{"id":64387,"date":"2017-02-11T14:00:07","date_gmt":"2017-02-11T06:00:07","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=64387"},"modified":"2017-03-18T21:56:35","modified_gmt":"2017-03-18T13:56:35","slug":"%e5%8c%97%e4%ba%ac%e7%90%86%e5%b7%a5%e5%a4%a7%e5%ad%a6adv-mater-%ef%bc%9a%e4%b8%80%e7%a7%8d%e7%94%a8%e4%ba%8e%e5%a4%a7%e9%87%8f%e7%94%9f%e4%ba%a7mof%e6%bb%a4%e8%86%9c%e7%9a%84%e5%af%b9%e8%be%8a","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=64387","title":{"rendered":"\u5317\u4eac\u7406\u5de5\u5927\u5b66Adv. Mater. \uff1a\u4e00\u79cd\u7528\u4e8e\u5927\u91cf\u751f\u4ea7MOF\u6ee4\u819c\u7684\u5bf9\u8f8a\u70ed\u538b\u5370\u65b9\u6cd5"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u5728\u8fc7\u53bb\u7684\u51e0\u5341\u5e74\u4e2d\uff0c\u7531\u4e8e\u4eba\u7c7b\u6d3b\u52a8\u9020\u6210\u7684\u7a7a\u6c14\u6c61\u67d3\u5df2\u6210\u4e3a\u4e00\u4e2a\u4e16\u754c\u6027\u7684\u95ee\u9898\u3002\u7279\u522b\u662f\u5728\u4e2d\u56fd\u7b49\u53d1\u5c55\u4e2d\u56fd\u5bb6\uff0c\u9897\u7c92\u7269\uff08Particulate matters\uff0cPMs\uff09\u4f5c\u4e3a\u4e00\u79cd\u4e3b\u8981\u7684\u6c61\u67d3\u6e90\uff0c\u5df2\u7ecf\u9020\u6210\u4e25\u5cfb\u7684\u73af\u5883\u95ee\u9898\u3002\u4f20\u7edf\u888b\u5f0f\u9664\u5c18\u5668\uff08\u4e5f\u53eb\u7ec7\u7269\u8fc7\u6ee4\u5668\uff09\u5df2\u7ecf\u4e0d\u80fd\u6ee4\u6389\u6781\u7ec6PM\uff08\u5fae\u7c73\u548c\u4e9a\u5fae\u7c73\u7ea7\u522b\uff09\uff0c\u800c\u4e14\u7531\u4e8e\u888b\u5f0f\u9664\u5c18\u5668\u7684\u6750\u6599\u6210\u5206\u9650\u5236\uff0c\u5b83\u7684\u5de5\u4f5c\u73af\u5883\u6709\u4e25\u683c\u7684\u6e29\u5ea6\u63a7\u5236\u3002\u56e0\u6b64\uff0c\u67d4\u97e7\u7684\u3001\u6613\u83b7\u53d6\u7684\u3001\u80fd\u5728\u5927\u5de5\u4f5c\u6e29\u5ea6\u8303\u56f4\u4e2d\u4fdd\u6301\u9ad8\u5f3a\u5ea6\u548c\u6548\u7387\u800c\u4e14\u5bb9\u6613\u88c5\u914d\u5728\u73b0\u5b58\u7684\u7ba1\u9053\u7cfb\u7edf\u3001\u8f66\u8f86\u6216\u98de\u673a\u53d1\u52a8\u673a\u7ba1\u548c\u53cd\u5e94\u5bb9\u5668\u7684\u8fc7\u6ee4\u5668\u662f\u957f\u671f\u7684\u8ffd\u6c42\u76ee\u6807\uff0c\u4f46\u662f\u5927\u90e8\u5206\u5e76\u6ca1\u6709\u5f97\u5230\u6ee1\u8db3\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\u5317\u4eac\u7406\u5de5\u5927\u5b66\u738b\u535a\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\u5728Adv. Mater.\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u9898\u4e3a\u201cRoll-to-Roll Production of Metal-Organic Framework Coatings for Particulate Matter Removal\u201d\u6587\u7ae0\u3002\u6587\u7ae0\u4e3b\u8981\u4ecb\u7ecd\u4e86\u4e00\u79cd\u7528\u4e8e\u6279\u91cf\u5236\u5907\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u914d\u5408\u7269\uff08MOF\uff09\u57fa\u6ee4\u819c\u7684\u5bf9\u8f8a\u70ed\u538b\u5370\u65b9\u6cd5\u3002\u7814\u7a76\u4eba\u5458\u5c1d\u8bd5\u4e86\u4e94\u79cd\u67d4\u6027\u886c\u5e95\uff08\u5851\u6599\u7f51\u3001\u73bb\u7483\u5e03\u3001\u91d1\u5c5e\u7f51\u3001\u65e0\u7eba\u5e03\u548c\u4e09\u805a\u6c30\u80fa\u6d77\u7ef5\uff09\u548c\u4e09\u79cd\u4e0d\u540c\u7684MOF\u4f53\u7cfb\uff08\u6cb8\u77f3\u54aa\u5511\u76d0\u6846\u67b6-8\u5373ZIF-8\u3001ZIF-67\u548cNi-ZIF-8\uff09\u3002\u8fd8\u5c06\u8fd9\u79cd\u65b9\u6cd5\u6269\u5c55\u5230\u5c42\u53e0\u5f62\u5f0f\u3002\u5236\u9020\u51fa\u7684MOF\u6ee4\u819c\u8868\u73b0\u51fa\u4f18\u79c0\u7684PM\u8fc7\u6ee4\u6027\u80fd\uff0c\u5e76\u80fd\u572880-300\u2103\u7684\u6e29\u5ea6\u8303\u56f4\u5185\u62e5\u6709\u9ad8\u5f3a\u5ea6\u3002PM\u53bb\u9664\u6548\u7387\u5728\u957f\u65f6\u95f4\u7684\u6d4b\u8bd5\u8fc7\u7a0b\uff0830\u5929\uff09\u4fdd\u6301\u572890%\u4ee5\u4e0a\u3002\u6d4b\u8bd5\u8fc7\u540e\uff0cZIF-8@\u5851\u6599\u7f51\u5bb9\u6613\u6e05\u6d17\uff0c\u5e76\u4e14\u53ef\u4ee5\u91cd\u590d\u4f7f\u7528\u4e09\u6b21\u540e\uff0c\u4e0d\u51fa\u73b0\u660e\u663e\u7684\u6548\u7387\u635f\u5931\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1. <\/strong>\u5236\u9020\u53bb\u9664<\/strong>PM<\/strong>\u7684<\/strong>MOF<\/strong>\u57fa\u6ee4\u819c\u7684\u5bf9\u8f8a\u5de5\u827a\u793a\u610f\u56fe<\/strong><\/p>\n

