{"id":84510,"date":"2017-06-07T06:30:58","date_gmt":"2017-06-06T22:30:58","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=84510"},"modified":"2017-06-06T12:55:14","modified_gmt":"2017-06-06T04:55:14","slug":"jacs%ef%bc%9a%e5%a4%aa%e9%98%b3%e8%83%bd%e9%a9%b1%e5%8a%a8%e7%9a%84%e4%ba%8c%e6%b0%a7%e5%8c%96%e7%a2%b3%e8%bf%98%e5%8e%9f%e4%b8%ad%e7%bc%ba%e9%99%b7%e4%bb%8b%e5%af%bc%e7%9a%84%e7%94%b5%e5%ad%90","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=84510","title":{"rendered":"JACS\uff1a\u592a\u9633\u80fd\u9a71\u52a8\u7684\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u4e2d\u7f3a\u9677\u4ecb\u5bfc\u7684\u7535\u5b50\u7a7a\u7a74\u5206\u79bb"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u5316\u77f3\u71c3\u6599\u8fc7\u5ea6\u5229\u7528\u9020\u6210\u7684\u4e8c\u6c27\u5316\u78b3\u6392\u653e\u91cf\u65e5\u76ca\u589e\u52a0\uff0c\u9020\u6210\u4e86\u5168\u7403\u73af\u5883\u53d8\u5316\u7684\u5de8\u5927\u53d8\u5316\uff0c\u6781\u5927\u5730\u963b\u788d\u4e86\u4eba\u7c7b\u793e\u4f1a\u7684\u53ef\u6301\u7eed\u53d1\u5c55\u3002\u5728\u8fd9\u79cd\u60c5\u51b5\u4e0b\uff0c\u5c06\u6e29\u5ba4\u6c14\u4f53\u4e8c\u6c27\u5316\u78b3\u8f6c\u5316\u4e3a\u53ef\u7528\u78b3\u5f62\u5f0f\u5c24\u5176\u5f15\u8d77\u4e86\u4e16\u754c\u7684\u5173\u6ce8\uff0c\u5176\u4e2d\u5c06\u78b3\u6c22\u5316\u5408\u7269\u71c3\u6599\u4e2d\u7684\u4e8c\u6c27\u5316\u78b3\u5149\u8fd8\u539f\u901a\u5e38\u88ab\u8ba4\u4e3a\u662f\u540c\u65f6\u89e3\u51b3\u80fd\u6e90\u95ee\u9898\u7684\u6709\u5438\u5f15\u529b\u7684\u89e3\u51b3\u65b9\u6848\uff0c\u8fc4\u4eca\u4e3a\u6b62\uff0c\u5df2\u7ecf\u62a5\u9053\u4e86\u5305\u62ecZnO\uff0cTiO2<\/sub>\uff0cBi2<\/sub>WO6<\/sub>\u548cZnGe2<\/sub>O4<\/sub>\u5728\u5185\u7684\u5404\u79cd\u534a\u5bfc\u4f53\u5df2\u7ecf\u88ab\u62a5\u9053\u4e3a\u7528\u4e8e\u51cf\u5c11\u4e8c\u6c27\u5316\u78b3\u7684\u5149\u50ac\u5316\u5242\u3002\u4f46\u662f\uff0c\u5149\u50ac\u5316\u5242\u901a\u5e38\u5177\u6709\u975e\u5e38\u4f4e\u7684CO2<\/sub>\u8f6c\u5316\u6548\u7387\uff0c\u8fdc\u4f4e\u4e8e\u5b9e\u9645\u5b9e\u65bd\u7684\u8981\u6c42\u3002\u8fd1\u6765\uff0c\u5df2\u7ecf\u62a5\u9053\u4e86\u5149\u50ac\u5316\u5242\u7684\u7f3a\u9677\u5de5\u7a0b\u589e\u52a0\