{"id":78739,"date":"2017-05-03T06:30:38","date_gmt":"2017-05-02T22:30:38","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=78739"},"modified":"2017-12-11T15:05:31","modified_gmt":"2017-12-11T07:05:31","slug":"materials-horizons%e5%b0%81%e9%9d%a2%e6%96%87%e7%ab%a0-%e6%96%b0%e5%9e%8b%e9%92%99%e9%92%9b%e7%9f%bf%e5%9e%8b%e5%85%89%e4%bc%8f%e6%9d%90%e6%96%99%e8%ae%be%e8%ae%a1-%e9%ab%98%e7%94%b5%e5%ad%90","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=78739","title":{"rendered":"Materials Horizons\u5c01\u9762\u6587\u7ae0: \u65b0\u578b\u9499\u949b\u77ff\u578b\u5149\u4f0f\u6750\u6599\u8bbe\u8ba1\u2014\u9ad8\u7535\u5b50\u7ef4\u5ea6\uff0c\u5f88\u91cd\u8981\uff01"},"content":{"rendered":"<p><strong><span style=\"color: #ff0000;\">\u3010\u524d\u8a00\u3011<\/span><\/strong><\/p>\n<p>\u4ee5CH<sub>3<\/sub>NH<sub>3<\/sub>PbI<sub>3<\/sub>\u4e3a\u4ee3\u8868\u7684\u6709\u673a\u2212\u65e0\u673a\u6742\u5316\u9499\u949b\u77ff\u5df2\u6210\u4e3a\u5149\u4f0f\u8fd0\u7528\u7684\u65b0\u578b\u5438\u6536\u6750\u6599\uff0c\u4ee5\u8fd9\u79cd\u9499\u949b\u77ff\u5438\u6536\u6750\u6599\u5236\u5907\u7684\u5149\u4f0f\u5668\u4ef6\u6548\u7387\u5df2\u7ecf\u8d85\u8fc722%\u3002\u7136\u800c\u5176\u5546\u4e1a\u5316\u4ecd\u7136\u9762\u4e34\u7740\u7a33\u5b9a\u6027\u548c\u6709\u6bd2\u6027\u7684\u6311\u6218\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u65e0\u6bd2\u6216\u4f4e\u6bd2\u6027\u3001\u7a33\u5b9a\u7684\u5364\u5316\u7269\u9499\u949b\u77ff\u578b\u592a\u9633\u80fd\u7535\u6c60\u5438\u6536\u6750\u6599\u6210\u4e86\u8be5\u9886\u57df\u7684\u4e00\u4e2a\u7814\u7a76\u70ed\u70b9\u3002\u7406\u8bba\u7814\u7a76\u8868\u660e\u94c5\u5364\u5316\u7269\u9499\u949b\u77ff\u6750\u6599\u7684\u4f18\u826f\u5149\u4f0f\u6027\u8d28\u90e8\u5206\u5f52\u56e0\u4e8e\u5176\u72ec\u7279\u7684\u7535\u5b50\u7279\u6027\uff0c\u5305\u62ec\u5f15\u8d77Pb 6s\u2212I 5p\u8f68\u9053\u6742\u5316\u7684Pb 6s<sup>2<\/sup>\u5b64\u7acb\u7535\u5b50\u5bf9\u4ee5\u53ca\u9499\u949b\u77ff\u7ed3\u6784\u7684\u9ad8\u5bf9\u79f0\u6027\u3002\u56e0\u6b64\u65b0\u578b\u9499\u949b\u77ff\u578b\u5149\u4f0f\u6750\u6599\u7684\u63a2\u7d22\u4e3b\u8981\u96c6\u4e2d\u4e8e\u542b\u6709Sn<sup>2+<\/sup>\u3001Ge<sup>2+<\/sup>\u3001Bi<sup>3+<\/sup>\u548cSb<sup>3+<\/sup>\u7b49\u5b64\u7acb\u7535\u5b50\u5bf9\u9633\u79bb\u5b50\u7684\u5364\u5316\u7269\u3002\u76ee\u524d\uff0c\u5df2\u6709\u5927\u91cf\u7684\u65e0\u94c5\u7684\u5364\u5316\u7269\u9499\u949b\u77ff\u4ee5\u53ca\u9499\u949b\u77ff\u884d\u751f\u7269\u88ab\u62a5\u9053\u3002\u7136\u540e\u53ea\u6709\u57fa\u4e8eSn\u57fa\u5364\u5316\u7269\u9499\u949b\u77ff\u7684\u592a\u9633\u80fd\u7535\u6c60\u53ef\u4ee5\u83b7\u5f97\u53ef\u89c2\u7684\u80fd\u91cf\u8f6c\u5316\u6548\u7387\uff1b\u800c\u5176\u5b83\u7684\u57fa\u4e8eGe\u3001Bi\u548cSb\u7684\u9499\u949b\u77ff\u578b\u53ca\u975e\u9499\u949b\u77ff\u578b\u5364\u5316\u7269\u7684\u592a\u9633\u80fd\u7535\u6c60\u6548\u7387\u5374\u4e0d\u751a\u7406\u60f3\u3002\u56e0\u6b64\uff0c\u7406\u89e3\u6240\u6709\u62a5\u9053\u7684\u4e0d\u540c\u6750\u6599\u7684\u7535\u5b50\u7279\u6027\uff08\u6bd4\u5982\u80fd\u9699\uff09\u548c\u5149\u4f0f\u7279\u6027\u7684\u8d8b\u52bf\u4ee5\u53ca\u6b20\u4f73\u7684\u5668\u4ef6\u6027\u80fd\u5bf9\u4e8e\u65b0\u578b\u9499\u949b\u77ff\u578b\u5149\u4f0f\u6750\u6599\u7684\u63a2\u7d22\u975e\u5e38\u91cd\u8981\u3002<\/p>\n<p><strong><span