<\/p>\n

\u4ee5ZIF-8@\u5851\u6599\u7f51\u4e3a\u4f8b\u3002300\u03bcm\u539a10cm\u5bbd\u7684\u5851\u6599\u7f51\uff0c\u9996\u5148\u6d82\u8986ZIF-8\u524d\u9a71\uff08Zn(OAc)2<\/sub>\u00b72H2<\/sub>O\uff0c2-\u7532\u57fa\u54aa\u5511\u548c\u805a\u4e59\u4e8c\u9187\uff08\u4f5c\u4e3a\u5f15\u53d1\u5242\uff09\uff09\uff0c\u968f\u540e\u572880\u2103\u300115rpm\u7684\u6761\u4ef6\u4e0b\u5728\u4e24\u4e2a\u8f67\u8f8a\u4e4b\u95f4\u8fdb\u884c\u8f67\u5236\u3002\u524d\u540e\u8f67\u5236\u51e0\u6b21\u540e\uff0c\u5851\u6599\u7684\u7ebf\u4e0a\u4ea7\u751fZIF-8\u7eb3\u7c73\u6676\u4f53\u3002<\/p>\n

\u56fe<\/strong>2.<\/strong>\u5851\u6599\u7f51\u4e0a\u9010\u5c42\u6d82\u8986<\/strong>MOF<\/strong>\u793a\u610f\u56fe\u53ca\u76f8\u5173\u8868\u5f81<\/strong><\/p>\n

<\/p>\n

\uff08a\uff09\u53e0\u5c42\u5236\u9020MOF\u6d82\u5c42\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\uff08b\uff09ZIF-8\u7684\u9644\u7740\u548c\u76f8\u5e94\u7684\u5269\u4f59\u900f\u5149\u7387\uff08\u4e0e\u88f8\u5851\u6599\u7f51\u76f8\u6bd4\uff09\u3002\u88f8\u5851\u6599\u7f51\uff085 mm \u00d7 1.5 mm\uff09\u7684\u900f\u5149\u7387\u4e3a68.8%\u3002\u5269\u4f59\u900f\u5149\u7387\u662fZIF-8@\u5851\u6599\u7f51\u4e0e\u88f8\u5851\u6599\u7f51\u7684\u900f\u5149\u7387\u4e4b\u6bd4\u3002\u8bef\u5dee\u68d2\u8868\u793a\u4e09\u7ec4\u5e73\u884c\u8bd5\u9a8c\u4e4b\u95f4\u7684\u6807\u51c6\u504f\u5dee\u3002<\/p>\n

