4e4b\u805a\u5408\u7269\u6a21\u677f\u6cd5\u5236\u5907Fe<sub>3<\/sub>O<sub>4<\/sub>@TiO<sub>2<\/sub>\u7eb3\u7c73\u9897\u7c92<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58111 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/8-3.jpeg\" alt=\"\" width=\"680\" height=\"690\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/8-3.jpeg 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/8-3-296x300.jpeg 296w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\uff08a\uff09\u5408\u6210\u805a\uff08\u4e19\u70ef\u9178\uff09\u805a\u96c6\u4f53\u4e3a\u6a21\u677f\u7684Fe<sub>3<\/sub>O<sub>4<\/sub>@TiO<sub>2<\/sub>\u7eb3\u7c73\u9897\u7c92\u7684\u65b9\u6cd5\u793a\u610f\u56fe\u3002<\/p>\n<p>\uff08b\uff09\u4e2d\u7a7aTiO<sub>2<\/sub>TEM\u663e\u5fae\u7167\u7247\u3002<sub>\u00a0<\/sub><\/p>\n<p>\uff08c\uff09\u6838-\u58f3Fe<sub>3<\/sub>O<sub>4<\/sub>@TiO<sub>2<\/sub>\u548c\uff08d\u548ce\uff09\u62e8\u6d6a\u9f13\u578bFe<sub>3<\/sub>O<sub>4<\/sub>@TiO<sub>2<\/sub>\u7eb3\u7c73\u9897\u7c92\u7684TEM\u663e\u5fae\u7167\u7247\u3002<\/p>\n<p><strong>\u56fe9 \u6e7f\u5316\u5b66\u6cd5\u4e4b\u786c\u6a21\u677f\u6cd5\u5f62\u6210\u7a7a\u5fc3\u7ed3\u6784<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58112 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/9-2.jpeg\" alt=\"\" width=\"680\" height=\"1190\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/9-2.jpeg 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/9-2-171x300.jpeg 171w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/9-2-585x1024.jpeg 585w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\uff08a\uff09\u901a\u8fc7\u78b3\u6a21\u677f\u4e0a\u7684\u5438\u9644\u5408\u6210\u7a7a\u5fc3\u91d1\u5c5e\u6c27\u5316\u7269\u7403\u4f53\u7684\u65b9\u6848\u3002<\/p>\n<p>\uff08b\uff09\u9010\u5c42\u6c89\u79ef\u6cd5\uff0c\u5728SiO<sub>2<\/sub>\u786c\u6a21\u677f\u4e0a\uff0c\u5408\u6210\u4e2d\u7a7a\u94f6\u7eb3\u7c73\u9897\u7c92\u3002<\/p>\n<p>\uff08c\uff09\u5728Au@SiO<sub>2<\/sub>\u6838-\u58f3\u6a21\u677f\u4e0a\u901a\u8fc7\u5316\u5b66\u6c89\u79ef\uff0c\u5408\u6210Au@ZrO<sub>2<\/sub>\u5375\u58f3-\u9ec4\u6838\u7eb3\u7c73\u9897\u7c92\u3002<\/p>\n<p><strong>\u56fe10 \u6e7f\u5316\u5b66\u6cd5\u4e4b\u7eb3\u7c73\u94f8\u9020\u65b9\u6848<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58113 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/10-2.jpeg\" alt=\"\" width=\"680\" height=\"1105\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/10-2.jpeg 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/10-2-185x300.jpeg 185w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/10-2-630x1024.jpeg 630w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\uff08a\uff09\u5728\u6838-\u58f3SiO<sub>2<\/sub>\u6a21\u677f\u4e0a\u5408\u6210\u7a7a\u5fc3\u4ecb\u5b54\u78b3\u7403\u3002<\/p>\n<p>\uff08b\uff09\u5728\u56fa\u4f53SiO<sub>2<\/sub>\u6a21\u677f\u4e0a\u901a\u8fc7\u7eb3\u7c73\u6d47\u94f8\u83b7\u5f97\u7684\u4e2d\u7a7a\u78b3\u7403\u7684TEM\u663e\u5fae\u7167\u7247\u3002<\/p>\n<p>\u4f3d\u51e1\u5c3c\u7535\u7f6e\u6362\u53cd\u5e94\u548c\u53ef\u80af\u8fbe\u5c14\uff08Kirkendall\uff09\u6548\u5e94\u76f8\u4e92\u8865\u5145\uff0c\u63ed\u793a\u4e86\u201c\u7a7a\u5fc3\u201d\u5f62\u6210\u8fc7\u7a0b\u3002Gonz\u00e1lez\u7b49\u4eba\u5bf9Au-Ag\u4e2d\u7a7a\u7eb3\u7c73\u7c92\u5b50\u7684\u7814\u7a76\u53d1\u73b0\uff0c\u4f3d\u51e1\u5c3c\u7535\u7f6e\u6362\u53cd\u5e94\u4f7f\u5f97\u5728Ag\u7eb3\u7c73\u9897\u7c92\u7684\u5185\u5916\u8986\u76d6\u4e86Au\u7c92\u5b50\uff0c\u901a\u8fc7Kirkendall\u6269\u6563\u8fc7\u7a0b\uff0cAu\/Ag\u5185\u90e8\u7a7a\u9699\u4e0a\u4ea7\u751f\u7f3a\u53e3\uff0c\u5bfc\u81f4\u4ea7\u751f\u989d\u5916\u7684\u7a7a\u9699\uff0c\u6700\u540e\u5f62\u6210\u53cc\u58c1\u7eb3\u7c73\u76d2\uff08\u56fe11\uff09\u3002<\/p>\n<p><strong>\u56fe11 \u6e7f\u5316\u5b66\u6cd5\u4e4b\u4f3d\u51e1\u5c3c\u7535\u7f6e\u6362\u53cd\u5e94(galvanic replacement reaction)\u8fc7\u7a0b<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58114 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/11-2.jpeg\" alt=\"\" width=\"680\" height=\"137\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/11-2.jpeg 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/11-2-300x60.jpeg 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p><strong>\u56fe12 \u6e7f\u5316\u5b66\u6cd5\u4e4b\u65e0\u6a21\u677f\u6cd5<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58115 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/12-2.jpeg\" alt=\"\" width=\"680\" height=\"253\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/12-2.jpeg 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/12-2-300x112.jpeg 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\uff08a\uff09\u901a\u8fc7\u5bf9\u79f0\u548c\u4e0d\u5bf9\u79f0\u7684Ostwald\u719f\u5316\u5f62\u6210\u7a7a\u5fc3\u6750\u6599\u7684\u6a2a\u622a\u9762\u793a\u610f\u56fe\u3002\u9ed1\u6697\u5730\u533a\u8f83\u6d45\u7684\u533a\u57df\u8868\u793a\u8f83\u5c0f\u548c\/\u6216\u677e\u6563\u586b\u5145\u7684\u5fae\u6676\uff0c\u767d\u8272\u533a\u57df\u5bf9\u5e94\u4e8e\u7a7a\u9699\u7a7a\u95f4\u3002<\/p>\n<p>\uff08b\uff09SEM\u663e\u5fae\u7167\u7247\uff08\u5de6\uff09\u548c\u5b9a\u5411\u5806\u79ef\u7684\u8fc7\u7a0b\uff08\u53f3\uff09\u5bfc\u81f4\u7a7a\u5fc3\u84b2\u516c\u82f1\u6750\u6599\u7684\u5f62\u6210\u3002<\/p>\n<p><span style=\"color: #0000ff;\"><strong>\u4e8c\u3001\u55b7\u96fe\u6cd5\u5236\u5907\u7a7a\u5fc3\u6750\u6599<\/strong><\/span><\/p>\n<p>\u55b7\u96fe\u6280\u672f\u5305\u62ec\u4e00\u7cfb\u5217\u7684\u5408\u6210\u65b9\u6cd5\uff0c\u901a\u8fc7\u5904\u7406\u96fe\u5316\u7684\u6db2\u4f53\u6216\u6c14\u4f53\uff0c\u63a5\u7740\u8fdb\u884c\u77ed\u65f6\u95f4\u70ed\u5904\u7406\u4ee5\u4ea7\u751f\u56fa\u4f53\u4ea7\u7269\u3002\u4e0e\u201c\u6e7f\u5316\u5b66\u5408\u6210\u65b9\u6cd5\u201d\u76f8\u6bd4\uff0c\u55b7\u96fe\u65b9\u6cd5\u9700\u8981\u7684\u8bd5\u5242\u66f4\u5c11\uff0c\u4e14\u9644\u52a0\u4ea7\u7269\u5c11\u3002\u55b7\u96fe\u65b9\u6cd5\u975e\u5e38\u9002\u5408\u5408\u6210\u7a7a\u5fc3\u7b49\u56fa\u4f53\u7eb3\u7c73\u6750\u6599\u3002\u57fa\u672c\u4e0a\uff0c\u6839\u636e\u64cd\u4f5c\u6a21\u5f0f\u548c\u64cd\u4f5c\u7684\u6e29\u5ea6\u8303\u56f4\u7279\u6027\uff0c\u4e00\u822c\u8ba4\u4e3a\u6709\u4e09\u4e2a\u4e3b\u8981\u7684\u65b9\u6cd5\uff1a\u55b7\u96fe\u5e72\u71e5\uff0c\u55b7\u96fe\u70ed\u89e3\u548c\u706b\u7130\u55b7\u96fe\u70ed\u89e3\u3002<\/p>\n<p>\u65e0\u8bba\u4f7f\u7528\u4ec0\u4e48\u55b7\u96fe\u6280\u672f\uff0c\u7a7a\u5fc3\u7403\u90fd\u662f\u4ece\u5177\u6709\u4e00\u5b9a\u5927\u5c0f\u7684\u6c14\u6eb6\u80f6\u6db2\u6ef4\u5f00\u59cb\uff0c\u901a\u8fc7\u63a7\u5236\u5f84\u5411\u6e29\u5ea6\u68af\u5ea6\u6765\u751f\u957f\u3002\u56fe12\u7ed9\u51fa\u4e86\u5408\u6210\u8fc7\u7a0b\u53ef\u80fd\u7684\u793a\u610f\u56fe\u3002\u5f53\u6db2\u6ef4\u5230\u8fbe\u70ed\u7aef\uff0c\u6eb6\u89e3\u7684\u56fa\u4f53\u524d\u9a71\u4f53\u5f00\u59cb\u53cd\u5e94\/\u6216\u6c89\u6dc0\u5f62\u6210\uff0c\u5728\u6db2-\u6c14\u754c\u9762\u5904\u4e0e\u6eb6\u5242\u540c\u65f6\u805a\u96c6\u84b8\u53d1\u3002\u521d\u59cb\u7684\u58f3\u8fc5\u901f\u53d1\u80b2\uff0c\u8fd9\u91cc\u53ef\u80fd\u6709\u591a\u4e2a\u7ed3\u679c\u3002\u5982\u679c\u58f3\u662f\u5bc6\u96c6\u7684\uff0c\u4ee5\u53ca\u6240\u6355\u83b7\u7684\u6eb6\u5242\u7684\u4e0d\u53ef\u6e17\u900f\u7684\uff0c\u90a3\u4e48\u4f53\u79ef\u81a8\u80c0\u53ef\u80fd\u5bfc\u81f4\u5305\u88f9\u7684\u58f3\u4f53\u7834\u88c2\uff0c\u7279\u522b\u662f\u8fbe\u5230\u9ad8\u4e8e\u6eb6\u5242\u6cb8\u70b9\u7684\u6e29\u5ea6\u65f6\u3002\u76f8\u53cd\uff0c\u5982\u679c\u65b0\u751f\u7684\u58f3\u662f\u591a\u5b54\u7684\uff0c\u5e76\u5141\u8bb8\u6eb6\u5242\u901a\u8fc7\u58f3\u4f53\u84b8\u53d1\u800c\u4e0d\u53d7\u81a8\u80c0\u7ea6\u675f\uff0c\u90a3\u4e48\u4e2d\u7a7a\u7403\u5f62\u9897\u7c92\u53ef\u4ee5\u901a\u8fc7\u53e0\u52a0\u7684\u987a\u5e8f\u5728\u5916\u58f3\u7684\u5185\u8868\u9762\u4e0a\u6c89\u79ef\u3002\u8fd9\u6837\uff0c\u53cd\u5e94\u6216\u6c89\u6dc0\u5728\u6db2\u76f8\u4e2d\u7684\u8fc7\u7a0b\u53ef\u80fd\u5bfc\u81f4\u9644\u52a0\u7684\u5185\u90e8\u7ed3\u6784\uff0c\u5bfc\u81f4\u540c\u5fc3\u58f3\u5c42\u7ed3\u6784\uff0c\u6216\u9644\u805a\u6210\u4ea7\u751f\u86cb\u9ec4-\u86cb\u58f3\u7ed3\u6784\u3002\u6700\u7ec8\u7684\u7c92\u5b50\u7ed3\u6784\u4ee5\u53ca\u5176\u5728\u52a0\u70ed\u533a\u57df\u5185\u7684\u505c\u7559\u8fc7\u7a0b\u4e2d\u7684\u5f62\u8c8c\u4f9d\u8d56\u4e8e\u521d\u59cb\u6c14\u6eb6\u80f6\u6db2\u6ef4\u5c3a\u5bf8\u548c\u6e29\u5ea6\u3002\u540c\u65f6\uff0c\u7531\u4e8e\u6c14\u6eb6\u80f6\u53d1\u5c55\u7684\u4e0d\u5747\u5300\u6027\uff0c\u5c06\u5bfc\u81f4\u5728\u5355\u4e2a\u7c92\u5b50\u6c34\u5e73\u7684\u5404\u79cd\u5f84\u5411\u70ed\u68af\u5ea6\uff0c\u4ee5\u53ca\u6cbf\u7740\u52a0\u70ed\u7684\u6e29\u5ea6\u68af\u5ea6\uff0c\u6700\u7ec8\u7684\u7c89\u672b\u53ef\u80fd\u4e0d\u4ec5\u6709\u5bbd\u7684\u7c92\u5ea6\u5206\u5e03\uff0c\u4e5f\u53ef\u80fd\u6709\u591a\u79cd\u5927\u5c0f\u5206\u5e03\u7684\u7c92\u5b50\u5171\u5b58\u3002\u4e3a\u83b7\u5f97\u5747\u5300\u7684\u5f62\u6001\uff0c\u53ef\u4f7f\u7528\u8f6f\/\u786c\u6a21\u677f\uff0c\u6216\u8005\u590d\u5408\u578b\u524d\u9a71\u4f53\u6eb6\u6db2\u6216\u60ac\u6d6e\u6db2\u3002<\/p>\n<p><strong>\u56fe13 \u4ece\u6c14\u6eb6\u80f6\u6db2\u6ef4\u751f\u957f\u56fa\u4f53\u9897\u7c92\u7684\u8def\u7ebf\u793a\u610f\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58116 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/13-2.jpg\" alt=\"\" width=\"680\" height=\"1022\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/13-2.jpg 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/13-2-200x300.jpg 200w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p><strong>\u56fe14 \u55b7\u96fe\u6cd5\u4e4b\u55b7\u96fe\u5e72\u71e5\u793a\u610f\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58117 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/14-1-2.jpg\" alt=\"\" width=\"680\" height=\"267\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/14-1-2.jpg 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/14-1-2-300x118.jpg 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\uff08a\uff09\u55b7\u96fe\u5e72\u71e5\u5ba4\u7684\u65b9\u6848\u3002<\/p>\n<p>\uff08b\uff09\u901a\u8fc7\u55b7\u96fe\u5e72\u71e5\u5f62\u6210\u4e2d\u7a7a\u591a\u6676\u7eb3\u7c73MOF\u80f6\u56ca\u3002<\/p>\n<p>\uff08c\uff09\u5b9e\u9a8c\u5ba4\u89c4\u6a21\u7684\u55b7\u96fe\u5e72\u71e5\u5668\u7684\u56fe\u7247\u3002<\/p>\n<p><strong>\u56fe15 \u55b7\u96fe\u6cd5\u4e4b\u706b\u7130\u55b7\u96fe\u70ed\u89e3\u793a\u610f\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58118 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/15-2.jpeg\" alt=\"\" width=\"680\" height=\"866\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/15-2.jpeg 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/15-2-236x300.jpeg 236w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>(a)\u4e59\u9187\u6eb6\u6db2\u4e2d\u5b58\u5728\u548c(b\uff09\u4e0d\u5b58\u5728\u805a\u4e59\u4e8c\u9187\uff08PEG\uff09\u4f5c\u8868\u9762\u6d3b\u6027\u5242\uff0c\u901a\u8fc7Al(NO<sub>3<\/sub>)<sub>3<\/sub>\u7684\u706b\u7130\u70ed\u89e3\u6765\u5236\u5907\u4e2d\u7a7aAl<sub>2<\/sub>O<sub>3<\/sub>\u7eb3\u7c73\u9897\u7c92\u5f62\u6210\u7684\u793a\u610f\u56fe\u3002<\/p>\n<p>(c)\u5b58\u5728\u548c(d)\u4e0d\u5b58\u5728PEG\u7684\u60c5\u51b5\u4e0b\u83b7\u5f97\u7684Al<sub>2<\/sub>O<sub>3<\/sub>\u7a7a\u5fc3\u7ed3\u6784\u7684TEM\u663e\u5fae\u7167\u7247\u3002<\/p>\n<p><strong>\u56fe16 \u55b7\u96fe\u6cd5\u4e4b\u55b7\u96fe\u88c2\u89e3\u5236\u5907\u7a7a\u5fc3\u7ed3\u6784<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58119 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/16-2.jpeg\" alt=\"\" width=\"680\" height=\"707\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/16-2.jpeg 