{"id":88399,"date":"2017-06-30T06:30:14","date_gmt":"2017-06-29T22:30:14","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=88399"},"modified":"2017-08-04T19:19:44","modified_gmt":"2017-08-04T11:19:44","slug":"%e9%87%8d%e7%a3%85%ef%bc%81%e4%b8%ad%e5%9b%bd%e7%a7%91%e6%8a%80%e5%a4%a7%e5%ad%a6%e6%b1%9f%e6%b5%b7%e9%be%99%e8%af%be%e9%a2%98%e7%bb%84chem-soc-rev-%e6%9c%80%e6%96%b0%e7%bb%bc%e8%bf%b0%ef%bc%9amofs","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=88399","title":{"rendered":"\u4e2d\u56fd\u79d1\u5927\u6c5f\u6d77\u9f99Chem.Soc.Rev.\u6700\u65b0\u7efc\u8ff0\uff1aMOFs\u57fa\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\uff1a\u589e\u6548\u50ac\u5316\u7684\u534f\u540c\u4f5c\u7528"},"content":{"rendered":"<p><strong>1. \u5f15\u8a00<\/strong><\/p>\n<p>\u91d1\u5c5e-\u6709\u673a\u9aa8\u67b6\uff08MOF\uff09\u7684\u9ad8\u8868\u9762\u79ef\uff0c\u7ed3\u6784\u591a\u6837\u6027\u548c\u5b9a\u5236\u6027\u7684\u7ed3\u6676\u591a\u5b54\u6750\u6599\uff0c\u5f15\u8d77\u4e86\u5e7f\u6cdb\u7684\u5174\u8da3\u5e76\u8868\u73b0\u51fa\u5404\u79cd\u5e94\u7528\u3002\u672c\u7efc\u8ff0\u603b\u7ed3MNP\/MOF\u6750\u6599\u5236\u5907\u548c\u8868\u5f81\u65b9\u6cd5\u53ca\u5176\u5e94\u7528\uff0c\u5c0f\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\uff08MNP\uff09\u548cMOF\u4e4b\u95f4\u534f\u540c\u4f5c\u7528\u662f\u50ac\u5316\u4e2d\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u4e24\u4e2a\u7ec4\u5206\u7684\u5408\u7406\u6574\u5408\u80fd\u591f\u6709\u6548\u5730\u534f\u8c03\u5404\u81ea\u7684\u4f18\u52bf\uff0c\u5e76\u62b5\u6d88\u589e\u5f3a\u50ac\u5316\u4f5c\u7528\u7684\u7f3a\u70b9\u3002\u7136\u800c\uff0c\u534f\u540c\u50ac\u5316\u5bf9MNP\/MOF\u590d\u5408\u6750\u6599\u7684\u91cd\u8981\u6027\u672a\u5f97\u5230\u5f88\u597d\u7684\u7406\u89e3\u3002\u6700\u8fd1\u7814\u7a76\u8868\u660e\uff0cMNP\u548cMOF\u4e4b\u95f4\u7684\u534f\u540c\u6548\u5e94\u6709\u6548\u5730\u6574\u5408\u4e86\u5176\u5404\u81ea\u7684\u4f18\u70b9\uff0c\u4ece\u800c\u5927\u5927\u63d0\u9ad8\u4e86\u50ac\u5316\u6027\u80fd\u3002<\/p>\n<p>\u6700\u8fd1\uff0c<strong>\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u6c5f\u6d77\u9f99\u8bfe\u9898\u7ec4\u5728Chem.Soc.Rev.