{"id":77639,"date":"2017-04-29T06:30:13","date_gmt":"2017-04-28T22:30:13","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=77639"},"modified":"2017-05-03T14:04:04","modified_gmt":"2017-05-03T06:04:04","slug":"jacs%ef%bc%9a%e7%bb%bf%e8%89%b2%e5%8c%96%e5%ad%a6-%e6%b2%89%e7%a7%af%e4%ba%8ewo2-72%e4%b8%8a%e7%9a%84agpd%e7%ba%b3%e7%b1%b3%e9%a2%97%e8%83%bd%e5%a4%9f%e9%ab%98%e6%95%88%e5%82%ac%e5%8c%96","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=77639","title":{"rendered":"JACS\uff1a\u7eff\u8272\u5316\u5b66-\u6c89\u79ef\u4e8eWO2.72\u4e0a\u7684AgPd\u7eb3\u7c73\u9897\u7c92\u80fd\u591f\u9ad8\u6548\u50ac\u5316"},"content":{"rendered":"

\u3010\u5f15\u8a00<\/strong>\u3011<\/p>\n

\u4ee5\u73af\u5883\u7b2c\u4e00\u7684\u524d\u63d0\u4e0b\uff0c\u50ac\u5316\u79d1\u5b66\u7684\u9996\u8981\u76ee\u6807\u662f\u5f00\u53d1\u51fa\u901a\u8fc7\u591a\u6b65\u5316\u5b66\u53cd\u5e94\u5f97\u5230\u6709\u6548\u4e14\u53ef\u91cd\u590d\u4f7f\u7528\u7684\u50ac\u5316\u5242\u3002<\/span>\u8fd9\u6fc0\u53d1\u4e86\u65e8\u5728\u4e86\u89e3\u7ed3\u6784\u4f9d\u8d56\u6027\u50ac\u5316\u4ee5\u53ca\u53ef\u4ee5\u5728\u591a\u4e2a\u50ac\u5316\u5242\u4f53\u7cfb\u4e2d\u4f7f\u7528\u7684\u534f\u540c\u6548\u5e94\u65b9\u9762\u4e0a\u7684\u5de8\u5927\u7814\u7a76\u5174\u8da3\uff0c\u4ece\u800c\u5c06\u50ac\u5316\u529f\u7387\u4ece\u4e00\u4e2a\u53cd\u5e94\u5ef6\u4f38\u5230\u53e6\u4e00\u4e2a\u53cd\u5e94\u3002\u5728\u672c\u7bc7\u6587\u7ae0\u4e2d AgPd NPs\uff08\u7eb3\u7c73\u7c92\u5b50\uff09\u548cWO2.72<\/sub> NRs\uff08\u7eb3\u7c73\u68d2\uff09\u4e4b\u95f4\u7684\u5f3a\u76f8\u4e92\u4f5c\u7528\u4f7f\u5f97\u590d\u5408\u6750\u6599\uff0c\u7279\u522b\u662fAg48<\/sub>Pd52<\/sub> \/ WO2.72<\/sub>\uff0c\u5bf9\u7532\u9178\u8131\u6c22\u5177\u6709\u50ac\u5316\u6d3b\u6027\u3002\u50ac\u5316\u8fd8\u53ef\u4ee5\u6269\u5c55\u5230\u7532\u9178\u94f5\uff0c2-\u785d\u57fa\u82ef\u4e59\u916e\u548c\u919b\u7684\u4e00\u6b65\u53cd\u5e94\uff0c\u7528\u4e8e\u55b9\u8bfa\u916e\u7684\u9ad8\u4ea7\u7387\u5408\u6210\u3002<\/span><\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n

\u6700\u8fd1\uff0c\u7531\u6765\u81ea\u5e03\u6717\u5927\u5b66\u7684\u6559\u6388\u5b59\u5b88\u6052\u548cChristopher T. Seto(\u8054\u5408\u901a\u8baf<\/strong>)\u5728Journal of the Amerian Chemical \u00a0Society<\/strong>\u4e0a\u53d1\u8868\u4e00\u7bc7\u540d\u4e3a\u201cAgPd Nanoparticles Deposited on WO2.72 Nanorods as an Efficient Catalyst for One-Pot Conversion of Nitrophenol\/Nitroacetophenone into Benzoxazole\/Quinazoline<\/strong>\u201d\u00a0\u7684\u6587\u7ae0\u00a0\u3002\u4ecb\u7ecd\u4e86\u4e00\u79cd\u65b0\u8bbe\u8ba1\u7684\u50ac\u5316\u5242\uff0c\u4ee5\u5b9e\u73b0\u82ef\u5e76\u6076\u5511\u548c\u55b9\u5511\u5549\u901a\u8fc7\u4e00\u6b65\u53cd\u5e94\u5408\u6210\u7684\u4e00\u79cd\u7eff\u8272\u5316\u5b66\u65b9\u6cd5\u3002\u8fd9\u5bf9\u5728\u672a\u6765\u81ea\u7136\u4ea7\u54c1\u548c\u5236\u836f\u5e94\u7528\u4e0a\u662f\u5341\u5206\u91cd\u8981\u7684\u3002<\/p>\n

