{"id":76036,"date":"2017-04-19T11:30:13","date_gmt":"2017-04-19T03:30:13","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=76036"},"modified":"2017-04-19T11:25:02","modified_gmt":"2017-04-19T03:25:02","slug":"%e9%87%91%e5%b1%9e%e6%9c%89%e6%9c%ba%e6%a1%86%e6%9e%b6%e5%8c%96%e5%90%88%e7%89%a9%e8%a1%8d%e7%94%9f%e7%9a%84%e6%9d%82%e5%8c%96%e5%be%ae%e7%ba%b3%e7%bb%93%e6%9e%84%ef%bc%9a%e5%88%b6%e5%a4%87%e5%8f%8a","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=76036","title":{"rendered":"\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u5316\u5408\u7269\u884d\u751f\u7684\u6742\u5316\u5fae\u7eb3\u7ed3\u6784\uff1a\u5236\u5907\u53ca\u5176\u80fd\u91cf\u50a8\u5b58\u548c\u8f6c\u5316\u5e94\u7528"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n

\u6742\u5316\u5fae\u7eb3\u7ed3\u6784\u6750\u6599\u5728\u8bf8\u5982\u53ef\u518d\u5145\u7535\u7535\u6c60\u3001\u8d85\u7ea7\u7535\u5bb9\u5668\u548c\u71c3\u6599\u7535\u6c60\u7b49\u9ad8\u6548\u80fd\u91cf\u50a8\u5b58\u548c\u8f6c\u6362\u5e94\u7528\u4e2d\u8d77\u7740\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\u3002\u5230\u76ee\u524d\u4e3a\u6b62\uff0c\u5404\u79cd\u6742\u5316\u5fae\u7eb3\u7ed3\u6784\u5df2\u7ecf\u901a\u8fc7\u591a\u79cd\u5408\u6210\u65b9\u6cd5\u6210\u529f\u5236\u5907\u3002\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u6846\u67b6\u5316\u5408\u7269\uff08MOF\uff09\u662f\u4e00\u7c7b\u91cd\u8981\u7684\u591a\u5b54\u7ed3\u6784\u65e0\u673a-\u6709\u673a\u6742\u5316\u6676\u4f53\uff0c\u5c06\u5176\u4f5c\u4e3a\u524d\u9a71\u4f53\/\u727a\u7272\u6a21\u677f\u7528\u4e8e\u5236\u5907\u5177\u6709\u590d\u6742\u7ec4\u6210\u6216\u7ed3\u6784\u4ee5\u53ca\u9884\u5b9a\u529f\u80fd\u7684\u5404\u79cd\u6742\u5316\u5fae\u7eb3\u7ed3\u6784\u7684\u65b9\u6cd5\u5438\u5f15\u4e86\u5e7f\u5927\u7814\u7a76\u8005\u7684\u5174\u8da3\u3002\u6700\u8fd1\uff0c\u6d59\u6c5f\u5de5\u4e1a\u5927\u5b66\u7684\u66f9\u6fa5\u5b8f\u548c\u5357\u6d0b\u7406\u5de5\u5927\u5b66\u7684\u5f20\u534e\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\u64b0\u5199\u4e86\u9898\u4e3a\u201cHybrid Micro-\/Nano-Structures Derived from Metal-Organic Frameworks: Preparation and Applications in Energy Storage and Conversion\u201d<\/strong>\u7684\u7efc\u8ff0\uff0c\u6587\u4e2d\u9996\u5148\u4ecb\u7ecd\u4e86MOF\u884d\u751f\u6742\u5316\u5fae\u7eb3\u7ed3\u6784\u7684\u5404\u79cd\u5408\u6210\u7b56\u7565\uff0c\u7136\u540e\u8ba8\u8bbaMOF\u884d\u751f\u6742\u5316\u5fae\u7eb3\u7ed3\u6784\u5728\u9502\u79bb\u5b50\u7535\u6c60\u3001\u9502\u786b\u7535\u6c60\u3001\u8d85\u7ea7\u7535\u5bb9\u5668\u3001\u50ac\u5316\u7b49\u65b9\u9762\u7684\u6f5c\u5728\u5e94\u7528\uff0c\u6700\u540e\u5bf9MOF\u884d\u751f\u6742\u5316\u5fae\u7eb3\u7ed3\u6784\u7814\u7a76\u65b9\u5411\u5f53\u524d\u9762\u4e34\u7684\u6311\u6218\u548c\u673a\u9047\u63d0\u4f9b\u4e86\u4e00\u4e9b\u4e2a\u4eba\u89c1\u89e3\u3002<\/p>\n