style=\"color: #ff0000;\">\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/span><\/strong><\/p>\n<p>\u8fd1\u671f\uff0cMaterials Horizons\u53d1\u8868\u4e86\u4e00\u7bc7\u9898\u4e3a\u201cSearching for promising new perovskite-based photovoltaic absorbers: the importance of electronic dimensionality\u201d\u7684\u5c01\u9762\u6587\u7ae0\u3002\u8bba\u6587\u5171\u540c\u901a\u8baf\u4f5c\u8005\u662f\u6765\u81ea\u7f8e\u56fdToledo\u5927\u5b66\u7684\u8096\u6cfd\u6587\u535a\u58eb\u3001\u9122\u708e\u53d1\u6559\u6388\u548c\u7f8e\u56fdDuke\u5927\u5b66\u7684David B. Mitzi\u6559\u6388\u3002\u8be5\u6587\u7ae0\u9996\u6b21\u63d0\u51fa\u4e86\u7535\u5b50\u7ef4\u5ea6\u7684\u6982\u5ff5\u2014\u8d21\u732e\u4ef7\u5e26\u9876\u548c\u5bfc\u5e26\u5e95\u7684\u539f\u5b50\u8f68\u9053\u7684\u8fde\u63a5\u6027\u3002\u4e0e\u4f20\u7edf\u7684\u7ed3\u6784\u7ef4\u5ea6\u76f8\u6bd4\uff0c\u7535\u5b50\u7ef4\u5ea6\u80fd\u66f4\u597d\u5730\u89e3\u91ca\u4e0d\u540c\u7ef4\u5ea6\u7684\u9499\u949b\u77ff\u578b\u5149\u4f0f\u6750\u6599\u7684\u6027\u80fd\u3002\u8be5\u6587\u7ae0\u901a\u8fc7DFT\u8868\u660e\uff0c\u964d\u4f4e\u7535\u5b50\u7ef4\u5ea6\u4f1a\u589e\u5927\u80fd\u9699\uff0c\u589e\u5927\u8f7d\u6d41\u5b50\u6709\u6548\u8d28\u91cf\uff0c\u964d\u4f4e\u5149\u5b66\u5438\u6536\uff0c\u964d\u4f4e\u7f3a\u9677\u5bb9\u5fcd\u6027\u3002\u8be5\u6587\u7ae0\u6307\u51fa\u53ea\u5177\u6709\u9ad8\u7684\u7ed3\u6784\u7ef4\u5ea6\u800c\u4e0d\u5177\u6709\u9ad8\u7684\u7535\u5b50\u7ef4\u5ea6\u7684\u6750\u6599\u96be\u4ee5\u6210\u4e3a\u6709\u6f5c\u529b\u7684\u5149\u4f0f\u5438\u6536\u6750\u6599\u3002\u56e0\u6b64\uff0c\u9ad8\u7535\u5b50\u7ef4\u5ea6\u662f\u9ad8\u6548\u7387\u5149\u4f0f\u5438\u6536\u6750\u6599\u7684\u5fc5\u8981\u6761\u4ef6\u3002\u8be5\u6587\u7ae0\u5bf9\u4e8e\u65b0\u578b\u9499\u949b\u77ff\u5149\u4f0f\u6750\u6599\u63a2\u7d22\u63d0\u4f9b\u4e86\u7b80\u5355\u800c\u5b9e\u7528\u7684\u7406\u8bba\u6307\u5bfc\u3002<\/p>\n<p><strong><span style=\"color: #ff0000;\">\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/span><\/strong><\/p>\n<p><strong>\u56fe1 \u9499\u949b\u77ff\u578b\u548c\u975e\u9499\u949b\u77ff\u578b\u7898\u5316\u7269\u5149\u4f0f\u6750\u6599\u80fd\u9699\u548c\u5df2\u62a5\u9053\u6700\u9ad8\u6548\u7387\u4e0e\u7ed3\u6784\/\u7535\u5b50\u7ef4\u5ea6\u7684\u5173\u7cfb<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-78782\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/05\/c6mh00519e-f1_hi-res.gif\" alt=\"\" width=\"600\" height=\"1127\" 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3D\uff0c2D\uff0c1D\u548c0D\u9499\u949b\u77ff\u6750\u6599\u7684\u7535\u5b50\u548c\u5149\u5b66\u6027\u8d28<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-78783\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/05\/c6mh00519e-f2_hi-res.gif\" alt=\"\" width=\"600\" height=\"760\" 