\u3010\u56fe\u6587\u4fe1\u606f<\/strong>\u3011<\/p>\n

\u56fe1 \u7531AgPd\/WO2.72<\/sub>\u50ac\u5316\u7684\u785d\u57fa\u82ef\u915a\/\u919b\u7ecf\u8131\u6c22\u548c\u8f6c\u5316\u53cd\u5e94\u5f62\u6210\u82ef\u5e76\u6076\u5511\u7684\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"
\n \u56fe2 \u00a0TEM\u56fe\u50cf<\/span><\/strong><\/p>\n

\"\"<\/p>\n

\u00a0\u56fe\uff08A\uff0cB\uff09\u662f\u5728\u4e0d\u540c\u7684\u6bd4\u4f8b\u5c3a\u4e0b\uff0cAg48<\/sub>Pd52<\/sub> \/ WO2.72<\/sub>\u7eb3\u7c73\u590d\u5408\u6750\u6599\u7684TEM\u56fe\u50cf\u3002
\n \u00a0\u56fe\uff08C\uff09\u662fAg48<\/sub>Pd52<\/sub> \/ WO2.72<\/sub>\u7684HRTEM\u56fe\u50cf\u3002<\/span>\u63d2\u56fe\u662f\u5728\u7f3a\u4e4fWO2.72<\/sub>\u4e0b\uff0c\u5408\u6210\u7684Ag48<\/sub>Pd52<\/sub> \u7684HRTEM \u00a0\u56fe\u50cf\u3002<\/span>\u00a0<\/p>\n

\u88681 \u5728FAa<\/sup>\u7684\u6761\u4ef6\u4e0b\u7ecfAg48<\/sub>Pd52<\/sub> \/ WO 2.72<\/sub>\u50ac\u5316\u7684Ar-NO2<\/sub>\u7684\u6c22\u5316\u53cd\u5e94<\/span><\/strong><\/p>\n

\"\"<\/p>\n

a<\/sup>\u53cd\u5e94\u6761\u4ef6\uff1aR-NO2<\/sub>\uff081mmol\uff09\uff0cAg48<\/sub>Pd52<\/sub> \/ WO2.72<\/sub>\uff083mol\uff05\uff09\uff0c\u4e8c\u6076\u70f7\uff086mL\uff09\uff0cH 2<\/sub> O\uff083mL\uff09\uff0cFA\uff083mmol\uff09\uff0c50\u2103\u3002<\/span><\/p>\n

\u88682 \u7ecfAg48Pd52 \/ WO2.72\u50ac\u5316\u7684\u82b3\u9999\u5316\u76842-\u785d\u57fa\u82ef\u915a\u548c\u5404\u79cd\u919b\u7c7ba<\/sup><\/span><\/strong><\/p>\n

\"\"<\/p>\n

a<\/sup>\u53cd\u5e94\u6761\u4ef6\uff1a2-\u785d\u57fa\u82ef\u915a(1mmol),\u82b3\u65cf\u6216\u8102\u80aa\u65cf\u919b(1.2mmol),Ag48<\/sub>Pd52<\/sub> \/ WO2.72<\/sub>\uff083mol\uff05),\u4e8c\u6076\u70f7(6mL),H 2<\/sub> O(3mL)\u548cFA\uff084mmol),8\u5c0f\u65f6.<\/span><\/p>\n

\u88683\u00a0 \u7ecfAg48<\/sub>Pd52<\/sub> \/ WO2.72<\/sub>\u50ac\u5316\u7684\u82b3\u9999\u5316<\/span>\u76842-\u785d\u57fa\u82ef\u4e59\u916e\u4e0e\u5404\u79cd\u919ba<\/sup><\/span><\/strong><\/p>\n

