{"id":80897,"date":"2017-05-16T06:30:07","date_gmt":"2017-05-15T22:30:07","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=80897"},"modified":"2017-05-14T14:08:16","modified_gmt":"2017-05-14T06:08:16","slug":"angew-chem-int-ed-%e4%b8%ad%e7%a7%91%e9%99%a2%e7%a6%8f%e5%bb%ba%e7%89%a9%e6%9e%84%e6%89%80%e5%bc%a0%e5%81%a5%e8%af%be%e9%a2%98%e7%bb%84%e7%a0%94%e5%8f%91mof%e5%90%88%e6%88%90%e8%b6%85%e5%b0%8f","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=80897","title":{"rendered":"Angew. Chem. Int. Ed. \u4e2d\u79d1\u9662\u798f\u5efa\u7269\u6784\u6240\u5f20\u5065\u8bfe\u9898\u7ec4\u7814\u53d1MOF\u5408\u6210\u8d85\u5c0f\u8367\u5149\u78b3-\u7eb3\u7c73\u70b9\u9635\u5217\u53ca\u5149\u5b66\u5e94\u7528"},"content":{"rendered":"

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u79d1\u9662\u798f\u5efa\u7269\u6784\u6240\u5f20\u5065\uff08<\/strong>\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u8bfe\u9898\u7ec4<\/strong>\u5728Angew. Chem. Int.\u00a0Ed.\u00a0<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cMOF-Templated Synthesis of Ultrasmall Photoluminescent Carbon-Nanodot Arrays for Optical Applications<\/strong>\u201d \u7684\u6587\u7ae0\u3002\u8be5\u7814\u7a76\u56e2\u961f\u5f00\u53d1\u51fa\u8461\u8404\u7cd6\uff08C6<\/sub>H12<\/sub>O6<\/sub>\uff09\u4f5c\u4e3a\u78b3\u6e90\u6e17\u900fMOF\uff08\u547d\u540d\uff1aHKUST-1\uff09\u5b54\u9053\uff0cN2<\/sub>\u6c14\u6c1b\u4e2d\u7145\u70e7\u5f62\u6210\u7684CD\u88ab\u9650\u5236\u5728MOF\u5b54\u4e2d\uff0c\u4ece\u800c\u4ea7\u751f\u660e\u786e\u5b9a\u4e49\u7684CD\u9635\u5217CD@MOF\u3002\u968f\u540e\uff0c\u53ef\u4ee5\u5bf93DCD\u9635\u5217\u8fdb\u884c\u5149\u7269\u7406\u5b9e\u9a8c\u6d4b\u8bd5\u3002\u867d\u7136\u5df2\u7ecf\u62a5\u9053\u4e86MOF\u76f8\u5173\u7684CD\u5236\u9020\u65b9\u6cd5\uff0c\u4f46\u662f\u8fd8\u672a\u62a5\u9053MOF\u7684\u6bdb\u5b54\u4e2d\u76f4\u63a5\u5408\u6210CD\u4ee5\u4ea7\u751f\u5305\u542b\u5728\uff08\u4ecd\u7136\u5b8c\u6574\u7684\uff09MOF\u4e2d\u7684CD\u9635\u5217\u3002\u6b64\u7c7b\u6750\u6599\u53ef\u4ee5\u4e3a\u8bbe\u8ba1\u548c\u5f00\u53d1\u65b0\u7684\u591a\u529f\u80fd\u7eb3\u7c73\u70b9\u9635\u5217\u63d0\u4f9b\u91cd\u8981\u501f\u9274\u610f\u4e49\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u65b9\u6848<\/strong>1 MOF<\/strong>\u6a21\u677f\u5236\u5907\u5149\u81f4\u53d1\u5149<\/strong>CD<\/strong>\u7684\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u901a\u8fc7MOF\u6a21\u677f\u5236\u5907\u5149\u81f4\u53d1\u5149CD\u7684\u6d41\u7a0b\u56fe\u3002<\/p>\n

\u56fe<\/strong>1 C6<\/sub>H12<\/sub>O6<\/sub><\/strong>\u4f5c\u4e3a\u78b3\u6e90\uff0c\u5229\u7528<\/strong>MOF<\/strong>\u6a21\u677f\u5236\u5907\u5149\u81f4\u53d1\u5149<\/strong>CD<\/strong>\u7684\u76f8\u5173\u7269\u5316\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u8461\u8404\u7cd6\uff08G\uff09\uff0cHKUST-1\uff0cG\u88c5\u8f7dHKUST-1\u7684XRD\u56fe\uff1b<\/p>\n

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\u56fe<\/strong>2 <\/strong>\u5229\u7528\u4e0d\u540c\u7684\u6a21\u7248\u5236\u5907<\/strong>CD<\/strong>\u7684<\/strong>TEM\u3001<\/strong>\u5c3a\u5bf8\u5206\u5e03\u53ca\u5b54\u5f84\u5206\u5e03<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09HKUST-1\u5236\u5907\u7684CD\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

\uff08b\uff09ZIF-8\u5236\u5907CD\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

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\uff08d\uff09HKUST-1\u5236\u5907CD\u7684\u5c3a\u5bf8\u5206\u5e03\uff1b<\/p>\n

\uff08e\uff09ZIF-8\u5236\u5907CD\u7684\u5c3a\u5bf8\u5206\u5e03\uff1b<\/p>\n

\uff08f\uff09MIL-101\u5236\u5907CD\u7684\u5c3a\u5bf8\u5206\u5e03\uff1b<\/p>\n

\uff08g\uff09\u901a\u8fc7MOFs\u6a21\u62df\u7684CD\u7684\u5c3a\u5bf8\u548c\u76f8\u5e94\u7684\u6a21\u62df\u7684MOF\u5b54\u5f84\u4e4b\u95f4\u7684\u6bd4\u8f83\u3002<\/p>\n

\u56fe<\/strong>3 <\/strong>\u4e0d\u540c\u5927\u5c0f\u7684<\/strong>CD<\/strong>\u7684\u5149\u81f4\u53d1\u5149\u548c\u53d1\u5c04\u6ce2\u957f\u5bf9<\/strong>CD<\/strong>\u5927\u5c0f\u7684\u5bf9\u5e94\u5173\u7cfb<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u4e0d\u540c\u5927\u5c0fCD\u7684\u5149\u81f4\u53d1\u5149\uff1b \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0\u00a0\uff08b\uff09\u53d1\u5c04\u6ce2\u957f\u5bf9CD\u5927\u5c0f\u7684\u5bf9\u5e94\u5173\u7cfb\u3002<\/p>\n

\u56fe<\/strong>4 <\/strong>\u8d85\u5c0f\u8367\u5149<\/strong>CD<\/strong>\u9635\u5217\u53ca\u5149\u5b66\u5e94\u7528<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u521d\u59cb\u529f\u80fd\u5316\u77f3\u82f1\u73bb\u7483\u7684\u7167\u7247\uff0c\u77f3\u82f1\u73bb\u7483\u4e0a\u751f\u957f\u7684G@HKUST-1-200\u8584\u819c\uff0c\u4ee5\u53ca\u5408\u6210\u4e2d\u7684\u4e2d\u95f4\u6750\u6599;<\/p>\n

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\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1a<\/strong> MOF-Templated Synthesis of Ultrasmall Photoluminescent Carbon-Nanodot Arrays for Optical Applications<\/a>\uff08Angew. Chem. Int. Ed., 2017, DOI: 10.1002\/anie.201702162\uff09<\/p>\n

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