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/16-2-289x300.jpeg 289w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\uff08a\uff09\u7531\u5d4c\u6bb5\u5171\u805a\u7269\u8f85\u52a9\u55b7\u96fe\u70ed\u89e3\u6cd5\u5236\u5907\u7684ZnS\u4e2d\u7a7a\u7403\u7684TEM\u7167\u7247\uff0c\u76f4\u5f84\u4e4b\u95f450-300 nm\u3002<\/p>\n<p>\uff08b\uff09ZnS\u58f3\u653e\u5927\u7684TEM\u7167\u7247\u3002<\/p>\n<p>\uff08c\uff09\u6d82\u8986\u6709\u65e0\u5b9a\u5f62\u949b\u7684\u805a\u82ef\u4e59\u70ef\u7403\u6c22\u6c27\u5316\u7269\u8986\u5c42\u7684TEM\u7167\u7247\u3002<\/p>\n<p>\uff08d\uff09\u901a\u8fc7\u786c\u6a21\u677f\u548c\u55b7\u96fe\u70ed\u89e3\u6cd5\u5236\u5907\u7684\u7a7a\u5fc3TiO<sub>2<\/sub>\u58f3TEM\u7167\u7247\u3002<\/p>\n<p><strong><span style=\"color: #0000ff;\">\u4e09\u3001\u7a7a\u5fc3\u6750\u6599\u7684\u5e94\u7528<\/span><\/strong><\/p>\n<p><strong>\u56fe17 \u4e2d\u7a7a\u6750\u6599\u5185\u7684\u4e0d\u540c\u50ac\u5316\u529f\u80fd\u7684\u7c92\u5b50\u793a\u610f\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58120 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/17-2.jpeg\" alt=\"\" width=\"680\" height=\"677\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/17-2.jpeg 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/17-2-150x150.jpeg 150w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/17-2-300x300.jpeg 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\uff08a\uff09\u5375\u9ec4-\u58f3\u86cb\u4e2d\u7684\u5375\u9ec4\u7c92\u5b50;<\/p>\n<p>\uff08b\uff09\u5305\u57cb\u7684\u5206\u5b50\u6216\u9176\u50ac\u5316\u5242;<\/p>\n<p>\uff08c\uff09\u8868\u9762\u951a\u5b9a\/\u4fee\u9970\u7684\u50ac\u5316\u90e8\u5206;<\/p>\n<p>\uff08d\uff09\u68d8\u8f6e\u578b\u56fa\u4f53\u4e2d\u7684\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92;<\/p>\n<p>\uff08e\uff09\u951a\u5b9a\u5728\u591a\u5b54\u58f3\u5185\u7684\u7eb3\u7c73\u9897\u7c92\u3002<\/p>\n<p>\u5982\u56fe17\u6240\u793a\uff0c\u5728\u4e2d\u7a7a\u50ac\u5316\u5242\u4e2d\uff0c\u6d3b\u6027\u4f4d\u70b9\u901a\u5e38\u4f4d\u4e8e\u5b83\u4eec\u7684\u5185\u8868\u9762\u4e0a\u6216\u5176\u5185\u90e8\u7a7a\u95f4\u5185\uff0c\u56e0\u6b64\u53cd\u5e94\u7269\u9700\u8981\u901a\u8fc7\u5916\u58f3\u6269\u6563\u5230\u6838\u5185\u3002\u6240\u4ee5\uff0c\u6839\u636e\u58f3\u7684\u5b54\u9699\u7387\u548c\u539a\u5ea6\uff0c\u53cd\u5e94\u6761\u4ef6\u548c\u58f3\u5185\u5305\u8986\u7684\u6d3b\u6027\u4f4d\u70b9\uff0c\u53cd\u5e94\u7269\uff08\u548c\u4ea7\u7269\uff09\u5206\u5b50\u7684\u6269\u6563\uff08\u4ece\u5176\u4e2d\u6269\u6563\uff09\uff0c\u5c31\u53ef\u4ee5\u63a7\u5236\u6574\u4f53\u7684\u53cd\u5e94\u901f\u7387\u3002<\/p>\n<p><strong>\u56fe 18 \u7a7a\u5fc3\u6750\u6599\u50ac\u5316\u5e94\u7528<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58121 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/18-3.png\" alt=\"\" width=\"680\" height=\"595\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/18-3.png 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/18-3-300x263.png 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p><span style=\"color: #0000ff;\"><strong>3.1 \u56fa\u4f53\u50ac\u5316<\/strong><\/span><\/p>\n<p><span style=\"color: #0000ff;\"><strong>3.1.1 \u56fa\u4f53\u50ac\u5316\u4e2d\u7684\u4f20\u8d28<\/strong><\/span><\/p>\n<p><strong>\u56fe19.\u9897\u7c92\u751f\u957f\u7684\u4e24\u4e2a\u4e3b\u8981\u9014\u5f84<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58122 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/19-2.jpeg\" alt=\"\" width=\"680\" height=\"363\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/19-2.jpeg 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/19-2-300x160.jpeg 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\u5728\u805a\u96c6\u9014\u5f84\u4e2d\uff0c\u5f53\u4e24\u4e2a\u9897\u7c92\u78b0\u649e\u65f6\uff0c\u9897\u7c92\u5728\u8f7d\u4f53\u4e0a\u8fc1\u79fb\u5e76\u805a\u96c6\u3002\u5728\u5965\u65af\u7279\u74e6\u5c14\u5fb7\u719f\u5316\u9014\u5f84\u4e2d\uff0c\u539f\u5b50\u5c3a\u5bf8\u7684\u5c0f\u788e\u7247\u901a\u8fc7\u6c14\u76f8\u6216\u6db2\u76f8\u6216\u901a\u8fc7\u9897\u7c92\u4e4b\u95f4\u7684\u8868\u9762\u6269\u6563\u6765\u8fd0\u8f93\u3002\u7531\u4e8e\u8f83\u5927\u9897\u7c92\u5177\u6709\u8f83\u5c0f\u7684\u8868\u9762\u80fd\uff0c\u8be5\u8def\u5f84\u4e3b\u8981\u662f\u653e\u5927\u5c3a\u5bf8\u5dee\u5f02\uff0c\u5e76\u5bfc\u81f4\u8f83\u5927\u9897\u7c92\u751f\u957f\u800c\u727a\u7272\u8f83\u5c0f\u7684\u9897\u7c92\u3002<\/p>\n<p><strong>\u56fe20 \u50ac\u5316\u5242\u901a\u8fc7\u7a7a\u5fc3\u7ed3\u6784\u5305\u8986\u63d0\u9ad8\u70e7\u7ed3\u7684\u7a33\u5b9a\u6027<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58123 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/20-2.gif\" alt=\"\" width=\"680\" height=\"1544\" \/><\/p>\n<p>Au@ZrO<sub>2<\/sub>\u7eb3\u7c73\u9897\u7c92\u70ed\u7a33\u5b9a\u6027\u7814\u7a76\u3002<\/p>\n<p>\uff08a\uff09\u5728100MP\u7684\u9759\u538b\u529b\u4e0b\u7834\u788eZrO<sub>2<\/sub>\u58f3\u4e4b\u540e\uff0c\u91d1\u9897\u7c92\u5c3a\u5bf8\u4e0e\u7834\u788e\u4e4b\u524d\u7684\u539f\u59cbAu@ZrO<sub>2<\/sub>\u5375\u9ec4-\u58f3\u86cb\u6750\u6599\u76f8\u6bd4\u57fa\u672c\u4e0a\u6ca1\u6709\u53d8\u5316\u3002<\/p>\n<p>\uff08b\uff09\u5728800\u2103\u4e0b\u70ed\u5904\u7406\u540e\u7684\u7834\u788e\u6837\u54c1\u3002\u7531\u4e8e\u91d1\u5c5e\u9897\u7c92\u751f\u957f\uff0c\u5e73\u5747\u9897\u7c92\u5c3a\u5bf8\u660e\u663e\u589e\u52a0\u3002<\/p>\n<p>\uff08c\uff09\u5728800\u2103\u70ed\u5904\u7406\u540e\u7684\u5305\u8986\u6837\u54c1\u3002\u6240\u6709\u91d1\u9897\u7c92\u4fdd\u6301\u539f\u59cb\u5c3a\u5bf8\uff0c\u7a7a\u5fc3\u58f3\u4ecd\u7136\u5b8c\u597d\u65e0\u635f\u3002<\/p>\n<p><strong><span style=\"color: #0000ff;\">3.1.2 \u5305\u8986\u7eb3\u7c73\u7c92\u5b50\u5728\u6db2\u76f8\u53cd\u5e94\u4e2d\u7684\u8131\u51fa\u548c\u805a\u96c6\u7684\u7a33\u5b9a\u6027<\/span><\/strong><\/p>\n<p>\u5965\u65af\u7279\u74e6\u5c14\u5fb7\u719f\u5316\u5f15\u8d77\u7684\u9897\u7c92\u751f\u957f\uff0c\u901a\u5e38\u4f34\u968f\u6709\u7269\u8d28\u6d78\u51fa\uff0c\u662f\u6db2\u76f8\u53cd\u5e94\u4e2d\u4e3b\u8981\u7684\u5931\u6d3b\u9014\u5f84\u3002\u901a\u8fc7\u6eb6\u89e3\/\u518d\u6c89\u79ef\uff0c\u7279\u522b\u662f\u4f5c\u4e3a\u53cd\u5e94\u7269\u6216\u4ea7\u7269\u7684\u826f\u597d\u914d\u4f53\u7684\u5f71\u54cd\u4e0b\u3002\u7a7a\u5fc3\u58f3\u5c42\u63d0\u4f9b\u4e86\u201c\u7eb3\u7c73\u53cd\u5e94\u5668\u201d\u73af\u5883\uff0c\u53ef\u4ee5\u9632\u6b62\u6eb6\u89e3\u7269\u8d28\u5feb\u901f\u6d78\u51fa\u6269\u6563\u79bb\u5f00\u9897\u7c92\uff0c\u4ece\u800c\u589e\u52a0\u5176\u5728\u540c\u4e00\u9897\u7c92\u5185\u518d\u6c89\u79ef\u7684\u6982\u7387\u3002<\/p>\n<p><strong><span style=\"color: #0000ff;\">3.1.3 \u901a\u8fc7\u5206\u5b50\u7b5b\u5c3a\u5bf8\u8bbe\u8ba1\u50ac\u5316\u5242\u7684\u9009\u62e9\u6027\u548c\u50ac\u5316\u7684\u6297\u6bd2\u6027<\/span><\/strong><\/p>\n<p>\u901a\u5e38\uff0c\u6839\u636e\u53cd\u5e94\u7269\u6216\u4ea7\u7269\u5206\u5b50\u7684\u5206\u5b50\u5927\u5c0f\uff0c\u8c03\u8282\u50ac\u5316\u5242\u591a\u5b54\u7ed3\u6784\uff0c\u4ece\u800c\u8c03\u8282\u7269\u8d28\u4f20\u8f93\u901f\u7387\u3002\u5c3a\u5bf8\u9009\u62e9\u6027\u4e5f\u53ef\u4ee5\u901a\u8fc7\u5bf9\u8fc7\u6e21\u6001\u7269\u8d28\u7684\u5f62\u6210\u65bd\u52a0\u7a7a\u95f4\u9650\u5236\u6765\u5b9e\u73b0\uff0c\u5e76\u4e14\u5f53\u5c3a\u5bf8\u9009\u62e9\u6269\u5c55\u5230\u7ed3\u6784\u5f02\u6784\u4f53\u65f6\uff0c\u901a\u5e38\u88ab\u79f0\u4e3a\u5f62\u72b6\u9009\u62e9\u6027\u3002\u50ac\u5316\u5242\u7684\u5c3a\u5bf8\u9009\u62e9\u6027\uff0c\u4e0d\u4ec5\u53ef\u4ee5\u4f9d\u9760\u67d0\u4e9b\u5316\u5408\u7269\u7684\u590d\u6742\u6df7\u5408\u7269\uff0c\u8fd8\u53ef\u4ee5\u901a\u8fc7\u5f15\u5165\u52a8\u529b\u5b66\u9650\u5236\uff08\u5982\u679c\u5d4c\u5165\u6d3b\u6027\u4f4d\u70b9\u7684\u591a\u5b54\u57fa\u8d28\u9650\u5236\u4e86\u57fa\u4e8e\u70ed\u529b\u5b66\u53cd\u5e94\u4ea7\u7269\u7684\u6269\u6563\uff0c\u53ef\u4ee5\u5b9e\u73b0\u9664\u4e86\u7531\u53cd\u5e94\u5e73\u8861\u901f\u7387\u51b3\u5b9a\u7684\u4ea7\u7387\u4e4b\u5916\u7684\u4e2d\u95f4\u4ea7\u7269\u7684\u4ea7\u7387\uff09\u3002\u6b64\u5916\uff0c\u5728\u5177\u6709\u5c3a\u5bf8\u9009\u62e9\u6027\u7684\u591a\u5b54\u57fa\u8d28\u5185\u5d4c\u5165\u50ac\u5316\u529f\u80fd\u7684\u57fa\u56e2\uff0c\u53ef\u4ee5\u963b\u788d\u6709\u6bd2\u7269\u8d28\uff08\u4f8b\u5982\uff0c\u6bd4\u53cd\u5e94\u7269\u548c\u4ea7\u7269\u66f4\u5927\u7684\u7269\u8d28\uff09\u8fdb\u5165\u6d3b\u6027\u4e2d\u5fc3\u4ece\u800c\u9632\u6b62\u50ac\u5316\u5242\u4e2d\u6bd2\u3002<\/p>\n<p><span style=\"color: #0000ff;\"><strong>3.1.4 \u65e0\u5b9a\u5f62\u5305\u8986\u7a7a\u5fc3\u6750\u6599<\/strong><\/span><\/p>\n<p>\u7531\u65e0\u5b9a\u5f62\u58f3\u5305\u8986\u7684\u7a7a\u5fc3\u6750\u6599\uff0c\u901a\u5e38\u4e3a\u4ecb\u5b54\u6750\u6599\u3002\u867d\u7136\u5b54\u5f84\u8f83\u5927\u4f7f\u5f97\u4e25\u683c\u7684\u5206\u5b50\u7b5b\u6548\u5e94\u4ec5\u5bf9\u975e\u5e38\u5927\u7684\u5206\u5b50\u6709\u7528\uff0c\u4f46\u662f\u901a\u8fc7\u7269\u8d28\u5728\u58f3\u4e0a\u7684\u6269\u6563\u901f\u7387\u7684\u5c3a\u5bf8\u4f9d\u8d56\u6027\u5dee\u5f02\uff0c\u8db3\u4ee5\u8bf1\u5bfc\u50ac\u5316\u5242\u5b9e\u73b0\u5c3a\u5bf8\u9009\u62e9\u6027\u50ac\u5316\u3002<\/p>\n<p><strong>\u56fe21 Pd@SiO<sub>2<\/sub>\u7a7a\u5fc3\u7eb3\u7c73\u9897\u7c92\u7684\u5c3a\u5bf8\u9009\u62e9\u6027<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58124 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/21-2.jpeg\" alt=\"\" width=\"680\" height=\"384\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/21-2.jpeg 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/21-2-300x169.jpeg 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\uff08a\uff09\u5728\u5185\u90e8\u542b\u6709Pd\u7eb3\u7c73\u9897\u7c92\u7684Pd@SiO<sub>2<\/sub>\u7a7a\u5fc3\u7eb3\u7c73\u9897\u7c92\u7684\u793a\u610f\u56fe\u3002<\/p>\n<p>\uff08b\uff09\u5404\u79cd\u787c\u9178\u5982\u4f55\u5f71\u54cd\u58f3\u5c42\u5b54\u9699\u4e2d\u7684\u81ea\u7531\u7a0b\u3002<\/p>\n<p>\uff08c\uff09\u62e8\u6d6a\u9f13\u578bPd@SiO<sub>2<\/sub>\u7684TEM\u663e\u5fae\u7167\u7247\u3002<\/p>\n<p>\uff08d\uff093-\u8054\u82ef\u57fa\u787c\u9178\u4e0e\u82ef\u57fa\u787c\u9178\u53cd\u5e94\u7269\u7684\u6bd4\u4f8b\u5bf9\u50ac\u5316\u5242\u7684\u5c3a\u5bf8\u9009\u62e9\u6027\u884c\u4e3a\u7684\u5f71\u54cd\u3002<\/p>\n<p><span style=\"color: #0000ff;\"><strong>3.1.5 \u5206\u5b50\u7b5b\u6676\u4f53\u5305\u8986\u7684\u7a7a\u5fc3\u6750\u6599<\/strong><\/span><\/p>\n<p>\u6cb8\u77f3\u7b49\u4e00\u7c7b\u6750\u6599\uff0c\u4ee5\u53caMOF\u662f\u4e24\u7c7b\u7ed3\u6676\u6750\u6599\uff0c\u5176\u89c4\u5219\u7ed3\u6784\u5728\u5206\u5b50\u5c3a\u5bf8\u8303\u56f4\u5185\u5177\u6709\u7279\u522b\u5747\u5300\u7684\u5b54\uff08\u548c\u7a7a\u8154\uff09\u3002\u8fd9\u4e9b\u6027\u8d28\u4f7f\u8fd9\u4e9b\u6750\u6599\u5177\u6709\u7a81\u51fa\u7684\u5206\u5b50\u7b5b\u9009\u6027\u8d28\uff0c\u5728\u5206\u79bb\u548c\u50ac\u5316\u6280\u672f\u4e2d\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u5b83\u4eec\u975e\u51e1\u7684\u5b54\u5c3a\u5bf8\u5747\u5300\u6027\uff0c\u901a\u8fc7\u4e25\u683c\u7684\u5c3a\u5bf8\u6392\u963b\u673a\u5236\uff0c\u80fd\u591f\u7cbe\u786e\u5730\u533a\u5206\u5177\u6709\u975e\u5e38\u76f8\u4f3c\u5c3a\u5bf8\u7684\u5206\u5b50\u3002\u8fd1\u5e74\u6765\uff0c\u4f5c\u4e3a\u7a7a\u5fc3\u7ed3\u6784\u7684\u7ed3\u6676\u5206\u5b50\u7b5b\u7684\u5408\u6210\uff0c\u62d3\u5bbd\u4e86\u5b83\u4eec\u4f5c\u4e3a\u5c3a\u5bf8\u9009\u62e9\u6027\u7269\u8d28\u7528\u4e8e\u6355\u83b7\u6d3b\u6027\u50ac\u5316\u5242\u7684\u5e94\u7528\u8303\u56f4\u3002<\/p>\n<p><strong>\u56fe22 ZIF-8\u4f5c\u4e3a\u58f3\u5c42\u7684\u7a7a\u5fc3\u6750\u6599<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58125 