{"id":87203,"date":"2017-06-20T06:30:47","date_gmt":"2017-06-19T22:30:47","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=87203"},"modified":"2017-06-19T17:22:18","modified_gmt":"2017-06-19T09:22:18","slug":"%e5%93%88%e5%b7%a5%e5%a4%a7%e9%82%b5%e8%b7%af%e5%9b%a2%e9%98%9fees%e5%b0%81%e9%9d%a2%e4%ba%8c%e6%b0%a7%e5%8c%96%e7%a2%b3%e6%8d%95%e9%9b%86%e5%8d%8a%e4%ba%92%e7%a9%bf%e7%bd%91%e7%bb%9c%e8%b6%85","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=87203","title":{"rendered":"\u54c8\u5de5\u5927\u90b5\u8def\u56e2\u961fEES\u5c01\u9762:\u4e8c\u6c27\u5316\u78b3\u6355\u96c6\u534a\u4e92\u7a7f\u7f51\u7edc\u8d85\u7ea7\u5206\u79bb\u819c"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n

\u76ee\u524d\u5316\u77f3\u71c3\u6599\u4f9d\u7136\u5728\u5168\u7403\u80fd\u6e90\u9886\u57df\u5360\u636e\u4e3b\u5bfc\u5730\u4f4d\uff0c\u5f00\u53d1\u5e76\u91c7\u7528\u5148\u8fdb\u7684\u6c14\u4f53\u5206\u79bb\u6280\u672f\u5927\u89c4\u6a21\u5730\u6355\u96c6CO2<\/sub>\u53ef\u4ee5\u6709\u6548\u964d\u4f4e\u78b3\u6392\u653e\uff0c\u4fc3\u8fdb\u6e05\u6d01\u80fd\u6e90\u53d1\u5c55\uff0c\u8fbe\u5230\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u76ee\u6807\u3002\u819c\u5206\u79bb\u6280\u672f\u662f\u76ee\u524d\u552f\u4e00\u4e00\u79cd\u6709\u671b\u5b9e\u73b0CO2<\/sub>\u9ad8\u6548\u5206\u79bb\u7684\u65b0\u578b\u4f4e\u78b3\u6280\u672f\uff0c\u5177\u6709\u80fd\u6548\u9ad8\u3001\u6613\u64cd\u4f5c\u3001\u6210\u672c\u4f4e\u548c\u73af\u5883\u53cb\u597d\u7b49\u4f18\u52bf\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u5177\u6709\u9ad8CO2<\/sub>\u6e17\u900f\u901a\u91cf\u548c\u9009\u62e9\u6027\u7684\u5206\u79bb\u819c\u6750\u6599\u5bf9\u586b\u8865\u76f8\u5173\u6280\u672f\u7a7a\u767d\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/span><\/p>\n

