{"id":82640,"date":"2017-05-24T06:30:50","date_gmt":"2017-05-23T22:30:50","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=82640"},"modified":"2017-05-24T20:22:53","modified_gmt":"2017-05-24T12:22:53","slug":"%e5%8c%97%e4%ba%ac%e8%88%aa%e7%a9%ba%e8%88%aa%e5%a4%a9%e5%a4%a7%e5%ad%a6%e6%9d%a8%e6%a0%91%e6%96%8c%e6%95%99%e6%8e%88adv-energy-mater-%ef%bc%9a%e6%b6%b2%e7%9b%b8%e5%89%a5%e7%a6%bb%e5%be%97%e5%88%b0","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=82640","title":{"rendered":"\u5317\u4eac\u822a\u7a7a\u822a\u5929\u5927\u5b66\u6768\u6811\u658c\u6559\u6388Adv.Energy Mater. \uff1a\u6db2\u76f8\u5265\u79bb\u5f97\u5230\u7684\u9ad8\u4f53\u79ef\u5bb9\u91cf\u94a0\u7535\u6750\u6599\u91d1\u5c5e\u9511\u7eb3\u7c73\u7247"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n

\u94a0\u7535\u6c60\u7531\u4e8e\u4ef7\u683c\u4f4e\u5ec9\uff0c\u73af\u5883\u53cb\u597d\uff0c\u4e14\u539f\u6599\u6765\u6e90\u5e7f\u6cdb\u88ab\u4eba\u4eec\u8ba4\u4e3a\u662f\u4e00\u79cd\u80fd\u591f\u4ee3\u66ff\u9502\u7535\u6c60\u7684\u65b0\u578b\u80fd\u6e90\u3002\u7136\u800c\uff0c\u76ee\u524d\u94a0\u7535\u6c60\u4f9d\u65e7\u9762\u4e34\u8bb8\u591a\u6311\u6218\uff0c\u7531\u4e8e\u94a0\u79bb\u5b50\uff081.02\u57c3\uff09\u5927\u4e8e\u9502\u79bb\u5b50\u534a\u5f84\uff0c\u4e14\u94a0\u79bb\u5b50\u5d4c\u5165\u548c\u8131\u51fa\u9700\u8981\u66f4\u591a\u7684\u80fd\u91cf\uff0c\u56e0\u6b64\u5f53\u628a\u4f20\u7edf\u9502\u7535\u6c60\u8d1f\u6781\u6750\u6599\u76f4\u63a5\u7528\u4f5c\u94a0\u7535\u6750\u6599\u65f6\uff0c\u6750\u6599\u50a8\u5b58\u79bb\u5b50\u80fd\u529b\u4f1a\u8fc5\u901f\u8870\u51cf\u3002\u5c31\u76ee\u524d\u800c\u8a00\uff0c\u4f20\u7edf\u78b3\u8d1f\u6781\u6750\u6599\u7528\u4f5c\u94a0\u7535\u6c60\u7535\u6781\u6750\u6599\uff0c\u5176\u6bd4\u5bb9\u91cf\u5f88\u5c0f\uff0830 \u2013 40 mAh cm\u20133<\/sup>\uff09\u3002\u56e0\u6b64\uff0c\u6211\u4eec\u66f4\u52a0\u5173\u6ce8\u4e00\u4e9b\u9ad8\u6bd4\u5bb9\u91cf\u7684\u91d1\u5c5e\u6c27\u5316\u7269\uff08Sn, Sb, SnO2<\/sub>, Sb2<\/sub>O4<\/sub>\uff09\u3002\u91d1\u5c5eSb\u7eb3\u7c73\u7247\u5728\u94a0\u7535\u6c60\u4e2d\u7406\u8bba\u5bb9\u91cf\u8fbe\u5230660 mAh cm\u20133<\/sup>\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/span><\/p>\n

