{"id":71660,"date":"2017-03-18T06:30:50","date_gmt":"2017-03-17T22:30:50","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=71660"},"modified":"2017-03-16T22:49:26","modified_gmt":"2017-03-16T14:49:26","slug":"%e5%a4%a9%e6%b4%a5%e5%a4%a7%e5%ad%a6angew-chem-int-ed-%e5%b0%81%e9%9d%a2%ef%bc%9a%e5%85%89%e7%94%b5%e6%b0%b4%e6%b0%a7%e5%8c%96%e9%a2%86%e5%9f%9f%e5%8f%96%e5%be%97%e6%96%b0%e8%bf%9b%e5%b1%95","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=71660","title":{"rendered":"\u5929\u6d25\u5927\u5b66Angew. Chem. Int. Ed.\u5c01\u9762\uff1a\u5149\u7535\u6c34\u6c27\u5316\u9886\u57df\u53d6\u5f97\u65b0\u8fdb\u5c55-\u6210\u529f\u5236\u5907\u9ad8\u6e29\u7145\u70e7\u8d64\u94c1\u77ff\u7eb3\u7c73\u7ba1\u9635\u5217"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u5bf9\u7eb3\u7c73\u6750\u6599\u5f62\u8c8c\u3001\u7ed3\u6784\u3001\u7ef4\u6570\u4ee5\u53ca\u7ed3\u6676\u5ea6\u7684\u826f\u597d\u8c03\u63a7\uff0c\u53ef\u4ee5\u5b9e\u73b0\u5176\u529b\u5b66\u3001\u7535\u5b66\u3001\u70ed\u5b66\u3001\u5149\u5b66\u7b49\u7279\u6027\u7684\u63d0\u9ad8\u548c\u6539\u5584\u3002\u8fd1\u5e74\u6765\uff0c\u4e00\u7ef4\u7eb3\u7c73\u7ba1\u7531\u4e8e\u5176\u4f18\u8d8a\u7684\u7535\u78c1\u5b66\u53ca\u5149\u5b66\u7279\u6027\u800c\u5907\u53d7\u5173\u6ce8\u3002\u8d64\u94c1\u77ff(\u03b1-Fe<sub>2<\/sub>O<sub>3<\/sub>)\u662f\u4e00\u7c7b\u975e\u5e38\u7a33\u5b9a\u7684n-\u578b\u6c27\u5316\u7269\u534a\u5bfc\u4f53\u6750\u6599\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u8bf8\u591a\u9886\u57df\uff0c\u5982\u80fd\u6e90\u8f6c\u6362\u548c\u73af\u5883\u6cbb\u7406\u3002Fe<sub>2<\/sub>O<sub>3<\/sub>\u7eb3\u7c73\u7ba1\u53ef\u4ee5\u7528\u4f5c\u9502\u79bb\u5b50\u7535\u6c60\u3001\u8d85\u7ea7\u7535\u5bb9\u5668\u3001\u5316\u5b66\u4f20\u611f\u5668\u548c\u5149\u89e3\u6c34\u7b49\u7535\u6781\u6750\u6599\uff0c\u7ecf\u8fc7\u5f62\u8c8c\u8c03\u63a7\u5408\u6210\u548c\u540e\u7eed\u70ed\u5de5\u827a\u5904\u7406\uff0c\u53ef\u4ee5\u5927\u5e45\u5ea6\u6539\u5584\u5176\u5149\u7535\u5b66\u6027\u80fd\u3002\u9ad8\u6e29\u7145\u70e7\uff08High-Temperature Calcination\uff0c HTC\uff09\u540e\u7684\u8d64\u94c1\u77ff\u6750\u6599\u7ed3\u6676\u5ea6\u663e\u8457\u5347\u9ad8\uff0c\u8f7d\u6d41\u5b50\u8f93\u8fd0\u901f\u7387\u548c\u5438\u9644\u7cfb\u6570\u4e5f\u968f\u4e4b\u589e\u5927\u3002<\/p>\n<p>\u8fd1\u671f\u7814\u7a76\u8868\u660e\uff0c\u5728\u5149\u7535\u6c34\u88c2\u89e3\u7684\u7814\u7a76\u4e2d\uff0c\u5bf9\u4e8e\u8d64\u94c1\u77ff\u5149\u9633\u6781\u5149\u7535\u6d41\u548c\u521d\u59cb\u7535\u4f4d\u7684\u63d0\u9ad8\u800c\u8a00\uff0c750\u2103\u4ee5\u4e0a\u7684\u9ad8\u6e29\u7145\u70e7\u662f\u975e\u5e38\u5173\u952e\uff0c\u9664\u4e86\u63d0\u9ad8\u7ed3\u6676\u5ea6\u4e4b\u5916\uff0cHTC\u8fd8\u52a0\u5f3a\u4e86Fe<sub>2<\/sub>O<sub>3<\/sub>\u548c \u57fa\u5e95\u4e4b\u95f4\u7684\u754c\u9762\u63a5\u89e6\uff0c\u964d\u4f4e\u4e86\u8868\u9762\u9677\u9631\u6001\u3002\u4f46Fe<sub>2<\/sub>O<sub>3<\/sub>\u7eb3\u7c73\u7ba1\u5728\u9ad8\u6e29\u4e0b\u6613\u4e8e\u5408\u5e76\uff0c\u56e0\u800c\u9ad8\u6e29\u7145\u70e7\uff08\u2265750\u2103\uff09\u540e\u96be\u4ee5\u4fdd\u6301\u539f\u6709\u7684\u7eb3\u7c73\u7ba1\u7ed3\u6784\u3002\u56e0\u6b64\uff0c\u8bbe\u8ba1\u4e0d\u540c\u7684\u5408\u6210\u7b56\u7565\u5236\u5907\u80fd\u627f\u53d7\u9ad8\u6e29\u7145\u70e7\u7684Fe<sub>2<\/sub>O<sub>3<\/sub>\u7eb3\u7c73\u7ba1\uff0c\u5bf9\u4e8e\u5f53\u524d\u5149\u7535\u6c34\u88c2\u89e3\u7814\u7a76\u548c\u5176\u4ed6\u9886\u57df\u800c\u8a00\uff0c\u4f9d\u7136\u662f\u4e00\u4e2a\u6709\u5f85\u653b\u514b\u96be\u9898\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u5929\u6d25\u5927\u5b66\u5316\u5de5\u5b66\u9662\u5de9\u91d1\u9f99\u6559\u6388\u3001\u738b\u62d3\u535a\u58eb\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u8bfe\u9898\u7ec4<\/strong>\u5728<strong>Angew. Chem. Int. Ed.<\/strong>\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u9898\u4e3a\u201c<strong>Surviving High-Temperature Calcination: ZrO2-Induced Hematite Nanotubes for Photoelectrochemical Water Oxidation<\/strong>\u201d\u7684\u5c01\u9762\u6587\u7ae0\u3002\u6587\u4e2d\u62a5\u9053\u4e86\u4e00\u79cd\u4e2d\u7a7a\u6c27\u5316\u9506\u8bf1\u5bfc\u7684\u8d64\u94c1\u77ff\u7eb3\u7c73\u7ba1\u9635\u5217\uff08Zr-Fe<sub>2<\/sub>O<sub>3<\/sub> NT\uff09\u7684\u65b0\u578b\u5408\u6210\u7b56\u7565\uff0c\u5e76\u5c06\u91c7\u7528FTO\u4e3a\u57fa\u5e95\u5408\u6210\u7684Zr-Fe<sub>2<\/sub>O<sub>3<\/sub> NT\u7528\u4e8e\u5149\u7535\u6c34\u6c27\u5316\u3002\u5728\u9ad8\u6e29\u7145\u70e7\u8fc7\u7a0b\u4e2d\uff0c\u67ef\u80af\u8fbe\u5c14\u6548\u5e94\u8f83\u4e3a\u663e\u8457 \uff0c\u56e0\u800c\u5f62\u6210\u4e86\u4e2d\u7a7a\u7ed3\u6784\u7684Zr-Fe<sub>2<\/sub>O<sub>3<\/sub> NT\uff0c\u4ece\u800c\u7f29\u77ed\u4e86\u7535\u8377\u7684\u8f6c\u79fb\u8ddd\u79bb\u3002\u76f8\u6bd4\u4e8eFe<sub>2<\/sub>O<sub>3<\/sub>\u7eb3\u7c73\u68d2\uff0cZr-Fe<sub>2<\/sub>O<sub>3<\/sub> NT\u5149\u9633\u6781\u8868\u73b0\u51fa\u4e86\u8f83\u5f3a\u7684\u5149\u7535\u50ac\u5316\u6d3b\u6027\u3002<\/p>\n<p>\u5b9e\u9a8c\u4eba\u5458\u91c7\u7528\u539f\u5b50\u5c42\u6c89\u79ef\uff08ALD\uff09\u6280\u672f\uff0c\u5728\u03b2-FeOOH\u7eb3\u7c73\u68d2\u8868\u9762\u6c89\u79ef\u4e86\u4e00\u5c42ZrO<sub>2<\/sub>\u8584\u819c\u3002\u7531\u4e8eFe\u548cZr\u4e0d\u540c\u7684\u6269\u6563\u7cfb\u6570\uff0c\u5728800\u2103\u7684\u56fa\u76f8\u53cd\u5e94\u8fc7\u7a0b\u4e2d\uff0c\u4ea7\u751f\u4e86\u663e\u8457\u7684\u67ef\u80af\u8fbe\u5c14\u6548\u5e94\uff0c\u6700\u7ec8\u5f62\u6210\u4e86\u4e2d\u7a7a\u7684Zr-Fe<sub>2<\/sub>O<sub>3<\/sub> NT\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-71713 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/03\/10.1002@anie-covering-1.png\" alt=\"\" width=\"450\" height=\"639\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/03\/10.1002@anie-covering-1.png 