\uff08 c-i\uff097\u4e2a\u9053\u6b21\u4e2dZIF-8@\u5851\u6599\u7f51\u7684\u626b\u63cf\u7535\u955c\u56fe\u3002\u4e2d\u95f4\u548c\u6700\u4e0b\u9762\u4e00\u884c\u7684\u56fe\u662f\u5bf9\u5e94\u4e8e\u4e0a\u4e00\u884c\u65b9\u5f62\u6807\u5fd7\u5185\u7684\u653e\u5927\u56fe\uff1b\u6807\u5c3a\uff1a\u6700\u4e0a\u884c\uff1a500 \u03bcm\uff0c\u4e2d\u95f4\u884c\uff1a100\u03bcm\uff0c\u6700\u4e0b\u884c\uff1a10\u03bcm\u3002<\/p>\n

\u56fe<\/strong>3. <\/strong>\u4e09\u9053\u6b21<\/strong>ZIF-8@<\/strong>\u5bc6\u80fa\u6ce1\u6cab\u7684\u67d4\u6027\u5c55\u793a\u548c\u53bb\u9664<\/strong> PM <\/strong>\u6027\u80fd\u6d4b\u8bd5<\/strong><\/p>\n

<\/p>\n

\uff08a\uff09\u5f2f\u66f2\u7684\u4e09\u9053\u6b21ZIF-8@\u5bc6\u80fa\u6ce1\u6cab\u3002<\/p>\n

\uff08b\uff09\u626d\u66f2\u7684\u4e09\u9053\u6b21ZIF-8@\u5bc6\u80fa\u6ce1\u6cab\u3002<\/p>\n

\uff08c\uff09\u7528\u4e8ePM\u53bb\u9664\u8bd5\u9a8c\u7684\u6a21\u62df\u7ba1\u9053\u6761\u4ef6\uff0c\u70df\u96fe\u7531\u711a\u9999\u5236\u9020\u3002<\/p>\n

\uff08d\uff09 \u4e09\u9053\u6b21ZIF-8@\u5bc6\u80fa\u6ce1\u6cab\u7684\u957f\u671fPM\u53bb\u9664\u80fd\u529b\u3002\u84dd\u8272\u5bf9\u5e94PM2.5\uff0c\u7eff\u8272\u5bf9\u5e94PM10\u3002\u8bef\u5dee\u68d2\u8868\u793a\u4e09\u7ec4\u5e73\u884c\u8bd5\u9a8c\u4e4b\u95f4\u7684\u6807\u51c6\u504f\u5dee\u3002<\/p>\n

\u56fe<\/strong>4. <\/strong>\u4e03\u9053\u6b21<\/strong>ZIF-8@<\/strong>\u5851\u6599\u7f51\u7684\u8868\u5f81\u548c\u53bb\u9664<\/strong>PM<\/strong>\u6027\u80fd\u6d4b\u8bd5<\/strong><\/p>\n

<\/p>\n

\uff08a\uff09\u7802\u7eb8\u4e0a\u7684\u4e03\u9053\u6b21ZIF-8@\u5851\u6599\u7f51\u3002<\/p>\n

\uff08b\uff09PM\u53bb\u9664\u6d4b\u8bd5\u4e2d\u7684\u4e03\u9053\u6b21ZIF-8@\u5851\u6599\u7f51\u3002<\/p>\n

\uff08c\uff09PM\u53bb\u9664\u6d4b\u8bd5\u540e\u7684\u626b\u63cf\u7535\u955c\u56fe\uff1bPM\u9897\u7c92\u5728\u7b2c\u4e8c\u884c\u7684\u56fe\u4e2d\u88ab\u5708\u51fa\u3002<\/p>\n

\uff08d\uff09\u7528\u6c34\u6e05\u6d01\u540e\u7684\u4e03\u9053\u6b21ZIF-8@\u5851\u6599\u7f51\u626b\u63cf\u7535\u955c\u56fe\u3002<\/p>\n

\uff08e\uff09\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\uff08f\uff09\u5927\u578b\u4e03\u9053\u6b21ZIF-8@\u5851\u6599\u7f51\u56fe\u3002<\/p>\n