u8f7d\u4f53\u5206\u79bb\u6548\u7387\uff0c\u5176\u4e2d\u5f15\u5165\u7f3a\u9677\u53ef\u4ee5\u4f5c\u4e3a\u6355\u83b7\u5149\u6fc0\u53d1\u7535\u5b50\u7684\u4e2d\u5fc3\uff0c\u4ece\u800c\u9632\u6b62\u5b83\u4eec\u4e0e\u5149\u751f\u7a7a\u7a74\u7684\u590d\u5408\u3002\u7136\u800c\uff0c\u5176\u4ed6\u4e00\u4e9b\u7814\u7a76\u663e\u793a\u51fa\u4e0d\u540c\u7684\u7ed3\u679c\uff0c\u7f3a\u9677\u53ef\u80fd\u4e0d\u5229\u5730\u4f5c\u4e3a\u7535\u5b50-\u7a7a\u7a74\u590d\u5408\u4e2d\u5fc3\u4f7f\u5149\u50ac\u5316\u6d3b\u6027\u6076\u5316\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u7f3a\u9677\u7684\u77db\u76fe\u4f5c\u7528\u53ef\u80fd\u4e3b\u8981\u5f52\u56e0\u4e8e\u5e38\u89c4\u5236\u5907\u7684\u5149\u50ac\u5316\u5242\u7684\u590d\u6742\u7ed3\u6784\u4ee5\u53ca\u7f3a\u4e4f\u76f4\u63a5\u7684\u7f3a\u9677\u8868\u5f81\u6280\u672f\u3002\u4e5f\u5c31\u662f\u8bf4\uff0c\u590d\u6742\u5fae\u89c2\u7ed3\u6784\u5982\u6676\u754c\u548c\u7f3a\u9677\u7ed3\u6784\u7684\u95f4\u63a5\u5149\u8c31\u5206\u6790\u7684\u5b58\u5728\u4f7f\u5f97\u5b83\u4eec\u53ea\u80fd\u5728\u8fd9\u4e9b\u7f3a\u9677\u7ed3\u6784\u548c\u5149\u50ac\u5316\u6d3b\u6027\u4e4b\u95f4\u83b7\u5f97\u6a21\u7cca\u4f46\u5408\u7406\u7684\u76f8\u5173\u6027\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u8c22\u6bc5\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u8bfe\u9898\u7ec4\u5728JACS<\/strong>\u4e0a\u53d1\u8868\u4e86<\/strong>\u4e86\u9898\u4e3a\u201cDefect-Mediated Electron-Hole Separation in One-Unit-Cell ZnIn2<\/sub>S4<\/sub> Layers for Boosted Solar-Driven CO2<\/sub> Reduction<\/strong>\u201d\u7684\u6587\u7ae0\u3002<\/strong>\u901a\u8fc7\u539f\u5b50\u5c42\u6b21\u4e0a\u5efa\u7acb\u660e\u786e\u7684\u7ed3\u6784-\u6027\u8d28\u5173\u7cfb\u3002\u6700\u521d\u5efa\u7acb\u4e86\u5177\u6709\u53ef\u8c03\u7f3a\u9677\u6d53\u5ea6\u7684\u4e8c\u7ef4\u539f\u5b50\u5c42\u7684\u6e05\u6670\u6a21\u578b\uff0c\u56e0\u6b64\u76f4\u63a5\u516c\u5f00\u4e86\u539f\u5b50\u7ea7\u7684\u7f3a\u9677\u7c7b\u578b\u548c\u5206\u5e03\u3002\u4f5c\u4e3a\u539f\u578b\uff0c\u9996\u6b21\u6210\u529f\u5408\u6210\u4e86\u6709\u7f3a\u9677\u7684\u5355\u6676\u5355\u5143ZnIn2<\/sub>S4<\/sub>\u539f\u5b50\u5c42\u3002\u7ecf\u504f\u632