{"id":85252,"date":"2017-06-11T06:30:27","date_gmt":"2017-06-10T22:30:27","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=85252"},"modified":"2017-06-11T19:45:00","modified_gmt":"2017-06-11T11:45:00","slug":"%e5%a4%8d%e6%97%a6%e9%95%bf%e6%98%a5%e5%ba%94%e5%8c%96%e6%89%80macromolecules-%ef%bc%9a%e5%85%89%e5%bc%95%e5%8f%91%e7%9a%84%e5%8e%9f%e4%bd%8d%e8%87%aa%e7%bb%84%e8%a3%85%ef%bc%88lisa%ef%bc%89%e6%9e%84","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=85252","title":{"rendered":"\u590d\u65e6&\u957f\u6625\u5e94\u5316\u6240Macromolecules \uff1a\u5149\u5f15\u53d1\u7684\u539f\u4f4d\u81ea\u7ec4\u88c5\uff08LISA\uff09\u6784\u5efa\u591a\u91cd\u5747\u805a\u7269"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong>
\n \u81f3\u4eca\uff0c\u51e0\u4e4e\u6240\u6709\u7684\u805a\u5408\u7269\u7eb3\u7c73\u7ed3\u6784\u90fd\u662f\u901a\u8fc7\u7ecf\u5178\u7684\u81ea\u7ec4\u88c5\u65b9\u6cd5\u6765\u5236\u5907\u7684\u3002\u6240\u4ee5\uff0c\u5bfb\u6c42\u65b0\u7684\u805a\u5408\u7269\u539f\u4f4d\u81ea\u7ec4\u88c5\u65b9\u5f0f\u975e\u5e38\u91cd\u8981\u4e14\u6781\u5177\u524d\u666f\u3002\u672c\u6587\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u63d0\u51fa\u4e86\u4e00\u79cd\u5149\u5f15\u53d1\u7684\u539f\u4f4d\u81ea\u7ec4\u88c5\u65b9\u6cd5\uff0c\u547d\u540d\u4e3aLISA\uff0c\u901a\u8fc7\u591a\u4e2a\u5747\u805a\u7269\u7684\u5149\u5f15\u53d1\uff0c\u4ece\u800c\u5f62\u6210\u5404\u79cd\u7eb3\u7c73\u7ed3\u6784\u3002\u8c03\u6574\u521d\u59cb\u7ec4\u5206\u6216\u5149\u53c2\u6570\uff0c\u53ef\u4ee5\u9884\u6d4b\u548c\u7ba1\u7406\u7cfb\u7edf\u7684\u5f62\u6001\u6f14\u5316\u3002 \u8fd9\u79cd\u65b9\u6cd5\u907f\u514d\u4e86\u805a\u5408\u81ea\u7ec4\u88c5\u65b9\u6cd5\u4e2d\u5d4c\u6bb5\u5171\u805a\u7269\u7e41\u7410\u7684\u5408\u6210\u548c\u6eb6\u6db2\u5904\u7406\u7a0b\u5e8f\u3002\u7814\u7a76\u4eba\u5458\u8ba4\u4e3a\uff0c\u8fd9\u79cd\u5149\u63a7\u539f\u4f4d\u81ea\u7ec4\u88c5\u65b9\u6cd5\u5c06\u4f1a\u5f00\u542f\u7531\u5747\u805a\u7269\u8f7b\u677e\u6784\u5efa\u9ad8\u9636\u7eb3\u7c73\u7ed3\u6784\u7684\u65b0\u7bc7\u7ae0\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u6700\u8fd1\uff0c\u805a\u5408\u5f15\u53d1\u7684\u81ea\u7ec4\u88c5\u914d\u65b9\uff08PISA\uff09\u5f00\u542f\u4e86\u539f\u4f4d\u5d4c\u6bb5\u5171\u805a\u7269\u81ea\u7ec4\u88c5\u7684\u65b0\u65f6\u4ee3\u3002\u5728\u805a\u5408\u8fc7\u7a0b\u4e2d\u83b7\u5f97\u4e0d\u540c\u7684\u7eb3\u7c73\u4f53\u7cfb\u662f\u552f\u4e00\u7684\u9014\u5f84\u3002\u8be5\u65b9\u6cd5\u7684\u673a\u7406\u662f\u57fa\u4e8e\u94fe\u589e\u957f\u548c\u80f6\u675f\u751f\u957f\u7684\u4e00\u81f4\u6027\uff0c\u7279\u522b\u9002\u7528\u4e8e\u4ece\u5355\u4f53\u5f15\u53d1\u7684\u805a\u5408\u7269\u81ea\u7ec4\u88c5\u4f53\u7cfb\uff0c\u4f46\u5904\u7406\u591a\u7ec4\u5206\u4f53\u7cfb\u7684\u8fc7\u7a0b\u5f88\u590d\u6742\u3002\u56e0\u6b64\uff0c\u63a2\u7d22\u5176\u5b83\u539f\u4f4d\u81ea\u7ec4\u88c5\u6280\u672f\u65b9\u6cd5\u5907\u53d7\u5173\u6ce8\u3002<\/p>\n

