{"id":67183,"date":"2017-02-28T06:30:45","date_gmt":"2017-02-27T22:30:45","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=67183"},"modified":"2017-03-04T10:34:52","modified_gmt":"2017-03-04T02:34:52","slug":"%e9%ba%a6%e7%ab%8b%e5%bc%baam%e6%9c%80%e6%96%b0%e7%bb%bc%e8%bf%b0%ef%bc%9a%e5%a4%8d%e6%9d%82%e4%b8%ad%e7%a9%ba%e7%bb%93%e6%9e%84%e7%9a%84%e5%8f%af%e6%8e%a7%e5%90%88%e6%88%90%e5%8f%8a%e5%85%b6%e5%9c%a8","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=67183","title":{"rendered":"\u9ea6\u7acb\u5f3aAM\u6700\u65b0\u7efc\u8ff0\uff1a\u590d\u6742\u4e2d\u7a7a\u7ed3\u6784\u7684\u53ef\u63a7\u5408\u6210\u53ca\u5176\u5728\u80fd\u6e90\u5b58\u50a8\u4e0e\u8f6c\u6362\u4e2d\u7684\u5e94\u7528"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u590d\u6742\u7684\u4e2d\u7a7a\u7ed3\u6784\uff08intricate hollow structures\uff09\u7531\u4e8e\u5176\u72ec\u7279\u7684\u7ed3\u6784\u7279\u5f81\uff0c\u8ff7\u4eba\u7684\u7406\u5316\u6027\u8d28\u548c\u5e7f\u6cdb\u7684\u5e94\u7528\u9886\u57df\u6781\u5927\u5730\u5438\u5f15\u4e86\u79d1\u7814\u5de5\u4f5c\u8005\u7684\u5174\u8da3\u3002\u6700\u8fd1\uff0c<strong>\u6b66\u6c49\u7406\u5de5\u5927\u5b66\u7684\u9ea6\u7acb\u5f3a\u6559\u6388\u548c\u5468\u4eae\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\uff09<\/strong>\u7b49\u4eba\u5728\u8457\u540d\u6750\u6599\u7c7b\u671f\u520a<strong>Advanced Materials<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a<strong>\u201cIntricate Hollow Structures: Controlled Synthesis and Applications in Energy Storage and Conversion\u201d<\/strong>\u7684\u7efc\u8ff0\u6587\u7ae0\u3002\u8fd9\u7bc7\u7efc\u8ff0\u4e3b\u8981\u4ece\u590d\u6742\u7684\u4e2d\u7a7a\u7ed3\u6784\u53ef\u63a7\u5408\u6210\u65b9\u6cd5\u53ca\u5176\u5728\u80fd\u6e90\u5b58\u50a8\u4e0e\u8f6c\u6362\u4e2d\u7684\u5e94\u7528\u8fd9\u4e24\u65b9\u9762\u56de\u987e\u4e86\u590d\u6742\u4e2d\u7a7a\u7eb3\u7c73\u7ed3\u6784\u7684\u7814\u7a76\u8fdb\u5c55\uff0c\u4e3b\u8981\u5bf9\u5176\u5408\u6210\u65b9\u6cd5\u8bba\u505a\u4e86\u4e00\u4e2a\u8be6\u7ec6\u7684\u5206\u7c7b\u548c\u8bb2\u89e3\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-67193 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/\u6355\u83b72.jpg\" width=\"600\" height=\"477\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/\u6355\u83b72.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/\u6355\u83b72-300x239.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u7efc\u8ff0\u5bfc\u89c8\u56fe<\/strong><\/p>\n<p><span style=\"color: #000000;\"><strong>1 \u6982\u51b5<\/strong><\/span><\/p>\n<p style=\"text-align: left;\">\u4f5c\u4e3a\u529f\u80fd\u6750\u6599\u5bb6\u65cf\u4e2d\u975e\u5e38\u91cd\u8981\u7684\u7ec4\u6210\u90e8\u5206\uff0c\u62e5\u6709\u529f\u80fd\u5316\u5916\u58f3\u548c\u5185\u90e8\u7a7a\u8154\u7ed3\u6784\u7684\u4e2d\u7a7a\u7eb3\u7c73\u7ed3\u6784\u5177\u5907\u5bc6\u5ea6\u4f4e\u3001\u9ad8\u5b54\u9699\u5bb9\u79ef\u7b49\u4f18\u52bf\uff0c\u53ef\u7f29\u77ed\u8d28\u91cf\u4f20\u8f93\u548c\u7535\u8377\u4f20\u8f93\u8fc7\u7a0b\u8def\u5f84\u3002\u8fd9\u4e9b\u72ec\u7279\u7684\u7ed3\u6784\u7279\u70b9\u4f7f\u7a7a\u5fc3\u7ed3\u6784\u5728\u7eb3\u7c73\u53cd\u5e94\u5668\u3001\u6c14\u4f53\u4f20\u611f\u5668\u3001\u836f\u7269\u4f20\u8f93\u3001\u5149\u50ac\u5316\u3001\u4e8c\u6b21\u7535\u6c60\u3001\u8d85\u7ea7\u7535\u5bb9\u5668\u3001\u71c3\u6599\u7535\u6c60\u7b49\u8bf8\u591a\u9886\u57df\u5f97\u5230\u5e7f\u6cdb\u5e94\u7528\u3002\u57fa\u4e8e\u5b83\u4eec\u7684\u7ed3\u6784\u590d\u6742\u6027\uff0c\u4e2d\u7a7a\u7ed3\u6784\u53ef\u4ee5\u5206\u4e3a\u62e5\u6709\u5355\u58f3\u578b\u7a7a\u5fc3\u7ed3\u6784\u7684\u7b80\u5355\u578b\u548c\u591a\u8fb9\u754c\u591a\u7a7a\u8154\u7684\u590d\u6742\u578b\u4e24\u79cd\u3002\u8fd1\u6765\uff0c\u6765\u81ea\u5e94\u7528\u9700\u6c42\uff0c\u76f8\u6bd4\u4e8e\u7b80\u5355\u4e2d\u7a7a\u7ed3\u6784\uff0c\u590d\u6742\u4e2d\u7a7a\u7ed3\u6784\u80fd\u63d0\u4f9b\u66f4\u591a\u673a\u4f1a\u6765\u8c03\u6574\u5176\u7269\u7406\u5316\u5b66\u6027\u8d28\uff0c\u6027\u80fd\u8868\u73b0\u66f4\u4e3a\u4f18\u5f02\u3002<\/p>\n<p style=\"text-align: left;\"><span style=\"color: #000000;\"><strong>2 \u591a\u58f3\u5c42\u4e2d\u7a7a\u7ed3\u6784\u5408\u6210\u65b9\u6cd5<\/strong><\/span><\/p>\n<p style=\"text-align: left;\">\u591a\u58f3\u5c42\u7a7a\u5fc3\u7ed3\u6784\u7c7b\u4f3c\u4e8e\u4fc4\u7f57\u65af\u5957\u5a03\uff0c\u4ed6\u4eec\u6709\u591a\u4e2a\u4e0d\u540c\u5c3a\u5bf8\u540c\u5fc3\u6216\u504f\u5fc3\u58f3\u3002\u56e0\u4e3a\u5b83\u4eec\u590d\u6742\u7684\u4e2d\u7a7a\u7ed3\u6784\uff0c\u5176\u5408\u6210\u548c\u64cd\u4f5c\u6bd4\u5355\u58f3\u5c42\u7ed3\u6784\u66f4\u5177\u6311\u6218\u6027\u3002\u4e00\u822c\u8d8a\u590d\u6742\u7684\u76ee\u6807\u7ed3\u6784\uff0c\u5176\u5408\u6210\u8fc7\u7a0b\u4e5f\u8d8a\u590d\u6742\u3002\u56e0\u6b64\uff0c\u4e00\u4e9b\u4e0d\u540c\u4e8e\u5e38\u89c4\u65b9\u6cd5\u7684\u7279\u6b8a\u5408\u6210\u7b56\u7565\u5e38\u88ab\u7528\u6765\u5408\u6210\u591a\u58f3\u5c42\u7a7a\u5fc3\u7ed3\u6784\uff0c\u6b64\u8282\u5c06\u5bf9\u591a\u58f3\u5c42\u7a7a\u5fc3\u7ed3\u6784\u7684\u5408\u6210\u65b9\u6cd5\u505a\u4e00\u4e2a\u7efc\u5408\u8bc4\u8ff0\u3002<\/p>\n<p><span style=\"color: #000000;\"><strong>2.1 <\/strong><strong>\u786c\u6a21\u677f\u6cd5<\/strong><\/span><\/p>\n<p>\u786c\u6a21\u677f\u662f\u5408\u6210\u7a7a\u5fc3\u7ed3\u6784\u6700\u5e7f\u6cdb\u4f7f\u7528\u7684\u65b9\u6cd5\uff0c\u7b80\u5355\u3001\u6709\u6548\u3001\u6982\u5ff5\u7b80\u5355\u3002\u6700\u7ecf\u5e38\u4f7f\u7528\u7684\u786c\u6a21\u677f\u5305\u62ec\u5355\u5206\u6563\u805a\u5408\u7269\uff0c\u4e8c\u6c27\u5316\u7845\uff0c\u78b3\uff0c\u91d1\u5c5e\u548c\u91d1\u5c5e\u6c27\u5316\u7269\u80f6\u4f53\u3002\u9009\u62e9\u8fd9\u4e9b\u6a21\u677f\u662f\u56e0\u4e3a\u5b83\u4eec\u7684\u5355\u5206\u6563\u6027\u597d\uff0c\u5c3a\u5bf8\u548c\u5f62\u72b6\u6613\u4e8e\u63a7\u5236\uff0c\u53ef\u5927\u91cf\u51c6\u5907\u53ca\u6613\u4e8e\u5408\u6210\u7b49\u7279\u70b9\u3002\u4ece\u6982\u5ff5\u4e0a\u8bb2\uff0c\u7528\u786c\u6a21\u677f\u6cd5\u5236\u4f5c\u590d\u6742\u7a7a\u5fc3\u7ed3\u6784\u662f\u53ef\u884c\u7684\uff0c\u5c06\u76ee\u6807\u58f3\u548c\u727a\u7272\u5939\u5c42\u4f9d\u6b21\u6d82\u5728\u6a21\u677f\u4e0a\uff0c\u7136\u540e\u9664\u53bb\u76f8\u5e94\u7684\u727a\u7272\u6a21\u677f\u548c\u5939\u5c42\uff0c\u5373\u5f97\u5230\u590d\u6742\u7a7a\u5fc3\u7ed3\u6784\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-67205\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/1-43.jpg\" alt=\"\" width=\"600\" height=\"585\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/1-43.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/1-43-300x293.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe1 \u786c\u6a21\u677f\u6cd5\u5236\u5907\u7684TiO<sub>2<\/sub>\u591a\u58f3\u5c42\u7a7a\u5fc3\u7403\u4f53<\/strong><\/p>\n<p style=\"text-align: left;\"><strong>2.2 \u8f6f\u6a21\u677f\u6cd5<\/strong><\/p>\n<p style=\"text-align: left;\">\u4e24\u6027\u5206\u5b50\u5982\u8868\u9762\u6d3b\u6027\u5242\u548c\u5d4c\u6bb5\u5171\u805a\u7269\u5728\u6eb6\u6db2\u4e2d\u6d53\u5ea6\u8d85\u8fc7\u4e34\u754c\u80f6\u675f\u6d53\u5ea6\u65f6\u80fd\u591f\u81ea\u6211\u7ec4\u88c5\u6210\u4e0d\u540c\u7684\u80f6\u675f\u6216\u56ca\u6ce1\u7ed3\u6784\uff0c\u8fd9\u6837\u7684\u80f6\u675f\u548c\u56ca\u6ce1\u53ef\u4ee5\u4f5c\u4e3a\u8f6f\u6a21\u677f\u6307\u5bfc\u5f62\u6210\u7a7a\u5fc3\u7ed3\u6784\u3002\u7136\u800c\u80f6\u675f\u548c\u56ca\u6ce1\u5bf9\u6e29\u5ea6\u3001pH\u503c\u3001\u4e24\u6027\u5206\u5b50\u7684\u6d53\u5ea6\u7b49\u5408\u6210\u53c2\u6570\u662f\u975e\u5e38\u654f\u611f\u7684\u3002\u539f\u5219\u4e0a\u8fd9\u79cd\u654f\u611f\u6027\u53ef\u4ee5\u5fae\u5999\u7684\u63a7\u5236\u80f6\u675f\/\u56ca\u6ce1\u6a21\u677f\u7684\u7ed3\u6784\u548c\u5f62\u6001\uff0c\u5b9e\u9645\u4e0a\u76ee\u6807\u524d\u9a71\u4f53\u8fdb\u5165\u5408\u6210\u4f53\u7cfb\u53ef\u80fd\u4f1a\u5f71\u54cd\u80f6\u675f\/\u56ca\u6ce1\u7684\u5f62\u6210\u3002\u5c3d\u7ba1\u5b83\u5177\u6709\u6311\u6218\u6027\uff0c\u4f46\u662f\u5404\u79cd\u7a7a\u5fc3\u7ed3\u6784\u7684\u65e0\u673a\u6750\u6599\u5df2\u7531\u80f6\u675f\/\u6a21\u677f\u5236\u5907\u800c\u6210\u3002\u5728\u8fd9\u4e9b\u6750\u6599\u4e2d\uff0c\u4e8c\u6c27\u5316\u7845\u548c\u4ee5\u4e8c\u6c27\u5316\u7845\u4e3a\u57fa\u7840\u7684\u6df7\u5408\u6750\u6599\u65e0\u7591\u662f\u6700\u6210\u529f\u7684\u4f8b\u5b50\uff0c\u8fd9\u662f\u56e0\u4e3a\u4e8c\u6c27\u5316\u7845\u524d\u9a71\u4f53\u5728\u6c34\u6eb6\u6db2\u4e2d\u80fd\u5f88\u597d\u5730\u63a7\u5236\u6c34\u89e3\u548c\u7f29\u5408\u884c\u4e3a\u3002\u9664\u4e86\u4e00\u822c\u7845\u548c\u78b3\u4e3a\u57fa\u7840\u7684\u6750\u6599\uff0c\u80f6\u675f\/\u56ca\u6ce1\u6a21\u677f\u4e5f\u53ef\u4ee5\u5e94\u7528\u5230\u5176\u4ed6\u7ec4\u5206\u7a7a\u5fc3\u7ed3\u6784\u7684\u5408\u6210\u3002\u5982\u4ee5CTAB\uff08\u5341\u516d\u70f7\u57fa\u4e09\u7532\u57fa\u6eb4\u5316\u94f5\uff09\u4e3a\u6a21\u677f\u5408\u6210\u4e86Cu<sub>2<\/sub>O\u7a7a\u5fc3\u7403\u4f53\uff0c\u901a\u8fc7\u8c03\u8282CTAB\u7684\u6d53\u5ea6\u6765\u5f97\u5230\u4e0d\u540c\u58f3\u5c42\u7684Cu<sub>2<\/sub>O\u7a7a\u5fc3\u7403\u4f53\u3002<\/p>\n<p style=\"text-align: left;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-67206\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/2-28.jpg\" alt=\"\" width=\"600\" height=\"598\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/2-28.