{"id":88047,"date":"2017-06-24T06:30:06","date_gmt":"2017-06-23T22:30:06","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=88047"},"modified":"2017-06-23T15:15:15","modified_gmt":"2017-06-23T07:15:15","slug":"%e5%90%8c%e6%b5%8e%e5%a4%a7%e5%ad%a6%e6%9d%a8%e9%87%91%e8%99%8e%e6%95%99%e6%8e%88adv-mater-%ef%bc%9a%e9%94%82%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0%e8%b4%9f%e6%9e%81%e6%8a%97%e7%b2%89%e5%8c%96%e8%b6%85","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=88047","title":{"rendered":"\u540c\u6d4e\u5927\u5b66\u6768\u91d1\u864e\u6559\u6388Adv. Mater.\uff1a\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6297\u7c89\u5316\u8d85\u7ed3\u6784\u8bbe\u8ba1"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u9502\u79bb\u5b50\u7535\u6c60\u4f5c\u4e3a\u76ee\u524d\u4e3b\u8981\u7684\u50a8\u80fd\u6280\u672f\u4e4b\u4e00\uff0c\u4e3a\u65b0\u5174\u7684\u4fbf\u643a\u5f0f\u7535\u5b50\u8bbe\u5907\u548c\u7535\u52a8\u6c7d\u8f66\u63d0\u4f9b\u4e3b\u8981\u52a8\u529b\u3002\u4e3a\u4e86\u6ee1\u8db3\u5e02\u573a\u9700\u6c42\uff0c\u5f00\u53d1\u5177\u6709\u957f\u5faa\u73af\u5bff\u547d\u7684\u9ad8\u529f\u7387\uff0c\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u9502\u79bb\u5b50\u7535\u6c60\u8feb\u5728\u7709\u776b\u3002\u7136\u800c\uff0c\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u5728\u957f\u65f6\u95f4\u9502\u5316\/\u53bb\u9502\u5316\u8fc7\u7a0b\u4e2d\u4f34\u968f\u5de8\u5927\u4f53\u79ef\u53d8\u5316\uff0c\u5f15\u8d77\u6750\u6599\u7684\u4e25\u91cd\u7c89\u788e\uff0c\u5bfc\u81f4\u4e0d\u53ef\u9006\u5bb9\u91cf\u635f\u5931\u4ee5\u53ca\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u500d\u7387\u6027\u80fd\u53d8\u5dee\u3002\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e2a\u95ee\u9898\uff0c\u5728\u5927\u591a\u6570\u60c5\u51b5\u4e0b\uff0c\u91c7\u7528\u5bfc\u7535\u6027\u597d\uff0c\u673a\u68b0\u6027\u80fd\u4f18\u826f\u7684\u77f3\u58a8\u78b3\u4f5c\u4e3a\u8d1f\u6781\u6750\u6599\u7684\u67d4\u6027\u57fa\u4f53\uff0c\u4ee5\u63d0\u9ad8\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u3002\u7136\u800c\uff0c\u7531\u4e8e\u77f3\u58a8\u78b3\uff08~372 mAh g-1<\/sup>\uff09\u7684\u7406\u8bba\u5bb9\u91cf\u8f83\u4f4e\uff0c\u9ad8\u78b3\u542b\u91cf\uff08\u901a\u5e38\u5927\u4e8e30\uff05\uff09\u4f1a\u5bfc\u81f4\u5bb9\u91cf\u964d\u4f4e\uff0c\u4ece\u800c\u6781\u5927\u5730\u9650\u5236\u4e86\u5176\u5728\u7535\u52a8\u6c7d\u8f66\u4e2d\u7684\u5b9e\u9645\u5e94\u7528\u3002\u63d0\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u4e00\u4e2a\u6709\u6548\u65b9\u6cd5\u662f\u964d\u4f4e\u8d1f\u6781\u6750\u6599\u4e2d\u7684\u78b3\u542b\u91cf\u3002\u7136\u800c\uff0c\u6784\u7b51\u4f4e\u78b3\u542b\u91cf\u7684\u6297\u7c89\u5316\u8d1f\u6781\u6750\u6599\uff0c\u5bf9\u4e8e\u5f00\u53d1\u9ad8\u80fd\u91cf\u548c\u957f\u5bff\u547d\u7684\u9502\u79bb\u5b50\u7535\u6c60\u81f3\u5173\u91cd\u8981\uff0c\u4e5f\u6781\u5177\u6311\u6218\u3002<\/p>\n