\u8fd1\u671f\uff0c\u6765\u81ea\u590d\u65e6\u5927\u5b66<\/strong>\u7684\u95eb\u5f3a<\/strong>\u548c\u957f\u6625\u5e94\u7528\u5316\u5b66\u7814\u7a76\u6240Jun Hu\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\u5728Macromolecules<\/strong>\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u5173\u4e8e\u539f\u4f4d\u81ea\u7ec4\u88c5\u65b0\u65b9\u6cd5\u7684\u6587\u7ae0\uff0c\u9898\u4e3a\u201cLight-Initiated in Situ Self-Assembly (LISA) from Multiple Homopolymers<\/strong>\u201d\u3002\u6587\u4e2d\u63cf\u8ff0\u4e86\u4e00\u79cd\u901a\u8fc7\u6b63\u4ea4\u5149\u5408\u4f5c\u7528\u4ea7\u751f\u805a\u5408\u7269\u7eb3\u7c73\u7ed3\u6784\u7684\u9ad8\u6548\u65b9\u6cd5\u3002\u8fd9\u79cd\u65b9\u6cd5\u53ef\u4ee5\u901a\u8fc7\u5149\u53cd\u5e94\u4ea7\u751f\u5177\u6709\u53ef\u8c03\u51e0\u4f55\u5f62\u72b6\u7684\u7eb3\u7c73\u5bf9\u8c61\u5e8f\u5217\u3002\u6b64\u5916\uff0c\u8c03\u6574\u521d\u59cb\u53c2\u6570\uff0c\u53ef\u4ee5\u9884\u6d4b\u4e09\u7ec4\u5206\u7cfb\u7edf\u7684\u76f8\u56fe\u5e76\u63a7\u5236\u5176\u52a8\u529b\u5b66\u5f62\u6001\u6f14\u5316\u3002\u9884\u8ba1\u8fd9\u79cd\u5149\u5f15\u53d1\u7684\u539f\u4f4d\u81ea\u7ec4\u88c5\uff08LISA\uff09\u4ec5\u901a\u8fc7\u4f7f\u7528\u7b80\u5355\u7684\u5747\u805a\u7269\u5c31\u53ef\u4ee5\u76f4\u63a5\u6784\u5efa\u590d\u6742\u7684\u7eb3\u7c73\u7ed3\u6784\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1 \u5f62\u6210\u5404\u79cd\u7eb3\u7c73\u805a\u5408\u7269\u7684\u65b9\u6848<\/strong><\/p>\n

\"\"<\/p>\n

a \u90bb\u7532\u57fa\u82ef\u7532\u919b\uff08MB\uff09\u548c\u9a6c\u6765\u9170\u4e9a\u80fa\uff08MI\uff09\u7684\u6b63\u4ea4\u5149\u5408\u53cd\u5e94\u793a\u610f\u56fe\u3002<\/p>\n

b \u4e09\u91cd\u5747\u805a\u7269\u7684\u539f\u4f4d\u81ea\u7ec4\u88c5\u3002<\/p>\n

\u56fe2 NMR\u548cGPC\u56fe\u8c31<\/strong><\/p>\n

\"\"<\/a><\/p>\n

\n a \u4f7f\u7528PEG-MB\uff08\u5e95\u7247\uff09\u548cPLA-MI\uff08\u9876\u56fe\uff09\u8fdb\u884c\u7684\u7167\u76f8\u7ed3\u5408\u76841H \u6838\u78c1\u5171\u632f\uff08NMR\uff09\u7814\u7a76\uff0c\u5f97\u5230\u5927\u5206\u5b50\u52a0\u6210\u7269\uff08PEG-b-PLA\uff0c\u4e2d\u95f4\u7247\uff09\u3002<\/p>\n

b \u805a\u4e59\u4e8c\u9187\uff08PEG-MB\uff09\uff0c\u805a\u4e73\u9178\uff08PLA-MI\uff09\u548c\u5149\u751fPEG-b-PLA\u7684\u51dd\u80f6\u6e17\u900f\u8272\u8c31\uff08GPC\uff09\u3002 \u5c06\u5177\u6709\u7b49\u6469\u5c14\u91cf\u7684PLA-MI\u7684PEG-MB\u66b4\u9732\u4e8e\u5927\u529f\u7387LED\u706f\uff08320nm\uff091\u5c0f\u65f6\u3002<\/p>\n