f\u6821\u6b63\u7684\u626b\u63cf\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\u76f4\u63a5\u663e\u793a\u51fa\u5b83\u4eec\u7684\u4e0d\u540c\u950c\u7a7a\u4f4d\u6d53\u5ea6\uff0c\u901a\u8fc7\u6b63\u7535\u5b50\u6e6e\u6ca1\u5149\u8c31\u548c\u7535\u5b50\u81ea\u65cb\u5171\u632f\u5206\u6790\u8bc1\u5b9e\u3002\u5bc6\u5ea6\u51fd\u6570\u8ba1\u7b97\u8868\u660e\uff0c\u950c\u7a7a\u4f4d\u7684\u5b58\u5728\u786e\u4fdd\u66f4\u9ad8\u7684\u7535\u8377\u5bc6\u5ea6\u548c\u6709\u6548\u7684\u8f7d\u6d41\u5b50\u4f20\u8f93\uff0c\u901a\u8fc7\u4eceZnIn2<\/sub>S4<\/sub>\u7684\u5bfc\u5e26\u5230\u6355\u83b7\u6001\u7684\u301c15ps\u7684\u8d85\u5feb\u5149\u5b50\u7535\u5b50\u8f6c\u79fb\u65f6\u95f4\u9a8c\u8bc1\u3002\u8d85\u5feb\u901f\u77ac\u6001\u5438\u6536\u5149\u8c31\u8868\u660e\u950c\u7a7a\u4f4d\u6d53\u5ea6\u8d8a\u9ad8\uff0c\u901a\u8fc7\u8868\u9762\u5149\u7535\u538b\u8c31\u548cPL\u5149\u8c31\u5206\u6790\u8bc1\u5b9e\uff0c\u5176\u5e73\u5747\u6062\u590d\u5bff\u547d\u63d0\u9ad8\u4e86\u7ea61.7\u500d\uff0c\u8fd9\u786e\u4fdd\u4e86\u8f7d\u4f53\u5206\u79bb\u901f\u7387\u7684\u63d0\u9ad8\u3002\u7ed3\u679c\u8868\u660e\uff0c\u5177\u6709\u4e30\u5bcc\u7684\u950c\u7a7a\u4f4d\u7684\u5355\u7535\u6c60ZnIn2<\/sub>S4<\/sub>\u5c42\u7684\u4e00\u6c27\u5316\u78b3\u5f62\u6210\u901f\u7387\u4e3a33.2\u03bcmolg-1<\/sup> h-1<\/sup>\uff0c\u6bd4\u5355\u6676\u7845ZnIn2<\/sub>S4<\/sub>\u5c42\u5dee\u4e0d\u52303.6\uff05\u7a7a\u4f4d\uff0c\u800c\u524d\u8005\u7684\u5149\u50ac\u5316\u6d3b\u6027\u572824\u5c0f\u65f6\u5149\u50ac\u5316\u540e\u663e\u793a\u51fa\u53ef\u5ffd\u7565\u7684\u635f\u5931\u3002\u672c\u5de5\u4f5c\u63ed\u793a\u4e86\u7f3a\u9677\u5728\u539f\u5b50\u7ea7\u522b\u5f71\u54cd\u7535\u5b50-\u7a7a\u7a74\u5206\u79bb\u4e2d\u7684\u4f5c\u7528\uff0c\u4e3a\u5b9e\u73b0\u9ad8\u6548\u592a\u9633\u80fd\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u6027\u80fd\u5f00\u8f9f\u4e86\u65b0\u673a\u9047\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1\u00a0<\/strong>\u901a\u8fc7\u7b80\u5355\u76f4\u63a5\u7684\u6c34\u70ed\u8fc7\u7a0b\uff0c\u5177\u6709\u53ef\u8c03\u7f3a\u9677\u6d53\u5ea6\u7684\u5355\u4f4d\u5355\u5143<\/strong>ZnIn2<\/sub>S4<\/sub><\/strong>\u5c42<\/strong><\/p>\n

