{"id":88329,"date":"2017-06-29T06:30:09","date_gmt":"2017-06-28T22:30:09","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=88329"},"modified":"2017-06-29T09:35:33","modified_gmt":"2017-06-29T01:35:33","slug":"%e3%80%90%e6%8a%95%e7%a8%bf%e5%be%85%e5%ae%9a%e3%80%91%e5%8d%8e%e5%8d%97%e5%b8%88%e8%8c%83%e5%a4%a7%e5%ad%a6%e5%a4%a7%e5%ad%a6%e6%9d%8e%e4%bc%9f%e5%96%84adv-mater-%ef%bc%9a%e4%bb%8e%e5%89%8d%e9%a9%b1","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=88329","title":{"rendered":"\u534e\u5357\u5e08\u8303\u5927\u5b66\u674e\u4f1f\u5584Adv. Mater.\uff1a\u4ece\u524d\u9a71\u4f53\u5f62\u8c8c\u8f6c\u5316\u6d45\u6de1\u91d1\u5c5e\u57fa\u591a\u7ea7\u591a\u5b54\u7ed3\u6784\u7684\u5408\u6210\u53ca\u5e94\u7528"},"content":{"rendered":"

1. \u5f15\u8a00<\/strong><\/span><\/p>\n

\u591a\u7ea7\u591a\u5b54\u7ed3\u6784\u6750\u6599\u56e0\u5176\u5177\u6709\u5982\u4e0b\u7279\u70b9\u88ab\u5e7f\u6cdb\u5730\u5e94\u7528\u4e8e\u80fd\u6e90\u5b58\u50a8\u4e0e\u8f6c\u6362\u9886\u57df\uff1a<\/p>\n

\uff081\uff09\u53ef\u6709\u6548\u5730\u907f\u514d\u7eb3\u7c73\u9897\u7c92\u95f4\u7684\u56e2\u805a\uff0c\u964d\u4f4e\u6750\u6599\u754c\u9762\u7684\u754c\u9762\u5f20\u529b\uff1b<\/p>\n

\uff082\uff09\u76f8\u8f83\u4e8e\u5927\u9897\u7c92\u56e2\u805a\u4f53\u53ef\u63d0\u4f9b\u66f4\u591a\u7684\u53cd\u5e94\u6d3b\u6027\u4f4d\u70b9\uff0c\u51cf\u5c11\u79bb\u5b50\u7684\u8fc1\u79fb\u8ddd\u79bb\uff1b<\/p>\n

\uff083\uff09\u6709\u5229\u4e8e\u7535\u89e3\u6db2\u7684\u6d78\u6da6\uff0c\u63d0\u4f9b\u66f4\u591a\u7684\u4f53\u79ef\u81a8\u80c0\u7f13\u51b2\u7a7a\u95f4\uff1b<\/p>\n

\uff084\uff09\u52a0\u5f3a\u5149\u6563\u8272<\/p>\n

\u591a\u7ea7\u591a\u5b54\u6750\u6599\u662f\u6307\u7531\u4e00\u4e9b\u5c0f\u7684\u6b21\u7ea7\u9897\u7c92\u901a\u8fc7\u4e00\u5b9a\u7684\u65b9\u5f0f\u7ec4\u6210\u7684\u591a\u7ea7\u9897\u7c92\uff0c\u6b21\u7ea7\u9897\u7c92\u5305\u542b\u96f6\u7ef4\u7684\u7eb3\u7c73\u9897\u7c92\uff0c\u4e00\u7ef4\u7684\u7eb3\u7c73\u7ebf\u3001\u7eb3\u7c73\u5e26\u3001\u7eb3\u7c73\u68d2\uff0c\u4e8c\u7ef4\u7684\u7eb3\u7c73\u7247\u7b49\uff0c\u5b54\u5f84\u5206\u5e03\u901a\u5e38\u5728\u5c0f\u4e8e2nm\u52302-50nm\u53ca\u5927\u4e8e50nm \u95f4\u3002\u6545\u6750\u6599\u7684\u5927\u5c0f\u3001\u5c3a\u5bf8\u3001\u5f62\u8c8c\u3001\u5b54\u5f84\u53ca\u5bc6\u5ea6\u901a\u5e38\u5f71\u54cd\u6750\u6599\u7684\u6027\u80fd\u3002\u5982\u4f55\u53ef\u63a7\u5730\u5236\u5907\u51fa\u591a\u7ea7\u591a\u5b54\u6750\u6599\u6210\u4e3a\u4eba\u4eec\u5173\u6ce8\u7684\u91cd\u70b9\u3002\u4ee5\u524d\uff0c\u4eba\u4eec\u901a\u5e38\u4f7f\u7528\u7684\u662f\u6a21\u677f\u6cd5\u3001\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\u3001\u9759\u7535\u7eba\u4e1d\u6cd5\u7b49\u3002\u4f46\u7531\u4e8e\u6a21\u677f\u6cd5\u7684\u5236\u5907\u5de5\u827a\u8f83\u590d\u6742\uff0c\u6d89\u53ca\u53bb\u6a21\u677f\u7b49\u7e41\u7410\u6b65\u9aa4\uff0c\u5de5\u827a\u8017\u80fd\u8f83\u5927\u3002\u9759\u7535\u7eba\u4e1d\u6cd5\u901a\u5e38\u91c7\u7528\u9ad8\u538b\u9759\u7535\uff0c\u6761\u4ef6\u82db\u523b\u4e0d\u9002\u5b9c\u5927\u89c4\u6a21\u751f\u4ea7\u3002\u800c\u91c7\u7528\u5f62\u8c8c\u8f6c\u5316\u7406\u8bba\u53ef\u7b80\u5355\u7684\u5b9e\u73b0\uff0c\u5176\u6b65\u9aa4\u901a\u5e38\u6d89\u53ca2\u6b65\uff1a1\uff09\u524d\u9a71\u4f53\u7684\u5408\u6210\uff1b2\uff09\u524d\u9a71\u4f53\u5411\u76ee\u6807\u4ea7\u7269\u7684\u8f6c\u5316\u3002<\/p>\n