\"\"<\/p>\n

1. \u6982\u8ff0<\/strong><\/span><\/p>\n

MOFs\u6700\u5f15\u4eba\u5165\u80dc\u7684\u4f18\u70b9\u4e4b\u4e00\u662f\u5b83\u4eec\u72ec\u7279\u7684\u7ec4\u6210\uff1aMOFs\u6676\u4f53\u7ed3\u6784\u5185\u91d1\u5c5e\u548c\u6709\u673a\u914d\u4f53\u7684\u89c4\u6574\u6709\u5e8f\u6392\u5217\u3002MOFs\u7684\u8fd9\u4e00\u7279\u70b9\u5bfc\u81f4\u4e86MOF\u884d\u751f\u6742\u5316\u7ed3\u6784\u4e2d\u4e0d\u540c\u7ec4\u5206\uff08\u5982\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u548c\u78b3\uff09\u7684\u5747\u5300\u5206\u5e03\u3002\u6b64\u5916\uff0cMOFs\u4e2d\u5b58\u5728\u7684\u6709\u673a\u914d\u4f53\u4f7fMOFs\u5728\u4e0d\u5f15\u5165\u5916\u90e8\u78b3\u6e90\u7684\u6761\u4ef6\u4e0b\uff0c\u7ecf\u8fc7\u7145\u70e7\uff0c\u8f6c\u5316\u6210\u591a\u79cd\u78b3\u57fa\u7eb3\u7c73\u6750\u6599\uff08\u5982\u65e0\u5b9a\u5f62\u78b3\u548c\u77f3\u58a8\u5316\u78b3\uff09\u3002\u4e00\u4e9b\u7531\u542b\u6c2e\u6709\u673a\u914d\u4f53\uff08\u5982\u7532\u57fa\u54aa\u5511\uff09\u7ec4\u6210\u7684MOFs\u53ef\u4ee5\u5728\u70ed\u89e3\u540e\u751f\u6210\u6c2e\u63ba\u6742\u7684\u78b3\u7eb3\u7c73\u6750\u6599\uff0c\u6240\u5f97\u7eb3\u7c73\u6750\u6599\u56e0\u6b64\u5177\u6709\u66f4\u9ad8\u7684\u5bfc\u7535\u6027\u548c\u7535\u5316\u5b66\u6d3b\u6027\u3002\u5c06MOFs\u4e3a\u524d\u9a71\u4f53\/\u727a\u7272\u6a21\u677f\uff0c\u901a\u8fc7\u5408\u7406\u5730\u8bbe\u8ba1MOFs\uff08\u5982\u7ec4\u6210\u548c\u5f62\u8c8c\uff09\u53ca\u5176\u7145\u70e7\u6761\u4ef6\uff08\u5982\u9000\u706b\u6e29\u5ea6\/\u65f6\u95f4\uff0c\u52a0\u70ed\u901f\u7387\u548c\/\u6216\u6c14\u4f53\u6c14\u6c1b\uff09\uff0c\u53ef\u4ee5\u7cbe\u7ec6\u5730\u8c03\u8282MOF\u884d\u751f\u6750\u6599\u7684\u5fae\u89c2\u7ed3\u6784\uff0c\u5b9e\u73b0\u5177\u6709\u5747\u5300\u5b54\u5f84\u3001\u9ad8\u5b54\u9699\u7387\u548c\u53ef\u63a7\u5f62\u8c8c\u7684\u591a\u5b54\u7eb3\u7c73\u7ed3\u6784\u3002\u81f3\u4eca\uff0c\u4ee5MOFs\u4e3a\u524d\u9a71\u4f53\/\u727a\u7272\u6a21\u677f\uff0c\u5df2\u7ecf\u6210\u529f\u5236\u5907\u4e86\u5927\u91cf\u5177\u6709\u590d\u6742\u7ec4\u6210\u3001\u7ed3\u6784\u548c\u529f\u80fd\u7684\u6742\u5316\u5fae\u7eb3\u7ed3\u6784\u3002\u8fd9\u4e9bMOF\u884d\u751f\u7684\u6742\u5316\u5fae\u7eb3\u7ed3\u6784\u7531\u4e8e\u4e0d\u540c\u7ec4\u5206\u4e4b\u95f4\u7684\u534f\u540c\u6548\u5e94\u800c\u4e0e\u5176\u5404\u81ea\u7684\u5bf9\u5e94\u7269\u76f8\u6bd4\u8868\u73b0\u51fa\u589e\u5f3a\u7684\u6027\u80fd\uff0c\u4f7f\u5176\u5728\u9ad8\u6027\u80fd\u50a8\u80fd\/\u8f6c\u6362\u5e94\u7528\u7b49\u7814\u7a76\u9886\u57df\u5177\u6709\u5438\u5f15\u529b\u3002<\/p>\n

2. MOF<\/strong>\u884d\u751f\u7684\u6df7\u5408\u5fae<\/strong>\/<\/strong>\u7eb3\u7c73\u7ed3\u6784\uff1a\u7ed3\u6784\uff0c\u7ec4\u6210\u548c\u5236\u5907\u7b56\u7565<\/strong><\/span><\/p>\n