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\u5c42\u72b6\u6750\u6599\u7684\u7535\u5b50\u548c\u5149\u5b66\u7279\u6027<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-78784\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/05\/c6mh00519e-f3_hi-res.gif\" alt=\"\" width=\"600\" height=\"950\" \/><\/p>\n<ul>\n<li>\u5bf9\u4e8e\u5c42\u72b6\u9499\u949b\u77ff\uff0c\u516b\u9762\u4f53\u5c42\u6570\u53ef\u4ee5\u964d\u4f4e\u80fd\u9699\uff0c\u964d\u4f4e\u8f7d\u6d41\u5b50\u7684\u5c42\u5185\u65b9\u5411\u7684\u6709\u6548\u8d28\u91cf\uff0c\u964d\u4f4e\u5149\u5b66\u5438\u6536\u7684\u5404\u5411\u5f02\u6027\uff0c\u4ee5\u53ca\u63d0\u9ad8\u5149\u5b66\u5438\u6536\u7cfb\u6570\u3002<\/li>\n<li>\u5c06\u5c42\u72b6\u6750\u6599\u5782\u76f4\u4e8e\u57fa\u677f\u751f\u957f\u53ef\u4ee5\u83b7\u5f97\u6700\u4f73\u7684\u8f7d\u6d41\u5b50\u4f20\u8f93\u6027\u80fd\u548c\u5149\u5b66\u5438\u6536\u7279\u6027\u3002<\/li>\n<\/ul>\n<p><strong>\u56fe4 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src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/05\/c6mh00519e-f5_hi-res.gif\" alt=\"\" width=\"600\" height=\"944\" 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href=\"http:\/\/pubs.rsc.org\/en\/content\/articlehtml\/2017\/mh\/c6mh00519e\">Searching for promising new perovskite-based photovoltaic absorbers: the importance of electronic dimensionality<\/a> (Mater. Horiz., 2017, 4, 206-216)<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"http:\/\/www.cailiaoniu.com\/25127.html\" target=\"_blank\" rel=\"noopener noreferrer\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n<p><strong><span style=\"color: #ff0000;\">\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1axiaofire-18\uff0c\u5434\u73ab\uff0c\u6211\u4eec\u4f1a\u62c9\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/span><\/strong><\/p>\n<p><strong>\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e<a href=\"http:\/\/mai.cailiaoren.com\/\" target=\"_blank\" rel=\"noopener noreferrer\">\u6750\u6599\u4eba<\/a>\u3001\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener noreferrer\">\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u524d\u8a00\u3011 \u4ee5CH3NH3PbI3\u4e3a\u4ee3\u8868\u7684\u6709\u673a\u2212\u65e0\u673a\u6742\u5316\u9499\u949b\u77ff\u5df2\u6210\u4e3a\u5149\u4f0f\u8fd0\u7528\u7684\u65b0\u578b\u5438\u6536\u6750\u6599\uff0c\u4ee5\u8fd9\u79cd\u9499\u949b\u77ff\u5438\u6536\u6750\u6599\u5236\u5907\u7684\u5149\u4f0f\u5668\u4ef6\u6548\u7387\u5df2\u7ecf\u8d85\u8fc722%\u3002\u7136\u800c\u5176\u5546\u4e1a\u5316\u4ecd\u7136&#8230;<\/p>\n","protected":false},"author":32,"featured_media":78789,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[78,2634,18,244],"class_list":["post-78739","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-photovoltaic","tag-fengmian","tag-xinnengyuan","tag-gaitaikuang"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/78739"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/32"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=78739"}],"version-history":[{"count":5,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/78739\/revisions"}],"predecessor-version":[{"id":79179,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/78739\/revisions\/79179"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/78789"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=78739"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=78739"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=78739"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}