\u8fd1\u65e5\uff0c\u6765\u81ea\u534e\u5357\u5e08\u8303\u5927\u5b66\u5927\u5b66\u7684\u674e\u4f1f\u5584\u6559\u6388\u548c\u534e\u5357\u7406\u5de5\u5927\u5b66\u7684\u4e18\u52c7\u624d\u6559\u6388\uff0c\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u7684\u6768\u4e16\u548c\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\uff09\u7b49\u4eba\u7efc\u8ff0\u4e86\u4e00\u79cd\u4ece\u524d\u9a71\u4f53\u51fa\u53d1\u5236\u5907\u591a\u7ea7\u591a\u5b54\u7ed3\u6784\u7684\u6750\u6599\u7684\u7406\u8bba\u5e76\u4ee5\u201cMorphology-Conserved Transformations of Metal-Based Precursors to Hierarchically Porous Micro-\/Nanostructures for Electrochemical Energy Conversion and Storage\u201d\u4e3a\u9898\u53d1\u8868\u5728Adv. Mater.\u4e0a\u3002\u8be5\u6587\u91cd\u70b9\u7efc\u8ff0\u4e86\u51e0\u7c7b\u91cd\u8981\u7684\u524d\u9a71\u4f53\uff1a\u91d1\u5c5e\u6c22\u6c27\u5316\u7269\u524d\u9a71\u4f53\uff08Metal Hydroxide Precursors\uff09\u3001\u91d1\u5c5e\u78b3\u9178\u76d0\u524d\u9a71\u4f53\uff08Metal Carbonate Precursors\uff09\u3001\u91d1\u5c5e\u6c22\u6c27\u78b3\u9178\u76d0\u524d\u9a71\u4f53\uff08Metal Carbonate Hydroxide Precursors\uff09\u3001\u6709\u673a\u91d1\u5c5e\u6846\u67b6\u524d\u9a71\u4f53\uff08MOF Precursors\uff09\u53ca\u5176\u8f6c\u5316\u540e\u7684\u591a\u7ea7\u591a\u5b54\u6750\u6599\u5728\u9502\u79bb\u5b50\u7535\u6c60\u6b63\u8d1f\u6781\u6750\u6599\u3001\u8d85\u7ea7\u7535\u5bb9\u5668\u7535\u6781\u6750\u6599\u3001\u9502\u786b\u56fa\u786b\u6750\u6599\u3001\u9502\u7a7a\u6c14\u7535\u6c60\u7535\u6781\u50ac\u5316\u5242\u3001\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u7b49\u65b9\u9762\u7684\u5e94\u7528\u3002\u6700\u540e\u63d0\u51fa\u5408\u6210\u53ca\u5e94\u7528\u591a\u7ea7\u591a\u5b54\u6240\u9047\u7684\u6311\u6218\u4e0e\u5c55\u671b\u3002<\/p>\n

\"\"<\/p>\n

\u56fe1\uff1a\u7efc\u8ff0\u603b\u89c8\u56fe<\/strong><\/p>\n

2.<\/strong>\u51e0\u7c7b\u91cd\u8981\u7684\u524d\u9a71\u4f53<\/strong><\/span><\/p>\n

2.1<\/strong>\u91d1\u5c5e\u6c22\u6c27\u5316\u7269\u524d\u9a71\u4f53<\/strong><\/p>\n

\u5e38\u89c1\u7684\u6c22\u6c27\u5316\u7269\u524d\u9a71\u4f53\u6709Mn(OH)2<\/sub>, Co(OH)2<\/sub>, Ni(OH)2<\/sub>, Sn(OH)2<\/sub>, Ce(OH)2<\/sub>, La(OH)3<\/sub>, In(OH)3<\/sub>, Y(OH)3<\/sub>, \u548c Ni-Co \u53cc\u91d1\u5c5e\u6c22\u6c27\u5316\u7269\u7b49\u3002\u91d1\u5c5e\u6c22\u6c27\u5316\u7269\u524d\u9a71\u4f53\u7684\u5236\u5907\u5e38\u6d89\u53ca\u5230\u91d1\u5c5e\u79bb\u5b50\u4e0e\u6c22\u6c27\u6839\u7684\u53cd\u5e94\uff0c\u5e38\u89c1\u7684\u6c22\u6c27\u6839\u7531NaOH\u63d0\u4f9b\u3002\u5728\u6709\u4e9b\u53cd\u5e94\u4e2d\u6c22\u6c27\u6839\u7531\u6c28\u6c34\uff0c\u5c3f\u7d20\u6216\u5f31\u9178\u76d0\u7684\u81ea\u8eab\u6c34\u89e3\u63d0\u4f9b\u3002\u7531\u5c3f\u7d20\u63d0\u4f9b\u65f6\u5e38\u4f34\u6709\u5982\u4e0b\u4e24\u6b65\u53cd\u5e94\uff1a<\/p>\n

CO(NH2<\/sub>)2<\/sub> + 2H2<\/sub>O \u2192 2NH3<\/sub> +CO2 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0\u00a0<\/sub>(1)<\/p>\n

M1<\/sub>x+<\/sup> + x NH3<\/sub> + x H2<\/sub>O \u2192 M1<\/sub>(OH)x<\/sub> + xNH4<\/sub>+\u00a0\u00a0 <\/sup>(2)<\/p>\n

\uff08M=\u91d1\u5c5e\u79bb\u5b50\uff09
\n \u7531\u5f31\u9178\u76d0\u81ea\u8eab\u6c34\u89e3\u7684\u53cd\u5e94\u6b65\u9aa4\u5982\u4e0b\uff1a<\/p>\n

M2<\/sub>(Ac)y<\/sub>+ yH2<\/sub>O \u2192 yHAc + M2<\/sub>y+<\/sup> + yOH–\u00a0\u00a0\u00a0\u00a0\u00a0 <\/sup>(3)<\/p>\n

M2<\/sub>y+<\/sup> + yOH–<\/sup> \u2192 M2<\/sub>(OH)y \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0<\/sub>(4)<\/p>\n

\u751f\u6210\u7684\u6c22\u6c27\u5316\u7269\u524d\u9a71\u4f53\u5728\u7a7a\u6c14\u6216\u8005\u5176\u4ed6\u6c14\u6c1b\u4e2d\u70e7\u7ed3\u53ef\u8f6c\u5316\u4e3a\u591a\u7ea7\u591a\u5b54\u7684\u76ee\u6807\u4ea7\u7269\u3002<\/p>\n

2.2<\/strong>\u91d1\u5c5e\u78b3\u9178\u76d0\u524d\u9a71\u4f53<\/strong><\/p>\n

\u78b3\u9178\u76d0\u524d\u9a71\u4f53\u4e5f\u662f\u5e38\u89c1\u7684\u524d\u9a71\u4f53\uff0c\u5982\u78b3\u9178\u9530\uff0c\u78b3\u9178\u94b4\uff0cCo-Mn\u53cc\u91d1\u5c5e\u78b3\u9178\u76d0\u7b49\u3002\u7c7b\u4f3c\u6c22\u6c27\u5316\u7269\uff0c\u91d1\u5c5e\u78b3\u9178\u76d0\u524d\u9a71\u4f53\u5e38\u7531\u91d1\u5c5e\u79bb\u5b50\u4e0e\u78b3\u9178\u6839\u53cd\u5e94\u5f97\u5230\u3002\u901a\u5e38\u7528\u6765\u63d0\u4f9b\u78b3\u9178\u6839\u7684\u6709\u65e0\u673a\u7c7b\u7684NH4<\/sub>HCO3<\/sub>\u548cNa2<\/sub>CO3<\/sub>\uff0c\u6709\u673a\u7c7b\u7684\u5c3f\u7d20\uff0c\u9187\u7f9f\u57fa\u7684\u6c27\u5316\u7b49\u3002<\/p>\n