\"\"<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u540c\u6d4e\u5927\u5b66\u6768\u91d1\u864e\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u590d\u65e6\u5927\u5b66\u5f6d\u6167\u80dc\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u5728\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\u6297\u7c89\u5316\u7814\u7a76\u4e2d\u53d6\u5f97\u4e86\u91cd\u8981\u8fdb\u5c55\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cAntipulverization Electrode Based on Low-Carbon Triple-Shelled Superstructures for Lithium-Ion Batteries<\/strong>\u201d\u4e3a\u9898\u5728\u7ebf\u53d1\u8868\u5728 Advanced Materials<\/em><\/strong>\uff08\u5f71\u54cd\u56e0\u5b50\u4e3a19.79\uff09\u4e0a\u3002\u8bba\u6587\u7b2c\u4e00\u4f5c\u8005\u4e3a\u540c\u6d4e\u5927\u5b66\u5316\u5b66\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u535a\u58eb\u7814\u7a76\u751f\u7956\u8fde\u6d77\uff0c\u53e6\u5916\u540c\u6d4e\u5927\u5b66\u535a\u58eb\u751f\u6731\u5cf0\uff0c\u9648\u70b3\u6770\u4e5f\u53c2\u4e0e\u4e86\u8be5\u8bfe\u9898\u7814\u7a76\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00<\/strong>. <\/strong>SnO2 <\/sub>TSHS<\/strong>\u548c<\/strong>DSHS<\/strong>\u5408\u6210\u8def\u7ebf\u53ca\u7ed3\u6784\u8868\u5f81\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

(a) SnO2<\/sub>\u53cc\u5c42\u7ed3\u6784(DSHSs)\u548c\u4e09\u5c42\u7ed3\u6784(TSHSs)\u7684\u5408\u6210\u8def\u7ebf<\/p>\n

(b) SnO2<\/sub> DSHSs\u626b\u63cf\u7535\u955c\u56fe<\/p>\n

(c-d) SnO2<\/sub> DSHSs\u900f\u5c04\u7535\u955c\u56fe\u7247\uff0c(d)\u63d2\u56fe\u4e3aSnO2<\/sub>@C\u7eb3\u7c73\u70b9\u9ad8\u5206\u8fa8\u900f\u5c04\u7535\u955c\u56fe<\/p>\n

(e) SnO2<\/sub> TSHSs\u626b\u63cf\u7535\u955c\u56fe<\/p>\n

(f-g) SnO2 TSHSs\u58f3\u5c42\u548c\u7eb3\u7c73\u68d2\u7684\u9ad8\u5206\u8fa8\u900f\u5c04\u7535\u955c\u56fe<\/p>\n