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/2-28-150x150.jpg 150w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/2-28-300x300.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe2 \u4e0d\u540c\u58f3\u5c42\u7684Cu<sub>2<\/sub>O\u7a7a\u5fc3\u7403<\/strong><\/p>\n<p><strong>2.3 \u201c<\/strong><strong>\u8f6f<\/strong><strong>@<\/strong><strong>\u786c<\/strong><strong>\u201d<\/strong><strong>\u7c92\u5b50\u9009\u62e9\u6027\u523b\u8680<\/strong><\/p>\n<p>\u5728\u7a7a\u5fc3\u7ed3\u6784\u7684\u5236\u5907\u8fc7\u7a0b\u4e2d\uff0c\u8680\u523b\u5df2\u88ab\u5e7f\u6cdb\u7528\u4e8e\u53bb\u9664\u6a21\u677f\u548c\u727a\u7272\u5c42\u3002\u6a21\u677f\u548c\u727a\u7272\u5c42\u7ec4\u6210\u901a\u5e38\u4e0e\u6240\u9700\u6750\u6599\u4e0d\u540c\u3002\u6700\u8fd1\u4e00\u4e9b\u7a7a\u5fc3\u7ed3\u6784\u7684\u5408\u6210\u53ef\u901a\u8fc7\u9009\u62e9\u6027\u8680\u523b\u5355\u7ec4\u5206\u6750\u6599\u7684\u65b9\u6cd5\u5236\u5907\uff0c\u4f8b\u5982SiO<sub>2<\/sub>\uff0c\u666e\u9c81\u58eb\u84dd\uff08PB\uff09\u3001ZnSn(OH)<sub>6<\/sub>\u548cCoSn(OH)<sub>6<\/sub>\u7b49\u3002\u8fd9\u4e9b\u6bcd\u4f53\u6750\u6599\u7684\u5171\u540c\u7279\u5f81\u662f\u4ed6\u4eec\u90fd\u6709\u4e00\u4e9b\u201c\u8f6f\u533a\u57df\u201d\u548c\u201c\u786c\u533a\u57df\u201d\uff0c\u800c\u540e\u53ef\u4ee5\u9009\u62e9\u6027\u5730\u79fb\u9664\u201c\u8f6f\u533a\u57df\u201d\uff0c\u4fdd\u5b58\u201c\u786c\u533a\u57df\u201d\u8fdb\u800c\u53ef\u5f62\u6210\u4e2d\u7a7a\u7ed3\u6784\u3002\u5982\u5728\u5341\u516d\u70f7\u57fa\u4e09\u7532\u57fa\u6eb4\u5316\u94f5 (CTAB) \u4e3a\u8f6f\u6a21\u677f\uff0c1,2-\u53cc\uff08\u4e09\u4e59\u6c27\u57fa\u7845\u57fa\uff09\u4e59\u70f7 (BTSE) \u548c\u6b63\u7845\u9178\u4e59\u916f (TEOS) \u4e3a\u524d\u9a71\u4f53\u5408\u6210\u4ecb\u5b54\u4e59\u70f7\u6865\u8054\u6709\u673a\u7845\u5fae\u7403\u65f6\uff0cBTSE\u548cTEOS\u7684\u91cd\u590d\u6dfb\u52a0\u751f\u6210\u4e86\u591a\u5c42\u6709\u673a\u7845\/ CTAB\u590d\u5408\u5fae\u7403\uff0c\u65e9\u671f\u53cd\u5e94\u9636\u6bb5\u5728\u6709\u673a\u5c42\u7684\u5185\u90e8\u533a\u57df\u5f62\u6210\u4f4e\u7f29\u5408\u5ea6\u7684\u201c\u8f6f\u533a\u57df\u201d\uff0c\u540e\u671f\u5219\u5728\u6bcf\u4e2a\u5c42\u7684\u5916\u90e8\u533a\u57df\u5f62\u6210\u4e86\u9ad8\u7f29\u5408\u7a0b\u5ea6\u7684\u201c\u786c\u533a\u57df\u201d\uff0c\u6709\u673a\u7845\/ CTAB\u590d\u5408\u5fae\u7403\u5728\u7ecf\u53d7\u70ed\u5904\u7406\u65f6\uff0c\u201c\u8f6f\u533a\u57df\u201d\u53d7\u6c34\u7684\u5f71\u54cd\u800c\u6eb6\u89e3\uff0c\u201c\u786c\u533a\u57df\u201d\u5219\u4e0d\u53d7\u5f71\u54cd\u800c\u5f62\u6210\u591a\u91cd\u7a7a\u5fc3\u58f3\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-67207\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/3-30.jpg\" alt=\"\" width=\"600\" height=\"763\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/3-30.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/3-30-236x300.jpg 236w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe3 \u4e09\u58f3\u5c42\u7684\u5468\u671f\u6027\u4ecb\u5b54\u6709\u673a\u7845\u7a7a\u5fc3\u7403\u5408\u6210\u793a\u610f\u56fe<\/strong><\/p>\n<p><strong>2.4 <\/strong><strong>\u5965\u65af\u74e6\u5c14\u5fb7\u719f\u5316\u6cd5<\/strong><\/p>\n<p>\u5965\u65af\u7279\u74e6\u5c14\u5fb7\u719f\u5316 (Ostwald Ripening) \u662f\u4e00\u4e2a\u4f17\u6240\u5468\u77e5\u7684\u6676\u4f53\u751f\u957f\u73b0\u8c61\uff0c\u5b83\u6307\u7684\u662f\u201c\u5c0f\u6676\u4f53\u6216\u6eb6\u80f6\u7c92\u5b50\u6eb6\u89e3\u540e\u5176\u6eb6\u89e3\u7269\u5728\u8f83\u5927\u6676\u4f53\u6216\u6eb6\u80f6\u7c92\u5b50\u7684\u8868\u9762\u518d\u6c89\u79ef\u201d\u7684\u73b0\u8c61\u3002\u5728\u6210\u6838\u548c\u6676\u4f53\u751f\u957f\u7684\u65e9\u671f\u5f62\u6210\u7684\u5185\u90e8\u5fae\u6676\u76f8\u5bf9\u8f83\u5c0f\uff0c\u5177\u6709\u8f83\u9ad8\u7684\u8868\u9762\u80fd\uff0c\u800c\u90a3\u4e9b\u6210\u5f62\u4e8e\u540e\u671f\u5728\u5916\u8868\u9762\u7684\u6676\u4f53\u6bd4\u8f83\u5927\u3002\u56e0\u6b64\uff0c\u7403\u4f53\u7684\u4e2d\u5fc3\u533a\u57df\u5f00\u59cb\u901a\u8fc7\u6eb6\u89e3\u758f\u6563\uff0c\u7ed3\u679c\u4ea7\u751f\u7a7a\u5fc3\u8154\uff0c\u4ece\u800c\u5f62\u6210\u7a7a\u5fc3\u7ed3\u6784\u3002\u5229\u7528\u8fd9\u79cd\u73b0\u8c61\uff0c\u4eba\u4eec\u5229\u7528\u79cd\u5b50\u4ecb\u5bfc\u751f\u957f\u91c7\u7528\u8fde\u7eed\u7684\u5965\u65af\u7279\u74e6\u5c14\u5fb7\u719f\u5316\u6cd5\u5408\u6210\u4e86Cu<sub>2<\/sub>O(@Cu<sub>2<\/sub>O)<sub>n<\/sub>\u591a\u91cd\u58f3\u7ed3\u6784\u3002\u7b2c\u4e00\u6b21\u719f\u5316\u65f6\u65b0\u751f\u6210\u7684Cu<sub>2<\/sub>O\u6c89\u79ef\u5728Cu<sub>2<