\u4ee5\u591a\u5143\u9187\u5728\u5f3a\u6c27\u5316\u5242KMnO4<\/sub>\u6761\u4ef6\u4e0b\u88ab\u6c27\u5316\u4e3a\u4f8b\uff0c\u5176\u53cd\u5e94\u5e38\u6d89\u53ca\uff1a<\/p>\n

4R\u2013CH2<\/sub>OH + MnO4<\/sub>–<\/sup>\u2192MnOOH + 4R\u2013CHO + OH–<\/sup> +H2<\/sub>O\u00a0\u00a0 (5)<\/p>\n

R\u2013CHO + MnO4<\/sub>–<\/sup>\u2192MnOOH + R\u2013COO–<\/sup> +H2<\/sub>O\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (6)<\/p>\n

5R\u2013COO–<\/sup> + 2MnO4<\/sub>–<\/sup> +6H+<\/sup>\u2192 2Mn2+<\/sup>+ 5CO2<\/sub> +8H2<\/sub>O\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (7)<\/p>\n

CO2<\/sub> +H2<\/sub>O \u2192 2H+<\/sup> +CO3<\/sub>2-<\/sup>\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (8)<\/p>\n

Mn2+<\/sup> +CO3<\/sub>2-<\/sup>\u2192 MnCO3<\/sub>\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (9)<\/p>\n

\u540e\u5bf9\u5408\u6210\u7684\u78b3\u9178\u524d\u9a71\u4f53\u8fdb\u884c\u4e00\u4e9b\u5904\u7406\uff0c\u53ef\u5f97\u5230\u4e00\u4e9b\u7279\u6b8a\u5f62\u8c8c\u7684\u591a\u5b54\u6750\u6599\u3002\u4f8b\u5982MnCO3<\/sub>\u5728KMnO4<\/sub>\u7684\u5904\u7406\u4e0b\u53ef\u5f97\u5230\u4e00\u4e9b\u4e2d\u7a7a\u7684\u6750\u6599\uff0c\u673a\u7406\u5982\u4e0b\uff1a<\/p>\n

3MnCO3<\/sub> +2KMnO4<\/sub> \u2192 5MnO2<\/sub> + K2<\/sub>CO3<\/sub> + 2CO2 <\/sub>\u00a0\u00a0(10)<\/p>\n

\u518d\u8005\uff0c\u4ee5\u5c3f\u7d20\u4e3a\u78b3\u9178\u6839\u6e90\u5408\u6210Co3<\/sub>O4<\/sub>\u5e38\u6d89\u53ca\u5982\u4e0b\u6b65\u9aa4\uff1a<\/p>\n

CO(NH2<\/sub>)2<\/sub> + 3H2<\/sub>O \u2192 2NH4+<\/sup> + CO2<\/sub> + 2OH–<\/sup>\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (11)<\/p>\n

2NH4+<\/sup> + CO2<\/sub> +2OH–<\/sup> \u2192 2NH4+<\/sup> + CO3<\/sub>2 –<\/sup> + H2<\/sub>O\u00a0\u00a0\u00a0\u00a0\u00a0 (12)<\/p>\n

Co2+<\/sup> + CO3<\/sub>2 –<\/sup>\u2192 CoCO3 <\/sub>\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0(13)<\/p>\n

6CoCO3 <\/sub>+ O2<\/sub> \u2192 2Co3<\/sub>O4<\/sub> + 6CO2\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 <\/sub>(14)<\/p>\n

\u5728\u6c34\u70ed\u6761\u4ef6\u4e0b\uff0c\u9996\u5148CO(NH2<\/sub>)2<\/sub>\u70ed\u89e3\u6210NH4+<\/sup>\uff0c CO2<\/sub>\u548cOH–<\/sup>\uff0c\u7136\u540e\u5728OH–<\/sup>\u7684\u4f5c\u7528\u4e0bNH4+<\/sup>\u548c CO2<\/sub>\u751f\u6210\u78b3\u9178\u6839\u79bb\u5b50\uff0c\u7d27\u63a5\u7740\u751f\u6210\u7684CO3<\/sub>2 \u2013<\/sup>\u4e0e\u6eb6\u6db2\u4e2d\u7684\u91d1\u5c5e\u79bb\u5b50\u7ed3\u5408\u751f\u6210\u78b3\u9178\u76d0\u524d\u9a71\u4f53\uff0c\u8fd9\u91cc\u6d89\u53ca\u5230\u78b3\u9178\u76d0\u7684\u751f\u6210\u6eb6\u89e3\u4e0e\u7ed3\u5408\uff0c\u6b64\u8fc7\u7a0b\u6b63\u597d\u53ef\u63d0\u4f9b\u65f6\u95f4\u4fbf\u4e8e\u6750\u6599\u8fdb\u884c\u81ea\u7ec4\u88c5\u3002<\/p>\n

\"\"<\/p>\n

\u56fe2\uff1a\u78b3\u9178\u76d0\u5408\u6210\u53ca\u8f6c\u5316\u4e3a\u76ee\u6807\u4ea7\u7269\u7684\u8fc7\u7a0b\u56fe<\/strong><\/p>\n

\u6b64\u5916\uff0c\u5728\u751f\u6210\u7684\u78b3\u9178\u76d0\u524d\u9a71\u4f53\u7684\u57fa\u7840\u4e0a\uff0c\u53ef\u901a\u8fc7\u63a7\u5236\u6750\u6599\u7684\u70e7\u7ed3\u6b65\u9aa4\u5b9e\u73b0\u591a\u7ea7\u7ed3\u6784\uff0c\u5982\u674e\u4f1f\u5584\u8bfe\u9898\u7ec4\u901a\u8fc7\u63a7\u5236\u7acb\u65b9\u4f53\u72b6MnCO3<\/sub>\u7684\u7a0b\u5e8f\u5347\u6e29\u53ef\u5f97\u5230\u4e09\u5c42\u591a\u5b54\u7ed3\u6784\u7684Mn2<\/sub>O3<\/sub>\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3\uff1aMn2<\/sub>O3<\/sub>\u901a\u8fc7MnCO3<\/sub>\u8f6c\u5316\u7684\u5f62\u6210\u793a\u610f\u56fe<\/strong><\/p>\n