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/22-2.jpeg\" alt=\"\" width=\"680\" height=\"681\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/22-2.jpeg 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/22-2-150x150.jpeg 150w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/22-2-300x300.jpeg 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\uff08a\uff09SEM\u663e\u5fae\u7167\u7247\uff0c<\/p>\n<p>\uff08b\uff0cc\uff09\u5d4c\u5165\u5355\u4e00Pd\u7eb3\u7c73\u9897\u7c92\u7684\u4e2d\u7a7a\u591a\u6676ZIF-8\u58f3\u7684TEM\u663e\u5fae\u7167\u7247\u3002<\/p>\n<p>\uff08d\uff09\u5375\u9ec4-\u58f3\u86cb\u7eb3\u7c73\u7ed3\u6784\u7684\u5206\u5b50\u7b5b\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n<p style=\"text-align: left;\"><span style=\"color: #0000ff;\"><strong>3.1.6 \u50ac\u5316\u4e2d\u7684\u7a7a\u9699\u7ea6\u675f\u6548\u5e94<\/strong><\/span><\/p>\n<p>\u6709\u8bc1\u636e\u8868\u660e\uff0c\u7eb3\u7c73\u7ea7\u7a7a\u95f4\u5185\u7684\u7269\u8d28\u7684\u7a7a\u95f4\u9650\u5236\uff0c\u5bfc\u81f4\u5176\u70ed\u529b\u5b66\u6027\u8d28\u76f8\u5bf9\u4e8e\u5728\u975e\u9650\u5236\u72b6\u6001\u4e0b\u70ed\u529b\u5b66\u6027\u8d28\u7684\u6539\u53d8\u3002\u5728\u50ac\u5316\u4e2d\u5982\u679c\u53d1\u751f\u5316\u5b66\u53cd\u5e94\uff0c\u5219\u9650\u5236\u4e5f\u53ef\u80fd\u5f71\u54cd\u53cd\u5e94\u52a8\u529b\u5b66\uff0c\u7a7a\u95f4\u9650\u5236\u7684\u6548\u679c\u5bf9\u4e8e\u5c3a\u5bf8\u51e0\u7eb3\u7c73\uff08\u4f8b\u5982\uff0c\u4e2d\u5b54\u50ac\u5316\u5242\uff09\u5341\u5206\u663e\u8457\uff0c\u7279\u522b\u662f\u5fae\u7c73\u7ea7\u50ac\u5316\u5242\u4e2d\u7684\u4e9a\u7eb3\u7c73\u7a7a\u9699\u3002\u7a7a\u5fc3\u5fae\u7c73\/\u7eb3\u7c73\u6750\u6599\u4e2d\u7684\u7a7a\u9699\u7a7a\u95f4\u8f83\u5927\uff0c\u8fd9\u51cf\u5c0f\u4e86\u5728\u50ac\u5316\u5e94\u7528\u4e2d\u53ef\u80fd\u8d77\u4f5c\u7528\u7684\u90a3\u4e9b\u9650\u5236\u6548\u5e94\u7684\u8303\u56f4\u548c\u91cf\u7ea7\u3002\u7136\u800c\uff0c\u5185\u90e8\u7a7a\u9699\u7684\u591a\u5b54\u58f3\u4e9a\u5355\u5143\uff0c\u53ef\u4ee5\u5c40\u90e8\u6539\u53d8\u7cfb\u7edf\u7684\u6d41\u4f53\u529b\u5b66\uff08\u4f8b\u5982\uff0c\u589e\u52a0\u53cd\u5e94\u7269\uff0c\u4e2d\u95f4\u7269\u8d28\u6216\u4ea7\u7269\u5728\u7a7a\u8154\u5185\u7684\u5b58\u7559\u65f6\u95f4\uff09\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u6bdb\u7ec6\u4f5c\u7528\u6216\u5438\u9644\u73b0\u8c61\uff0c\u591a\u5b54\u58f3\u53ef\u80fd\u8bf1\u5bfc\u53cd\u5e94\u7269\u5206\u5b50\u5728\u5185\u90e8\u7a7a\u9699\u4e2d\u7684\u6c89\u79ef\u3002\u5f53\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\u4e5f\u4f4d\u4e8e\u7a7a\u8154\u4e2d\u65f6\uff0c\u8fd9\u79cd\u53cd\u5e94\u7269\u6d53\u5ea6\u53d8\u5316\u53ef\u80fd\u5bf9\u53cd\u5e94\u901f\u7387\u5177\u6709\u76f4\u63a5\u4fc3\u8fdb\u4f5c\u7528\u3002<\/p>\n<p><span style=\"color: #0000ff;\"><strong>3.1.7 \u7a7a\u95f4\u5206\u533a\u7684\u591a\u4e2a\u50ac\u5316\u529f\u80fd<\/strong><\/span><\/p>\n<p>Yang<sup>2<\/sup>\u7b49\u4eba\u91c7\u7528\u9009\u62e9\u6027\u6838\u5fc3\u8680\u523b\u9014\u5f84\uff0c\u5408\u6210\u4e86\u7531100nm\u80fa\u5b98\u80fd\u5316\u7684SiO<sub>2<\/sub>\u6838\u7ec4\u6210\u7684\u5375\u9ec4-\u58f3\u86cb\u7eb3\u7c73\u9897\u7c92\uff0c\u5305\u88f9\u5728\u5177\u6709\u63a5\u679d\u7684-SO<sub>3<\/sub>H\u9178\u6027\u90e8\u5206\u768420nm\u539a\u7684\u591a\u5b54SiO<sub>2<\/sub>\u58f3\u5185\uff08\u56fe22\uff09\u3002\u8fd9\u79cd\u7eb3\u7c73\u7ed3\u6784\u63d0\u4f9b\u4e86\u4e24\u79cd\u7c7b\u578b\u7684\u6d3b\u6027\u4f4d\u70b9\u5728\u7a7a\u95f4\u4e2d\u6709\u7ec4\u7ec7\u7684\u6574\u5408\u3002\u8fd9\u79cd\u53cc\u529f\u80fd\u50ac\u5316\u5242\u663e\u793a\u4e86\u7ea7\u8054\u50ac\u5316\u53cd\u5e94\u7684\u6d3b\u6027\uff0c\u5305\u62ec\u9996\u5148\u5728\u58f3\u7684\u4f4d\u70b9\u4e0a\u8fdb\u884c\u7f29\u919b\u5e95\u7269\u7684\u9178\u50ac\u5316\u6c34\u89e3\uff0c\u968f\u540e\u5728\u6838\u8868\u9762\u4e0a\u8fdb\u884c\u78b1\u50ac\u5316\u7684\u4ea8\u5229\u52a0\u6210\u53cd\u5e94\u3002<\/p>\n<p><strong>\u56fe23 NH<sub>2<\/sub>\u2013SiO<sub>2<\/sub>@SO<sub>3<\/sub>H-SiO<sub>2<\/sub>\u591a\u529f\u80fd\u50ac\u5316\u5242<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58126 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/23-2.jpeg\" alt=\"\" width=\"680\" height=\"789\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/23-2.jpeg 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/23-2-259x300.jpeg 259w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\uff08a\uff09\u5177\u6709\u95f4\u9694\u7684\u9178\u6027\u548c\u78b1\u6027\u4f4d\u70b9\u7684\u5375\u9ec4-\u58f3\u86cbNH<sub>2<\/sub>\u2013SiO<sub>2<\/sub>@SO<sub>3<\/sub>H-SiO<sub>2<\/sub>\u50ac\u5316\u5242\u4e2d\u7684\u8131\u7f29\u919b\u5316-\u4ea8\u5229\u7ea7\u8054\u53cd\u5e94\u7684\u793a\u610f\u56fe\u3002<\/p>\n<p>\uff08b\uff09NH<sub>2<\/sub>\u2013SiO<sub>2<\/sub>@SO<sub>3<\/sub>H-SiO<sub>2<\/sub>\u5375\u9ec4-\u58f3\u86cb\u7eb3\u7c73\u9897\u7c92\u7684TEM\u663e\u5fae\u7167\u7247\u3002<\/p>\n<p>\uff08c\uff09\uff08i\uff09\u7528NH<sub>2<\/sub>\u2013SiO<sub>2<\/sub>@SO<sub>3<\/sub>H-SiO<sub>2<\/sub>\u5375\u9ec4-\u58f3\u86cb\u53cc\u529f\u80fd\u50ac\u5316\u5242\u548c\uff08ii\uff09NH 2-\u4e59\u70f7\u4e8c\u7845\u6c27\u70f7-SO<sub>3<\/sub>H-SiO<sub>2<\/sub>\u5355\u5b98\u80fd\u50ac\u5316\u5242\u7684\u5171\u6df7\u7269\u83b7\u5f97\u7684\u53cd\u5e94\u66f2\u7ebf\u3002<\/p>\n<p><span style=\"color: #0000ff;\"><strong>3.1.8 \u523a\u6fc0\u54cd\u5e94\u50ac\u5316\u6750\u6599<\/strong><\/span><\/p>\n<p>\u523a\u6fc0\u54cd\u5e94\u6750\u6599\u88ab\u8ba4\u4e3a\u662f\u8bf8\u5982\u611f\u6d4b\u6216\u751f\u7269\u533b\u5b66\u7b49\u9886\u57df\u4e2d\u6709\u53d1\u5c55\u524d\u666f\u7684\u6750\u6599\u4e4b\u4e00\uff0c\u5b83\u4eec\u5177\u6709\u4f5c\u4e3a\u836f\u7269\u7684\u53d7\u63a7\u9012\u9001\u548c\u7ed9\u836f\u8f7d\u4f53\u7684\u6f5c\u529b\u3002\u5982\u901a\u8fc7\u572825\u81f350\u2103\u4e4b\u95f4\u7684\u6e29\u5ea6\u5faa\u73af\u65f6\uff0c\u5728Au@SiO<sub>2<\/sub>@PMAA\u7eb3\u7c73\u6447\u94c3\u7684\u6c34\u6027\u60ac\u6d6e\u6db2\u7684\u5149\u900f\u5c04\u7387\u4e2d\u89c2\u5bdf\u5230\u7684\u5faa\u73af\u53d8\u5316\u6240\u793a\uff08\u56fe23\uff09\u3002\u7528NaBH<sub>4<\/sub>\u8fd8\u539f\u5bf9\u785d\u57fa\u82ef\u915a\u4f5c\u4e3a\u8bd5\u9a8c\u53cd\u5e94\uff0c\u8bf4\u660e\u7a7a\u5fc3\u50ac\u5316\u5242\u7684\u70ed\u81f4\u53cd\u5e94\u7279\u6027\u3002<\/p>\n<p><strong>\u56fe24 Au@SiO<sub>2<\/sub>@PMAA\u7eb3\u7c73\u6447\u94c3\u50ac\u5316\u5242\u7684\u70ed\u81f4\u53cd\u5e94\u7279\u6027<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58127 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/24-2.jpeg\" alt=\"\" width=\"680\" height=\"1198\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/24-2.jpeg 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/24-2-170x300.jpeg 170w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/24-2-581x1024.jpeg 581w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\uff08a\uff09PNIPAM\/Au@\u5185\u6d88\u65cbSiO<sub>2<\/sub>\u7eb3\u7c73\u6447\u94c3\u7684\u5408\u6210\u65b9\u6cd5\u7684\u793a\u610f\u56fe\u3002<\/p>\n<p>\uff08b\uff0cc\uff09Au@\u4ecb\u5b54-SiO<sub>2<\/sub>\u590d\u5408\u6750\u6599\u5728\u4e0d\u540c\u653e\u5927\u500d\u6570\u4e0b\u7684TEM\u56fe\u50cf\u3002<\/p>\n<p>\uff08d\uff09PNIPAM\/Au @\u4ecb\u5b54-SiO<sub>2<\/sub>\u7eb3\u7c73\u9897\u7c92\uff080.5g L<sup>-1<\/sup>\uff09\u7684\u6c34\u6027\u60ac\u6d6e\u6db2\u5bf9\u65f6\u95f4\u7684\u6e29\u5ea6\u4f9d\u8d56\u6027\u5149\u900f\u5c04\u7387\u66f2\u7ebf\u3002\u5728\u521d\u59cb\u6e29\u5ea6\u4e3a25\u2103\u65f6\uff0c\u6d4b\u8bd5\u6e29\u5ea6\u4ee51 \u2103 min<sup>-1<\/sup>\u5347\u9ad8\u6216\u964d\u4f4e\u3002<\/p>\n<p><span style=\"color: #0000ff;\"><strong>3.2 \u7a7a\u5fc3\u7eb3\u7c73\u548c\u5fae\u7ed3\u6784\u4f5c\u4e3a\u751f\u7269\u50ac\u5316\u5242\u7684\u5e94\u7528<\/strong><\/span><\/p>\n<p><strong><span style=\"color: #0000ff;\">3.2.1 \u5305\u8986\u589e\u5f3a\u9176\u7a33\u5b9a\u6027<\/span><\/strong><\/p>\n<p><strong>\u56fe25\u4e8c\u6c27\u5316\u7845\u5305\u8986\u9176<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58128 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/25-2.jpeg\" alt=\"\" width=\"680\" height=\"1049\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/25-2.jpeg 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/25-2-194x300.jpeg 194w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/25-2-664x1024.jpeg 664w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\u7528\u4e8e\u5305\u8986\u9176\u7684\uff0c\u5177\u6709\u4e0d\u540c\u58f3\u539a\u5ea6\u548c\u5b54\u5f84\u7684\u4e8c\u6c27\u5316\u7845\u80f6\u56ca\u7684STEM\/SEM\u56fe\u3002<\/p>\n<p><span style=\"color: #0000ff;\"><strong>3.2.2 \u5bf9\u5e95\u7269\u5927\u5c0f\u5177\u6709\u9009\u62e9\u6027\u7684\u751f\u7269\u50ac\u5316\u5242<\/strong><\/span><\/p>\n<p>Huo<sup>3<\/sup>\u7b49\u4eba\u4f7f\u7528\u4fdd\u62a4\u5728\u4e2d\u7a7aZIF-8\u5fae\u80f6\u56ca\u5185\u90e8\u7684<em>candida Antarctica<\/em> B (CalB) lipase (<em>M<\/em><sub>w<\/sub>\u223c 33 kDa) (\u5357\u6781\u5047\u4e1d\u9175\u6bcdB\uff08CalB\uff09\u8102\u80aa\u9176\uff08<em>M<\/em><sub>w<\/sub>\u301c33kDa\uff09)\u8bc1\u660e\u4e86\u751f\u7269\u5e95\u7269\u5927\u5c0f\u7684\u9009\u62e9\u6027\u50ac\u5316\u3002<\/p>\n<p><span style=\"color: #0000ff;\"><strong>3.2.3 \u751f\u7269\u9176\u7684\u591a\u533a\u57df\u50ac\u5316<\/strong><\/span><\/p>\n<p><strong>\u56fe26 \u8461\u8404\u7cd6\u6c27\u5316\u9176\uff08GOD\uff09\u548c\u8102\u80aa\u9176B\uff08CALB\uff09\u9176\u7ec4\u6210\u7684\u53cc\u529f\u80fd\u751f\u7269\u50ac\u5316\u5242<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58129 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/26-2.jpeg\" alt=\"\" width=\"680\" height=\"1500\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/26-2.jpeg 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/26-2-136x300.jpeg 136w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/26-2-464x1024.jpeg 464w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\uff08a\uff09\u7a7a\u5fc3\u5fae\u7ea4\u7ef4\u8f7d\u4f53\u4e0a\u7a7a\u5fc3\u6838\u4e2d\u8054\u5408\u5916\u8868\u9762\u4e0a\u7684\u8461\u8404\u7cd6\u6c27\u5316\u9176\uff08GOD\uff09\u548c\u8102\u80aa\u9176B\uff08CALB\uff09\u9176\u7ec4\u6210\u7684\u53cc\u529f\u80fd\u751f\u7269\u50ac\u5316\u5242\uff0c\u5728\u6cb9-\u6c34\u754c\u9762\u5904\u7684\u7ea7\u8054\u53cd\u5e94\u7684\u793a\u610f\u56fe\u3002<\/p>\n<p>\uff08b\uff0cc\uff09\u5171\u805a\u7126\u6fc0\u5149\u626b\u63cf\u663e\u5fae\u955c\u56fe\u50cf\uff0c\u663e\u793a\u5728\u5185\u8154\u4e2d\u6216\u5fae\u7ea4\u7ef4\u8f7d\u4f53\u7684\u5916\u8868\u9762\u4e0a\u7684GOD CALB\u9176\u7684\u4f4d\u7f6e\u9009\u62e9\u6027\u7ec4\u88c5\u3002GOD\u548cCALB\u5206\u522b\u7528FITC\uff08\u7eff\u8272\uff09\u548c\u78fa\u9170\u7f57\u4e39\u660e\uff08\u7ea2\u8272\uff09\u6807\u8bb0\uff0c\u7136\u540e\u8fdb\u884c\u5b9a\u4f4d\u88c5\u914d\u3002<\/p>\n<p>\uff08d\uff09\u5728\u4e24\u76f8\u4e32\u8054\u53cd\u5e94\u4e2d\uff0c\u5c06\u4e24\u79cd\u9176\u63ba\u5165\u4e0d\u540c\u4f4d\u7f6e\u7684\u53cc\u9176\u7a7a\u5fc3\u751f\u7269\u50ac\u5316\u5242\u7684\u7a33\u5b9a\u6027\u3002\u6bcf\u4e2a\u5faa\u73af\u6301\u7eed12\u5c0f\u65f6\u3002<\/p>\n<p><strong><span style=\"color: #0000ff;\">3.3 \u7a7a\u5fc3\u7eb3\u7c73\/\u5fae\u7ed3\u6784\u4f5c\u4e3a\u7535-\u5149\u50ac\u5316\u5242\u7684\u5e94\u7528<\/span><\/strong><\/p>\n<p><strong>\u56fe27 \u7a7a\u5fc3\u6750\u6599\u4f5c\u4e3a\u7535-\u5149\u50ac\u5316\u5242\u7684\u7279\u5f81<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58130 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/27-2.jpeg\" alt=\"\" width=\"680\" height=\"340\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/27-2.jpeg 