\/sub>O\u6676\u4f53\u79cd\u5b50\u7684\u8868\u9762\uff0c\u5f62\u6210\u4e00\u5c42\u8f83\u539a\u7684\u5916\u58f3\uff0c\u7b2c\u4e8c\u6b21\u719f\u5316\u65f6\u8d34\u8fd1\u7b2c\u4e00\u58f3\u4f53\u65b0\u5f62\u6210\u7684\u5c3a\u5bf8\u76f8\u5bf9\u8f83\u5c0f\u7684\u6676\u7c92\u758f\u6563\u6eb6\u89e3\uff0c\u800c\u4f4d\u4e8e\u6700\u5916\u5c42\u7684\u8f83\u5927\u7684\u6676\u7c92\u4fdd\u7559\u4e0b\u6765\uff0c\u7136\u540e\u91cd\u590d\u6c89\u79ef\u719f\u5316\uff0c\u5373\u53ef\u83b7\u5f97\u591a\u91cd\u58f3\u7a7a\u5fc3\u7ed3\u6784\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-67208\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/4-26.jpg\" alt=\"\" width=\"600\" height=\"445\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/4-26.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/4-26-300x223.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe4 \u6838-\u58f3\u548c\u5375\u9ec4-\u58f3\u7ed3\u6784\u7684Cu<sub>2<\/sub>O(@Cu<sub>2<\/sub>O)<sub>n<\/sub>\u5408\u6210\u793a\u610f\u56fe<\/strong><\/p>\n<p><strong>2.5 <\/strong><strong>\u79bb\u5b50\u4ea4\u6362\u6cd5<\/strong><\/p>\n<p>\u79bb\u5b50\u4ea4\u6362\u662f\u5728\u6eb6\u6db2\u4e2d\u7684\u79bb\u5b50\uff08\u9633\u79bb\u5b50\u6216\u9634\u79bb\u5b50\uff09\u548c\u4e0d\u6eb6\u56fa\u4f53\u4e4b\u95f4\u4ea4\u6362\u7684\u8fc7\u7a0b\u3002\u5b83\u88ab\u5e7f\u6cdb\u5e94\u7528\u5728\u63d0\u7eaf\uff0c\u5206\u79bb\u548c\u6c34\u51c0\u5316\u9886\u57df\u3002\u6700\u8fd1\uff0c\u79bb\u5b50\u4ea4\u6362\u5df2\u7ecf\u6210\u4e3a\u88ab\u7528\u4f5c\u5236\u5907\u7a7a\u5fc3\u7ed3\u6784\u7684\u5f3a\u6709\u6548\u7684\u65b9\u6cd5\u3002\u5982\u6709\u7814\u7a76\u8005\u4ee5Cu<sub>2<\/sub>O-PVP\u6df7\u5408\u80f6\u4f53\u4e3a\u524d\u9a71\u4f53\u91c7\u7528\u8fde\u7eed\u7684\u79bb\u5b50\u4ea4\u6362\u6cd5\u5236\u5907\u51fa\u4e86Cu<sub>2<\/sub>S\u591a\u58f3\u7a7a\u5fc3\u7403\u3002\u6765\u81ea\u786b\u8132\u7684S<sup>2-<\/sup>\u79bb\u5b50\u4e0eCu<sub>2<\/sub>O\u53cd\u5e94\u751f\u6210\u4e00\u4e2aCu<sub>2<\/sub>S\u8868\u9762\u5c42\uff0c\u4e4b\u540e\u751f\u6210\u7684O<sup>2\u2212<\/sup>\u5feb\u901f\u5411\u5916\u90e8\u6269\u6563\uff0c\u800cS<sup>2-<\/sup>\u6162\u6162\u5411\u5176\u5185\u90e8\u6269\u6563\uff0c\u4ece\u800c\u5728Cu<sub>2<\/sub>O\u6838\u4e0eCu<sub>2<\/sub>S\u58f3\u4e4b\u95f4\u5f62\u6210\u4e00\u5c42\u95f4\u9699\uff0c\u7136\u540eS<sup>2-<\/sup>\u5728\u5185\u90e8\u7684Cu<sub>2<\/sub>O\u6838\u4e0a\u7ee7\u7eed\u8fdb\u884c\u79bb\u5b50\u4ea4\u6362\uff0c\u5982\u6b64\u53cd\u590d\uff0c\u6700\u7ec8\u5f62\u6210\u4e86\u591a\u58f3\u7a7a\u5fc3\u7ed3\u6784\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-67209\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/5-15.jpg\" alt=\"\" width=\"600\" height=\"522\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/5-15.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/5-15-300x261.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe5 Cu<sub>2<\/sub>S\u591a\u58f3\u7a7a\u5fc3\u7403\u7684\u5f62\u6210\u793a\u610f\u56fe<\/strong><\/p>\n<p><strong>2.6 <\/strong><strong>\u70ed\u8bf1\u5bfc\u7269\u8d28\u8fc1\u79fb\u6cd5<\/strong><\/p>\n<p>\u7269\u8d28\u8fc1\u79fb\u5728\u5965\u65af\u7279\u74e6\u5c14\u5fb7\u719f\u5316 (Ostwald Ripening)\u3001\u79bb\u5b50\u4ea4\u6362\u3001\u67ef\u80af\u8fbe\u5c14\u6548\u5e94(Kirkendall effect)\u8fd9\u4e09\u5927\u6784\u5efa\u7a7a\u5fc3\u7ed3\u6784\u7814\u7a76\u673a\u5236\u4e2d\u8d77\u7740\u91cd\u8981\u7684\u4f5c\u7528\u3002\u6700\u8fd1\uff0c\u4eba\u4eec\u5df2\u7ecf\u53d1\u73b0\uff0c\u4e00\u7cfb\u5217\u6750\u6599\u7684\u70ed\u5206\u89e3\u53ef\u80fd\u5bfc\u81f4\u5f62\u6210\u7b80\u5355\u6216\u590d\u6742\u7684\u4e2d\u7a7a\u7ed3\u6784\uff0c\u8fd9\u5728\u70ed\u8bf1\u5bfc\u7269\u8d28\u7684\u8fc1\u79fb\u4e2d\u8d77\u7740\u4e0d\u53ef\u6216\u7f3a\u7684\u4f5c\u7528\u3002\u8fd9\u4e9b\u6750\u6599\u5305\u62ec\u91d1\u5c5e\u78b3\u9178\u76d0\u3001\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u3001\u7518\u6cb9\u9178\u76d0\u7b49\uff0c\u4ed6\u4eec\u662f\u7531\u91d1\u5c5e\u90e8\u5206\u548c\u53ef\u5206\u89e3\u7684\u6709\u673a\/\u65e0\u673a\u90e8\u5206\u7ec4\u6210\u3002\u5728\u5927\u591a\u6570\u7684\u60c5\u51b5\u4e0b\uff0c\u91d1\u5c5e\u90e8\u5206\u4ee5\u539f\u5b50\u6216\u7eb3\u7c73\u5c3a\u5ea6\u5747\u5300\u5206\u6563\u5728\u53ef\u5206\u89e3\u7684\u6709\u673a\/\u65e0\u673a\u57fa\u8d28\u4e2d\uff0c\u901a\u8fc7\u5728\u7a7a\u6c14\u4e2d\u8fdb\u884c\u70ed\u5206\u89e3\uff0c\u6709\u673a\u90e8\u5206\u88ab\u70e7\u6389\u91ca\u653e\u6c14\u4f53\uff0c\u800c\u5176\u4ed6\u7269\u8d28\u540c\u65f6\u5728\u70ed\u5206\u89e3\u8fc7\u7a0b\u4e2d\u53d1\u751f\u8fc1\u79fb\uff0c\u4ece\u800c\u5