2.3<\/strong>\u91d1\u5c5e\u6c22\u6c27\u78b3\u9178\u76d0\u524d\u9a71\u4f53<\/strong><\/p>\n

\u76f8\u8f83\u4e8e\u524d\u4e24\u79cd\u524d\u9a71\u4f53\uff0c\u91d1\u5c5e\u6c22\u6c27\u78b3\u9178\u76d0\u524d\u9a71\u4f53\u7684\u79cd\u7c7b\u5c31\u4e0d\u90a3\u4e48\u591a\u4e86\uff0c\u4e3b\u8981\u96c6\u4e2d\u5728\u8fc7\u6e21\u91d1\u5c5eZn, Mn, Co, Ni\u4e0a\u3002\u5176\u4e2dZn\u53ef\u5f62\u6210\u4e24\u79cd\u5e38\u89c1\u7684\u6c22\u6c27\u78b3\u9178\u76d0\uff0c\u5f62\u6210\u8fc7\u7a0b\u5982\u4e0b\u56fe\u6240\u793a\uff1a<\/p>\n

5Zn2+<\/sup> + 6OH–<\/sup> + 2CO3<\/sub>2-<\/sup> \u2192 Zn5<\/sub>(CO3<\/sub>)2<\/sub>(OH)6<\/sub>\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (15)<\/p>\n

4Zn2+<\/sup> + 6OH–<\/sup> + CO3<\/sub>2-<\/sup> + xH2<\/sub>O \u2192 Zn4<\/sub>(CO3<\/sub>)(OH)6<\/sub>\u00b7xH2<\/sub>O (x= 0\u6216 1)\u00a0\u00a0\u00a0 (16)<\/p>\n

\u6700\u540e\u6c22\u6c27\u78b3\u9178\u950c\u5206\u89e3\u751f\u6210\u6c27\u5316\u950c<\/p>\n

Znx<\/sub>(CO3<\/sub>)y<\/sub>(OH)6<\/sub>\u00b7zH2<\/sub>O \u2192 xZnO + yCO2<\/sub>\u2191+(z+3)H2<\/sub>O\u2191\u00a0\u00a0\u00a0\u00a0 (17)<\/p>\n

\"\"<\/p>\n

\u56fe4\uff1a\u4e24\u79cd\u4e0d\u540c\u6c22\u6c27\u78b3\u9178\u950c\u524d\u9a71\u4f53\u7684\u5f62\u6210\u53ca\u8f6c\u5316\u8fc7\u7a0b<\/strong><\/p>\n

2.4<\/strong>\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u524d\u9a71\u4f53<\/strong><\/p>\n

\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u524d\u9a71\u4f53\u53ef\u6839\u636e\u5176\u914d\u4f53\u7684\u5f62\u5f0f\u7b80\u5355\u7684\u5212\u5206\u4e3a\u91d1\u5c5e\u7fa7\u57fa\u914d\u5408\u7269\u3001\u91d1\u5c5e\u7f9f\u57fa\u4e59\u9178\u914d\u5408\u7269\u3001\u91d1\u5c5e\u9187\u76d0\u914d\u5408\u7269\u3001\u91d1\u5c5e\u4e59\u4e8c\u9187\u914d\u5408\u7269\u3001\u666e\u9c81\u58eb\u84dd\u914d\u5408\u3001\u91d1\u5c5e\u54aa\u5511\u57fa\u6216\u54cc\u5576\u57fa\u914d\u5408\u7269\u3002<\/p>\n

2.4.1<\/strong>\u91d1\u5c5e\u7fa7\u57fa\u914d\u5408\u7269<\/strong><\/p>\n

\u91d1\u5c5e\u7fa7\u57fa\u914d\u5408\u7269\uff0c\u53ef\u6839\u636e\u7fa7\u57fa\u7684\u4e2a\u6570\u5206\u4e3a\u5355\u7fa7\u57fa\u914d\u5408\u7269\uff0c\u4e8c\u7fa7\u57fa\u914d\u5408\u7269\uff0c\u591a\u7fa7\u57fa\u914d\u5408\u7269\u3002\u5e38\u89c1\u7684\u5355\u7fa7\u57fa\u914d\u5408\u7269\u4e3a\u7532\u9178\uff0c\u4e8c\u7fa7\u57fa\u914d\u5408\u7269\u4e3a\u8349\u9178\uff0c1,4-\u82ef\u7532\u4e8c\u9178\u7b49\u3002\u591a\u7fa7\u57fa\u914d\u4f531,3,5-\u82ef\u7532\u4e09\u9178\u3002\u5982\u91c7\u7528Cao\u7b49\u4eba\u91c7\u7528\u7532\u9178\u4e3a\u914d\u4f53\uff0c\u901a\u8fc7\u5f62\u8c8c\u8f6c\u53d8\u6cd5\u5408\u6210\u4e86\u591a\u5b54\u591a\u89d2\u7684Mn2<\/sub>O3<\/sub>\u3002JaephilCho\u7b49\u4eba\u91c7\u75281,4-\u82ef\u7532\u4e8c\u9178\u4e3a\u914d\u4f53\u5408\u6210\u51fa\u4e86Fe \u57faMOF \uff08MIL-88-Fe\uff09\u3002\u518d\u540e\u7eed\u52a0\u70ed\u4e2d\u5f62\u6210\u591a\u5b54\u7eba\u9524\u4f53\u72b6\u7684\u03b1-Fe2<\/sub>O3<\/sub>\u3002<\/p>\n

2.4.2<\/strong>\u91d1\u5c5e\u7f9f\u57fa\u4e59\u9178\u914d\u5408\u7269<\/strong><\/p>\n