\uff08g\uff097\u670810\u53f7\u81f38\u670810\u53f7\u4e00\u4e2a\u6708\u4e4b\u95f4\u7684\u957f\u671fPM\u53bb\u9664\u6027\u80fd\uff08\u5355\u65e5\u6700\u59275\u503c>100 \u03bcg\/ m3<\/sup>\uff09\u3002\u8bef\u5dee\u68d2\u8868\u793a\u4e09\u7ec4\u5e73\u884c\u8bd5\u9a8c\u4e4b\u95f4\u7684\u6807\u51c6\u504f\u5dee\u3002<\/p>\n

\u3010\u7ed3\u8bba\u3011<\/strong><\/p>\n

\u4e00\u79cd\u901a\u7528\u4e14\u53ef\u6269\u5c55\u7684\u7528\u4e8e\u5927\u91cf\u751f\u4ea7MOF\u6ee4\u819c\u7684\u5bf9\u8f8a\u70ed\u538b\u5370\u65b9\u6cd5\u5df2\u7ecf\u51fa\u73b0\u3002\u8fd9\u79cd\u65b9\u6cd5\u5df2\u7ecf\u5e94\u7528\u4e8e\u4e0d\u540c\u7684MOF\u4f53\u7cfb\u4e2d\uff08\u5982ZIF-8\u3001ZIF-67\u548cNi-ZIF-8\uff09\u548c\u4e0d\u540c\u7684\u57fa\u6750\uff08\u5982\u5851\u6599\u7f51\u3001\u73bb\u7483\u5e03\u3001\u91d1\u5c5e\u7f51\u548c\u65e0\u7eba\u5e03\uff09\uff0c\u5e76\u4e14\u5df2\u7ecf\u5ef6\u4f38\u5230\u5c42\u53e0\u5f62\u5f0f\u3002\u8fd9\u79cd\u65b9\u6cd5\u83b7\u5f97\u7684MOF\u6ee4\u819c\u663e\u793a\u51fa\u4f18\u79c0\u7684\u5f3a\u5ea6\uff0c\u8f83\u5927\u7684\u5de5\u4f5c\u6e29\u5ea6\u8303\u56f4\uff0880-300\u2103\uff09\uff0c\u5728\u5ba4\u6e29\u548c200\u2103\u4e0b\u90fd\u6709\u4f18\u79c0\u7684PM\u53bb\u9664\u6548\u7387\u3002\u8fd9\u4e9b\u591a\u7528\u7684MOF\u6ee4\u819c\u53ef\u4ee5\u5e94\u7528\u4e8e\u5404\u79cd\u5b9e\u9645\u5e94\u7528\uff0c\u4f8b\u5982\u6ee4\u6c34\u7ba1\u3001\u888b\u5f0f\u9664\u5c18\u5668\u4ee5\u53ca\u7528\u4e8e\u8f66\u8f86\u6216\u98de\u673a\u53d1\u52a8\u673a\u7cfb\u7edf\u7684\u5165\u53e3\u5c4f\u969c\u8fc7\u6ee4\u3002\u5728\u6d4b\u8bd5\u6761\u4ef6\u4e0b\u548c\u5ba4\u5185\u73af\u5883\uff0cMOF\u6ee4\u819c\u7684\u900f\u5149\u7387\u672a\u53d1\u751f\u6539\u53d8\u5e76\u4e14\u6709\u5f88\u597d\u7684\u6e17\u900f\u6027\u3001\u9ad8PM\u53bb\u9664\u6548\u7387\u3001\u8f83\u597d\u7684\u957f\u671f\u7559\u5b58\u7387\u4ee5\u53ca\u6613\u4e8e\u91cd\u65b0\u4f7f\u7528\u3002\u8fd9\u4e9b\u9ad8\u6027\u80fd\u7684MOF\u6ee4\u819c\u4ee5\u53ca\u8fde\u7eed\u5377\u8f74\u5927\u91cf\u751f\u4ea7\u6280\u672f\uff0c\u65e0\u8bba\u5728\u5ba4\u5185\u8fd8\u662f\u5de5\u4e1a\u73af\u5883\u90fd\u6709\u5f88\u597d\u7684\u524d\u666f\u3002<\/p>\n

\u3010\u6587\u732e\u4fe1\u606f\u3011<\/strong><\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Roll-to-Roll Production of Metal-Organic Framework Coatings for Particulate Matter Removal<\/a>\u00a0\uff08Adv. Mater. 2017, DOI: 10.1002\/adma.201606221\uff09<\/p>\n

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