\u8fd1\u5e74\u6765\uff0c\u7814\u7a76\u8005\u4ee5MOFs\u4e3a\u524d\u9a71\u4f53\/\u727a\u7272\u6a21\u677f\uff0c\u901a\u8fc7\u5404\u79cd\u5408\u6210\u65b9\u6cd5\u5df2\u6210\u529f\u5236\u5907\u51fa\u8bf8\u5982\u591a\u5b54\u6742\u5316\u591a\u9762\u4f53\uff08\u56fe1\uff09\uff0c\u51c6\u4e8c\u7ef4\uff082D\uff09\u7ed3\u6784\uff0c\u57fa\u677f\u8d1f\u8f7d\u7684MOF\u884d\u751f\u7684\u6750\u6599\uff0c\u7403\u5f62\/\u975e\u7403\u5f62\u4e2d\u7a7a\u6750\u6599\u548c\u5206\u7ea7\u78b3\u7ed3\u6784\u7b49\u591a\u79cdMOF\u884d\u751f\u7684\u6742\u5316\u5fae\u7eb3\u7ed3\u6784\u3002\u7531\u4e8e\u5176\u72ec\u7279\u7684\u7ed3\u6784\u4ee5\u53ca\u7531\u7ec4\u5206\u4e4b\u95f4\u7684\u534f\u540c\u6548\u5e94\u6240\u5e26\u6765\u7684\u589e\u5f3a\u6027\u80fd\uff0cMOF\u884d\u751f\u7684\u6742\u5316\u5fae\u7eb3\u7ed3\u6784\u5df2\u7ecf\u5728\u80fd\u91cf\u50a8\u5b58\/\u8f6c\u5316\u3001\u50ac\u5316\u548c\u73af\u5883\u76f8\u5173\u9886\u57df\u4e2d\u663e\u793a\u51fa\u6781\u5927\u7684\u5e94\u7528\u524d\u666f\u3002<\/p>\n

\"\"<\/p>\n

\u56fe1.\uff08a\uff09\u5404\u79cdMOF\u884d\u751f\u6742\u5316\u5fae\u7eb3\u7ed3\u6784\u7684\u793a\u610f\u56fe\u3002\uff08b-e\uff09\u5df2\u62a5\u9053\u7684\u5178\u578bMOF\u884d\u751f<\/b><\/strong>\u6742\u5316<\/b><\/strong>\u5fae\u7eb3\u7ed3\u6784<\/b><\/strong><\/p>\n

2.1 MOF\u884d\u751f\u6742\u5316\u5fae\u7eb3\u7ed3\u6784\u7684\u7ed3\u6784\u548c\u7ec4\u6210<\/b><\/strong><\/p>\n

2.1.1 MOF\u884d\u751f\u6742\u5316\u5fae\u7eb3\u7ed3\u6784<\/b><\/strong><\/p>\n

MOF\u884d\u751f\u6742\u5316\u6750\u6599\u7684\u6700\u5178\u578b\u7684\u7ed3\u6784\u4e4b\u4e00\u662f\u591a\u5b54\u6742\u5316\u591a\u9762\u4f53\u3002\u5927\u591a\u6570MOFs\u53ef\u4ee5\u901a\u8fc7\u7b80\u5355\u7684\u9000\u706b\u8f6c\u5316\u6210\u91d1\u5c5e\u5316\u5408\u7269\uff08\u6216\u91d1\u5c5e\uff09\u548c\u78b3\u7ec4\u6210\u7684\u6742\u5316\u6750\u6599\u3002\u4f8b\u5982\uff1aZnO\/ZnFe2<\/sub>O4<\/sub>\/C\u516b\u9762\u4f53\uff0c CuO\/Cu2<\/sub>O\u591a\u9762\u4f53\uff0cNiCo2<\/sub>O4<\/sub>\/NiO \u5341\u4e8c\u9762\u4f53\uff0c\u548cCoFe2<\/sub>O4<\/sub>\u7eb3\u7c73\u7ba1\u3001\u591a\u58f3\u7a7a\u5fc3\u7403\u7b49\u3002\u53e6\u5916\uff0c\u51c6\u4e8c\u7ef4\u7ed3\u6784\u7684\u8d85\u8584\u7eb3\u7c73\u7247\u56e0\u5176\u5177\u6709\u5927\u8868\u9762\u79ef\u548c\u9ad8\u5bc6\u5ea6\u8fb9\u7f18\u4f4d\u70b9\u7b49\u7279\u70b9\uff0c\u88ab\u5e7f\u6cdb\u5730\u5e94\u7528\u4e8e\u5404\u4e2a\u7814\u7a76\u9886\u57df\u3002\u901a\u8fc7\u5728\u77f3\u58a8\u70ef\u6a21\u677f\u4e0a\u6c89\u79efMOF\u819c\uff0c\u518d\u7ecf\u8fc7\u7145\u70e7\u548c\u9178\u6d17\u8fc7\u7a0b\u4ee5\u9664\u53bb\u91d1\u5c5e\u6210\u5206\uff0c\u53ef\u4ee5\u5b9e\u73b0\u5177\u6709\u8d85\u8584\u539a\u5ea6\u548c\u7247\u72b6\u5f62\u6001\u7684MOF\u884d\u751f2D\u6742\u5316\u7269\u3002\u4f8b\u5982\uff0cCao\u7b49\u4eba\u901a\u8fc7\u7145\u70e7porphyrin paddlewheel framework-3\uff08PPF-3\uff09\u7eb3\u7c73\u7247\u5236\u5907\u4e862D CoS1.097<\/sub>-\u78b3\u7eb3\u7c73\u590d\u5408\u6750\u6599\uff08\u56fe1e\uff09\uff0c\u5e76\u5c06\u5176\u7528\u4f5c\u8d85\u7ea7\u7535\u5bb9\u5668\u7535\u6781\u3002<\/p>\n

2.1.2 <\/b><\/strong>MOF\u884d\u751f\u6742\u5316\u5fae\u7eb3\u7ed3\u6784<\/b><\/strong>\u7684\u7ec4\u6210<\/b><\/strong><\/p>\n

