{"id":75372,"date":"2017-04-15T06:30:08","date_gmt":"2017-04-14T22:30:08","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=75372"},"modified":"2017-04-12T20:11:02","modified_gmt":"2017-04-12T12:11:02","slug":"angew-chem-int-ed-%e7%83%ad%e9%97%a8%e6%96%87%e7%ab%a0%ef%bc%9a%e5%a4%9a%e5%a3%b3%e4%b8%ad%e7%a9%bamofs","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=75372","title":{"rendered":"Angew. Chem. Int. Ed.\u70ed\u95e8\u6587\u7ae0\uff1a\u591a\u58f3\u4e2d\u7a7aMOFs"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u7531\u91d1\u5c5e\u4e2d\u5fc3\u6216\u91d1\u5c5e\u7c07\u548c\u591a\u529f\u80fd\u6709\u673a\u914d\u4f53\u7ec4\u88c5\u7684MOFs\u5728\u6700\u8fd1\u51e0\u5341\u5e74\u4ecd\u662f\u6700\u5438\u5f15\u4eba\u7684\u7814\u7a76\u9886\u57df\u4e4b\u4e00\u3002MOFs\u62e5\u6709\u7edf\u4e00\u548c\u53ef\u8c03\u8c10\u7684\u5fae\u5b54\u7ed3\u6784\u4e0e\u5927\u578b\u7684\u8868\u9762\u533a\u57df\uff0c\u5e94\u7528\u4e8e\u6c14\u4f53\u5438\u9644\u3001\u50ac\u5316\u548c\u836f\u7269\u8f93\u9001\u7b49\u9886\u57df\u3002\u800c\u5bf9MOF\u5f62\u72b6\u3001\u5c3a\u5bf8\u3001\u7a7a\u9699\u7ed3\u6784\u7684\u5408\u7406\u8bbe\u8ba1\u548c\u63a7\u5236\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u662f\u4e2a\u6311\u6218\uff0c\u7279\u522b\u662f\u5bf9\u5404\u79cd\u65e0\u673a\u7a7a\u5fc3\u7eb3\u7c73\u7ed3\u6784\u7684\u5f00\u53d1\u3002\u4e2d\u7a7aMOF\u4f5c\u4e3a\u5947\u7279\u7684\u6750\u6599\u5177\u6709\u8bf8\u5982\u591a\u58f3\u7ed3\u6784\u7684\u590d\u6742\u7ed3\u6784\u3002\u8fd9\u4e9b\u7ed3\u6784\u4e0d\u4f46\u80fd\u6539\u5584MOF\u7684\u6027\u8d28\u8fd8\u80fd\u8d4b\u4e88MOFs\u65b0\u7684\u529f\u80fd\u3002\u542b\u6709\u5927\u578b\u5c01\u95ed\u7a7a\u8154\u548c\u8584\u58f3\u7684\u4e2d\u7a7aMOF\u7531\u4e8e\u5176\u5c01\u95ed\u7a7a\u95f4\u53ef\u7528\u4e8e\u50ac\u5316\u3001\u836f\u7269\u4f20\u8f93\u3001\u80fd\u6e90\u50a8\u5b58\u7b49\u5316\u5b66\u50a8\u5b58\u548c\u9694\u79bb\u800c\u5f15\u8d77\u5e7f\u6cdb\u7684\u7814\u7a76\u5174\u8da3\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5357\u4eac\u5de5\u4e1a\u5927\u5b66\u970d\u5cf0\u851a\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u5317\u4eac\u5316\u5de5\u5927\u5b66\u5218\u519b\u67ab\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\u5728Angew. Chem. Int. Ed.<\/strong>\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u9898\u4e3a\u201cMulti-Shelled Hollow Metal\u2013Organic Frameworks<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u8be5\u7814\u7a76\u7ec4\u901a\u8fc7\u6676\u5c42\u9010\u6b65\u751f\u957f\u548c\u540e\u7eed\u523b\u8680\u8fc7\u7a0b\u6784\u5efa\u4e86\u6676\u5c42\u591a\u58f3\u7684\u4e2d\u7a7aCr-MOF(MIL-101)\u3002\u8fd9\u9879\u5408\u6210\u7b56\u7565\u53d6\u51b3\u4e8e\u975e\u5747\u4e00\u7684MOF\u7684\u6676\u4f53\u5916\u5c42\u6bd4\u6676\u4f53\u5185\u5c42\u7684\u5316\u5b66\u952e\u66f4\u7a33\u56fa\uff0c\u8fd9\u6837\u624d\u80fd\u88ab\u918b\u9178\u9009\u62e9\u6027\u523b\u8680\u3002MOF\u6210\u6838\u548c\u7ed3\u6676\u8fc7\u7a0b\u4e2d\u901a\u8fc7\u523b\u8680\u6539\u53d8\u7a7a\u7a74\u5c3a\u5bf8\u548c\u6bcf\u5c42\u7684\u58f3\u58c1\u539a\u5ea6\u3002\u6700\u7ec8\u5f97\u5230\u7684\u591a\u58f3\u5c42\u4e2d\u7a7aMIL-101\u6676\u4f53\u5728\u82ef\u4e59\u70ef\u7684\u6c27\u5316\u8fc7\u7a0b\u4e2d\u8868\u73b0\u51fa\u663e\u8457\u5730\u50ac\u5316\u6d3b\u6027\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1\uff1a \u56fa\u6001MIL-101(Cr)\u3001SSHM\uff08\u4e00\u6b21\u523b\u8680\uff09\u3001DSHM\uff08\u4e8c\u6b21\u523b\u8680\uff09\u3001TSHM\uff08\u4e09\u6b21\u523b\u8680\uff09\u7684TEM\u548cHRTEM\u56fe<\/strong><\/p>\n