\u91d1\u5c5e\u7f9f\u57fa\u4e59\u9178\u914d\u5408\u7269\u4f5c\u4e3a\u53e6\u4e00\u7c7b\u91d1\u5c5e\u6709\u673a\u914d\u4f53\uff0c\u53cd\u5e94\u5e38\u53d1\u751f\u5728\u91d1\u5c5e\u4e59\u9178\u76d0\u4e0e\u9187\u6eb6\u6db2\u95f4\u3002\u697c\u96c4\u6587\u8bfe\u9898\u7ec4\u5229\u7528\u6b64\u53cd\u5e94\u673a\u7406\u6210\u529f\u7684\u5236\u5907\u51fa\u4e86\u7eb3\u7c73\u51b7\u67f1\u72b6Ni-Co\u53cc\u91d1\u5c5e\u7f9f\u57fa\u4e59\u9178\u914d\u5408\u7269\uff0c\u7d27\u63a5\u7740\u5bf9\u5176\u8fdb\u884c\u70ed\u5904\u7406\u53ef\u5f97\u5230\u591a\u5b54\u68f1\u67f1\u72b6Ni-Co\u53cc\u91d1\u5c5e\u6c27\u5316\u7269\u3002<\/p>\n

xCo(CH3<\/sub>COO)2<\/sub> + (5-x)Ni(CH3<\/sub>COO)2 <\/sub>+ 4H2<\/sub>O<\/p>\n

\u2192 (Ni, Co)5<\/sub>(OH)2<\/sub>(CH3<\/sub>COO)8<\/sub>\u00b72H2<\/sub>O+2CH3<\/sub>COOH\u00a0\u00a0\u00a0 (18)<\/p>\n

\"\"<\/p>\n

\u56fe5\uff1aFe\u57fa\u7fa7\u9178\u914d\u5408\u7269\uff08MIL-88-Fe\uff09\u4e0eNi-Co\u53cc\u91d1\u5c5e\u7f9f\u57fa\u4e59\u9178\u914d\u5408\u7269<\/strong><\/p>\n

2.4.3<\/strong>\u91d1\u5c5e\u9187\u76d0\u914d\u5408\u7269<\/strong><\/p>\n

\u91d1\u5c5e\u9187\u76d0\u914d\u5408\u7269\u53ef\u8868\u793a\u4e3aM(OR)n<\/sub>\uff0c\u5e38\u4ee5\u91d1\u5c5e\u79bb\u5b50\uff08Co, Zn, Fe, Mn, Ti, Ni\uff09\u5728\u4e59\u4e8c\u9187\uff0c\u56db\u4e59\u4e8c\u9187\uff0c1,2-\u4e19\u4e8c\u9187\uff0c1,3-\u4e19\u4e8c\u9187\uff0c1,2-\u4e01\u4e8c\u9187\uff0c1,3-\u4e01\u4e8c\u9187\uff0c1,4-\u4e01\u4e8c\u9187\u7b49\u6eb6\u6db2\u4e2d\u53cd\u5e94\u5f97\u5230\u3002\u4ee5\u4e59\u4e8c\u9187\u4e3a\u4f8b\uff0c\u5176\u53cd\u5e94\u53ef\u8868\u793a\u4e3a\uff1a<\/p>\n

HOC2<\/sub>H4<\/sub>OH + 2OH–<\/sup> \u2194 OC2<\/sub>H4<\/sub>O2-<\/sup> +2H2<\/sub>O\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (19)<\/p>\n

Mx+<\/sup> + x\/2 OC2<\/sub>H4<\/sub>O2- <\/sup>\u2192 M(OC2<\/sub>H4<\/sub>O)x\/2<\/sub>\u2193\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (20)<\/p>\n

\u5f97\u5230\u7684\u91d1\u5c5e\u9187\u76d0\u914d\u5408\u5728\u8fdb\u884c\u4e00\u5b9a\u7684\u5904\u7406\uff0c\u53ef\u5f97\u5230\u591a\u5b54\u72b6\u7684\u6807\u76ee\u4ea7\u7269\u3002\u5982Xuan\u7b49\u4eba\u5229\u7528\u4e0a\u8ff0\u53cd\u5e94\u6210\u529f\u5730\u5236\u5907\u51fa\u7403\u5f62\u7684Co-Mn\u53cc\u91d1\u5c5e\u9187\u76d0\u914d\u5408\u7269\uff0c\u5728\u7a7a\u6c14\u6c1b\u56f4\u4e2d\u7a0d\u540e\u53ef\u8f6c\u5316\u4e3a\u591a\u5b54\u7403\u72b6\u7684CoMn2<\/sub>O4<\/sub>\u3002<\/p>\n

2.4.4<\/strong>\u91d1\u5c5e\u4e59\u4e8c\u9187\u914d\u5408\u7269<\/strong><\/p>\n

\u4e0e\u91d1\u5c5e\u9187\u76d0\u914d\u5408\u7269\u76f8\u4f3c\u7684\u53e6\u4e00\u7c7b\u914d\u5408\u7269\u53eb\u505a\u91d1\u5c5e\u4e59\u4e8c\u9187\u914d\u5408\u7269\uff0c\u5176\u53cd\u5e94\u673a\u7406\u53ef\u7b80\u5355\u5730\u8868\u793a\u4e3a\uff1a<\/p>\n

\"\"\uff0821\uff09<\/p>\n

\u5176\u4e2d\uff0cM-O \u548cM\u2192OH\u7684\u914d\u4f4d\u6570\u4e0e\u91d1\u5c5e\u79bb\u5b50\u6240\u5e26\u7684\u7535\u8377\u6570\u6709\u5173\uff0c\u50cf\u4e8c\u4ef7\u7684\u91d1\u5c5e\u79bb\u5b50Sn2+<\/sup>, Mn2+<\/sup>\uff0c Pb2+<\/sup>\uff0c\u4ed6\u4eec\u7684\u914d\u4f4d\u6570\u662f2\u3002\u57fa\u4e8e\u6b64\u53cd\u5e94\u673a\u7406\uff0c\u590f\u5e7c\u5357\u8bfe\u9898\u7ec4\u6210\u529f\u5730\u5236\u5907\u51faSn(II), In(III), Pb(II)\u7684\u4e59\u4e8c\u9187\u914d\u5408\u7269\uff0c\u518d\u7ecf\u70ed\u5904\u7406\u540e\u53ef\u5f97\u5230\u591a\u5b54\u5f62\u72b6\u7684\u91d1\u5c5e\u6c27\u5316\u7269\u3002<\/p>\n

\"\"<\/p>\n

\u56fe6\uff1a SnO2<\/sub>\u7eb3\u7c73\u7ebf(A)\uff0c In2<\/sub>O3<\/sub>\u7eb3\u7c73\u7ebf( (B)\uff0cPbO\u7eb3\u7c73\u7ebf( (C)<\/strong><\/p>\n