450w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/03\/10.1002@anie-covering-1-211x300.png 211w\" sizes=\"(max-width: 450px) 100vw, 450px\" \/><\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>1\u00a0 <\/strong><strong>\u4e2d\u7a7a\u7ed3\u6784<\/strong><strong>Zr-Fe<sub>2<\/sub>O<sub>3<\/sub> NT<\/strong><strong>\u7684\u5236\u5907<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-71666 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/03\/10.1002@anie-fig.-1.png\" alt=\"\" width=\"700\" height=\"385\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/03\/10.1002@anie-fig.-1.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/03\/10.1002@anie-fig.-1-300x165.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u5229\u7528ALD\u548cHTC\u624b\u6bb5\uff0c\u5408\u6210\u4e2d\u7a7aZr-Fe<sub>2<\/sub>O<sub>3<\/sub> NT\u7684\u6d41\u7a0b\u793a\u610f\u56fe<\/p>\n<p><strong>\u56fe<\/strong><strong>2\u00a0 Zr-Fe<sub>2<\/sub>O<sub>3<\/sub> NT<\/strong><strong>\u6750\u6599\u7684\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-71667 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/03\/10.1002@anie-fig.-2.png\" alt=\"\" width=\"700\" height=\"444\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/03\/10.1002@anie-fig.-2.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/03\/10.1002@anie-fig.-2-300x190.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p><strong>(a)\u00a0 <\/strong>\u5355\u6839Zr-Fe<sub>2<\/sub>O<sub>3<\/sub> \u7eb3\u7c73\u7ba1\u7684TEM\u56fe\u50cf\uff0c\u63d2\u56fe\u4e3a\u76f8\u5e94\u7684SAED\u56fe\u50cf\uff1b<\/p>\n<p><strong>(b-e)\u00a0 <\/strong>Zr-Fe<sub>2<\/sub>O<sub>3<\/sub> NT\u4e2d\u5404\u79cd\u5143\u7d20\u7684\u5143\u7d20\u5206\u5e03\u56fe\uff1a(b) Fe, (c) Zr, (d) O\uff1b<\/p>\n<p><strong>(f)\u00a0 <\/strong>Zr-Fe<sub>2<\/sub>O<sub>3<\/sub> NT\u7684\u660e\u573aTEM\u56fe\u50cf\uff1b<\/p>\n<p><strong>(g)\u00a0 <\/strong>\u5bf9\u5e94\u4e8e\u56fe (f) \u7684EDS\u6a2a\u5207\u9762\u7ec4\u5206\u7ebf\u626b\u63cf\u56fe\u8c31\uff1b<\/p>\n<p><strong>(h)\u00a0 <\/strong>Zr-Fe<sub>2<\/sub>O<sub>3<\/sub> NT\u9635\u5217\u7684SEM\u4fef\u89c6\u56fe\u8c31\uff1b<\/p>\n<p><strong>(i)\u00a0 <\/strong>Zr-Fe<sub>2<\/sub>O<sub>3<\/sub> NT\u9635\u5217\u7684SEM\u4fa7\u89c6\u56fe\u8c31\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>3\u00a0 Zr-Fe<sub>2<\/sub>O<sub>3<\/sub> NT<\/strong><strong>\u7684\u6676\u4f53\u7ed3\u6784\u548c\u7ec4\u5206\u8868\u5f81<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-71668 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/03\/10.1002@anie-fig.-3.png\" alt=\"\" width=\"700\" height=\"612\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/03\/10.1002@anie-fig.-3.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/03\/10.1002@anie-fig.-3-300x262.