\"\"
\n (a-b)\u56fa\u6001MIL-101(Cr)\u7684TEM\u548cHRTEM\u56fe\uff1b<\/p>\n

(c-d)\u56fa\u6001MIL-101(Cr)\u7ecf\u8fc7\u7b2c\u4e00\u6b21\u523b\u8680\u540e\u5f97\u5230SSHM\u7684TEM\u548cHRTEM\u56fe\uff1b<\/p>\n

(e-f) \u56fa\u6001MIL-101(Cr)\u7ecf\u8fc7\u7b2c\u4e8c\u6b21\u523b\u8680\u540e\u5f97\u5230DSHM\u7684TEM\u548cHRTEM\u56fe\uff1b<\/p>\n

(g-h)\u56fa\u6001MIL-101(Cr)\u7ecf\u8fc7\u7b2c\u4e09\u6b21\u523b\u8680\u540e\u5f97\u5230TSHM\u7684TEM\u548cHRTEM\u56fe\u3002<\/p>\n

\u56fe2\uff1a\u4e2d\u7a7aMOF\u5728\u65f6\u95f4\u68af\u5ea6\u4e0b\u523b\u8680(MSHM)\u7684\u7a7a\u7a74\u5c3a\u5bf8\u53ca\u4e00\u6b21\u523b\u8680(SSHM)\u548c\u4e8c\u6b21\u523b\u8680(DSHM)\u5728\u4e0d\u540c\u523b\u8680\u65f6\u95f4\u4e0b\u7684\u7a7a\u7a74\u5c3a\u5bf8<\/strong><\/p>\n

\"\"<\/p>\n

(a)\u4e2d\u7a7aMOF\u5728\u65f6\u95f4\u68af\u5ea6\u4e0b\u523b\u8680(MSHM)\u7684\u7a7a\u7a74\u5c3a\u5bf8\u53d8\u5316\uff1b<\/p>\n

(b-d)\u4e00\u6b21\u523b\u8680(SSHM)\u5728\u4e0d\u540c\u65f6\u95f4\u4e0b\u7684\u7a7a\u7a74\u5c3a\u5bf8\u7684TEM\u56fe\uff1b<\/p>\n

(e-g)\u4e8c\u6b21\u523b\u8680(DSHM)\u5728\u4e0d\u540c\u65f6\u95f4\u4e0b\u7684\u7a7a\u7a74\u5c3a\u5bf8\u7684TEM\u56fe\u3002<\/p>\n

\u56fe3\uff1aMSHMs\u968f\u7740\u523b\u8680\u6db2\u6d53\u5ea6\u6539\u53d8\u7684\u7a7a\u8154\u5927\u5c0f\u548c\u58f3\u58c1\u539a\u5ea6\u7684\u6539\u53d8<\/strong><\/p>\n