\u7070\u8272\u91d1\u5c5eSb\u56e0\u5177\u6709\u76b1\u8936\u548c\u516d\u5143\u73af\u7b49\u7b49\u5fae\u89c2\u7ed3\u6784\uff0c\u957f\u671f\u4ee5\u6765\u88ab\u4eba\u4eec\u5f53\u4f5c\u4e8c\u7ef4\u7c7b\u77f3\u58a8\u70ef\u6750\u6599\u3002\u91d1\u5c5eSb\u7eb3\u7c73\u7247\u5177\u6709\u4e0e\u77f3\u58a8\u70ef\u76f8\u4f3c\u7684\u6027\u80fd\uff0c\u53ef\u4f5c\u4e3a\u4e00\u79cd\u65b0\u578b\u9ad8\u6027\u80fd\u8d1f\u6781\u6750\u6599\u7528\u4ee5\u94a0\u79bb\u5b50\u7684\u5b58\u50a8\u3002\u8fd1\u65e5\uff0c\u6765\u81ea\u5317\u4eac\u822a\u7a7a\u822a\u5929\u5927\u5b66\u6768\u6811\u658c\u6559\u6388\u5728Adv.Energy Mater.\u4e0a\u53d1\u6587\uff0c\u9898\u540d\u201cLiquid-Phase Exfoliated Metallic Antimony Nanosheets toward High Volumetric Sodium Storage\u201d\u3002\u6587\u4e2d\u4ecb\u7ecd\u4e86\u4e00\u79cd\u7b80\u5355\u9ad8\u6548\u65b9\u6cd5\u5236\u5907\u91d1\u5c5eSb\u7eb3\u7c73\u7247\uff0c\u5373\u5728\u5f02\u4e19\u9187\u4e0e\u7279\u5b9a\u6d53\u5ea6\u6c22\u6c27\u5316\u94a0\u6eb6\u6db2\u4e2d\u901a\u8fc7\u6db2\u76f8\u5265\u79bbSb\u91d1\u5c5e\u7c89\u672b\u7684\u65b9\u6cd5\u6765\u5f97\u5230\u91d1\u5c5eSb\u7eb3\u7c73\u7247\u3002\u901a\u8fc7\u63a7\u5236Sb\u4e0e\u77f3\u58a8\u70ef\u4e0d\u540c\u7684\u6bd4\u4f8b\uff0c\u4ece\u800c\u5f97\u5230\u4e00\u7cfb\u5217\u7684\u590d\u5408\u819c\u3002\u5b9e\u9a8c\u8868\u660e\uff0c\u77f3\u58a8\u70ef\u5177\u6709\u9ad8\u67d4\u6027\u7684\u7279\u70b9\u53ef\u6291\u5236\u91d1\u5c5eSb\u5728\u79bb\u5b50\u5d4c\u5165\u4e2d\u4f53\u79ef\u81a8\u80c0\u7684\u95ee\u9898\uff0c\u4f7f\u91d1\u5c5eSb\u50a8\u94a0\u6027\u80fd\u5f97\u5230\u663e\u8457\u7684\u63d0\u9ad8\u3002\u4f18\u5316Sb\u7eb3\u7c73\u7247\u4e0e\u77f3\u58a8\u70ef\u819c\u4f7f\u5176\u5728\u94a0\u79bb\u5b50\u5b58\u50a8\u4e2d\u5177\u6709\u9ad8\u4f53\u79ef\u5bb9\u91cf\u8fbe\u52301226 mAh cm\u20133<\/sup>\uff0c\u4ee5\u53ca\u9ad8\u500d\u7387\u6027\u80fd\u548c\u9ad8\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n

\u56fe<\/strong>1 <\/strong>\u6db2\u76f8\u5265\u79bb\u6cd5\u5236\u5907<\/strong>Sb<\/strong>\u7eb3\u7c73\u7247\u793a\u610f\u56fe<\/strong><\/span><\/p>\n

\"\"<\/p>\n

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\u56fe<\/strong>2 <\/strong>\u7eaf<\/strong>Sb<\/strong>\u7eb3\u7c73\u7247<\/strong>TEM<\/strong>\u548c<\/strong>AFM<\/strong>\u56fe<\/strong><\/span><\/p>\n

\"\"<\/p>\n

\u56fea. \u548c\u56feb. \u5206\u522b\u662fSb\u7eb3\u7c73\u7247\u7684TEM, HRTEM\u56fe\u50cf\u3002<\/p>\n

\u56fec. Sb\u7eb3\u7c73\u7247AFM\u56fe\u7247\u3002<\/p>\n

\u56fed. AFM\u56fe\u50cf\u4e2d\u7bad\u59341\u65b9\u5411\u9ad8\u5ea6\u5206\u5e03<\/p>\n

\u56fee. AFM\u56fe\u50cf\u4e2d\u7bad\u59342\u65b9\u5411\u9ad8\u5ea6\u5206\u5e03\u3002<\/p>\n

\u4ece\u56fe\u4e2d\u53ef\u5f97\u5230Sb\u7eb3\u7c73\u7247\u7684\u539a\u5ea6\u8303\u56f4\u57283.0 nm\u52304.3 nm\u4e4b\u95f4\u3002<\/p>\n

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\"\"<\/p>\n

\u56fea. Sb\u7eb3\u7c73\u7247-\u77f3\u58a8\u70ef\u590d\u5408\u819c\u7684\u5149\u5b66\u7167\u7247\uff0c\u8868\u660e\u5176\u5177\u6709\u826f\u597d\u7684\u67d4\u6027\u3002<\/p>\n

\u56feb. Sb\u7eb3\u7c73\u7247-\u77f3\u58a8\u70ef\u590d\u5408\u819c\u7684SEM\u7167\u7247\uff0c\u53ef\u770b\u51fa\u5176\u5206\u6563\u5747\u5300\u3002<\/p>\n