MOF\u884d\u751f\u7684\u78b3\u57fa\u6742\u5316\u7269\u5305\u62ec\u7531\u91d1\u5c5e\u3001\u91d1\u5c5e\u6c27\u5316\u7269\u6216\u91d1\u5c5e\u78b3\u5316\u7269\u9897\u7c92\u7ec4\u6210\u7684\u78b3\u57fa\u6742\u5316\u7269\u3002\u5229\u7528MOFs\u4f5c\u4e3a\u524d\u4f53\/\u6a21\u677f\u63d0\u4f9b\u4e86\u4e00\u79cd\u6709\u6548\u548c\u6709\u8da3\u7684\u65b9\u6cd5\u6765\u5236\u5907\u53cc\u7ec4\u5206\u91d1\u5c5e\u6c27\u5316\u7269\u6742\u5316\u7269\uff0c\u5982CuO@NiO\u548cNiO\/Co3<\/sub>O4<\/sub>\u6742\u5316\u7403\u3002\u53e6\u5916\uff0c\u5177\u6709\u4e09\u79cd\u6216\u66f4\u591a\u79cd\u6210\u5206\u7684MOF\u884d\u751f\u7684\u5fae\u7eb3\u7ed3\u6784\u4e5f\u5df2\u7ecf\u88ab\u6210\u529f\u5236\u5907\u3002\u4f8b\u5982\uff1a\u7a7a\u5fc3ZnO\/ZnFe2<\/sub>O4<\/sub>\/C\u6742\u5316\u516b\u9762\u4f53\uff0c\u6838\u58f3\u7ed3\u6784\u7684ZnO\/ZnCo2<\/sub>O4<\/sub>\/C\u6742\u5316\u7269\u3001\u86cb\u9ec4\u7ed3\u6784\u7684ZnO\/Ni3<\/sub>ZnC0.7<\/sub>\/C\u6742\u5316\u5fae\u7403\uff08\u56fe2a\uff0cb\uff09\u3001\u542b\u6709\u56db\u79cd\u7ec4\u5206\u7684MOF\u884d\u751f\u6742\u5316\u7ed3\u6784\uff08rGO\/C-Co-S\uff0c\u56fe2c-g\uff09\u3002<\/p>\n

\"\"<\/p>\n

\u56fe2. Zn-MOF \/ Ni\u884d\u751f\u6838\u58f3\u7ed3\u6784ZnO \/ Ni<\/b><\/strong>3<\/b><\/sub><\/strong>ZnC<\/b><\/strong>0.7<\/b><\/sub><\/strong>\u00a0\/ C\u6742\u5316\u5fae\u7403\u7684\uff08a\uff09SEM\u548c\uff08b\uff09TEM\u56fe\u50cf\u3002\uff08c\uff09\u4ee5ZIF-67\u4e3a\u524d\u9a71\u4f53\u5236\u5907rGO\/C-Co-S\u6742\u5316\u6750\u6599\u7684\u793a\u610f\u56fe\u3002\uff08d\uff09SEM\uff0c\uff08e-f\uff09TEM\u548c\uff08g\uff09rGO\/C-Co-S<\/b><\/strong>\u6742\u5316\u6750\u6599<\/b><\/strong>\u7684\u5143\u7d20\u5206\u5e03\u56fe<\/b><\/strong>\u3002<\/p>\n

2.2 <\/b><\/strong>MOF\u884d\u751f\u6742\u5316\u5fae\u7eb3\u7ed3\u6784<\/b><\/strong>\u7684\u5236\u5907\u65b9\u6cd5<\/b><\/strong><\/p>\n

\u5404\u79cdMOF\u884d\u751f\u7684\u6742\u5316\u5fae\u7eb3\u7ed3\u6784\u7684\u5236\u5907\u4e3b\u8981\u57fa\u4e8e\u4ee5\u4e0b\u4e09\u4e2a\u7b56\u7565\uff08\u56fe3\uff09\uff1a<\/p>\n

\uff081\uff09\u9884\u5148\u8bbe\u8ba1MOFs\u7684\u7ec4\u6210\/\u5f62\u8c8c\u518d\u901a\u8fc7\u7145\u70e7\u8fc7\u7a0b\u5236\u5907;<\/p>\n

\uff082\uff09\u5408\u6210MOF\u57fa\u6742\u5316\u6750\u6599\u518d\u901a\u8fc7\u7145\u70e7\u8fc7\u7a0b\u5236\u5907;<\/p>\n

\uff083\uff09MOF\u7145\u70e7\u540e\u518d\u8fdb\u884c\u540e\u5904\u7406\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3. \u4eceMOFs\u5230\u5176\u884d\u751f\u7684\u6742\u5316\u5fae\u7eb3\u7ed3\u6784\u7684\u4e00\u822c\u5236\u5907\u7b56\u7565\u7684\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

2.2.1\u9884\u5148\u8bbe\u8ba1MOFs\u7684\u7ec4\u6210\/\u5f62\u8c8c\u518d\u901a\u8fc7\u7145\u70e7\u8fc7\u7a0b\u5236\u5907<\/b><\/strong><\/p>\n