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p><strong>(a)\u00a0 <\/strong>Fe<sub>2<\/sub>O<sub>3<\/sub>\u548cFe<sub>2<\/sub>O<sub>3<\/sub> \u2013xZr\u8bd5\u6837\u7684XRD\u56fe\u8c31\uff1b<\/p>\n<p><strong>(b)\u00a0 <\/strong>Fe<sub>2<\/sub>O<sub>3<\/sub>\u548cFe<sub>2<\/sub>O<sub>3<\/sub> \u2013xZr\u8bd5\u6837\u7684\u62c9\u66fc\u56fe\u8c31\uff1b<\/p>\n<p><strong>(c)\u00a0 <\/strong>Fe<sub>2<\/sub>O<sub>3<\/sub>\u7eb3\u7c73\u68d2\u548cZr-Fe<sub>2<\/sub>O<sub>3<\/sub> NT\u4e2dFe 2p\u7535\u5b50\u7684XPS\u8868\u5f81\u56fe\u8c31\uff1b<\/p>\n<p><strong>(d)\u00a0 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RHE)\u6761\u4ef6\u4e0b\uff0cFe<sub>2<\/sub>O<sub>3<\/sub>\u548cFe<sub>2<\/sub>O<sub>3<\/sub> \u2013xZr\u5149\u9633\u6781\u7684\u5149\u7535\u8f6c\u5316\u6548\u7387 (IPCE) \u66f2\u7ebf\uff1b<\/p>\n<p><strong>(c)\u00a0 <\/strong>Fe<sub>2<\/sub>O<sub>3<\/sub>\u7eb3\u7c73\u68d2\u3001Zr-Fe<sub>2<\/sub>O<sub>3<\/sub> NT(Fe<sub>2<\/sub>O<sub>3<\/sub> \u201330Zr) \u548cZr-Fe<sub>2<\/sub>O<sub>3<\/sub> NT\/Co-Pi\u5149\u9633\u6781\u7684<em>J-V<\/em>\u66f2\u7ebf\uff1b<\/p>\n<p><strong>(d)\u00a0 <\/strong>\u57281.23 V(vs. RHE)\u6761\u4ef6\u4e0b\uff0c5 h\u5185\u7684\u8ba1\u65f6\u7535\u6d41\u66f2\u7ebf\uff1b<\/p>\n<p>\u5b9e\u9a8c\u6761\u4ef6\uff1a1 M KOH\u6eb6\u6db2\uff0cAM 1.5 G\u5149\u7167\u2014\u2014100 mW\u00b7cm<sup>-2<\/sup>\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>5\u00a0 <\/strong><strong>\u80fd\u5e26\u4f4d\u7f6e\u53ca\u7981\u5e26\u5bbd\u5ea6\u8868\u5f81<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-71662 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/03\/10.1002@anie-fig.-5.png\" alt=\"\" width=\"700\" height=\"478\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/03\/10.1002@anie-fig.-5.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/03\/10.1002@anie-fig.-5-300x205.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p><strong>(a)\u00a0 <\/strong>\u7406\u60f3\u5e73\u5e26\u6761\u4ef6(E<sub>F<\/sub>=E<sub>FB<\/sub>)\u4e0b\u7684\u80fd\u5e26\u56fe\u8c31\uff1b<\/p>\n<p><strong>(b)\u00a0 <\/strong>\u7406\u60f3\u5f00\u8def\u6761\u4ef6(E<sub>F<\/sub>=E<sub>OC<\/sub>)\u4e0b\u7684\u80fd\u5e26\u56fe\u8c31\uff1b<\/p>\n<p><strong>(c)\u00a0 <\/strong>\u5728\u9ed1\u6697\u6761\u4ef6\u4e0b\uff0c\u901a\u8fc7\u4e0d\u540c\u7535\u4f4d\u5bf9\u5e94\u7684\u7535\u5bb9\u62df\u5408\u6240\u5f97\u7684Mott-Schottky\u66f2\u7ebf\uff0c\u63d2\u56fe\u4e3a\u5b9e\u9645\u5e73\u5e26\u4f4d\u7f6e\u7684\u80fd\u5e26\u56fe\uff1b<\/p>\n<p><strong>(d)\u00a0 <\/strong>Fe<sub>2<\/sub>O<sub>3<\/sub>\u7eb3\u7c73\u68d2\u548cZr-Fe<sub>2<\/sub>O<sub>3<\/sub> NT\u7684\u5e73\u8861\u5f00\u8def\u7535\u4f4d(E<sub>OC<\/sub>)\uff0c\u63d2\u56fe\u4e3a\u5b9e\u9645\u5f00\u8def\u6761\u4ef6\u4e0b\u7684\u80fd\u5e26\u56fe\uff0c\u6d4b\u8bd5\u6240\u5f97\u7684E<sub>OC<\/sub>\u4e0eH<sub>2<\/sub>O\/O<sub>2<\/sub> \u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u5b58\u5728\u4e00\u5b9a\u7a0b\u5ea6\u7684\u4e0d\u5339\u914d\uff1b<\/p>\n<p>\u5b9e\u73b0\u6761\u4ef6\uff1a1 M KOH\u6eb6\u6db2\uff0c\u9ed1\u6697\u6761\u4ef6\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>6\u00a0 Zr-Fe<sub>2<\/sub>O<sub>3<\/sub> NT<\/strong><strong>\u6750\u6599\u7684\u8017\u5c3d\u5c42\u793a\u610f\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-71663 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/03\/10.1002@anie-fig.