\u90b5\u8def\u8bfe\u9898\u7ec4\u901a\u8fc7\u5bf9\u4f20\u7edf\u6750\u6599\u7269\u7406\u5316\u5b66\u7ed3\u6784\u7684\u5408\u7406\u8bbe\u8ba1\uff0c\u91c7\u7528CO2<\/sub>\u4eb2\u548c\u6027\u7684\u805a\u6c27\u5316\u4e59\u70ef\uff08PEO\uff09\u884d\u751f\u6750\u6599\uff0c\u7ecf\u8fc7\u7b80\u5355\u7684\u7d2b\u5916\u8f90\u7167\u4e00\u6b65\u6cd5\uff0c\u5728\u81ea\u7531\u57fa\u805a\u5408\u5f62\u6210\u4ea4\u8054\u7f51\u7edc\u7684\u540c\u65f6\u5411\u4f53\u7cfb\u4e2d\u5f15\u5165\u4f4e\u5206\u5b50\u91cf\u7684\u805a\u6c27\u5316\u4e59\u70ef\u94fe\u6bb5\uff0c\u5236\u5907\u51fa\u4e86\u4e00\u79cd\u65b0\u578bCO2<\/sub>\u4eb2\u548c\u6027\u534a\u4e92\u7a7f\u7f51\u7edc\uff08SIPN\uff09\u5206\u79bb\u819c\u3002\u8be5\u534a\u4e92\u7a7f\u7f51\u7edc\u5206\u79bb\u819c\u662f\u7531\u7acb\u4f53\u7684\u805a\u6c27\u5316\u4e59\u70ef\u4ea4\u8054\u7f51\u7edc\u548c\u4f4e\u5206\u5b50\u91cf\u9ad8\u919a\u6c27\u542b\u91cf\u7684\u805a\u6c27\u5316\u4e59\u70ef\u884d\u751f\u5206\u5b50\u94fe\u7a7f\u63d2\u6784\u6210\u3002\u4f4e\u5206\u5b50\u91cf\u7684\u805a\u6c27\u5316\u4e59\u70ef\u94fe\u6bb5\u6709\u6548\u589e\u52a0\u4e86\u5206\u79bb\u819c\u7684\u81ea\u7531\u4f53\u79ef\u5c3a\u5bf8\u548cCO2<\/sub>\u4eb2\u548c\u6027\uff0c\u4fc3\u8fdb\u4e86CO2<\/sub> \u6c14\u4f53\u5206\u5b50\u5728\u819c\u4e2d\u7684\u4f20\u8f93\uff0c\u5728\u6781\u5927\u5730\u63d0\u9ad8\u4e86\u5206\u79bb\u819cCO2<\/sub>\u6e17\u900f\u901a\u91cf\u7684\u540c\u65f6\u5e76\u4fdd\u6301\u7740\u8f83\u9ad8\u7684\u9009\u62e9\u6027\u3002<\/p>\n

\u3010\u56fe\u7247\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n

\u56fe1. SIPN \u819c\u7684\u7ed3\u6784\uff0c\u6c14\u4f53\u5206\u79bb\u793a\u610f\uff0cFT-IR\u8868\u5f81<\/span><\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09SIPN\u7684\u5408\u6210\u8def\u7ebf\u53ca\u7406\u60f3\u7ed3\u6784<\/p>\n

\uff08b\uff09SIPN \u819c\u5206\u79bbCO2<\/sub>\/N2<\/sub>, CO2<\/sub>\/H2<\/sub>\u793a\u610f<\/p>\n

\uff08c\uff09PEG\u5355\u4f53\u548cSIPN\u7684\u7ea2\u5916\u8c31\u56fe<\/p>\n

\u56fe2. SIPN\u819cXPS\uff0c13<\/sup>CNMR\u8c31\u56fe\u53cafree volume radii\u548cfractional free volume\u8868\u5f81<\/strong><\/span><\/p>\n

\"\"<\/p>\n

\uff08a\uff09SIPN XPS C1s \u5206\u5cf0\u8c31\u56fe<\/p>\n

\uff08b\uff09SIPN free volume radii \u968fPEGDME\u542b\u91cf\u53d8\u5316<\/p>\n

\uff08c\uff09SIPN 13C NMR \u8868\u5f81<\/p>\n

\uff08d\uff09SIPN fractional free volume \u968fPEGDME\u542b\u91cf\u53d8\u5316<\/p>\n

\u56fe3. SIPN\u819c\u7684\u6c14\u4f53\u6e17\u900f\u901a\u91cf\u548c\u9009\u62e9\u6027\uff0c\u6eb6\u89e3\u7cfb\u6570\u548c\u6269\u6563\u7cfb\u6570\uff0c\u957f\u671f\u7a33\u5b9a\u6027\u6d4b\u8bd5<\/span><\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09SIPN\u819c\u7684\u6c14\u4f53\u901a\u91cf\u548c\u9009\u62e9\u6027\u968fPEGDME\u542b\u91cf\u7684\u53d8\u5316\u8d8b\u52bf<\/p>\n