\u901a\u8fc7\u8bf8\u5982\u9633\u79bb\u5b50\u4ea4\u6362\u548c\u6c34\u70ed\u5904\u7406\u7b49\u5404\u79cd\u65b9\u6cd5\u53ef\u4ee5\u6539\u53d8MOF\u7684\u7ec4\u6210\uff0c\u518d\u7ecf\u8fc7\u7145\u70e7\u5373\u53ef\u83b7\u5f97\u5404\u79cd\u5177\u6709\u591a\u7ec4\u5206\u7684MOF\u884d\u751f\u6742\u5316\u5fae\u7eb3\u7ed3\u6784\u3002\u4f8b\u5982\uff0c\u4ee5Ni- MOF\u5fae\u7403\u4e3a\u524d\u4f53\uff08\u56fe4a\uff09\u53ef\u4ee5\u5236\u5907\u53cc\u91d1\u5c5eMOF\uff08Cu-Ni-BTC\uff0c\u56fe4b\uff09\uff0c\u7ecf\u8fc7\u7145\u70e7\u540e\uff0c\u53ef\u4ee5\u5f97\u5230CuO@NiO\u6838\u58f3\u7ed3\u6784\u3002<\/p>\n

\"\"<\/p>\n

\u56fe4\uff08a\uff09\u7531Cu-Ni-BTC\u5236\u5907\u5177\u6709\u591a\u58f3\u7ed3\u6784CuO@NiO\u6742\u5316\u5fae\u7403\u7684\u793a\u610f\u56fe\u3002\uff08b\uff0cc\uff09Cu-Ni-BTC\uff08b\uff09\u548cCuO@NiO\u6742\u5316\u5fae\u7403\uff08c\uff09\u7684TEM\u56fe\u50cf\u3002\uff08d\uff09CuO@NiO\u7684EDS\u8c31\u56fe\u3002<\/b><\/strong><\/p>\n

2.2.2\u5408\u6210MOF\u57fa\u6742\u5316\u6750\u6599\u518d\u901a\u8fc7\u7145\u70e7\u8fc7\u7a0b\u5236\u5907<\/b><\/strong><\/p>\n

\u81f3\u4eca\uff0c\u5404\u79cdMOF\u57fa\u6742\u5316\u6750\u6599\u5df2\u7ecf\u901a\u8fc7\u5404\u79cd\u5408\u6210\u65b9\u6cd5\u5236\u5907\u5f97\u5230\uff0c\u4f8b\u5982MOF-\u78b3\u548cMOF-\u91d1\u5c5e\u6c27\u5316\u7269\u6742\u5316\u6750\u6599\u3002\u5c24\u5176\u662fMOF-\u78b3\u6742\u5316\u6750\u6599\u7ecf\u8fc7\u70ed\u5904\u7406\u540e\u5f97\u5230\u7684MOF\u884d\u751f\u6750\u6599\u56e0\u5177\u6709\u8f83\u597d\u7684\u5bfc\u7535\u6027\uff0c\u53ef\u4ee5\u5e94\u7528\u4e8e\u7535\u5316\u5b66\u53cd\u5e94\u4e2d\u7684\u6d3b\u6027\u6750\u6599\u3002\u4f5c\u4e3a\u4e00\u4e2a\u5178\u578b\u7684\u4f8b\u5b50\uff0c\u4e09\u7ef4\u77f3\u58a8\u70ef\u8d1f\u8f7d\u7684MOF\u884d\u751f\u591a\u5b54\u91d1\u5c5e\u6c27\u5316\u7269\u590d\u5408\u6750\u6599\u5373\u662f\u901a\u8fc7\u5148\u5236\u5907\u4e09\u7ef4\u77f3\u58a8\u70ef\u8d1f\u8f7d\u7684MOFs\uff0c\u518d\u7ecf\u8fc7\u7145\u70e7\u5904\u7406\u5236\u5907\u83b7\u5f97\uff08\u56fe5\uff09\u3002<\/p>\n

\"\"<\/p>\n

\u56fe 5\uff08a-c\uff09ZIF-8 \/ 3DGN\u590d\u5408\u6750\u6599\uff08a-b\uff09\u548cMIL-88-Fe \/ 3DGN\u590d\u5408\u6750\u6599\uff08c\uff09\u7684SEM\u56fe\u50cf\u3002\uff08d\uff09ZnO\/3DGN\u590d\u5408\u6750\u6599\u7684SEM\u56fe\u50cf\u3002\uff08e\uff09\uff08d\uff09\u6240\u793a\u7684\u591a\u5b54ZnO\u7ed3\u6784\u7684TEM\u56fe\u50cf\u3002\uff08f\uff09Fe<\/b><\/strong>2<\/b><\/sub><\/strong>O<\/b><\/strong>3<\/b><\/sub><\/strong>\u00a0\/ 3DGN\u590d\u5408\u6750\u6599\u7684SEM\u56fe\u50cf\u3002\uff08g\uff0ch\uff09ZnO \/ 3DGN\uff08g\uff09\u548cFe<\/b><\/strong>2<\/b><\/sub><\/strong>O<\/b><\/strong>3<\/b><\/sub><\/strong>\u00a0\/ 3DGN\u590d\u5408\u6750\u6599\u7684\u7167\u7247\u3002<\/b><\/strong><\/p>\n

2.2.3<\/b><\/strong>\u00a0MOF\u7145\u70e7\u540e\u518d\u8fdb\u884c\u540e\u5904\u7406<\/b><\/strong><\/p>\n