\"\"<\/p>\n

\uff08A-B\uff09HAADF-STEM\u56fe\u50cf\uff1b<\/p>\n

\uff08C\uff09\u5bf9\u5e94\u4e8eB\u4e2d\u7684\u6df1\u84dd\u8272\u7bad\u5934\u7684\u5f3a\u5ea6\u5206\u5e03\uff0c\u8868\u660e\u539f\u5b50\u5c42\u4e2d\u5b58\u5728\u5927\u91cf\u7684\u950c\u7a7a\u4f4d\uff1b<\/p>\n

\uff08D\uff09\u76f8\u5e94\u7684\u6676\u4f53\u7ed3\u6784\uff1b<\/p>\n

\uff08E\uff09SAED\u56fe\uff1b<\/p>\n

\uff08F\uff09AFM\u56fe\u50cf\u548c\uff08G\uff09\u76f8\u5e94\u7684\u9ad8\u5ea6\u5256\u9762\u56fe\uff1b<\/p>\n

\uff08H\uff09\u5bccVZn<\/sub>–<\/sup>\u548c\u5deeVZn<\/sub>–<\/sup>\u7684\u5355\u4f4d\u5355\u5143ZIS\u5c42\u7684EPR\u5149\u8c31\u3002<\/p>\n

\u56fe<\/strong>2 <\/strong>\u5149\u6fc0\u53d1\u7535\u5b50\u548c\u7a7a\u7a74\u5bf9\u7684\u5206\u79bb\u6548\u7387\u7684\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08A\uff09VZn<\/sub>–<\/sup>\u5bcc\u96c6\u7684\u5355\u4f4d\u5355\u5143ZIS\u5c42\uff1b<\/p>\n

\uff08B\uff09\u5deeVZn<\/sub>–<\/sup>\u7684\u5355\u4f4d\u5355\u5143ZIS\u5c42\u7684\u8d85\u5febTA\u5149\u8c31\u3002\u5728mOD\u4e2d\u7ed9\u51faTA\u4fe1\u53f7\uff08\u5373\uff0c\u5dee\u5206\u5438\u5149\u5ea6\u0394A\uff09\uff0c\u5176\u4e2dOD\u8868\u793a\u5149\u5bc6\u5ea6\uff1b<\/p>\n

\uff08C\uff09SPV\u5149\u8c31\uff1b<\/p>\n

\uff08D\uff09\u5355\u76f8\u5355\u5143ZIS\u5c42\u7684\u76f8\u5e94\u76f8\u4f4d\u8c31\uff1b<\/p>\n

\uff08E\uff09\u5355\u4f4d\u5355\u5143ZIS\u5c42\u7684\u5ba4\u6e29PL\u5149\u8c31\uff1b<\/p>\n

\uff08F\uff09\u6240\u6d89\u673a\u5236\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe<\/strong>3 <\/strong>\u5728<\/strong>300W Xe<\/strong>\u706f\u7167\u5c04\u4e0b\uff0c\u5bf9\u4e8e\u5bcc<\/strong>VZn<\/strong>\u548c<\/strong>VZn<\/strong>\u5dee\u7684\u5355\u4f4d\u5355\u5143<\/strong>ZIS<\/strong>\u5c42\uff0c<\/strong>CO2<\/sub><\/strong>\u8fd8\u539f<\/strong><\/p>\n

\"\"<\/p>\n

\uff08A\uff091\u5c0f\u65f6\uff0c\uff08A\uff09\u4e2d\u7684\u5d4c\u5165\u8868\u793a\u5bcc\u542bVZn<\/sub>–<\/sup>\u7684\u5355\u4f4d\u5355\u5143ZIS\u5c42\u768413<\/sup>CO2<\/sub>\u5149\u8fd8\u539f\u6c14\u76f8\u4ea7\u7269\u7684MS\u8c31\u3002<\/p>\n

\uff08B\uff091\uff0c2\uff0c4\uff0c8\uff0c12\uff0c16\uff0c20\u548c24\u5c0f\u65f6\u7684\u7a33\u5b9a\u6027\u8bd5\u9a8c\uff1b<\/p>\n