\u7814\u7a76\u8005\u91c7\u7528\u591a\u79cd\u7eb3\u7c73\u7ed3\u6784\u5355\u5143\uff08\u7eb3\u7c73\u70b9\uff0c\u7eb3\u7c73\u68d2\uff09\u9010\u5c42\u7ec4\u88c5\u6784\u6210\u7684\u5177\u6709\u4f4e\u78b3\u542b\u91cf\uff084.83%\uff09\u7684SnO2<\/sub>\u4e09\u58f3\u5c42\u4e2d\u7a7a\u7ed3\u6784\uff08TSHS\uff09\u53ef\u4ee5\u627f\u53d7231.8% \u7684\u5de8\u5927\u4f53\u79ef\u81a8\u80c0\uff0c\u5373\u4f7f\u57281450\u6b21\u5faa\u73af\u540e\u4ecd\u7136\u80fd\u63d0\u4f9b\u9ad8\u8fbe1099 mAh g-1<\/sup>\u53ef\u9006\u6bd4\u5bb9\u91cf\u3002\u529b\u5b66\u6a21\u62df\u548c\u539f\u4f4d\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\u8868\u660e\uff0cTSHS\u5728\u9502\u5316\/\u53bb\u9502\u5316\u65f6\u80fd\u591f\u5b9e\u73b0\u81ea\u534f\u540c\u7ed3\u6784\u4fdd\u62a4\u884c\u4e3a\u200b\u200b\uff0c\u4fdd\u62a4\u4e0a\u5c42\u7ed3\u6784\u4e0d\u4f1a\u5d29\u584c\uff0c\u5e76\u4fdd\u8bc1\u957f\u671f\u5faa\u73af\u671f\u95f4\u7535\u6781\u7684\u7ed3\u6784\u5b8c\u6574\u6027\u3002\u5177\u4f53\u6765\u8bf4\uff0c\u5728\u9502\u5316\u8fc7\u7a0b\u4e2d\u7684\u5916\u58f3\u5c42\u5b8c\u5168\u9502\u5316\uff0c\u9632\u6b62\u5185\u58f3\u5c42\u7684\u8fc7\u9502\u5316\u548c\u7ed3\u6784\u584c\u9677; \u53cd\u8fc7\u6765\uff0c\u5728\u53bb\u9502\u5316\u8fc7\u7a0b\u4e2d\uff0c\u672a\u8fc7\u9502\u5316\u7684\u5185\u58f3\u5c42\u4f5c\u4e3a\u575a\u56fa\u7684\u6838\u5fc3\uff0c\u4ee5\u652f\u6301\u5916\u58f3\u5c42\u7684\u5de8\u5927\u4f53\u79ef\u6536\u7f29;\u540c\u65f6\uff0c\u5177\u6709\u4e30\u5bcc\u5b54\u9699\u7684\u4e2d\u95f4\u58f3\u5c42\u5728\u9502\u5316\u548c\u53bb\u9502\u5316\u8fc7\u7a0b\u4e2d\u63d0\u4f9b\u8db3\u591f\u7684\u7a7a\u95f4\u6765\u9002\u5e94\u5916\u58f3\u5c42\u7684\u4f53\u79ef\u53d8\u5316\u3002\u8fd9\u9879\u7814\u7a76\u4e3a\u5f00\u53d1\u5b9e\u7528\u6027\u7684\u9ad8\u6027\u80fd\u9502\u79bb\u5b50\u7535\u6c60\u5f00\u8f9f\u4e86\u65b0\u7684\u9014\u5f84\u3002<\/p>\n

\u56fe<\/strong>2. <\/strong>SnO2<\/sub>TSHSs<\/strong>\u548c<\/strong>DSHSs<\/strong>\u7535\u6c60\u6027\u80fd\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

(a) SnO2<\/sub> DSHS\u548cTSHS\u7535\u6781\u57280.5 A g-1<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c0.05-2.5 V\u7535\u538b\u8303\u56f4\u5185\u7684\u5faa\u73af\u6027\u80fd<\/p>\n

(b) SnO2<\/sub> TSHS\u7535\u6781\u57280.5 A g-1<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u7b2c10\uff0c100\uff0c400\uff0c1000\uff0c\u548c1450\u5faa\u73af\u7684\u6052\u7535\u6d41\u5145\u653e\u7535\u66f2\u7ebf<\/p>\n

(c-d) SnO2<\/sub> DSHS\u548cTSHS\u7535\u6781\u7684\u500d\u7387\u6027\u80fd<\/p>\n

(e) SnO2<\/sub> TSHS\u9502\u79bb\u5b50\u7535\u6c60\u4e0e\u5176\u4ed6SnO2<\/sub>\u57fa\u7535\u6781\u6750\u6599\u7684\u6027\u80fd\u5bf9\u6bd4\u56fe<\/p>\n

\u56fe<\/strong>3. SnO2<\/sub> DSHS<\/strong>\u548c<\/strong>TSHS<\/strong>\u7ed3\u6784\u7a33\u5b9a\u6027\u7814\u7a76<\/strong><\/p>\n

\"\"<\/p>\n

(a) SnO2<\/sub> TSHS\u548cDSHS\u7535\u6781\u7ecf\u8fc71450\u5faa\u73af\u7684\u9502\u5316\/\u53bb\u9502\u5316\u793a\u610f\u56fe<\/p>\n

(b-e) SnO2<\/sub> TSHS\u548cDSHS\u7403\u7ecf\u8fc71450\u5faa\u73af\u540e\u7684\u900f\u5c04\u7535\u955c\u56fe<\/p>\n