MOF\u884d\u751f\u7684\u6742\u5316\u5fae\u7eb3\u7ed3\u6784\u7684\u5236\u5907\u8fd8\u53ef\u4ee5\u901a\u8fc7\u5bf9MOF\u7145\u70e7\u4ea7\u7269\u8fdb\u4e00\u6b65\u5904\u7406\u5f97\u5230\u3002\u4f8b\u5982\uff0c\u5c06\u5176\u5b83\u6750\u6599\u586b\u5145\u5230MOF\u7145\u70e7\u4ea7\u7269\u7684\u591a\u5b54\u7ed3\u6784\u4e2d\uff0c\u6216\u6c89\u79ef\u5728MOF\u7145\u70e7\u4ea7\u7269\u7684\u8868\u9762\u3002Liu\u7b49\u4eba\u901a\u8fc7\u7145\u70e7Ni-BTC MOFs\u5f97\u5230\u591a\u5b54\u78b3\u7403\uff0c\u7136\u540e\u5229\u7528\u201c\u7194\u878d\u6269\u6563\u201d\u7684\u65b9\u5f0f\u5c06Se\u5d4c\u5165\u5230\u591a\u5b54\u78b3\u7403\u5185\u5f97\u5230\u4e86\u6742\u5316\u6750\u6599\uff08\u56fe6\uff09\u3002\u503c\u5f97\u63d0\u51fa\u7684\u662f\uff0c\u9664\u4e86\u56fe3\u6240\u793aMOF\u884d\u751f\u6742\u5316\u5fae\u7eb3\u7ed3\u6784\u7684\u5236\u5907\u7b56\u7565\u5916\uff0c\u591a\u79cd\u6750\u6599\u5408\u6210\u65b9\u6cd5\u7684\u5408\u7406\u7ec4\u5408\u4e5f\u53ef\u4ee5\u5b9e\u73b0\u5177\u6709\u590d\u6742\u7ed3\u6784\u548c\u591a\u7ec4\u5206\u7684MOF\u884d\u751f\u7684\u6742\u5316\u6750\u6599\u7684\u5236\u5907\u3002\u73b0\u6709\u7684\u591a\u79cd\u6750\u6599\u52a0\u5de5\u6280\u672f\uff0c\u5982\uff0c\u673a\u68b0\u6df7\u5408\uff0c\u9759\u7535\u5438\u9644\uff0c\u7535\u6cf3\/\u55b7\u6d82\u6c89\u79ef\u548c\u65cb\u6d82\u7b49\u4e5f\u53ef\u4ee5\u5e94\u7528\u4e8e\u5bf9MOF\u7145\u70e7\u4ea7\u7269\u7684\u540e\u5904\u7406\uff0c\u4ece\u800c\u83b7\u5f97MOF\u884d\u751f\u5fae\u7eb3\u7ed3\u6784\u3002<\/p>\n

\"\"<\/p>\n

\u56fe6\uff08a\uff09\u57fa\u4e8eMOF\u5236\u5907\u591a\u5b54\u78b3\u7403\u6742\u5316\u6750\u6599\u7684\u793a\u610f\u56fe\u3002\uff08b-g\uff09MOF\u884d\u751f\u591a\u5b54\u78b3\u7403\uff08b-d\uff09\u548cSe-\u591a\u5b54\u78b3\u7403\u6742\u5316\u7269\uff08e-g\uff09\u7684TEM\u56fe\u50cf\u3002\uff08c\uff0cf\uff09\u4e2d\u7684\u7bad\u5934\u5206\u522b\u8868\u793aMOF\u884d\u751f\u78b3\u7403\u7684\u5b54\uff08c\uff09\u548c\u5d4c\u5165\u5176\u5b54\u5185\u7684Se\u7eb3\u7c73\u9897\u7c92\uff08f\uff09\u3002<\/b><\/strong><\/p>\n

3.\u5e94\u7528<\/b><\/strong><\/span><\/p>\n

3.1\u9502\u79bb\u5b50\u7535\u6c60\uff08LIB\uff09<\/b><\/strong><\/p>\n

\u78b3\u3001\u91d1\u5c5e\u6c27\u5316\u7269\u53ca\u5176\u590d\u5408\u6750\u6599\u7b49MOF\u884d\u751f\u6750\u6599\u662f\u9502\u79bb\u5b50\u7535\u6c60\u7684\u4f18\u826f\u7535\u6781\u6d3b\u6027\u6750\u6599\u3002\u4f8b\u5982\uff0cGuo\u7b49\u4eba\u4ee5Cu-Ni\u53cc\u91d1\u5c5eMOF\u4e3a\u524d\u9a71\u4f53\u5236\u5907\u4e86\u5177\u6709\u591a\u4e2a\u58f3\uff08CuO@NiO\uff09\u7684\u4e8c\u5143\u91d1\u5c5e\u6c27\u5316\u7269\u6742\u5316\u5fae\u7403\u3002\u53d7\u76ca\u4e8e\u8fd9\u79cd\u72ec\u7279\u7684\u7ed3\u6784\u548c\u5316\u5b66\u7ec4\u6210\uff0cCuO@NiO\u6742\u5316\u5fae\u7403\u5728200\u6b21\u5faa\u73af\u540e\uff0c\u6bd4\u5bb9\u91cf\u4e3a1000mAh\/g\uff08\u56fe7a\uff09\uff0c\u9ad8\u4e8eCuO\uff08674mAh\/g\uff09\u548cNiO\uff08718mAh\/g\uff09\u7684\u7406\u8bba\u5bb9\u91cf\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u57fa\u4e8eNi-BTC\u5236\u5907\u7684NiO\u5fae\u7403\u572870\u6b21\u5145\u653e\u7535\u5faa\u73af\u540e\u6bd4\u5bb9\u91cf\u5feb\u901f\u8870\u51cf\uff0c\u5728200\u6b21\u5faa\u73af\u540e\u4ec5\u4e3a\u301c150mAh\/g\u3002<\/p>\n