2.4.5<\/strong>\u666e\u9c81\u58eb\u84dd\u914d\u5408<\/strong><\/p>\n

\u666e\u9c81\u58eb\u84dd\u914d\u5408\u7269\u5e38\u53ef\u8868\u793a\u4e3a Fe4<\/sub>[Fe(CN)6<\/sub>]3<\/sub>\u00b7xH2<\/sub>O\uff0cFe\u79bb\u5b50\u4e0eCN \u57fa\u56e2\u53d1\u751f\u6865\u8fde-(Fe-CN-Fe)-\u3002\u5229\u7528\u6b64\u53cd\u5e94\uff0c\u7acb\u65b9\u591a\u5b54\u72b6\u03b1-Fe2<\/sub>O3<\/sub>\u548c \u03b3-Fe2<\/sub>O3<\/sub>\u5747\u88ab\u6210\u529f\u5730\u5408\u6210\u8fc7\u3002\u4ee5\u666e\u9c81\u58eb\u84dd\u4e3a\u57fa\u7840\uff0c\u53ef\u53d1\u73b0\u53e6\u4e00\u7c7b\u7c7b\u666e\u9c81\u58eb\u84dd\u7684\u914d\u5408\u7269\uff0c\u5e38\u53ef\u8868\u793a\u4e3aM3<\/sub>II<\/sup>[MIII <\/sup>(CN)6<\/sub>]2<\/sub>\u00b7nH2<\/sub>O (M= \u8fc7\u6e21\u91d1\u5c5e)\u3002\u5982Co\u2013Co \u7c7b\u666e\u9c81\u58eb\u84dd\u914d\u5408(Co3<\/sub>[Co(CN)6<\/sub>]2<\/sub>\u00b7xH2<\/sub>O)\u3002Feng\u7b49\u4eba\u5229\u7528\u7c7b\u666e\u9c81\u58eb\u84dd\u914d\u5408\u7269Co3<\/sub>[Co(CN)6<\/sub>]2<\/sub>\u00b7xH2<\/sub>O\u6210\u529f\u7684\u5f97\u5230\u4e86\u7acb\u65b9\u591a\u5b54\u72b6Co3<\/sub>O4<\/sub>\u3002<\/p>\n

2.4.6<\/strong>\u91d1\u5c5e\u54aa\u5511\u57fa\u6216\u54cc\u5576\u57fa\u914d\u5408\u7269<\/strong><\/p>\n

ZIF\u4f5c\u4e3a\u4e00\u7c7b\u5f88\u5e38\u89c1\u7684\u91d1\u5c5e\u54aa\u5511\u57fa\u914d\u5408\u7269\u88ab\u5e7f\u6cdb\u7684\u5e94\u7528\u4e8e\u5408\u6210\u591a\u5b54\u7ed3\u6784\u7269\u8d28\u3002\u5176\u4e2d\u8f83\u4e3a\u5e38\u89c1\u7684\u662fZIF-67\u3002\u5982\u591a\u5b54\u7247\u72b6\u7684Co3<\/sub>O4<\/sub>\u90fd\u53ef\u6765\u81ea\u4e8eCo-ZIF-67\u3002\u54cc\u5576\u57fa\u914d\u5408\u7269\u4e5f\u53ef\u7528\u4e8e\u5408\u6210\u591a\u5b54\u6750\u6599\u3002<\/p>\n

3. \u591a\u7ea7\u591a\u5b54\u6750\u6599\u7684\u5e94\u7528<\/strong><\/span><\/p>\n

3.1<\/strong>\u9502\u79bb\u5b50\u7535\u6c60<\/strong><\/p>\n

\u9502\u79bb\u5b50\u7535\u6c60\u5177\u6709\u80fd\u91cf\u5bc6\u5ea6\u9ad8\uff0c\u5bf9\u73af\u5883\u53cb\u597d\uff0c\u65e0\u8bb0\u5fc6\u6548\u5e94\u7b49\u7279\u70b9\u88ab\u5e7f\u6cdb\u5730\u5e94\u7528\u4e8e3C\u6570\u7801\uff0c\u79fb\u52a8\u7535\u6e90\u4e0a\u3002\u591a\u5b54\u6750\u6599\u56e0\u5176\u81ea\u8eab\u6240\u5177\u6709\u7684\u4f18\u52bf\u5e7f\u6cdb\u7684\u7528\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\u7684\u7535\u6781\u6750\u6599\u4e2d\u3002\u5e38\u53ef\u5206\u4e3a\u4e24\u5927\u7c7b\uff0c\u8d1f\u6781\u548c\u6b63\u6781\u3002\u4f5c\u4e3a\u8d1f\u6781\u65f6\u53cd\u5e94\u53ef\u8868\u793a\u4e3a\uff1a<\/p>\n

Mx<\/sub>Oy<\/sub> + 2yLi+<\/sup> + 2ye–<\/sup> \u2192 xM + 2yLi2<\/sub>O\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 (22)<\/p>\n

\u7528\u4f5c\u8d1f\u6781\u65f6\u53ef\u5206\u4e3a\u5355\u91d1\u5c5e\u6c27\u5316\u7269\uff08CoO\uff0cCo3<\/sub>O4<\/sub>\uff0cMnO\uff0cMn3<\/sub>O4<\/sub>\uff0cMn2<\/sub>O3<\/sub>\uff0cMnO2<\/sub>\uff0cFe3<\/sub>O4<\/sub>\uff0cFe3<\/sub>O4<\/sub>\uff0cCu2<\/sub>O\uff0cCuO\u7b49\uff09\uff0c\u6df7\u5408\u578b\u91d1\u5c5e\u6c27\u5316\u7269\uff08NiCo2<\/sub>O4<\/sub>\uff0cCoMn2<\/sub>O4<\/sub>\u7b49\uff09\u3002\u697c\u96c4\u6587\u8bfe\u9898\u7ec4\u901a\u8fc7\u5148\u63a7\u5236\u5408\u6210\u94b4\u7684\u4e59\u4e8c\u9187\u914d\u5408\u7269\u524d\u9a71\u4f53\uff0c\u540e\u5bf9\u524d\u9a71\u4f53\u8fdb\u884c\u70ed\u5904\u7406\u5f97\u5230\u5355\u5c42\uff0c\u53cc\u5c42\uff0c\u4e09\u5c42\u72b6\u7684Co3<\/sub>O4<\/sub>\uff0c\u7528\u4f5c\u8d1f\u6781\u6750\u6599\u65f6\u8868\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>7<\/strong>\uff1a\u5355\u5c42\uff0c\u53cc\u5c42\uff0c\u4e09\u5c42\u72b6\u7684<\/strong>Co3<\/sub>O4<\/sub>\u53ca\u5176\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\u5f53\u591a\u7ea7\u7ed3\u6784\u7528\u4f5c\u6b63\u6781\u65f6\uff0c\u4e00\u822c\u6d89\u53ca3\u6b65\uff0c1\uff09\u524d\u9a71\u4f53\u7684\u5408\u6210\uff1b2\uff09\u524d\u9a71\u4f53\u7684\u8f6c\u5316\uff1b3\uff09\u9502\u6e90\u4e0e\u8f6c\u5316\u540e\u7684\u524d\u9a71\u4f53\u9ad8\u6e29\u53cd\u5e94\u3002\u5317\u4eac\u7406\u5de5\u5927\u5b66\u5434\u5cf0\u8bfe\u9898\u7ec4\u901a\u8fc7\u5148\u5408\u6210Ni0.2<\/sub>Mn0.6<\/sub>(OH)1.6<\/sub>\u524d\u9a71\u4f53\u53ef\u5f97\u5230\u5177\u6709\uff08010\uff09\u6676\u9762\u53d6\u5411\u7684\u5bcc\u9502\u6b63\u6781\u6750\u6599\uff0c\u5728\u7535\u5316\u5b66\u6027\u80fd\u6d4b\u8bd5\u4e2d\u8868\u73b0\u51fa\u4e86\u826f\u597d\u7684\u500d\u7387\u53ca\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>8<\/strong>\uff1a\u5bcc\u9502\u6b63\u6781\u6750\u6599\u7684\u5f62\u8c8c\u53ca\u5176\u6027\u80fd<\/strong>\u00a0<\/strong><\/p>\n