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/27-2-300x150.jpeg 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\u4e0e\u5176\u666e\u901a\u50ac\u5316\u5242\uff08\u5de6\uff09\u76f8\u6bd4\uff0c\u7a7a\u5fc3\u7ed3\u6784\uff08\u53f3\uff09\u7684\u7279\u5b9a\u6027\u8d28\uff1a\uff081\uff09\u7279\u5f81\u7535\u8377\u8f6c\u79fb\uff08\u6216\u8d28\u91cf\u6269\u6563\uff09\u957f\u5ea6\uff0c\uff082\uff09\u5149\u6355\u83b7\u6548\u5e94\uff0c\u4f53\u79ef\u81a8\u80c0\uff0c\u548c\uff084\uff09\u5305\u8986\u6d3b\u6027\u91d1\u5c5e\u7269\u8d28\u7684\u53ef\u80fd\u6027\u3002<\/p>\n<p><span style=\"color: #0000ff;\"><strong>3.3.1 \u7a7a\u5fc3\u7eb3\u7c73\/\u5fae\u7ed3\u6784\u4f5c\u4e3a\u7535\u50ac\u5316\u5242<\/strong><\/span><\/p>\n<p><strong>\u56fe28 \u6c34\u7535\u89e3\u7684\u6c27\u5316\u548c\u8fd8\u539f\u534a\u53cd\u5e94<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58131 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/28-2.jpeg\" alt=\"\" width=\"680\" height=\"891\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/28-2.jpeg 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/28-2-229x300.jpeg 229w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p><strong>\u56fe29 \u7a7a\u5fc3Co<sub>3<\/sub>O<sub>4<\/sub>\u7eb3\u7c73\u6750\u6599\u7684OER\u6027\u80fd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58132 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/29-2.jpeg\" alt=\"\" width=\"680\" height=\"169\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/29-2.jpeg 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/29-2-300x75.jpeg 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\uff08a\uff09\u4e2d\u7a7aCo<sub>3<\/sub>O<sub>4<\/sub>\u7eb3\u7c73\u9897\u7c92\u7684SEM\u7167\u7247<\/p>\n<p>\uff08b\uff09\u4e2d\u7a7aCo<sub>3<\/sub>O<sub>4<\/sub>\u7eb3\u7c73\u9897\u7c92\u7684TEM\u663e\u5fae\u7167\u7247\uff08h-Co-200\u2103\uff09<\/p>\n<p>\uff08c\uff09\u4e0d\u542b\u50ac\u5316\u5242\u76840.1M KOH\u6eb6\u6db2\uff08\u7a7a\u767dGCE\uff09\uff0ch-Co@T \u7a7a\u5fc3Co<sub>3<\/sub>O<sub>4<\/sub>\u7eb3\u7c73\u9897\u7c92\u548c\u5546\u4e1a\u7684\u5927\u5757Co<sub>3<\/sub>O<sub>4<\/sub>\uff08Com-Co\uff09\u4f5c\u4e3aOER\u7535\u50ac\u5316\u5242\uff0c\u5728\u4e0d\u540c\u6e29\u5ea6\u9000\u706b\uff08T\uff0c\u2103\uff09\u540e\u7684\u50ac\u5316\u6027\u80fd\u3002<\/p>\n<p>\u603b\u4e4b\uff0c\u4e2d\u7a7a\u6750\u6599\u4f5c\u4e3a\u7528\u4e8e\u5404\u79cd\u7535\u50ac\u5316\u53cd\u5e94\uff08\u4f8b\u5982\u6c34\u7535\u89e3\u548c\u71c3\u6599\u7535\u6c60\u6280\u672f\uff09\u4e2d\u7684\u521b\u65b0\u7684\u56fa\u4f53\u50ac\u5316\u5242\uff0c\u53d7\u5230\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u4e2d\u7a7a\u7ed3\u6784\u53ef\u4ee5\u5177\u6709\u4e24\u79cd\u4e0d\u540c\u7684\u529f\u80fd\u3002\u4e00\u65b9\u9762\uff0c\u4e2d\u7a7a\u91d1\u5c5e\uff08\u786b\u65cf\u5316\u7269\uff09\u7eb3\u7c73\u548c\u5fae\u7ed3\u6784\u53ef\u4ee5\u6784\u6210\u5148\u8fdb\u7684\u7535\u50ac\u5316\u6d3b\u6027\u76f8\uff0c\u8fd9\u4e3b\u8981\u5f52\u56e0\u4e8e\u4e0e\u4f53\u76f8\u7c7b\u4f3c\u7269\u76f8\u6bd4\u5b83\u4eec\u66f4\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u78b3\u57fa\u4e2d\u7a7a\u7eb3\u7c73\u7ed3\u6784\u4f5c\u4e3a\u8f7d\u4f53\u6750\u6599\uff0c\u5b83\u4eec\u63d0\u4f9b\u4e86\u7eb3\u7c73\u5305\u5c01\u6d3b\u6027\u91d1\u5c5e\u76f8\u7684\u624b\u6bb5\uff0c\u6539\u5584\u4e86\u5728\u5de5\u4f5c\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\uff0c\u8fd9\u589e\u52a0\u4e86\u7535\u6781\u5bff\u547d\u3002\u603b\u7684\u6765\u8bf4\uff0c\u867d\u7136\u5728\u5927\u591a\u6570\u60c5\u51b5\u4e0b\uff0c\u7a7a\u5fc3\u5fae\/\u7eb3\u7c73\u7ed3\u6784\u53ef\u4ee5\u4e3a\u7535\u5316\u5b66\u5e94\u7528\u63d0\u4f9b\u51e0\u4e2a\u4f18\u70b9:\u5b83\u4eec\u7684\u5c42\u6b21\u7ed3\u6784\uff0c\u5185\u90e8\u7a7a\u9699\uff0c\u591a\u5b54\u6027\u8d28\u53ef\u4ee5\u4ea7\u751f\u4f18\u8d8a\u7684\u4f20\u8d28\u548c\u7535\u89e3\u8d28\u8fc1\u79fb\u7387\u3002\u6b64\u5916\uff0c\u5b83\u4eec\u63d0\u4f9b\u9ad8\u8868\u9762\u79ef\uff0c\u8fd9\u53c8\u5bfc\u81f4\u9ad8\u6d53\u5ea6\u7684\u6d3b\u6027\u4f4d\u70b9\u3002\u7136\u800c\uff0c\u540e\u4e00\u6548\u5e94\u4e5f\u53ef\u4ee5\u7528\u7531\u5c0f\u9897\u7c92\u7ec4\u6210\u7684\u6750\u6599\u5b9e\u73b0\uff0c\u56e0\u6b64\u4e0d\u662f\u7a7a\u5fc3\u58f3\u5f62\u6001\u6240\u56fa\u6709\u7684\u3002<\/p>\n<p><span style=\"color: #0000ff;\"><strong>3.3.2 \u7a7a\u5fc3\u7eb3\u7c73\u548c\u5fae\u7ed3\u6784\u4f5c\u4e3a\u5149\u50ac\u5316\u5242<\/strong><\/span><\/p>\n<p><strong>\u56fe30 \u7a7a\u5fc3CuO-TiO<sub>2\u2013<em>x<\/em><\/sub>N<em><sub>x<\/sub><\/em>\u7eb3\u7c73\u7ed3\u6784\u7684\u5149\u50ac\u5316\u5b9e\u9a8c<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58133 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/30-2.jpeg\" alt=\"\" width=\"680\" height=\"531\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/30-2.jpeg 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/30-2-300x234.jpeg 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-58133 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/30-2.jpeg\" alt=\"\" width=\"680\" height=\"531\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/30-2.jpeg 680w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/30-2-300x234.jpeg 300w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>\uff08a\uff09\u7a7a\u5fc3CuO-TiO<sub>2\u2013<em>x<\/em><\/sub>N<em><sub>x<\/sub><\/em>\u7eb3\u7c73\u7ed3\u6784\u7684\u5408\u6210\u65b9\u6848\uff0c<\/p>\n<p>\uff08b\uff09\u7a7a\u5fc3CuO-TiO<sub>2\u2013<em>x<\/em><\/sub>N<em><sub>x<\/sub><\/em>\u7eb3\u7c73\u7acb\u65b9\u4f53\u7684FE-SEM\u663e\u5fae\u7167\u7247\uff0c<\/p>\n<p>\uff08c\uff09\u4e2d\u7a7aCuO-TiO<sub>2\u2013<em>x<\/em><\/sub>N<em><sub>x<\/sub><\/em>\u7eb3\u7c73\u7acb\u65b9\u4f53\u5728\u6a21\u62df\u592a\u9633\u8f90\u5c04\u4e0b\u5bf9\u7532\u70f7\u8f6c\u6362\u901f\u7387\uff08ppmg<sup>-1<\/sup> h<sup>-1<\/sup>\uff09\u3002<\/p>\n<p><span