\uff08b\uff09SIPN\u819c\u5bf9CO2\u7684\u6eb6\u89e3\u7cfb\u6570\u548c\u6269\u6563\u7cfb\u6570\u968fPEGDME\u542b\u91cf\u7684\u53d8\u5316\u8d8b\u52bf<\/p>\n

\uff08c\uff09SIPN-7-3-10 CO2<\/sub>\u901a\u91cf\u548c\u9009\u62e9\u6027\u7684\u957f\u671f\u7a33\u5b9a\u6027<\/p>\n

\u56fe4. SIPN\u819c\u5bf9CO2<\/sub>\/H2<\/sub> \u548c CO2<\/sub>\/N2<\/sub>\u6c14\u4f53\u5206\u79bb\u6027\u80fd\u4e0e2008 Robeson\u2019s upper bond \u5bf9\u6bd4<\/span><\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09SIPN CO2<\/sub>\/H2<\/sub> \u5206\u79bb\u6027\u80fd\u4e0eupper bond \u5bf9\u6bd4<\/p>\n

\uff08b\uff09SIPN CO2<\/sub>\/N2<\/sub> \u5206\u79bb\u6027\u80fd\u4e0eupper bond \u5bf9\u6bd4<\/p>\n

\u3010\u603b\u7ed3\u3011<\/span><\/strong><\/p>\n

\u672c\u6587\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u578bPEO\u7684\u534a\u4e92\u7a7f\u7f51\u7edc\u5206\u79bb\u819c\u8bbe\u8ba1\u65b9\u6cd5\uff0c\u7a81\u7834\u4f20\u7edf\u819c\u6750\u6599\u6e17\u900f\u901a\u91cf\u548c\u9009\u62e9\u6027\u4e4b\u95f4\u76f8\u4e92\u5236\u7ea6\u7684\u74f6\u9888\uff0c\u8fbe\u5230\u4e8c\u6c27\u5316\u78b3\u4eb2\u548c\u6027\u5206\u79bb\u819c\u76ee\u524d\u56fd\u9645\u6700\u9ad8\u6c34\u5e73\u3002\u8be5\u534a\u4e92\u7a7f\u7f51\u7edc\u5206\u79bb\u819c\u5236\u5907\u65b9\u6cd5\u6781\u5176\u7b80\u5355\u4e14\u7eff\u8272\u73af\u4fdd\uff0c\u65b0\u578b\u819c\u6750\u6599\u5177\u6709\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\uff0c\u6709\u671b\u4e0e\u76ee\u524d\u7684\u5de5\u4e1a\u5316\u751f\u4ea7\u8fc7\u7a0b\u5339\u914d\u3002\u8be5\u6210\u679c\u7684\u7814\u7a76\u601d\u8def\u4e3a\u5148\u8fdb\u819c\u6750\u6599\u5f00\u53d1\u53ca\u5176\u5728\u73af\u5883\u80fd\u6e90\u7b49\u9886\u57df\u7684\u5e94\u7528\u5efa\u7acb\u4e86\u9ad8\u6548\u7684\u8bbe\u8ba1\u8def\u5f84\u3002<\/p>\n

\u6587\u7ae0\u94fe\u63a5\uff1ahttp:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2017\/ee\/c6ee03566c#!divAbstract\uff08DOI\uff1a10.1039\/C6EE03566C<\/a>\uff08\u00a0Energy Environ. Sci., 2017,DOI:\u00a010.1039\/C6EE03566C\uff09<\/p>\n

\u90b5\u8def\u6559\u6388\u4e3b\u9875\uff1ahttp:\/\/www.polymer.cn\/ss\/shaolu\/index.html<\/a>\uff1b<\/p>\n

http:\/\/homepage.hit.edu.cn\/pages\/shaolu<\/a><\/p>\n

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\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e<\/strong>\u6750\u6599\u4eba<\/strong><\/a>\u3001\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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