f62\u6210\u591a\u6837\u7684\u4e2d\u7a7a\u7ed3\u6784\u3002\u5982\u91d1\u5c5e\u78b3\u9178\u76d0Co<sub>0.33<\/sub>Mn<sub>0.67<\/sub>CO<sub>3<\/sub>\u5fae\u7acb\u65b9\u4f53\u5728\u52a0\u70ed\u8fc7\u7a0b\u4e2d\u5206\u89e3\u6210\u91d1\u5c5e\u6c27\u5316\u7269CoMn<sub>2<\/sub>O<sub>4<\/sub>\u548cCO<sub>2<\/sub>\u6216CO\u6c14\u4f53\uff0c\u4f46\u7531\u4e8e\u975e\u5e73\u8861\u70ed\u5904\u7406\u5f15\u8d77\u7684\u975e\u5747\u5300\u6536\u7f29\uff0c\u5f62\u6210\u4e86\u53cc\u58f3CoMn2O4\u7a7a\u5fc3\u5fae\u7acb\u65b9\u4f53\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-67210\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/6-13.jpg\" alt=\"\" width=\"600\" height=\"342\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/6-13.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/6-13-300x171.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe6\u00a0\u53cc\u58f3CoMn<sub>2<\/sub>O<sub>4<\/sub>\u7a7a\u5fc3\u5fae\u7acb\u65b9\u4f53\u7684\u5236\u5907\u793a\u610f\u56fe<\/strong><\/p>\n<p><strong>3<\/strong> <strong>\u8d85\u8d8a\u591a\u58f3\u5c42\u66f4\u4e3a\u590d\u6742\u7684\u4e2d\u7a7a\u7ed3\u6784\u5408\u6210\u65b9\u6cd5<\/strong><\/p>\n<p>\u9664\u4e86\u4e0a\u8ff0\u5177\u6709\u540c\u5fc3\u6216\u504f\u5fc3\u591a\u58f3\u5c42\u7684\u7a7a\u5fc3\u7ed3\u6784\uff0c\u8fd8\u6709\u5404\u7c7b\u66f4\u4e3a\u590d\u6742\u7684\u7ec4\u5408\u5f0f\u4e2d\u7a7a\u7ed3\u6784\uff0c\u5982\u6ce1\u5185\u6ce1\u3001\u7ba1\u5185\u7ba1\u3001\u7ba1\u5185\u4e1d\u7ed3\u6784\u3001\u77f3\u69b4\u72b6\u7ed3\u6784\u7b49\u3002\u8fd9\u4e9b\u590d\u6742\u7684\u4e2d\u7a7a\u7ed3\u6784\u66f4\u6709\u5229\u4e8e\u80fd\u6e90\u7684\u50a8\u5b58\u548c\u8f6c\u6362\u5e94\u7528\u3002\u5982\u5927\u725b\u5d14\u5c79\u53d1\u5c55\u4e86\u4e00\u79cd\u81ea\u4e0b\u800c\u4e0a\u7684\u5fae\u4e73\u6db2\u7684\u65b9\u6cd5\u5408\u6210\u4e86\u7845\u57fa\u77f3\u69b4\u72b6\u5fae\u7403\uff0c\u6bcf\u4e2a\u5fae\u7c73\u77f3\u69b4\u7403\u7531\u4e9a\u5fae\u7c73\u7ea7\u5927\u5c0f\u7684Si@\u7a7a\u6d1e@C\u521d\u7ea7\u7eb3\u7c73\u7c92\u5b50\u7ec4\u6210\uff0c\u800c\u6bcf\u4e2a\u521d\u7ea7\u72ec\u7acb\u7684\u7845\u7eb3\u7c73\u9897\u7c92\u5f88\u597d\u7684\u5c01\u88c5\u5728\u78b3\u58f3\u91cc\u3002\u8fd8\u6709\u7684\u7814\u7a76\u8005\u5229\u7528\u201c\u5b9a\u5411\u7ec4\u88c5\u201d\u548c\u201c\u81ea\u6211\u6eda\u52a8\u201d\u7684\u673a\u5236\u6784\u5efa\u534a\u7a7a\u5fc3\u53cc\u5411\u8fde\u7eed\u7684\u77f3\u58a8\u70ef\u5377\u8f74\u7ed3\u6784\u3002\u603b\u7684\u6765\u8bf4\u8d8a\u590d\u6742\u591a\u6837\u7684\u7a7a\u5fc3\u7ed3\u6784\uff0c\u7528\u5230\u7684\u65b9\u6cd5\u4e5f\u662f\u591a\u79cd\u591a\u6837\uff0c\u4e0d\u4e00\u800c\u8db3\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-67211\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/7-9.jpg\" alt=\"\" width=\"600\" height=\"299\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/7-9.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/7-9-300x150.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe7 \u5404\u7c7b\u66f4\u4e3a\u590d\u6742\u7684\u7ec4\u5408\u5f0f\u4e2d\u7a7a\u7eb3\u7c73\u7ed3\u6784<\/strong><\/p>\n<p><strong>4<\/strong> <strong>\u80fd\u6e90\u5b58\u50a8\u548c\u8f6c\u6362\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n<p><strong>4.1 <\/strong><strong>\u9502\u79bb\u5b50\u7535\u6c60<\/strong><\/p>\n<p>\u9502\u79bb\u5b50\u7535\u6c60\u7531\u4e8e\u80fd\u91cf\u5bc6\u5ea6\u9ad8\uff0c\u8d28\u91cf\u8f7b\uff0c\u65e0\u8bb0\u5fc6\u6548\u5e94\uff0c\u81ea\u653e\u7535\u5c0f\uff0c\u73af\u5883\u53cb\u597d\u7b49\u4f18\u70b9\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u4fbf\u643a\u5f0f\u7535\u5b50\u4ea7\u54c1\uff0c\u4e5f\u88ab\u8ba4\u53ef\u4f5c\u4e3a\u5373\u5c06\u5230\u6765\u7684\u7535\u52a8\u6c7d\u8f66\u548c\u6df7\u5408\u52a8\u529b\u7535\u52a8\u6c7d\u8f66\u9009\u62e9\u7684\u52a8\u529b\u6e90\uff0c\u8fd9\u4e9b\u65b0\u9700\u6c42\u4e5f\u5bf9\u9502\u79bb\u5b50\u7535\u6c60\u7684\u80fd\u91cf\u5bc6\u5ea6\u63d0\u51fa\u4e86\u65b0\u7684\u8981\u6c42\u3002\u7a7a\u5fc3\u7ed3\u6784\u5219\u4e3a\u63d0\u9ad8\u9502\u79bb\u5b50\u7535\u6c60\u7684\u6bd4\u5bb9\u91cf\u3001\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u500d\u7387\u6027\u80fd\u63d0\u4f9b\u4e86\u65b0\u7684\u673a\u4f1a\u3002\u7a7a\u5fc3\u7ed3\u6784\u4e00\u822c\u5177\u6709\u9ad8\u6bd4\u8868\u9762\u79ef\uff0c\u53ef\u4e3a\u9502\u7684\u50a8\u5b58\u63d0\u4f9b\u989d\u5916\u7684\u6d3b\u6027\u4f4d\u70b9\uff1b\u5176\u7a7a\u8154\u53ef\u63d0\u4f9b\u7a7a\u95f4\u8c03\u8282\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u53d1\u751f\u7684\u5e94\u53d8\u5f1b\u8c6b\u548c\u4f53\u79ef\u53d8\u5316\uff0c\u4ece\u800c\u6709