\uff08C\uff09\u5149\u50ac\u5316O2<\/sub>\u4ea7\u751f\uff1b<\/p>\n

\uff08D\uff09\u572824\u5c0f\u65f6\u5149\u50ac\u5316\u8bd5\u9a8c\u524d\u540e\u7684VZn-<\/sub>\u5bcc\u96c6\u548c\u5deeVZn-<\/sub>\u7684\u5355\u4f4d\u5355\u5143ZnIn2<\/sub>S4<\/sub>\u5c42\u7684K\u8fb9XANES\u5149\u8c31\uff0c\u548cZnO\u8fdb\u884c\u6bd4\u8f83\u3002<\/p>\n

\u56fe<\/strong>4\u00a0<\/strong>\u9650\u5236\u5728\u5355\u4f4d\u5355\u5143<\/strong>ZIS<\/strong>\u5c42\u4e2d\u7684\u950c\u7a7a\u4f4d\u7684\u4f18\u70b9<\/strong><\/p>\n

\"\"<\/p>\n

\uff08A\uff09\u7d2b\u5916-\u53ef\u89c1\u6f2b\u53cd\u5c04\u5149\u8c31\uff1b\uff08A\uff09\u4e2d\u7684\u63d2\u5165\u8868\u793a\u6240\u83b7\u5f97\u7684\u5bccVZn<\/sub>–<\/sup>\u548c\u5deeVZn<\/sub>–<\/sup>\u7684\u5355\u4f4d\u5355\u5143ZIS\u5c42\u7684\u5e26\u9699\uff1b<\/p>\n

\uff08B\uff09CO2<\/sub>\u5438\u9644\u7b49\u6e29\u7ebf\uff1b<\/p>\n

\uff08C\uff09\u5bccVZn<\/sub>–<\/sup>\u7684\u5355\u4f4d\u5355\u5143ZIS\u5c42\u7684\u9759\u6c34\u63a5\u89e6\u89d2\u6d4b\u91cf\uff1b<\/p>\n

\uff08D\uff09\u5deeVZn<\/sub>–<\/sup>\u7684\u5355\u4f4d\u5355\u5143ZIS\u5c42\u7684\u9759\u6c34\u63a5\u89e6\u89d2\u6d4b\u91cf\uff1b<\/p>\n

\uff08E\uff09\u57280.5M Na2<\/sub>SO4<\/sub>\u6c34\u6eb6\u6db2\u4e2d\u5bccVZn<\/sub>–<\/sup>\u548c\u5deeVZn<\/sub>–<\/sup>\u7684\u5355\u4f53\u7535\u6c60ZIS\u5c42\u7684\u7535\u5316\u5b66\u963b\u6297\u8c31\u3002<\/p>\n

\u56fe<\/strong>5 DFT<\/strong>\u8ba1\u7b97\u548c\u65b9\u6848<\/strong><\/p>\n

\"\"<\/p>\n

\uff08A\uff09\u5bccVZn<\/sub>–<\/sup>\u5355\u4f4d\u5355\u5143ZIS\u5c42\u677f\u7684\u5bfc\u5e26\u8fb9\u7f18\u9644\u8fd1\u7684\u90e8\u5206\u7535\u8377\u5bc6\u5ea6\u5206\u5e03\uff1b<\/p>\n

\uff08B\uff09\u6cbf[001]\u65b9\u5411\u7684\u5deeVZn<\/sub>–<\/sup>\u7684\u5355\u4f4d\u5355\u5143ZIS\u5c42\u677f\uff1b<\/p>\n

\uff08C\uff09VZn<\/sub>–<\/sup>\u5bcc\u96c6\u7684\u5355\u4f4d\u5355\u5143ZIS\u5c42\u677f\uff1b<\/p>\n

\uff08D\uff09\u5deeVZn<\/sub>–<\/sup>\u7684\u5355\u4f4d\u5355\u5143ZIS\u5c42\u6cbf\u7740[001]\u53d6\u5411\u7684\u76f8\u5e94\u5355\u5143\u7ed3\u6784\uff1b<\/p>\n