(f) \u539f\u4f4d\u7535\u5316\u5b66\u900f\u5c04\u7535\u955c\u5de5\u4f5c\u793a\u610f\u56fe<\/p>\n

(g-h) SnO2<\/sub> TSHS\u548cDSHS\u7403\u5728\u539f\u4f4d\u900f\u5c04\u7535\u955c\u5185\u7684\u5145\u653e\u7535\u900f\u5c04\u7535\u955c\u56fe<\/p>\n

\u56fe<\/strong>4. SnO2<\/sub> TSHS<\/strong>\u9502\u5316\u8fc7\u7a0b\u4e2d\u7684\u529b\u5b66\u6a21\u62df\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

(a) SnO2<\/sub> TSHS\u5728\u9502\u5316\u65f6\u95f4\u4e3a0,120\u548c350s\u7684\u7ed3\u6784\u6f14\u53d8<\/p>\n

(b) SnO2<\/sub> TSHS\u4e09\u5c42\u7ed3\u6784\u7684\u529b\u5b66\u6f14\u53d8<\/p>\n

(c) SnO2<\/sub> TSHS\u5728\u4e0d\u540c\u9502\u5316\u65f6\u95f4\u7684\u73af\u5411\u5e94\u529b\u6f14\u53d8<\/p>\n

(d) \u7b2c\u4e00\u5c42\u7ed3\u6784\u7684\u6700\u5927\u62c9\u5e94\u529b-\u65f6\u95f4\u53d8\u5316\u66f2\u7ebf<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u4e3a\u7814\u7a76\u7a7a\u5fc3\/\u591a\u58f3\u5c42\u7ed3\u6784\u6750\u6599\u5728\u9502\u79bb\u5b50\u7535\u6c60\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u7684\u673a\u7406\uff0c\u672c\u7814\u7a76\u5efa\u7acb\u4e86\u4e00\u4e2a\u65b0\u7684\u6a21\u578b\u3002\u5728\u8be5\u6a21\u578b\u4e0b\uff0c\u65b0\u578b\u81ea\u534f\u540c\u7ed3\u6784\u4fdd\u6301\u7684\u6750\u6599\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7b56\u7565\uff0c\u5373\u4f7f\u7528\u65e0\u78b3\u8d1f\u6781\u6750\u6599\u6216\u4f4e\u78b3\u8d1f\u6781\u6750\u6599\u7684\u65b9\u6cd5\u5f00\u53d1\u9ad8\u80fd\u91cf\u3001\u957f\u5faa\u73af\u5bff\u547d\u548c\u9ad8\u529f\u7387\u7684\u9ad8\u6027\u80fd\u9502\u79bb\u5b50\u7535\u6c60\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aAntipulverization Electrode Based on Low-Carbon Triple-Shelled Superstructures for Lithium-Ion Batteries <\/a>\uff08Adv. Mater., 2017, DOI:\u00a010.1002\/adma.201701494\uff09<\/h4>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u9648\u70b3\u6770\u7f16\u8f91\uff0c\u5218\u5b87\u9f99\u5ba1\u6838\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u9502\u79bb\u5b50\u7535\u6c60\u4f5c\u4e3a\u76ee\u524d\u4e3b\u8981\u7684\u50a8\u80fd\u6280\u672f\u4e4b\u4e00\uff0c\u4e3a\u65b0\u5174\u7684\u4fbf\u643a\u5f0f\u7535\u5b50\u8bbe\u5907\u548c\u7535\u52a8\u6c7d\u8f66\u63d0\u4f9b\u4e3b\u8981\u52a8\u529b\u3002\u4e3a\u4e86\u6ee1\u8db3\u5e02\u573a\u9700\u6c42\uff0c\u5f00\u53d1\u5177\u6709\u957f\u5faa\u73af\u5bff\u547d\u7684\u9ad8\u529f\u7387\uff0c\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u9502\u79bb\u5b50\u7535…<\/p>\n","protected":false},"author":230,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[1698],"class_list":["post-88047","post","type-post","status-publish","format-standard","hentry","category-keji","tag-1698"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/88047"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/230"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=88047"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/88047\/revisions"}],"predecessor-version":[{"id":88112,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/88047\/revisions\/88112"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=88047"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=88047"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=88047"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}