\u6548\u51cf\u8f7b\u7535\u6781\u6750\u6599\u7834\u574f\u7a0b\u5ea6\uff0c\u63d0\u9ad8\u5faa\u73af\u6027\u80fd\uff1b\u7a7a\u5fc3\u7ed3\u6784\u8584\u4e14\u53ef\u6e17\u900f\u7684\u5916\u58f3\u5219\u53ef\u7f29\u77ed\u9502\u79bb\u5b50\u548c\u7535\u5b50\u7684\u6269\u6563\u8ddd\u79bb\uff0c\u63d0\u9ad8\u500d\u7387\u6027\u80fd\u3002\u7814\u7a76\u8005\u53d1\u73b0\u7528\u5408\u6210\u7684V<sub>2<\/sub>O<sub>5<\/sub>-SnO<sub>2<\/sub>\u53cc\u58f3\u7a7a\u5fc3\u80f6\u56ca\u4f5c\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\u7684\u9634\u6781\u548c\u9633\u6781\u6750\u6599\uff0c\u53ef\u63d0\u4f9b\u8f83\u9ad8\u7684\u53ef\u9006\u5bb9\u91cf\uff0c\u8868\u73b0\u51fa\u826f\u597d\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-67212\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/8-7.jpg\" alt=\"\" width=\"600\" height=\"430\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/8-7.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/8-7-300x215.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe8 V<sub>2<\/sub>O<sub>5<\/sub>-SnO<sub>2<\/sub>\u53cc\u58f3\u7a7a\u5fc3\u80f6\u56ca\u7684\u8868\u5f81\u53ca\u5176\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n<p><strong>4.2 <\/strong><strong>\u9502\u786b\u7535\u6c60<\/strong><\/p>\n<p>\u9502\u786b\u7535\u6c60\u56e0S\u4e30\u5bcc\u6210\u672c\u4f4e\uff0c\u5177\u6709\u8f83\u9ad8\u7684\u7406\u8bba\u91cd\u91cf\u548c\u4f53\u79ef\u80fd\u91cf\u5bc6\u5ea6\u800c\u88ab\u8ba4\u4e3a\u662f\u4e0b\u4e00\u4ee3\u6700\u6709\u6f5c\u529b\u7684\u53ef\u5145\u653e\u7535\u6c60\u4e4b\u4e00\u3002\u4f46\u5176\u79bb\u5b50\/\u7535\u5b50\u7535\u5bfc\u7387\u5dee\u3001\u591a\u786b\u5316\u7269\u7684\u201c\u7a7f\u68ad\u6548\u5e94\u201d\u4ee5\u53ca\u4f53\u79ef\u81a8\u80c0\u7b49\u95ee\u9898\u4e00\u76f4\u662f\u9502\u786b\u7535\u6c60\u9762\u5bf9\u7684\u91cd\u5927\u6311\u6218\u3002\u79d1\u7814\u5de5\u4f5c\u8005\u4e00\u76f4\u81f4\u529b\u4e8e\u7814\u7a76\u786b\u57fa\u6b63\u6781\u6750\u6599\uff0c\u7279\u522b\u662f\u78b3-\u786b\u590d\u5408\u6750\u6599\u3002\u5176\u4e2d\uff0c\u591a\u58f3\u5c42\u7a7a\u5fc3\u78b3\u7403\u53ef\u4ee5\u5bb9\u7eb3\u5927\u91cf\u7684S\uff0c\u63d0\u4f9b\u8db3\u591f\u7684\u81ea\u7531\u7a7a\u95f4\u4ee5\u9002\u5e94\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2dS\u7684\u4f53\u79ef\u53d8\u5316\u3002\u5176\u78b3\u58f3\u53ef\u4f5c\u4e3a\u7269\u7406\u5c4f\u969c\u6709\u6548\u5730\u6291\u5236\u591a\u786b\u5316\u7269\u5728\u7535\u89e3\u6db2\u4e2d\u7684\u6eb6\u89e3\u548c\u7a7f\u68ad\u6548\u5e94\u3002\u800c\u9ad8\u5bfc\u7535\u6027\u7a7a\u5fc3\u78b3\u7403\u53ef\u63d0\u9ad8S\u7684\u5bfc\u7535\u7387\uff0c\u63d0\u9ad8\u5176\u5229\u7528\u7387\u3002<\/p>\n<p><strong>4.3 <\/strong><strong>\u8d85\u7ea7\u7535\u5bb9\u5668<\/strong><\/p>\n<p style=\"text-align: left;\">\u8d85\u7ea7\u7535\u5bb9\u5668\u662f\u5177\u6709\u9ad8\u529f\u7387\u5bc6\u5ea6\uff0c\u8d85\u5feb\u5145\u653e\u7535\u901f\u7387\uff0c\u957f\u5faa\u73af\u5bff\u547d\u7684\u4e00\u7c7b\u72ec\u7279\u7684\u7535\u5316\u5b66\u50a8\u80fd\u88c5\u7f6e\uff0c\u4f46\u80fd\u91cf\u5bc6\u5ea6\u4f4e\u7b49\u95ee\u9898\u6781\u5927\u9650\u5236\u4e86\u8d85\u7ea7\u7535\u5bb9\u5668\u53d1\u5c55\u3002\u6839\u636e\u5176\u7535\u8377\u50a8\u5b58\u673a\u7406\uff0c\u8d85\u7ea7\u7535\u5bb9\u5668\u53ef\u4ee5\u5206\u4e3a\uff1a\uff081\uff09 \u7535\u53cc\u5c42\u7535\u5bb9\u5668\uff1b\uff082\uff09\u8d5d\u7535\u5bb9\u5668\uff1b\uff083\uff09 \u6df7\u5408\u7535\u5bb9\u5668\u3002\u5176\u4e2d\uff0c\u6df7\u5408\u7535\u5bb9\u5668\u7ed3\u5408\u4e00\u4e2a\u7535\u5bb9\u6216\u8d5d\u7535\u5bb9\u6d3b\u6027\u7269\u8d28\u4e0e\u7535\u6c60\u7684\u6d3b\u6027\u7269\u8d28\uff0c\u4f7f\u5176\u540c\u65f6\u5177\u5907\u4e86\u9ad8\u529f\u7387\u5bb9\u91cf\u548c\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3002\u5728\u4f17\u591a\u6750\u6599\u4e2d\uff0c\u590d\u6742\u7684\u4e2d\u7a7a\u7ed3\u6784\u53ef\u63d0\u4f9b\u9ad8\u6bd4\u8868\u9762\u79ef\u548c\u5b54\u9699\u7387\uff0c\u4fdd\u8bc1\u4e30\u5bcc\u7684\u6d3b\u6027\u4f4d\u70b9\u5e76\u4f7f\u7535\u89e3\u8d28\u5bb9\u6613\u6e17\u900f\uff0c\u63d0\u9ad8\u5176\u6bd4\u7535\u5bb9\u3002\u4e2d\u7a7a\u7ed3\u6784\u8fde\u540c\u58f3\u5c42\u6784\u9020\u80fd\u591f\u589e\u5f3a\u7ed3\u6784\u7a33\u5b9a\u6027\uff0c\u4e5f\u80fd\u63d0\u9ad8\u7535\u6781\u7684\u5faa\u73af\u6027\u80fd\u548c\u500d\u7387\u6027\u80fd\u3002<\/p>\n<p style=\"text-align: left;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-67213\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/9-8.jpg\" alt=\"\" width=\"600\" height=\"220\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/9-8.