\"\"<\/p>\n

\u56fe7\uff08a\uff09\u5206\u522b<\/b><\/strong>\u57fa\u4e8e<\/b><\/strong>Cu-Ni-<\/b><\/strong>MOF<\/b><\/strong>\u548cNi-BTC MOF<\/b><\/strong>\u5236\u5907<\/b><\/strong>\u7684CuO@NiO<\/b><\/strong>\u6742\u5316\u5fae\u7403<\/b><\/strong>\u548cNiO\u5fae\u7403\u7684\u5faa\u73af\u6027\u80fd\u3002 CuO @ NiO\u6742\u5316\u5fae\u7403<\/b><\/strong>\u7684<\/b><\/strong>\uff08b\uff09\u5faa\u73af\u4f0f\u5b89\u56fe\uff08CV\uff09\u66f2\u7ebf\u548c\uff08c\uff09\u7b2c\u4e00<\/b><\/strong>\u6b21<\/b><\/strong>\u5145\u653e\u7535\u66f2\u7ebf\u3002<\/b><\/strong><\/p>\n

3.2\u9502\u786b\u7535\u6c60\uff08Li-S\u7535\u6c60\uff09<\/b><\/strong><\/p>\n

MOF\u884d\u751f\u6742\u5316\u5fae\u7eb3\u7ed3\u6784\u7531\u4e8e\u5176\u591a\u5b54\u7ed3\u6784\u548c\u826f\u597d\u7684\u5bfc\u7535\u6027\uff0c\u6210\u4e3aLi-S\u7535\u6c60\u6709\u5438\u5f15\u529b\u7684\u5019\u9009\u8005\u3002\u6700\u8fd1\uff0c\u57fa\u4e8eMOF\u884d\u751f\u591a\u5b54\u78b3\u7403\u7684\u9502\u7852\uff08Li-Se\uff09\u7535\u6c60\u4e5f\u88ab\u62a5\u9053\u3002\u5728\u5ba4\u6e29\u4e0b\uff0c\u4e0eS\u76f8\u6bd4\uff0cSe\u5177\u6709\u66f4\u9ad8\u7684\u7535\u5bfc\u7387\uff0c\u8fd9\u53ef\u4ee5\u589e\u52a0\u9634\u6781\u6750\u6599\u7684\u7535\u5b50\u4f20\u8f93\u901f\u7387\u3002\u5236\u5907\u7684\u78b3-Si\u590d\u5408\u7535\u6781\u5728337.5mA \/ g\u4e0b\u63d0\u4f9b588.2mAh \/ g\u7684\u521d\u59cb\u6bd4\u5bb9\u91cf\u3002<\/p>\n

3.3\u8d85\u7ea7\u7535\u5bb9\u5668<\/b><\/strong><\/p>\n

\u7531\u4e8e\u72ec\u7279\u7684\u591a\u5b54\u7ed3\u6784\u548c\u65b9\u4fbf\u7684\u5236\u5907\u65b9\u6cd5\uff0cMOF\u884d\u751f\u6750\u6599\u5728\u9ad8\u6027\u80fd\u8d85\u7ea7\u7535\u5bb9\u5668\u7535\u6781\u7684\u5236\u5907\u65b9\u9762\u6709\u5de8\u5927\u7684\u5438\u5f15\u529b\u3002\u4e3a\u4e86\u63d0\u9ad8MOF\u884d\u751f\u7535\u6781\u6750\u6599\u7684\u5bfc\u7535\u6027\uff0c\u7814\u7a76\u8005\u4eec\u5f00\u53d1\u4e86\u5bfc\u7535\u5c42\u5305\u8986\u7684\u7b56\u7565\uff0c\u5373\u7528GO\u819c\u5305\u88f9Mo-MOF\uff0c\u518d\u7ecf\u8fc7\u540e\u7eed\u7684\u4e24\u6b65\u9000\u706b\u5904\u7406\u4ee5\u83b7\u5f97\u591a\u5b54rGO\/MoO3<\/sub>\u590d\u5408\u6750\u6599\uff08\u56fe8\uff09\u8fd9\u79cd\u5bfc\u7535\u5305\u8986\u7b56\u7565\u53ef\u4ee5\u9002\u7528\u4e8e\u5176\u4ed6GO\u5305\u88f9\u7684MOF\u590d\u5408\u6750\u6599\u53ca\u5176\u76f8\u5e94\u7684MOF\u884d\u751f\u7684\u591a\u5b54\u5fae\u7eb3\u7ed3\u6784\u7684\u5236\u5907\uff0c\u5e76\u5e94\u7528\u4e8e\u9ad8\u6027\u80fd\u50a8\u80fd\u5e94\u7528\u3002\u6700\u8fd1\uff0c\u4e8c\u7ef4\u6c2e\u63ba\u6742\u78b3\/CoS1.097<\/sub>\u6742\u5316\u6750\u6599\u4e5f\u88ab\u62a5\u9053\uff08\u56fe9\uff09\u3002\u5f53\u7528\u4f5c\u8d85\u7ea7\u7535\u5bb9\u5668\u7535\u6781\u65f6\uff0c\u4e8c\u7ef4\u6c2e\u63ba\u6742\u78b3\/CoS1.097<\/sub>\u6742\u5316\u6750\u6599\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a1.5\u00a0A \/g\u4e0b\u7684\u6bd4\u7535\u5bb9\u503c\u4e3a360.1\u00a0F\/g\u3002<\/p>\n