-6.png\" alt=\"\" width=\"700\" height=\"291\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/03\/10.1002@anie-fig.-6.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/03\/10.1002@anie-fig.-6-300x125.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>Fe<sub>2<\/sub>O<sub>3<\/sub>\u7eb3\u7c73\u68d2\u548cZr-Fe<sub>2<\/sub>O<sub>3<\/sub> NT\u7684\u534a\u5bfc\u4f53\/\u7535\u89e3\u8d28\u754c\u9762\u8017\u5c3d\u533a\uff08\u6df1\u7070\u8272\uff09\u56fe\u793a\uff1a\u4e0eFe<sub>2<\/sub>O<sub>3<\/sub>\u7eb3\u7c73\u68d2\u76f8\u6bd4\uff0cZr-Fe<sub>2<\/sub>O<sub>3<\/sub> NT\u6750\u6599\u7684\u8017\u5c3d\u5c42\u5360\u6574\u4f53\u6750\u6599\u7684\u6bd4\u4f8b\u8f83\u5927\uff0c\u80fd\u591f\u66f4\u6709\u6548\u5730\u53c2\u4e0e\u53cd\u5e94\u3002<\/p>\n<p><strong>\u3010\u603b\u7ed3\u4e0e\u5c55\u671b\u3011<\/strong><\/p>\n<p>Zr-Fe<sub>2<\/sub>O<sub>3<\/sub>\u7eb3\u7c73\u7ba1\u9635\u5217\u7684\u9996\u6b21\u6210\u529f\u5236\u5907\uff0c\u6807\u5fd7\u7740\u7eb3\u7c73\u7ba1\u7ed3\u6784\u53ef\u4ee5\u627f\u53d7\u9ad8\u6e29\u7145\u70e7\u5904\u7406\uff0c\u800c\u4e0d\u81f3\u4e8e\u5408\u5e76\u3002\u5229\u7528ALD\u6280\u672f\uff0c\u5728\u6c34\u70edFeOOH\u7eb3\u7c73\u68d2\u8868\u9762\u6c89\u79ef\u4e00\u5c42\u539a\u5ea6\u9002\u5408\u7684ZrO<sub>2<\/sub>\u8584\u819c\uff0c\u4fc3\u8fdb\u4e86\u9ad8\u6e29\u56fa\u76f8\u53cd\u5e94\u751f\u6210Zr-Fe<sub>2<\/sub>O<sub>3<\/sub> NT\u3002\u56e0\u4e3a\u72ec\u7279\u7684\u7eb3\u7c73\u7ed3\u6784\u548c\u8f83\u77ed\u7684\u7535\u8377\u8fc1\u79fb\u8ddd\u79bb\uff0cZr-Fe2O3 NT\u5149\u9633\u6781\u7684\u5149\u7535\u6027\u80fd\u5f97\u5230\u4e86\u63d0\u5347\uff0c\u57281.23 V vs. RHE\u7684\u6761\u4ef6\u4e0b\uff0c\u5149\u7535\u6d41\u53ef\u8fbe1.50 mA\u00b7cm<sup>-2<\/sup>\uff0c\u4e3aFe<sub>2<\/sub>O<sub>3<\/sub>\u7eb3\u7c73\u68d2\u76842.3\u500d\uff0c\u8fd9\u662f\u8fc4\u4eca\u4e3a\u6b62\uff0c\u65e0\u8d1f\u8f7d\u5171\u50ac\u5316\u5242\u7684\u8d64\u94c1\u77ff\u7eb3\u7c73\u7ba1\u6240\u8fbe\u5230\u7684\u6700\u9ad8\u503c\u3002<\/p>\n<p>\u5728\u8d1f\u8f7dCo-Pi\u5171\u50ac\u5316\u5242\u540e\uff0c\u50ac\u5316\u6d3b\u6027\u8fdb\u4e00\u6b65\u5f97\u5230\u63d0\u9ad8\uff0c\u521d\u59cb\u7535\u4f4d\u8fbe\u5230\u4e860.65 V (vs. RHE)\u3002\u57281.23 V (vs. RHE)\u7684\u6761\u4ef6\u4e0b\uff0c\u5149\u7535\u6d41\u8fbe\u5230\u4e861.87 mA\u00b7cm<sup>-2<\/sup>\u3002<\/p>\n<p>\u9ad8\u6e29\u7145\u70e7 (HTC) \u867d\u7136\u80fd\u591f\u63d0\u9ad8Fe<sub>2<\/sub>O<sub>3<\/sub>\u7eb3\u7c73\u7ba1\u7684\u7ed3\u6676\u5ea6\uff0c\u4ece\u800c\u63d0\u9ad8\u5bfc\u7535\u7387\u548c\u5438\u9644\u7cfb\u6570\uff0c\u4f46\u5176\u672c\u8eab\u6240\u5e26\u6709\u7684\u7ed3\u6784\u8106\u6027\u53c8\u627f\u53d7\u4e0d\u4e86\u9ad8\u6e29\u7145\u70e7\u3002\u672c\u6587\u4e3aFe<sub>2<\/sub>O<sub>3<\/sub>\u7eb3\u7c73\u7ba1\u5668\u4ef6\u89e3\u51b3\u8fd9\u4e00\u96be\u9898\u63d0\u4f9b\u4e86\u4e00\u4e2a\u8f83\u4e3a\u7406\u60f3\u7684\u89e3\u51b3\u65b9\u6848\u3002\u6587\u4e2d\u7684\u5408\u6210\u7b56\u7565\u53ef\u4ee5\u4e3a\u66f4\u591a\u5149\u7535\u50ac\u5316\u3001\u5316\u5b66\u4f20\u611f\u5668\u7b49\u6750\u6599\u7684\u8bbe\u8ba1\u548c\u5236\u5907\u63d0\u4f9b\u7406\u8bba\u6307\u5bfc\u3002<\/p>\n<p><strong>\u539f\u6587\u94fe\u63a5\uff1a<\/strong><a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201702266\/full\" target=\"_blank\">Surviving High-Temperature Calcination: ZrO2-Induced Hematite Nanotubes for Photoelectrochemical Water Oxidation<\/a>(Angew. Chem. Int. Ed., 2017, DOI: 10.1002\/anie.201702266)<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u7ec4 \u6df1\u6d77\u4e07\u91cc \u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"http:\/\/www.cailiaoniu.com\/25127.html\" target=\"_blank\">\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p>\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065952\u201d\u3002<\/p>\n<p><strong>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong><a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\"><strong>\u6d4b\u8bd5\u8c37<\/strong><\/a><strong>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u5bf9\u7eb3\u7c73\u6750\u6599\u5f62\u8c8c\u3001\u7ed3\u6784\u3001\u7ef4\u6570\u4ee5\u53ca\u7ed3\u6676\u5ea6\u7684\u826f\u597d\u8c03\u63a7\uff0c\u53ef\u4ee5\u5b9e\u73b0\u5176\u529b\u5b66\u3001\u7535\u5b66\u3001\u70ed\u5b66\u3001\u5149\u5b66\u7b49\u7279\u6027\u7684\u63d0\u9ad8\u548c\u6539\u5584\u3002\u8fd1\u5e74\u6765\uff0c\u4e00\u7ef4\u7eb3\u7c73\u7ba1\u7531\u4e8e\u5176\u4f18\u8d8a\u7684\u7535\u78c1\u5b66\u53ca\u5149\u5b66\u7279\u6027\u800c\u5907&#8230;<\/p>\n","protected":false},"author":2219,"featured_media":71664,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[1365],"class_list":["post-71660","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-gongjinglong"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/71660"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/2219"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=71660"}],"version-history":[{"count":5,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/71660\/revisions"}],"predecessor-version":[{"id":71715,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/71660\/revisions\/71715"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/71664"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=71660"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=71660"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=71660"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}