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/9-8-300x110.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe9 NiCo<sub>2<\/sub>S<sub>4<\/sub> \/\u77f3\u58a8\/\u78b3\u7403\u7eb8\u4e0d\u5bf9\u79f0\u8d85\u7ea7\u7535\u5bb9\u5668\u88c5\u7f6e\u7684\u793a\u610f\u56fe\u53ca\u5176\u57285 A g<sup>-1<\/sup>\u7684\u5faa\u73af\u6027\u80fd<\/strong><\/p>\n<p><strong>4.4 <\/strong><strong>\u9502\u7a7a\u6c14\u7535\u6c60<\/strong><\/p>\n<p style=\"text-align: left;\">\u9502\u7a7a\u6c14\u7535\u6c60\u662f\u4e00\u79cd\u76ee\u524d\u8fd8\u5904\u4e8e\u521d\u7ea7\u7406\u89e3\u9636\u6bb5\u7684\u6781\u5177\u6f5c\u529b\u7684\u50a8\u80fd\u6280\u672f\uff0c\u7406\u8bba\u4e0a\uff0c\u8fd9\u6837\u7684\u7535\u6c60\u53ef\u63d0\u4f9b\u7ea63500 W h kg<sup>-1<\/sup>\u7684\u9ad8\u80fd\u91cf\u5bc6\u5ea6\uff0c\u4f46\u4e00\u4e9b\u5173\u952e\u6027\u7684\u6311\u6218\u963b\u788d\u4e86\u9502\u7a7a\u6c14\u7535\u6c60\u7684\u5b9e\u9645\u5e94\u7528\u3002\u5176\u4e2d\u4e00\u4e2a\u4e3b\u8981\u95ee\u9898\u4e3a\u7535\u50ac\u5316\u8fc7\u7a0b\u4e2d\u6c27\u8fd8\u539f\u548c\u6790\u6c27\u53cd\u5e94\u7f13\u6162\u3002\u800c\u7528\u590d\u6742\u4e2d\u7a7a\u7ed3\u6784\u4f5c\u4e3a\u50ac\u5316\u5242\uff0c\u5176\u5185\u58f3\u53ef\u4ee5\u4f5c\u4e3a\u6d3b\u6027\u4e2d\u5fc3\u7528\u4e8e\u9ad8\u6548\u50ac\u5316\u8fd8\u539f\uff0c\u800c\u5728\u5916\u58f3\u5c42\u53ef\u6784\u5efa\u4e00\u4e2a\u7eb3\u7c73\u53cd\u5e94\u5668\u9632\u6b62\u5931\u6d3b\u3002\u5982\u57fa\u4e8eRuO<sub>2<\/sub>\/Mn<sub>2<\/sub>O<sub>3<\/sub>\u7684\u7ba1\u4e2d\u7ba1\u548c\u7ba1\u4e2d\u7ebf\u7684\u4e2d\u7a7a\u7eb3\u7c73\u7ed3\u6784\u8868\u73b0\u51fa\u826f\u597d\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n<p style=\"text-align: left;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-67214\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/10-8.jpg\" alt=\"\" width=\"600\" height=\"489\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/10-8.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/10-8-300x245.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe10 \u5177\u6709\u7ba1\u4e2d\u7ba1\u548c\u7ba1\u4e2d\u7ebf\u4e2d\u7a7a\u7eb3\u7c73\u7ed3\u6784\u7684RuO<sub>2<\/sub>\/Mn<sub>2<\/sub>O<sub>3<\/sub>\u53ca\u5176\u7535\u5316\u5b66\u6027\u80fd\u6bd4\u8f83<\/strong><\/p>\n<p><strong>4.5 <\/strong><strong>\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60<\/strong><\/p>\n<p style=\"text-align: left;\">\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u7531\u67d3\u6599\u654f\u5316\u7eb3\u7c73\u6676\u3001\u591a\u5b54\u5149\u7535\u9633\u6781\u3001\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u6db2\u6001\u7535\u89e3\u8d28\u548c\u5bf9\u7535\u6781\u7ec4\u6210\u7684\uff0c\u662f\u4e00\u79cd\u5f88\u6709\u524d\u9014\u7528\u4e8e\u592a\u9633\u80fd\u8f6c\u6362\u7684\u5149\u7535\u5316\u5b66\u7cfb\u7edf\u3002\u4e00\u4e2a\u7406\u60f3\u7684\u5149\u7535\u9633\u6781\u5e94\u5177\u6709\u7528\u4e8e\u67d3\u6599\u5438\u6536\u548c\u5149\u6355\u83b7\u7684\u9ad8\u6bd4\u8868\u9762\u79ef\u3002\u4e2d\u7a7a\u7ed3\u6784\uff0c\u5c24\u5176\u662f\u590d\u6742\u4e2d\u7a7a\u7ed3\u6784\u662f\u4e00\u79cd\u5f88\u6709\u6f5c\u529b\u7684\u5149\u7535\u9633\u6781\u6750\u6599\u3002\u5982\u5305\u8986TiO<sub>2<\/sub>\u7684\u591a\u58f3\u5c42SnO<sub>2<\/sub>\u7a7a\u5fc3\u7403\uff0c\u53ef\u5b9e\u73b0\u591a\u91cd\u5149\u53cd\u5c04\u548c\u4e0d\u540c\u58f3\u95f4\u6563\u5c04\uff0c\u4ece\u800c\u63d0\u9ad8\u5176\u8f6c\u6362\u6548\u7387\u3002<\/p>\n<p style=\"text-align: left;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-67215\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/11-7.jpg\" alt=\"\" width=\"600\" height=\"496\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/11-7.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/02\/11-7-300x248.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe11 \u57fa\u4e8e\u4e0d\u540c\u7a7a\u5fc3\u7ed3\u6784\u7684\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u7684\u7535\u6d41\u7535\u538b\u7279\u6027<\/strong><\/p>\n<p><strong>4.6 <\/strong><strong>\u5149\u50ac\u5316<\/strong><\/p>\n<p>\u5149\u50ac\u5316\u5df2\u7ecf\u6210\u4e3a\u4e00\u79cd\u5229\u7528\u592a\u9633\u80fd\u51c0\u5316\u548c\u6539\u5584\u6c34\u548c\u7a7a\u6c14\u7684\u65b0\u5174\u6280\u672f\u3002\u800c\u590d\u6742\u7a7a\u5fc3\u7ed3\u6784\u5728\u5149\u50ac\u5316\u4e2d\u6700\u7a81\u51fa\u7684\u4f18\u70b9\u662f\u80fd\u591f\u8ba9\u5165\u5c04\u5149\u591a\u6b21\u53cd\u5c04\uff0c\u63d0\u9ad8\u6355\u5149\u6548\u7387\uff0c\u4ece\u800c\u63d0\u9ad8\u5149\u50ac\u5316\u6027\u80fd\u3002<\/p>\n<p><strong>4.7 <\/strong><strong>\u71c3\u6599\u7535\u6c60<\/strong><\/p>\n<p>\u71c3\u6599\u7535\u6c60\u662f\u4e00\u79cd\u8f6c\u53d8\u71c3\u6599\u7684\u5316\u5b66\u80fd\u7684\u80fd\u6e90\u8f6c\u6362\u88c5\u7f6e\u3002\u901a\u8fc7\u71c3\u6599\u5728\u9633\u6781\u4e0a\u7684\u50ac\u5316\u6c27\u5316\u548c\u5728\u9634\u6781\u4e0a\u7684\u6c27\u6c14\u8fd8\u539f\u53cd\u5e94\u4ea7\u751f\u7535\u80fd\u3002\u800c\u71c3\u6599\u7535\u6c60\u7684\u6027\u80fd\u9ad8\u5ea6\u4f9d\u8d56\u4e8e\u4ed6\u4eec\u7684\u50ac\u5316\u5242\uff0c\u7531\u4e8e\u9ad8\u8868\u9762\u79ef\uff0c\u9ad8\u5b54\u9699\u4f53\u79ef\uff0c\u4f4e\u5bc6\u5ea6\uff0c\u53ef\u7f29\u77ed\u8d28\u91cf\u548c\u7535\u8377\u6269\u6563\u957f\u5ea6\uff0c\u7a7a\u5fc3\u7ed3\u6784\u4e00\u76f4\u88ab\u89c6\u4e3a\u5f88\u6709\u524d\u666f\u7684\u50ac\u5316\u5242\u548c\u50ac\u5316\u5242\u8f7d\u4f53\u3002<\/p>\n<p><strong>\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n<p style=\"text-align: left;\">\u672c\u6587\u4e3b\u8981\u5f3a\u8c03\u4e86\u590d\u6742\u4e2d\u7a7a\u7ed3\u6784\u91cd\u8981\u7684\u5408\u6210\u65b9\u6cd5\u53ca\u5728\u80fd\u6e90\u5b58\u50a8\u4e0e\u8f6c\u6362\u4e2d\u7684\u5e94\u7528\u3002\u5728\u8fc7\u53bb\u5341\u5e74\u4e2d\uff0c\u7528\u4e00\u4e9b\u65b0\u5174\u7684\u5408\u6210\u65b9\u6cd5\u5408\u6210\u590d\u6742\u7684\u4e2d\u7a7a\u7ed3\u6784\u5df2\u7ecf\u53d6\u5f97\u4e86\u91cd\u5927\u8fdb\u5c55\u3002\u4f46\u4e0d\u8bba\u662f\u4f20\u7edf\u7684\u8fd8\u662f\u65b0\u5174\u51fa\u73b0\u7684\u65b9\u6cd5\u90fd\u906d\u53d7\u4e00\u4e2a\u6216\u591a\u4e2a\u7f3a\u9677\uff0c\u5982\u5408\u6210\u8fc7\u7a0b\u9ebb\u70e6\uff0c\u7cbe\u786e\u63a7\u5236\u56f0\u96be\uff0c\u7f3a\u4e4f\u5747\u5300\u6027\u548c\u666e\u904d\u6027\uff0c\u4e0d\u53ef\u80fd\u5927\u6279\u91cf\u751f\u4ea7\uff0c\u751f\u4ea7\u6210\u672c\u9ad8\uff0c\u5f62\u6210\u673a\u5236\u77e5\u4e4b\u751a\u5c11\u7b49\u3002\u56e0\u6b64\u53d1\u5c55\u6e29\u548c\u3001\u529f\u80fd\u591a\u3001\u6210\u672c\u4f4e\u3001\u54c1\u8d28\u9ad8\u3001\u7ed3\u6784\u53c2\u6570\u53ef\u63a7\u7684\u590d\u6742\u4e2d\u7a7a\u7ed3\u6784\u5f88\u662f\u91cd\u8981\u3002\u590d\u6742\u7a7a\u5fc3\u7ed3\u6784\u5728\u5408\u6210\u65b9\u6cd5\u4e0a\u7684\u7a81\u7834\u80fd\u4e3a\u7269\u7406\u5316\u5b66\u6027\u8d28\u7684\u8c03\u6574\u63d0\u4f9b\u66f4\u591a\u673a\u4f1a\uff0c\u4ece\u800c\u4fc3\u8fdb\u4ed6\u4eec\u5728\u5404\u4e2a\u5e94\u7528\u9886\u57df\u4e2d\u7684\u53d1\u5c55\u3002\u6700\u540e\uff0c\u5e94\u8be5\u5f3a\u8c03\u7684\u662f\u590d\u6742\u7684\u4e2d\u7a7a\u7ed3\u6784\u7684\u5408\u6210\u53ca\u5176\u5e94\u7528\u4ecd\u5904\u4e8e\u8d77\u6b65\u9636\u6bb5\uff0c\u5546\u4e1a\u5316\u7684\u5927\u89c4\u6a21\u751f\u4ea7\u8fd8\u6709\u5f88\u957f\u7684\u8def\u8981\u8d70\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/adma.201602914\/full\" target=\"_blank\">Intricate Hollow Structures: Controlled Synthesis and Applications in Energy Storage and Conversion<\/a> (Adv. Mater., 2017, DOI: 10.1002\/adma.201602914)<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4\u7af9\u6797\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"http:\/\/www.cailiaoniu.com\/25127.html\" target=\"_blank\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p style=\"text-align: left;\"><strong>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\">\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u590d\u6742\u7684\u4e2d\u7a7a\u7ed3\u6784\uff08intricate hollow structures\uff09\u7531\u4e8e\u5176\u72ec\u7279\u7684\u7ed3\u6784\u7279\u5f81\uff0c\u8ff7\u4eba\u7684\u7406\u5316\u6027\u8d28\u548c\u5e7f\u6cdb\u7684\u5e94\u7528\u9886\u57df\u6781\u5927\u5730\u5438\u5f15\u4e86\u79d1\u7814\u5de5\u4f5c\u8005\u7684\u5174&#8230;<\/p>\n","protected":false},"author":2003,"featured_media":67211,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[533],"tags":[18,54,1295],"class_list":["post-67183","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zongshu","tag-xinnengyuan","tag-making","tag-mailiqiang"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/67183"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/2003"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=67183"}],"version-history":[{"count":4,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/67183\/revisions"}],"predecessor-version":[{"id":67315,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/67183\/revisions\/67315"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/67211"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=67183"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=67183"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=67183"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}