\"\"<\/p>\n

\u56fe8\uff08a\uff09rGO \/ MoO<\/b><\/strong>3<\/b><\/sub><\/strong>\u590d\u5408\u6750\u6599\u7684\u5236\u5907\u8fc7\u7a0b\u793a\u610f\u56fe\u3002\uff08b\uff09rGO \/ MoO<\/b><\/strong>3<\/b><\/sub><\/strong>\u590d\u5408\u6750\u6599\u7684TEM\u56fe\u50cf\u3002\uff08c\uff09\u5149\u5b66\u663e\u5fae\u955c\u56fe\u548crGO \/ MoO<\/b><\/strong>3<\/b><\/sub><\/strong>\u590d\u5408\u6750\u6599\u7684\u76f8\u5e94\u62c9\u66fc\u6620\u5c04\u3002\uff08d\uff09rGO \/ MoO<\/b><\/strong>3<\/b><\/sub><\/strong>\u590d\u5408\u6750\u6599\u5236\u9020\u7684\u5168\u56fa\u6001\u67d4\u6027\u8d85\u7ea7\u7535\u5bb9\u5668\u7684<\/b><\/strong>\u7ed3\u6784<\/b><\/strong>\u793a\u610f\u56fe\u3002\uff08e\uff09\u67d4\u6027\u8d85\u7ea7\u7535\u5bb9\u5668\u5728\u4e0d\u540c\u5f2f\u66f2\u72b6\u6001\u4e0b\u7684CV\u66f2\u7ebf\u3002\uff08f\uff09\u8d85\u7ea7\u7535\u5bb9\u5668\u88c5\u7f6e\u5c06LED\u706f\u70b9\u4eae\u7684\u7167\u7247\u3002<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe9\uff08a\uff092D MOF\uff08PPF-3\uff09\u7eb3\u7c73\u7247\u548c<\/b><\/strong>\u4e8c\u7ef4\u6c2e\u63ba\u6742\u78b3\/CoS1.097<\/b><\/strong>\u7eb3\u7c73\u590d\u5408\u6750\u6599\uff08CoSNC\uff09\u7684\u5236\u5907<\/b><\/strong>\u8fc7\u7a0b<\/b><\/strong>\u793a\u610f\u56fe\u3002\uff08b\uff0cc\uff09PPF-3\u7eb3\u7c73\u7247\uff08b\uff09\u548c2D CoSNC\u7eb3\u7c73\u590d\u5408\u6750\u6599\uff08c\uff09\u7684TEM\u56fe\u50cf\u3002\uff08d\uff09\u4e8c\u7ef4CoSNC\u7eb3\u7c73\u590d\u5408\u7535\u6781\u7684\u5145\u653e\u7535\u66f2\u7ebf\u3002\uff08e\uff092D CoSNC\u7eb3\u7c73\u590d\u5408\u6750\u6599\u548c\u5757<\/b><\/strong>\u4f53<\/b><\/strong>CoSNC\u590d\u5408\u7535\u6781\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u6bd4\u7535\u5bb9<\/b><\/strong>\u503c<\/b><\/strong>\u3002<\/b><\/strong><\/p>\n

3.4\u5176\u4ed6\u50a8\u80fd\u548c\u8f6c\u6362\u5e94\u7528<\/b><\/strong><\/p>\n

\u8bb8\u591aMOF\u884d\u751f\u6742\u5316\u5fae\u7eb3\u7ed3\u6784\u5728ORR\u3001\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u548c\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u7b49\u50ac\u5316\u53cd\u5e94\u4e2d\u4e5f\u8868\u73b0\u51fa\u4e86\u9ad8\u6d3b\u6027\u3002\u4f8b\u5982\uff0c\u4f7f\u7528ZIF-67\u4f5c\u4e3a\u524d\u4f53\u5408\u6210\u7684\u6c2e\u63ba\u6742CNT\u4e2d\u7a7a\u6846\u67b6\u6750\u6599\u8868\u73b0\u4e86\u4f18\u5f02\u50ac\u5316\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\uff08NCNTFs\uff0c\u56fe10\uff09\u3002<\/p>\n

\"\"<\/p>\n

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4\uff0e\u7ed3\u8bba<\/b><\/strong><\/span><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1aHybrid Micro-\/Nano-Structures Derived from Metal-Organic Frameworks: Preparation and Applications in Energy Storage and Conversion<\/a><\/strong><\/p>\n

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