3.2 <\/strong>\u9502\u786b\u7535\u6c60<\/strong><\/p>\n

\u9502\u786b\u7535\u6c60\u5177\u6709\u5f88\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\uff0c\u4f46\u662f\u591a\u786b\u5316\u7269\u7684\u7a7f\u68ad\u6548\u5e94\u9650\u5236\u5176\u8fdb\u4e00\u6b65\u53d1\u5c55\u3002\u591a\u5b54\u91d1\u5c5e\u57fa\u6c27\u5316\u7269\u5e38\u4f5c\u4e3a\u56fa\u786b\u5242\u88ab\u5e94\u7528\u4e8e\u9502\u786b\u7535\u6c60\u4e2d\u3002Nazar\u8bfe\u9898\u7ec4\u7cfb\u5217\u7684\u7814\u7a76\u4e86NiO, Cu2<\/sub>O, CoO, Co3<\/sub>O4<\/sub>, Fe2<\/sub>O3<\/sub>, NiOOH, V2<\/sub>O5<\/sub>, MnO2<\/sub>, VO2<\/sub>, V2<\/sub>O3<\/sub>\u4f5c\u4e3a\u56fa\u786b\u5242\uff0c\u53d1\u73b0\u4e2d\u7a7a\u7403\u5f62\u7684V2<\/sub>O5<\/sub>\u5728\u56fa\u786b\u65b9\u9762\u53ef\u8868\u73b0\u51fa\u8f83\u4e3a\u4f18\u8d8a\u7684\u6027\u80fd\u3002<\/p>\n

3.3 <\/strong>\u9502\u7a7a\u6c14\u7535\u6c60<\/strong><\/p>\n

\u9502\u7a7a\u6c14\u7535\u6c60\u7535\u6c60\u5177\u6709\u66f4\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\u88ab\u5e7f\u6cdb\u7814\u7a76\u3002\u5176\u4e2d\u7535\u6781\u6750\u6599\u4e2d\u7684\u50ac\u5316\u5242\u5bf9\u6574\u4e2a\u7535\u6c60\u4f53\u7cfb\u90fd\u6709\u51b3\u5b9a\u6027\u7684\u4f5c\u7528\u3002\u91d1\u5c5e\u57fa\u6c27\u5316\u7269\u5e38\u7528\u4f5c\u9502\u7a7a\u7535\u6c60\u7684\u50ac\u5316\u5242\uff0c\u76f8\u8f83\u4e8e\u5e38\u7528\u7684\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u91d1\u5c5e\u57fa\u6c27\u5316\u7269\u901a\u5e38\u5177\u6709\u66f4\u9ad8\u7684\u50ac\u5316\u6548\u5e94\uff0c\u66f4\u4f4e\u7684\u4ef7\u683c\u3002\u5982\u963f\u8d21\u5b9e\u9a8c\u5ba4\u7684Thackeray\u8bfe\u9898\u7ec4\u91c7\u7528\u03b1-MnO2<\/sub>\u4f5c\u4e3a\u7684\u50ac\u5316\u5242\u5e94\u7528\u5728\u9502\u7a7a\u7535\u6c60\u4e0a\u8868\u73b0\u51fa\u4e86\u826f\u597d\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n

3.4 <\/strong>\u8d85\u7ea7\u7535\u5bb9\u5668<\/strong><\/p>\n

\u91d1\u5c5e\u6c27\u5316\u7269\u5e38\u4f5c\u4e3a\u8d5d\u7535\u5bb9\u5668\u7684\u7535\u6781\u6750\u6599\uff0c\u4e0e\u4f20\u7edf\u53cc\u7535\u5c42\u7535\u5bb9\u5668\u76f8\u6bd4\u5b83\u5177\u6709\u66f4\u9ad8\u7684\u7535\u5bb9\u91cf\u3002\u4f5c\u4e3a\u7535\u5bb9\u5668\u7684\u7535\u6781\u6750\u6599\uff0c\u6bd4\u8868\u9762\u79ef\u662f\u4e00\u9879\u91cd\u8981\u7684\u8003\u8651\u56e0\u7d20\u3002\u591a\u5b54\u6750\u6599\u56e0\u5176\u5177\u6709\u8f83\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u6545\u5f88\u591a\u7684\u7535\u5bb9\u5668\u7535\u6781\u6750\u6599\u90fd\u88ab\u8bbe\u8ba1\u6210\u591a\u5b54\u72b6\u3002\u4e0e\u9502\u79bb\u5b50\u7535\u6781\u6750\u6599\u76f8\u4f3c\uff0c\u53ef\u5206\u4e3a\u5355\u91d1\u5c5e\u6c27\u5316\u7269\uff08NiO\uff0c MnO2<\/sub>, CoOx<\/sub>\u7b49\uff09\u548c\u6df7\u5408\u91d1\u5c5e\u6c27\u5316(Nix<\/sub>Co3-x<\/sub>O4<\/sub> (0<x\u22641), ZnCo2<\/sub>O4<\/sub>, CuFe2<\/sub>O4<\/sub>\u7b49)\u3002Zhang\u7b49\u4eba\u901a\u8fc7\u5bf9\u03b2-Ni(OH)2<\/sub>\u524d\u9a71\u4f53\u8fdb\u884c\u70ed\u5904\u7406\u53ef\u5f97\u591a\u5b54\u7eb3\u7c73\u7247\u72b6NiO\uff0c\u7528\u4e8e\u7535\u5bb9\u5668\u7535\u6781\u6750\u6599\u65f6\uff0c\u8868\u73b0\u51fa\u826f\u597d\u7684\u7535\u5bb9\u884c\u4e3a\u3002<\/p>\n