\uff08E\uff09\u5728\u5bcc\u542bVZn<\/sub>–<\/sup>\u7684\u5355\u4f53\u7535\u6c60ZIS\u5c42\u4e0a\u5c06CO2<\/sub>\u8fd8\u539f\u6210CO\u7684\u65b9\u6848\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u8be5\u7814\u7a76\u7ed3\u679c\u663e\u793a\u4e86\u6700\u521d\u5efa\u7acb\u4e86\u4e8c\u7ef4\u539f\u5b50\u5c42\u7684\u7406\u60f3\u6a21\u578b\uff0c\u5229\u7528HAADF-STEM\u56fe\u50cf\u76f4\u63a5\u62ab\u9732\u7f3a\u9677\u7c7b\u578b\u548c\u5206\u5e03\uff0c\u52aa\u529b\u63ed\u793a\u7f3a\u9677\u4f4d\u7f6e\u4e0e\u592a\u9633\u80fd\u4e8c\u6c27\u5316\u78b3\u51cf\u5c11\u4e4b\u95f4\u7684\u5173\u7cfb\u3002\u901a\u8fc7\u8c03\u6574\u53cd\u5e94\u6e29\u5ea6\uff0c\u6210\u529f\u5236\u4f5c\u4e86\u4e24\u4e2a\u5177\u6709\u5355\u4f4d\u7535\u6c60\u539a\u5ea6\u7684ZnIn2<\/sub>S4<\/sub>\u539f\u5b50\u5c42\u6837\u54c1\uff0c\u5176\u4e2dHAADF-STEM\u56fe\u50cf\uff0cEPR\u5149\u8c31\u548c\u6b63\u7535\u5b50\u6e6e\u6ca1\u5149\u8c31\u6cd5\u660e\u786e\u8868\u73b0\u51fa\u5176\u4e0d\u540c\u7684\u950c\u7a7a\u4f4d\u6d53\u5ea6\u3002DFT\u8ba1\u7b97\u8868\u660e\uff0c\u950c\u7a7a\u4f4d\u7684\u5b58\u5728\u8d4b\u4e88\u4e86\u589e\u52a0\u7684\u7535\u8377\u5bc6\u5ea6\u548c\u589e\u5f3a\u7684\u8f7d\u6d41\u5b50\u8fc1\u79fb\uff0c\u901a\u8fc7\u4eceZnIn2<\/sub>S4<\/sub>\u7684\u5bfc\u5e26\u5230\u9677\u9631\u6001\u7684\u301c15ps\u7684\u8d85\u5feb\u5149\u5b50\u7535\u5b50\u8f6c\u79fb\u65f6\u95f4\u9a8c\u8bc1\u3002\u6b64\u5916\uff0c\u8d85\u5feb\u901f\u77ac\u6001\u5438\u6536\u5149\u8c31\u516c\u5f0f\u8868\u660e\uff0c\u901a\u8fc7\u8868\u9762\u5149\u7535\u538b\u8c31\u548cPL\u5149\u8c31\u5206\u6790\u8bc1\u5b9e\uff0c\u8f83\u9ad8\u7684\u950c\u7a7a\u4f4d\u6d53\u5ea6\u5360\u89c2\u5bdf\u5230\u7684\u66f4\u9ad8\u6062\u590d\u5bff\u547d\u7684\u7ea61.7\u500d\uff0c\u8fd9\u6709\u5229\u4e8e\u5927\u5927\u4fc3\u8fdb\u8f7d\u4f53\u5206\u79bb\u6548\u7387\u3002\u6b64\u5916\uff0c\u8f83\u5927\u91cf\u7684\u950c\u7a7a\u4f4d\u8fd8\u5141\u8bb8\u589e\u52a0\u5149\u5438\u6536\uff0c\u66f4\u9ad8\u7684CO2<\/sub>\u5438\u9644\u80fd\u529b\u548c\u66f4\u5f3a\u7684\u8868\u9762\u4eb2\u6c34\u6027\u3002\u5728\u8fd9\u4e9b\u4f18\u70b9\u7684\u57fa\u7840\u4e0a\uff0c\u5bccVZn<\/sub>–<\/sup>\u5355\u76f8\u7535\u6c60ZnIn2<\/sub>S4<\/sub>\u5c42\u7684\u4e00\u6c27\u5316\u78b3\u5f62\u6210\u901f\u7387\u4e3a33.2\u03bcmolg-1<\/sup> h-1<\/sup>\uff0c\u6bd4\u5deeVZn<\/sub>–<\/sup>\u5355\u4f4d\u7535\u6c60\u9ad8\u4e00\u500d\u5de6\u53f3ZnIn2<\/sub>S4<\/sub>\u5c42\uff0c\u800c\u524d\u8005\u7684\u5149\u50ac\u5316\u6d3b\u6027\u572824h\u5149\u50ac\u5316\u540e\u663e\u793a\u51fa\u53ef\u5ffd\u7565\u7684\u635f\u5931\u3002\u7b80\u5355\u5730\u8bf4\uff0c\u8fd