style=\"color: #0000ff;\">\u3010<strong>\u7ed3\u8bed\u548c\u5c55\u671b<\/strong>\u3011<\/span><\/p>\n<p>\u672c\u7efc\u8ff0\u603b\u7ed3\u4e86\u8fd1\u4e8c\u5341\u5e74\u6765\uff0c\u5728\u50ac\u5316\u9886\u57df\u4e2d\u8bbe\u8ba1\u7684\u7a7a\u5fc3\u6750\u6599\u7684\u5408\u6210\u65b9\u6848\u548c\u5e94\u7528\uff0c\u7b80\u8ff0\u4e86\u8fc4\u4eca\u4e3a\u6b62\u53d6\u5f97\u7684\u8fdb\u5c55\u7684\u6700\u65b0\u548c\u91cd\u8981\u7684\u5e94\u7528\uff0c\u57fa\u672c\u4e0a\u6db5\u76d6\u4e86\u50ac\u5316\u7684\u6240\u6709\u5206\u652f\u3002\u4f5c\u8005\u7ad9\u5728\u5b8f\u89c2\u89d2\u5ea6\u51c6\u786e\u628a\u63e1\u7a7a\u5fc3\u6750\u6599\u7684\u7cbe\u5999\u4e4b\u5904\uff0c\u53c8\u5f15\u5165\u5b9e\u4f8b\uff0c\u6df1\u5ea6\u89e3\u6790\u5404\u4e2a\u65b9\u9762\u7684\u5177\u4f53\u53d1\u5c55\uff0c\u5e94\u8be5\u8bf4\u662f\u6b64\u7c7b\u7efc\u8ff0\u7684\u7cbe\u54c1\u3002\u57fa\u4e8e\u6b64\uff0c\u5c06\u7ed9\u7a7a\u5fc3\u6750\u6599\u7684\u5236\u5907\u548c\u5e94\u7528\u8d77\u5230\u7814\u7a76\u65b9\u5411\u4e0a\u7684\u6307\u5f15\uff0c\u540c\u65f6\u628a\u5229\u7528\u7a7a\u5fc3\u5fae\u7c73\/\u7eb3\u7c73\u6750\u6599\u7684\u4f18\u70b9\uff0c\u5c06\u5176\u5e94\u7528\u5230\u5de5\u4e1a\u751f\u4ea7\u63a8\u8fdb\u4e00\u6b65\u3002<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1a<a href=\"http:\/\/pubs.acs.org\/doi\/full\/10.1021\/acs.chemrev.6b00374\" target=\"_blank\">Hollow Nano- and Microstructures as Catalysts<\/a>\uff08<em>Chemical Reviews.\u00a0<\/em>2016,.10.1021\/acs.chemrev.6b00374\uff09<\/p>\n<p><span style=\"color: #0000ff;\">\u3010<strong>\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb<\/strong>\u3011<\/span><\/p>\n<p><a href=\"https:\/\/www.kofo.mpg.de\/en\/research\/heterogeneous-catalysis\" target=\"_blank\">Ferdi Sch\u00fcth<\/a>\uff1aFerdi Sch\u00fcth\u6559\u6388\u662f\u50ac\u5316\u53ca\u6750\u6599\u7814\u7a76\u9886\u57df\u77e5\u540d\u7684\u79d1\u5b66\u5bb6\uff0c\u5176\u7814\u7a76\u9886\u57df\u6d89\u53ca\u50ac\u5316\u6750\u6599\u5408\u6210\u3001\u50ac\u5316\u7814\u7a76\u4e2d\u7684\u9ad8\u901a\u91cf\u5b9e\u9a8c\u3001\u5206\u5b50\u7b5b\u3001\u6709\u5e8f\u4ecb\u5b54\u6750\u6599\u3001\u8d2e\u6c22\u6750\u6599\u7b49\u3002\u4ed6\u73b0\u4e3a\u201cAdvances in Catalysis\u201c\uff0c\u201cChemistry of Materials\u201d\uff0c\u201cChemical Communications\u201d \u548c\u201cAdvanced Materials\u201d\u7b49\u8457\u540d\u671f\u520a\u7684\u7f16\u8f91\u6216\u7f16\u59d4\uff0c\u540c\u65f6\u8fd8\u62c5\u4efb\u5fb7\u56fd\u6d2a\u5821\u5956\u52b1\u8bc4\u9009\u59d4\u5458\u4f1a\u4e3b\u5e2d\u7b49\u804c\u52a1\u3002<\/p>\n<p><span style=\"color: #0000ff;\">\u3010\u53c2\u8003\u6587\u732e\u3011<\/span><\/p>\n<p>1.Peto G, T\u00fcys\u00fcz H, Duyckaerts N, Knossalla J, Wang G-H, Sch\u00fcth F. Hollow Nano- and Microstructures as Catalysts. Chemical Reviews 2016, 116(22): 14056-14119.<br \/>\n2.Yang Y, Liu X, Li X, Zhao J, Bai S, Liu J, et al. A Yolk\u2013Shell Nanoreactor with a Basic Core and an Acidic Shell for Cascade Reactions. Angewandte Chemie International Edition 2012, 51(36): 9164-9168.<br \/>\n3.Huo J, Aguilera-Sigalat J, El-Hankari S, Bradshaw D. Magnetic MOF microreactors for recyclable size-selective biocatalysis. Chemical Science 2015, 6(3): 1938-1943.<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u5b66\u672f\u5c0f\u7ec4pamperhey\u6574\u7406\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165<a href=\"http:\/\/www.cailiaoniu.com\/25127.html\" target=\"_blank\">\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p><strong>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong><a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\">\u6d4b\u8bd5\u8c37<\/a><strong>\uff01<\/strong><\/p>\n<p>\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065952\u201d\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002\u6b22\u8fce\u5173\u6ce8\u5fae\u4fe1\u516c\u4f17\u53f7\uff0c\u5fae\u4fe1\u641c\u7d22\u201c\u65b0\u80fd\u6e90\u524d\u7ebf\u201d\u6216\u626b\u7801\u5173\u6ce8\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-57796 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/QQ\u56fe\u724720161105113102-4.png\" alt=\"\" width=\"327\" height=\"326\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/QQ\u56fe\u724720161105113102-4.png 327w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/QQ\u56fe\u724720161105113102-4-150x150.png 150w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/12\/QQ\u56fe\u724720161105113102-4-300x300.png 300w\" sizes=\"(max-width: 327px) 100vw, 327px\" \/><\/p>\n","protected":false},"excerpt":{"rendered":"<p>&nbsp; \u5317\u4eac\u65f6\u95f410\u67087\u53f7\uff0c\u7f8e\u56fd\u5316\u5b66\u4f1a\u65d7\u4e0b\u9876\u5c16\u7684\u7efc\u8ff0\u7c7b\u671f\u520aChemical Reviews\uff08IF= 44.509\uff0cJCR2014\uff09\u53d1\u8868\u4e86Ferdi Sch&#8230;<\/p>\n","protected":false},"author":1311,"featured_media":59042,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[533],"tags":[],"class_list":["post-57455","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zongshu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/57455"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/1311"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=57455"}],"version-history":[{"count":11,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/57455\/revisions"}],"predecessor-version":[{"id":59281,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/57455\/revisions\/59281"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/59042"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=57455"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=57455"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=57455"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}