\u56fe3 \u8f7b\u5ea6\u53d8\u5316\u7684\u4e8c\u5143\u548c\u4e09\u5143\u5747\u805a\u7269\u7684\u539f\u4f4d\u81ea\u7ec4\u88c5TEM\u548cDLS\u56fe\u50cf<\/strong><\/p>\n

\"\"<\/a><\/p>\n

a PEG-MB \/ PLA-MI\u7cfb\u7edf\u7684\u7403\u4f53\u72b6\u7ed3\u6784\u3002<\/p>\n

b PEG-MB \/ PCL-MI\u7cfb\u7edf\u7684\u5355\u56ca\u6ce1\u819c\u72b6\u7ed3\u6784\u3002<\/p>\n

c \u6765\u81eaPEG-MB \/ PLA-MI \/ PCL-MI\u7cfb\u7edf\u7684\u8815\u866b\u72b6\u7ed3\u6784\u3002<\/p>\n

d \u4e09\u79cd\u7ed3\u6784\u7684\u6d41\u4f53\u52a8\u529b\u5b66\u76f4\u5f84\u3002<\/p>\n

\u56fe4 \u4e09\u5143\u5747\u805a\u7269\uff08PEG-MB \/PLA-MI \/ PCL-MI\uff09\u7684\u7ec4\u6210\u6bd4<\/strong><\/p>\n

\"\"<\/a><\/p>\n

r =nPCL-MI \/ nPLA-MI
\n a \u7403\u4f53\u548c\u8815\u866b\u72b6\uff08r = 0.05\uff09\u3002<\/p>\n

b\uff0cc \u7403\u4f53\u6570\u91cf\u51cf\u5c11\uff0c\u8815\u866b\u72b6\u6570\u91cf\u589e\u52a0\uff0c\u540c\u65f6\u8815\u866b\u72b6\u4ece\u77ed\u6746\u8f6c\u53d8\u4e3a\u957f\u7ea4\u7ef4\u5f62\u72b6\uff08r = 0.1\u548c0.2\uff09\u3002<\/p>\n

d \u7eaf\u8815\u866b\u72b6\u671f\uff08r = 1.0\uff09\u3002<\/p>\n

e \u8815\u866b\u72b6\u3001\u5c0f\u56ca\u6ce1\u72b6\u548c\u80f6\u675f\u72b6\u591a\u76f8\u72b6\u6001\uff08r = 5.0\uff09\u3002<\/p>\n

f \u4e92\u8054\u819c\u7ed3\u6784\uff08r = 10.0\uff09\u3002<\/p>\n

g \u65b0\u751f\u5c0f\u6ce1\uff08r= 20.0\uff09\uff08\u6bd4\u4f8b\u5c3a\u4e3a200nm\uff09\u3002<\/p>\n