9\u9879\u7814\u7a76\u4e0d\u4ec5\u76f4\u63a5\u516c\u5f00\u4e86\u5728\u5355\u4e00\u5355\u4f4dZnIn2<\/sub>S4<\/sub>\u5c42\u4e2d\u950c\u7a7a\u4f4d\u7684\u5b58\u5728\uff0c\u800c\u4e14\u8fd8\u8868\u660e\u8fd9\u4e9b\u950c\u7a7a\u4f4d\u53ef\u4ee5\u5145\u5206\u4f18\u5316\u521d\u7ea7\u4e8c\u6c27\u5316\u78b3\u5149\u8fd8\u539f\u8fc7\u7a0b\uff0c\u4e3a\u5b9e\u73b0\u9ad8\u6548\u592a\u9633\u80fd\u71c3\u6599\u751f\u4ea7\u63d0\u4f9b\u4e86\u5de8\u5927\u524d\u666f\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a Defect-Mediated Electron\u2013Hole Separation in One-Unit-Cell ZnIn2S4 Layers for Boosted Solar-Driven CO2 Reduction<\/a><\/strong>\uff08JACS, 2017, DOI: 10.1021\/jacs.7b02290\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u7eb3\u7c73\u6750\u6599\u5b66\u672f\u7ec4\u575a\u6bc5\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406<\/strong>\u3002\u6b22\u8fce\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u7eb3\u7c73\u6750\u6599\u5b66\u672f\u4ea4\u6d41\u7fa4\uff08228686798\uff09\uff01<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u3002<\/a><\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790<\/strong>\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u5316\u77f3\u71c3\u6599\u8fc7\u5ea6\u5229\u7528\u9020\u6210\u7684\u4e8c\u6c27\u5316\u78b3\u6392\u653e\u91cf\u65e5\u76ca\u589e\u52a0\uff0c\u9020\u6210\u4e86\u5168\u7403\u73af\u5883\u53d8\u5316\u7684\u5de8\u5927\u53d8\u5316\uff0c\u6781\u5927\u5730\u963b\u788d\u4e86\u4eba\u7c7b\u793e\u4f1a\u7684\u53ef\u6301\u7eed\u53d1\u5c55\u3002\u5728\u8fd9\u79cd\u60c5\u51b5\u4e0b\uff0c\u5c06\u6e29\u5ba4\u6c14\u4f53\u4e8c\u6c27\u5316\u78b3\u8f6c\u5316\u4e3a\u53ef…<\/p>\n","protected":false},"author":3440,"featured_media":84516,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[54,981],"class_list":["post-84510","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-making","tag-test"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/84510"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/3440"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=84510"}],"version-history":[{"count":5,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/84510\/revisions"}],"predecessor-version":[{"id":85345,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/84510\/revisions\/85345"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/84516"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=84510"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=84510"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=84510"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}