\"\"<\/p>\n

a<\/sup>\u53cd\u5e94\u6761\u4ef6:\u5c062-\u785d\u57fa\u82ef\u4e59\u916e(1mmol),\u82b3\u65cf\u6216\u8102\u80aa\u919b(1.2mmol),Ag48<\/sub>Pd52<\/sub> \/ WO2.72(<\/sub>4mol\uff05),\u4e8c\u6076\u70f7(6mL)H2<\/sub> O(3mL)\u548cAF(3mmol),6\u5c0f\u65f6.<\/span><\/p>\n

\u3010\u7ed3\u8bba<\/b>\u3011<\/p>\n

\u672c\u6587\u4ecb\u7ecd\u4e86\u7814\u7a76\u8005\u53d1\u73b0AgPd NPs\uff08\u7eb3\u7c73\u9897\u7c92\uff09\u548cWO2.72<\/sub> NRs\uff08\u7eb3\u7c73\u68d2\uff09\u4e4b\u95f4\u7684\u5f3a\u76f8\u4e92\u4f5c\u7528\u4f7f\u5f97\u590d\u5408\u6750\u6599\uff0c\u7279\u522b\u662fAg48<\/sub>Pd52<\/sub> \/ WO2.72<\/sub>\uff0c\u5bf9\u7532\u9178\u8131\u6c22\u5177\u6709\u50ac\u5316\u6d3b\u6027\u3002\u4f7f\u7528\u4e00\u79cd\u65b9\u4fbf\u7684\u79cd\u5b50\u4ecb\u5bfc\u65b9\u6cd5\u6765\u5408\u6210\u590d\u5408AgPd \/WO2.72<\/sub>\u3002\u8fd9\u79cd\u50ac\u5316\u8fd8\u53ef\u4ee5\u6269\u5c55\u5230\u7532\u9178\u94f5\uff0c2-\u785d\u57fa\u82ef\u4e59\u916e\u548c\u919b\u7684\u4e00\u6b65\u53cd\u5e94\uff0c\u7528\u4e8e\u55b9\u8bfa\u916e\u7684\u9ad8\u4ea7\u7387\u5408\u6210\u3002\u901a\u8fc7\u591a\u4e2a\u5b9e\u9a8c\uff0c\u4ee5\u5b9e\u73b0\u82ef\u5e76\u6076\u5511\u548c\u55b9\u5511\u5549\u901a\u8fc7\u4e00\u6b65\u53cd\u5e94\u5408\u6210\u7684\u4e00\u79cd\u7eff\u8272\u5316\u5b66\u65b9\u6cd5\u3002\u8fd9\u5bf9\u5728\u672a\u6765\u81ea\u7136\u4ea7\u54c1\u548c\u5236\u836f\u5e94\u7528\u4e0a\u662f\u5341\u5206\u91cd\u8981\u7684\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5<\/strong>\uff1aAgPd Nanoparticles Deposited on WO2.72 Nanorods as an Efficient Catalyst for One-Pot Conversion of Nitrophenol\/ Nitroacetophenone into Benzoxazole\/Quinazoline<\/a>\uff08Journal of the Am<\/i>erican Chem<\/i>ical Soc<\/i>iety\uff0c2017\uff0cDOI:10.1021\/jacs.7b01983 )<\/p>\n

\u6574\u7406\u4eba\uff1a\u6bb5\u9e4f\u8d85<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/u><\/a><\/strong>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a><\/strong>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u4ee5\u73af\u5883\u7b2c\u4e00\u7684\u524d\u63d0\u4e0b\uff0c\u50ac\u5316\u79d1\u5b66\u7684\u9996\u8981\u76ee\u6807\u662f\u5f00\u53d1\u51fa\u901a\u8fc7\u591a\u6b65\u5316\u5b66\u53cd\u5e94\u5f97\u5230\u6709\u6548\u4e14\u53ef\u91cd\u590d\u4f7f\u7528\u7684\u50ac\u5316\u5242\u3002\u8fd9\u6fc0\u53d1\u4e86\u65e8\u5728\u4e86\u89e3\u7ed3\u6784\u4f9d\u8d56\u6027\u50ac\u5316\u4ee5\u53ca\u53ef\u4ee5\u5728\u591a\u4e2a\u50ac\u5316\u5242\u4f53\u7cfb\u4e2d\u4f7f…<\/p>\n","protected":false},"author":2999,"featured_media":77728,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[116,33,42],"class_list":["post-77639","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-catalyst","tag-nano","tag-gaofenzi"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/77639"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/2999"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=77639"}],"version-history":[{"count":28,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/77639\/revisions"}],"predecessor-version":[{"id":78932,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/77639\/revisions\/78932"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/77728"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=77639"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=77639"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=77639"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}