\u56fec, d. \u5177\u6709\u5c42\u5806\u79ef\u7ed3\u6784\u7684Sb\u7eb3\u7c73\u7247-\u77f3\u58a8\u70ef\u590d\u5408\u819c\u622a\u9762SEM\u56fe\u50cf\u3002<\/p>\n

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\u56fe<\/strong>4 Sb<\/strong>\u7eb3\u7c73\u7247\uff0c<\/strong>Sb<\/strong>\u7eb3\u7c73\u7247<\/strong>–<\/strong>\u77f3\u58a8\u70ef\u590d\u5408\u819c\u7684<\/strong>XRD\uff0c<\/strong>\u62c9\u66fc\u4ee5\u53ca<\/strong>XPS<\/strong>\u56fe<\/strong><\/span><\/p>\n

\"\"<\/p>\n

\u56fea, b. \u5206\u522b\u662fSb\u7eb3\u7c73\u7247-\u77f3\u58a8\u70ef\u590d\u5408\u819c\uff0cSb\u7eb3\u7c73\u7247\uff0c\u77f3\u58a8\u70ef\uff0c\u5757\u72b6\u5806\u79efSb\u7684XRD\u548c\u62c9\u66fc\u56fe\u8c31\u3002<\/p>\n

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\u56fed, e, f. \u5206\u522b\u4e3aSb\u76843d, C\u76841s\u4ee5\u53caO\u76841s\u80fd\u8c31\u56fe\u3002<\/p>\n

\u56fe<\/strong>5 Sb<\/strong>\u7eb3\u7c73\u7247<\/strong>–<\/strong>\u77f3\u58a8\u70ef\u590d\u5408\u819c\u4f5c\u4e3a\u94a0\u7535\u6c60\u7535\u6781\u6750\u6599\u7535\u5316\u5b66\u6027\u80fd\u56fe<\/strong><\/span><\/p>\n

\"\"<\/p>\n

\u56fea. \u9996\u4e24\u6b21\u7535\u6d41\u4e3a0.1 mA cm\u22122<\/sup>\u7684\u5145\u653e\u7535\u66f2\u7ebf\u3002<\/p>\n

\u56feb. \u4e0d\u540c\u8d1f\u8f7d\u91cf\u57280.1 mA cm\u22122<\/sup>\u4e0b\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n

\u56fec. \u8d1f\u8f7d\u91cf\u4e3a1.6 mg cm\u22122<\/sup>\u65f6\uff0c\u7535\u6d41\u5bc6\u5ea6\u4ece0.2\u52304.0 mA cm\u22122<\/sup>\u5145\u653e\u7535\u66f2\u7ebf\u3002<\/p>\n

\u56fed. \u4e0d\u540c\u8d1f\u8f7d\u91cf\u7684\u500d\u7387\u6027\u80fd\u3002<\/p>\n

\u56fee \u5728\u7535\u6d41\u5bc6\u5ea64.0 mA cm\u22122<\/sup>\u65f6\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/span><\/p>\n

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\u6587\u7ae0\u94fe\u63a5<\/strong>\uff1aLiquid-Phase Exfoliated Metallic Antimony Nanosheets toward High Volumetric Sodium Storage<\/strong> <\/a>\uff08Adv. Energy Mater. 2017, DOI: 10.1002\/aenm.201700447\uff09<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u4eba\u7ec4\u5434\u6dcf\u4f9b\u7a3f\uff0c\u9ec4\u8d85\u5ba1\u6838\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a><\/strong>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\u3002<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u94a0\u7535\u6c60\u7531\u4e8e\u4ef7\u683c\u4f4e\u5ec9\uff0c\u73af\u5883\u53cb\u597d\uff0c\u4e14\u539f\u6599\u6765\u6e90\u5e7f\u6cdb\u88ab\u4eba\u4eec\u8ba4\u4e3a\u662f\u4e00\u79cd\u80fd\u591f\u4ee3\u66ff\u9502\u7535\u6c60\u7684\u65b0\u578b\u80fd\u6e90\u3002\u7136\u800c\uff0c\u76ee\u524d\u94a0\u7535\u6c60\u4f9d\u65e7\u9762\u4e34\u8bb8\u591a\u6311\u6218\uff0c\u7531\u4e8e\u94a0\u79bb\u5b50\uff081.02\u57c3\uff09\u5927\u4e8e\u9502…<\/p>\n","protected":false},"author":230,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2],"tags":[1725,1434],"class_list":["post-82640","post","type-post","status-publish","format-standard","hentry","category-jiedu","category-keji","tag-1725","tag-1434"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/82640"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/230"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=82640"}],"version-history":[{"count":5,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/82640\/revisions"}],"predecessor-version":[{"id":83303,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/82640\/revisions\/83303"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=82640"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=82640"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=82640"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}