\"\"
\n (a-c) MIL-101(Cr)\u5206\u522b\u5728\u523b\u8680\u6d53\u5ea6\u4f4e\u3001\u4e2d\u3001\u9ad8\u4e0b\u7684\u7a7a\u8154\u5927\u5c0f\u548c\u58f3\u58c1\u539a\u5ea6\uff1b<\/p>\n

(d-f) \u4e00\u6b21\u523b\u8680(SSHM)\u5206\u522b\u5728\u523b\u8680\u6d53\u5ea6\u4f4e\u3001\u4e2d\u3001\u9ad8\u4e0b\u7684\u7a7a\u8154\u5927\u5c0f\u548c\u58f3\u58c1\u539a\u5ea6\uff1b<\/p>\n

(g-i) \u4e8c\u6b21\u523b\u8680(DSHM)\u5206\u522b\u5728\u523b\u8680\u6d53\u5ea6\u4f4e\u3001\u4e2d\u3001\u9ad8\u4e0b\u7684\u7a7a\u8154\u5927\u5c0f\u548c\u58f3\u58c1\u539a\u5ea6\u3002<\/p>\n

\u56fe4\uff1a\u4e0d\u540c\u523b\u8680\u7a0b\u5ea6\u7684\u4e2d\u7a7aMOFs\u5728\u53d4\u4e01\u57fa\u8fc7\u6c27\u5316\u6c22(TBHP)\u4f5c\u4e3a\u6c27\u5316\u5242\u7684\u82ef\u4e59\u70ef\u7684\u6c27\u5316\u8fc7\u7a0b\u7684\u50ac\u5316<\/strong><\/p>\n

\"\"
\n (a)\u53d4\u4e01\u57fa\u8fc7\u6c27\u5316\u6c22(TBHP)\u4f5c\u4e3a\u6c27\u5316\u5242\u7684\u82ef\u4e59\u70ef\u7684\u6c27\u5316\u8fc7\u7a0b\u3002\u53cd\u5e94\u6761\u4ef6\uff1a\u50ac\u5316\u524210mg\uff0c\u82ef\u4e59\u70ef(2mmol)\uff0cTBHP(6mmol)\u5728\u4e59\u8148\u6eb6\u6db2\u4e2d\uff0c80\u2103\u4e0b\u53cd\u5e9412h\uff1b<\/p>\n

(b)\u82ef\u4e59\u70ef\u7684\u6c27\u5316\u7531\u4e0d\u540c\u523b\u8680\u7a0b\u5ea6\u7684\u4e2d\u7a7aMOFs\u50ac\u5316\u7684\u8f6c\u5316\u7387\u548c\u9009\u62e9\u6027\uff1b<\/p>\n

(c) \u5c06TSHM\u4f5c\u4e3a\u50ac\u5316\u5242\u53ca\u4e0d\u540c\u5faa\u73af\u6b21\u6570\u4e0b\u7684\u82ef\u7532\u919b\u7684\u4ea7\u7387\u548c\u9009\u62e9\u6027\u3002<\/p>\n

\u3010\u5c55\u671b\u3011<\/strong><\/p>\n

\u8be5\u9879\u7814\u7a76\u5c06\u4e3a\u5408\u7406\u7684\u8bbe\u8ba1\u548c\u5408\u6210\u591a\u58f3\u5c42\u4e2d\u7a7a\u7ed3\u6784\u548c\u8fdb\u4e00\u6b65\u6269\u5927\u5e94\u7528\u63d0\u4f9b\u601d\u8def\u3002<\/p>\n

\u3010\u6587\u732e\u4fe1\u606f\u3011<\/strong><\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Multi-Shelled Hollow Metal\u2013Organic Frameworks<\/a>(Angew. Chem. Int. Ed.2017 , DoI:10.1002\/ange.201701604 )<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u7ec4\u7f51\u8001\u742a\u742a<\/strong>\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002\u6b22\u8fce\u52a0\u5165\u6750\u6599\u4ebaMOF\u5b66\u672f\u4ea4\u6d41\u7fa4\uff08120199039\uff09\uff01\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df<\/p>\n

\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/strong>\u6750\u6599\u4eba\u7f51\u5c0a\u91cd\u6240\u6709\u8fdb\u884c\u77e5\u8bc6\u4f20\u64ad\u7684\u5a92\u4f53\uff0c\u8f6c\u8f7d\u8bf7\u8054\u7cfbtougao@cailiaoren.com<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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