3.5 <\/strong>\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60<\/strong><\/p>\n

\u5728\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u4e2d\uff0c\u591a\u5b54\u7535\u6781\u6750\u6599\u5e38\u7528\u505a\u5149\u9633\u6781\u6750\u6599\u6765\u63d0\u9ad8\u5149\u6563\u5c04\uff0c\u5982TiO2<\/sub>, ZnO,SnO2<\/sub>, WO3<\/sub>\u7b49\u90fd\u662f\u5e38\u89c1\u7684\u5149\u9633\u6781\u6750\u6599\u3002TiO2<\/sub>, ZnO\u5c24\u4e3a\u5e38\u89c1\uff0cCheng\u8bfe\u9898\u7ec4\u91c7\u7528\u5148\u5408\u6210\u524d\u9a71\u4f53\u540e\u5bf9\u524d\u9a71\u4f53\u8fdb\u884c\u5904\u7406\u7684\u65b9\u5f0f\u5408\u6210\u4e86\u591a\u5b54\u7403\u5f62\u7684TiO2<\/sub>\uff0c\u7528\u5728\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u4e2d\uff0c\u53ef\u5c06\u80fd\u91cf\u8f6c\u5316\u6548\u7387\u63d0\u9ad8\u81f37.20%\u3002<\/p>\n

4<\/strong>\uff0e\u7ed3\u8bba\u4e0e\u5c55\u671b<\/strong><\/span><\/p>\n

\u591a\u5b54\u6750\u6599\u7528\u4e8e\u80fd\u6e90\u5b58\u50a8\u53ca\u8f6c\u6362\u9886\u57df\u663e\u793a\u4e86\u5de8\u5927\u7684\u6f5c\u529b\u3002\u5982\u4f55\u5feb\u901f\u53ef\u63a7\u7684\u5408\u6210\u591a\u5b54\u6750\u6599\u6210\u4e3a\u4eba\u4eec\u7814\u7a76\u7684\u70ed\u70b9\u3002\u672c\u6587\u7efc\u8ff0\u4e86\u4e00\u7c7b\u4ece\u524d\u9a71\u4f53\u51fa\u53d1\u518d\u8f6c\u5316\u5230\u76ee\u6807\u4ea7\u7269\u7684\u65b9\u6cd5\u3002\u5176\u4e2d\u9700\u8981\u8003\u8651\u7684\u56e0\u7d20\u6709\u5982\u4e0b\u51e0\u70b9\uff1a<\/p>\n

\uff081\uff09\u76ee\u6807\u4ea7\u7269\u7684\u5f62\u8c8c\u662f\u4ece\u524d\u9a71\u4f53\u4e2d\u8f6c\u53d8\u800c\u6210\u7684\uff0c\u6240\u4ee5\u9996\u5148\u9700\u8003\u8651\u524d\u9a71\u4f53\u5f62\u8c8c\u53ca\u5408\u6210\u65b9\u5f0f\uff0c\u9009\u62e9\u524d\u9a71\u4f53\u7684\u79cd\u7c7b\uff1b<\/p>\n

\uff082\uff09\u524d\u9a71\u4f53\u7684\u5f62\u8c8c\u53d7\u91d1\u5c5e\u79bb\u5b50\uff0c\u914d\u4f53\uff0c\u6eb6\u5242\uff0c\u8868\u9762\u6d3b\u6027\u5242\u53capH\u7684\u5f71\u54cd\uff0c\u6240\u4ee5\u5408\u6210\u65f6\u9700\u7efc\u5408\u8003\u8651\u5404\u79cd\u56e0\u7d20\uff1b<\/p>\n

\uff083\uff09\u5408\u6210\u591a\u5b54\u6750\u6599\u7684\u524d\u9a71\u4f53\u65f6\u5e38\u5e38\u4f34\u968f\u7684\u751f\u957f\u8fc7\u7a0b\u542b\u6210\u6838\uff0c\u751f\u957f\uff0c\u81ea\u7ec4\u88c5\u7b49\u3002<\/p>\n

\u4ece\u524d\u9a71\u4f53\u5230\u591a\u5b54\u6750\u6599\u7684\u8f6c\u53d8\u65f6\u5e38\u6d89\u53ca\u7684\u7406\u8bba\u6709Ostwald\u91cd\u6392\u548cKirkendall\u6548\u5e94\u3002\u672c\u6587\u7efc\u8ff0\u7684\u65b9\u6cd5\u5177\u6709\u666e\u9002\u6027\uff0c\u53ef\u63a8\u5e7f\u81f3\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u7535\u6781\u6750\u6599\u7684\u5408\u6210\u53ca\u5176\u5176\u4ed6\u80fd\u6e90\u5b58\u50a8\u9886\u57df\u4e2d\u3002<\/p>\n

\"\"<\/p>\n

\u56fe9\uff1a\u591a\u7ea7\u591a\u5b54\u6750\u6599\u7684\u5408\u6210\u53ca\u5176\u5e94\u7528\u793a\u610f\u56fe<\/strong><\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Morphology-Conserved Transformations of Metal-Based Precursors to Hierarchically Porous Micro-\/Nanostructures for Electrochemical Energy Conversion and Storage\u00a0<\/a>\uff08Adv. Mater., 2017, DOI: 10.1002\/adma.201607015\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37\uff01<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

1. \u5f15\u8a00 \u591a\u7ea7\u591a\u5b54\u7ed3\u6784\u6750\u6599\u56e0\u5176\u5177\u6709\u5982\u4e0b\u7279\u70b9\u88ab\u5e7f\u6cdb\u5730\u5e94\u7528\u4e8e\u80fd\u6e90\u5b58\u50a8\u4e0e\u8f6c\u6362\u9886\u57df\uff1a \uff081\uff09\u53ef\u6709\u6548\u5730\u907f\u514d\u7eb3\u7c73\u9897\u7c92\u95f4\u7684\u56e2\u805a\uff0c\u964d\u4f4e\u6750\u6599\u754c\u9762\u7684\u754c\u9762\u5f20\u529b\uff1b \uff082\uff09\u76f8\u8f83\u4e8e\u5927\u9897\u7c92…<\/p>\n","protected":false},"author":1369,"featured_media":88332,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[533],"tags":[],"class_list":["post-88329","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zongshu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/88329"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/1369"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=88329"}],"version-history":[{"count":1,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/88329\/revisions"}],"predecessor-version":[{"id":88342,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/88329\/revisions\/88342"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/88332"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=88329"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=88329"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=88329"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}