h \u4e09\u7ec4\u5206\u5747\u805a\u7269\u5728\u6d53\u7f29\u6eb6\u6db2\u4e2d\uff0c\u5149\u5f15\u53d1\u539f\u4f4d\u81ea\u7ec4\u88c5\u76f8\u5bf9\u4e8e\u5747\u805a\u7269\u7684\u6469\u5c14\u6bd4\u548c\u5149\u6ce2\u957f\u7684\u53d8\u5316\u76f8\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u672c\u6587\u5c55\u793a\u4e86\u8f7b\u578b\u539f\u4f4d\u81ea\u7ec4\u88c5\uff08LISA\uff09\u7684\u7b2c\u4e00\u4e2a\u8303\u4f8b\u3002\u5b83\u53ef\u4ee5\u4f7f\u7b80\u5355\u7684\u5747\u805a\u7269\u901a\u8fc7\u5149\u5f15\u53d1\u5f62\u6210\u89c4\u5219\u7684\u7eb3\u7c73\u7ed3\u6784\u3002\u8bbe\u5b9a\u521d\u59cb\u7167\u7247\u548c\u7ec4\u5206\u56e0\u5b50\uff0c\u53ef\u4ee5\u9884\u6d4b\u5e76\u4e14\u53ef\u91cd\u590d\u83b7\u5f97\u5404\u79cd\u7eaf\u805a\u5408\u7269\u5f62\u6001\u3002\u4e0e\u57fa\u4e8e\u6d3b\u6027\u805a\u5408\u548c\u80f6\u675f\u751f\u957f\u540c\u6b65\u7684ISA\u76f8\u6bd4\uff0c\u8be5LISA\u65b9\u6cd5\u4f9d\u8d56\u4e8e\u4e0d\u540c\u7684\u5149\u5316\u5b66\u8026\u5408\u548c\u81ea\u7ec4\u88c5\u8fc7\u7a0b\u7684\u5e76\u884c\u673a\u7406\u3002\u8fd9\u79cd\u66ff\u4ee3\u65b9\u6cd5\u53ef\u4ee5\u89e3\u51b3\u540e\u81ea\u7ec4\u88c5\uff08\u5982\u6d53\u5ea6\u9650\u5236\u548c\u5d4c\u6bb5\u5171\u805a\u7269\u5408\u6210\uff09\u7684\u957f\u671f\u95ee\u9898\uff0c\u514b\u670d\u4e86\u591a\u91cd\u805a\u5408\u7269\u4f53\u7cfb\uff08PISA\uff09\u7684\u7f3a\u70b9\u3002\u4f46\u662f\uff0c\u8fd9\u79cd\u65b9\u6cd5\u56e0\u4e3a\u5176\u6eb6\u89e3\u6027\u5dee\uff0c\u96be\u4ee5\u5904\u7406\u9ad8\u5206\u5b50\u91cf\u7684\u5747\u805a\u7269\uff08> 50kDa\uff09\uff0c\u73b0\u6b63\u5728\u4f18\u5316\u8fd9\u4e2a\u95ee\u9898\u3002\u5c3d\u7ba1\u6709\u4e00\u4e9b\u7455\u75b5\uff0c\u8fd9\u79cd\u65b0\u7684\u65b9\u6cd5\u4ecd\u7136\u6307\u660e\u4e86\u53cd\u5e94\u8bf1\u5bfc\u539f\u4f4d\u81ea\u7ec4\u88c5\u65b9\u6cd5\u7684\u8d70\u5411\u8d8b\u52bf\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aMicroporous Polyamide Membranes for Molecular Sieving of Nitrogen from Volatile Organic Compounds<\/a><\/strong>\uff08Macromolecules \uff0c2017\uff0cDOI: 10.1021\/acs.macromol.7b00505\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u9ad8\u5206\u5b50\u5c0f\u7ec4\u6c34\u624b\u63d0\u4f9b\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002\u53c2\u4e0e\u9ad8\u5206\u5b50\u8bdd\u9898\u8ba8\u8bba\u6216\u4e86\u89e3\u9ad8\u5206\u5b50\u7ec4\u62db\u52df\u8be6\u60c5\uff0c\u8bf7\u52a0\u9ad8\u5206\u5b50\u4ea4\u6d41\u7fa4\uff08298064863\uff09\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a><\/strong>\uff01<\/p>\n

<\/p>\n

\u505a\u4e00\u4e2a\u7231\u5206\u4eab\u7684\u79d1\u7814\u4eba\uff0c\u8bf7\u5173\u6ce8\u5927\u5206\u5b50<\/span>\u516c\u4f17\u53f7\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u81f3\u4eca\uff0c\u51e0\u4e4e\u6240\u6709\u7684\u805a\u5408\u7269\u7eb3\u7c73\u7ed3\u6784\u90fd\u662f\u901a\u8fc7\u7ecf\u5178\u7684\u81ea\u7ec4\u88c5\u65b9\u6cd5\u6765\u5236\u5907\u7684\u3002\u6240\u4ee5\uff0c\u5bfb\u6c42\u65b0\u7684\u805a\u5408\u7269\u539f\u4f4d\u81ea\u7ec4\u88c5\u65b9\u5f0f\u975e\u5e38\u91cd\u8981\u4e14\u6781\u5177\u524d\u666f\u3002\u672c\u6587\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u63d0\u51fa\u4e86\u4e00\u79cd\u5149\u5f15\u53d1…<\/p>\n","protected":false},"author":24,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[42],"class_list":["post-85252","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-gaofenzi"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/85252"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/24"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=85252"}],"version-history":[{"count":6,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/85252\/revisions"}],"predecessor-version":[{"id":86214,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/85252\/revisions\/86214"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=85252"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=85252"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=85252"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}