<\/strong>\u53d1\u8868\u4e86\u9898\u4e3a\u201c<strong>Metal-organic frameworks meet metal nanoparticles: synergistic effect for enhanced catalysis\u201d<\/strong>\u7684\u7efc\u8ff0\u3002\u6587\u4e2d\u6982\u8ff0\u4e86MNP\/MOF\u590d\u5408\u6750\u6599\u7684\u50ac\u5316\u4f5c\u7528\uff0c\u603b\u7ed3\u4e86MNPs\/MNP\u548cMNP@MOFs\u4e2d\u7684\u5408\u6210\u65b9\u6848\u548c\u8868\u5f81\u5de5\u5177\u3002\u7279\u522b\u5f3a\u8c03\u4e86MNP\/MOF\u590d\u5408\u6750\u6599\u4e2d\u4e24\u79cd\u7ec4\u5206\u5bf9\u589e\u5f3a\u50ac\u5316\u5242\u7684\u534f\u540c\u4f5c\u7528\uff0c\u4ece\u800c\u66f4\u6df1\u5165\u5730\u4e86\u89e3MNP\/MOF\u590d\u5408\u6750\u6599\u7684\u7814\u7a76\u8fdb\u800c\u63a8\u52a8\u76f8\u5173\u7814\u7a76\u9886\u57df\u7684\u8fdb\u4e00\u6b65\u53d1\u5c55\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-88403\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/06\/\u56fe\u72471-21.png\" alt=\"\" width=\"700\" height=\"631\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/06\/\u56fe\u72471-21.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/06\/\u56fe\u72471-21-300x270.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u7efc\u8ff0\u5bfc\u89c8\u56fe<\/strong><\/p>\n<p><strong>2. MNP\/MOF\u590d\u5408\u6750\u6599\u7684\u5408\u6210\u65b9\u6cd5<\/strong><\/p>\n<p>MOFs\u7a33\u5b9aMNP\u7684\u591a\u79cd\u5408\u6210\u65b9\u6cd5\u3002\u4e00\u822c\u6765\u8bf4\uff0cMN\uff30\/MOF\u590d\u5408\u6750\u6599\u7684\u5236\u5907\u53ef\u4ee5\u5206\u4e3a\u56db\u79cd\u65b9\u6cd5\uff1a\uff08\uff11\uff09MOF\u5f15\u5165\u5177\u6709\u91d1\u5c5e\u524d\u4f53\u7684\u6eb6\u6db2\uff08\u6216\u8005MOF\u4e0e\u56fa\u6001\u7684\u91d1\u5c5e\u524d\u4f53\u6df7\u5408\uff09\uff0c\u7136\u540e\u5728MOF\u7684\u5916\u8868\u9762\u5185\u548c\/\u6216\u5916\u8868\u9762\u4e0a\u5f62\u6210MNP\uff1b\uff08\uff12\uff09MNPs\u8fdb\u5165\u7528\u4e8e\u968f\u540e\u7684MOF\u5408\u6210\u7684\u53cd\u5e94\u6eb6\u6db2\u4e2d\u7684\u5206\u6563\u4f53\uff0c\u5373\u5e76\u5165MOF\u4e2d\u7684MNP\uff1b\uff08\uff13\uff09\u9010\u6b65\u5408\u6210\u8fc7\u7a0b\uff0c\u7528\u4e8eMNP\/MOF\u548c\u5939\u5fc3\u7ed3\u6784MOF\/MNP\/MOF\uff1b\uff08\uff14\uff09\u540c\u65f6\u5f62\u6210\u4e24\u79cd\u7ec4\u5206\u4ee5\u63d0\u4f9bMNP\/MOF\u590d\u5408\u6750\u6599\u3002<\/p>\n<p><strong>\u65b9\u6848<\/strong><strong>1 MOF<\/strong><strong>\u548c\u91d1\u5c5e<\/strong><strong>NPs<\/strong><strong>\u7684\u529f\u80fd\u4e0e\u534f\u540c\u50ac\u5316\u7684\u7ed3\u5408<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-88404\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/06\/c6cs00724d-s1_hi-res.gif\" alt=\"\" width=\"700\" height=\"443\" \/><\/p>\n<p><strong>2.1 \u5f62\u6210MNPs\u4e4b\u524d\u5408\u6210MOF<\/strong><\/p>\n<p>MOFs\u4f5c\u4e3a\u7a33\u5b9a\u4e3b\u4f53\u6750\u6599\uff0c\u901a\u8fc7\u8239\u4e0a\u74f6\u65b9\u6cd5\u4e3aMNP\u63d0\u4f9b\u4e86\u6709\u9650\u7684\u7a7a\u95f4\uff0c\u5176\u4e2dMNP\u5728MOF\u77e9\u9635\u4e2d\u7684\u5e76\u5165\u9884\u671f\u4f1a\u963b\u6b62\u805a\u96c6\u5e76\u9650\u5236MNP\u7684\u589e\u957f\u3002\u5e94\u8be5\u6ce8\u610f\u5c06\u6240\u6709MNP\u9650\u5236\u5728\u6bdb\u5b54\u5185\u4ecd\u7136\u662f\u5177\u6709\u91cd\u6311\u6218\u6027\uff0c\u5e76\u4e14\u5728MOF\u8868\u9762\u4e0a\u652f\u6301\u51e0\u4e2aMNP\u6709\u65f6\u662f\u4e0d\u53ef\u907f\u514d\u7684\u3002\u95ee\u9898\u8d77\u56e0\u4e8eMOF\u5fae\u89c2\u7ed3\u6784\u7684\u5f71\u54cd\uff0c\u5176\u5305\u62ec\u5185\u8868\u9762\u7279\u6027\uff0c\u91d1\u5c5e\u524d\u4f53\u6216MNP\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u548cMOF\u5b54\u8868\u9762\u73af\u5883\uff0c\u4ee5\u53ca\u6da6\u6e7f\u548c\u586b\u5145MOF\u5b54\u7684\u52a8\u529b\u5b66\u3002\u5728\u4f20\u7edf\u65b9\u6cd5\u4e2d\uff0c\u91d1\u5c5e\u524d\u4f53\u7684\u5f15\u5165\u53ef\u4ee5\u57fa\u4e8e\u4e0d\u540c\u7684\u6280\u672f\uff0c\u5305\u62ec\u6eb6\u6db2\u6e17\u900f\uff0c\u6c14\u76f8\u6c89\u79ef\u548c\u56fa\u4f53\u7814\u78e8\uff0c\u7136\u540e\u662f\u7528\u4e8e\u91d1\u5c5e\u524d\u4f53\u7684\u5404\u79cd\u8fd8\u539f\u65b9\u6cd5\u5bfc\u81f4MNPs\u76f8\u5bf9\u4e8eMOF\u9897\u7c92\u7684\u5c3a\u5bf8\u548c\/\u6216\u5206\u5e03\u63a7\u5236\u4e0d\u540c\u3002\u8003\u8651\u5230MOFs\u7684\u5316\u5b66\u548c\u70ed\u7a33\u5b9a\u6027\uff0c\u5e94\u4ed4\u7ec6\u9009\u62e9\u8fd8\u539f\u5242\uff0c\u8fd8\u539f\u65b9\u6cd5\u548c\u8fd8\u539f\u65f6\u95f4\uff0c\u5176\u5bf9MNP\u7684\u5c3a\u5bf8\u6709\u663e\u7740\u7684\u5f71\u54cd\u3002<\/p>\n<p><strong>2.1.1\u00a0<\/strong><strong>\u6eb6\u6db2\u6d78\u6e0d\u7cfb\u7edf<\/strong><\/p>\n<p>\u5c06MOF\u6676\u4f53\u5f15\u5165\u542b\u6709\u91d1\u5c5e\u524d\u4f53\u7684\u6eb6\u6db2\u4e2d\u5e76\u8fdb\u884c\u6709\u6548\u6df7\u5408\u3002\u6bdb\u7ec6\u7ba1\u538b\u529b\u5bfc\u81f4\u6db2\u4f53\uff08\u542b\u91d1\u5c5e\u524d\u4f53\uff09\u81ea\u53d1\u7a7f\u900fMOF\u7684\u5185\u90e8\u7a7a\u9699\u3002\u901a\u8fc7\u79bb\u5fc3\u548c\u6d17\u6da4\u6536\u96c6\u56fa\u4f53\u6216\u84b8\u53d1\u3002\u968f\u540e\uff0c\u91d1\u5c5e\u524d\u4f53\u8fd8\u539f\u6210MNP\u5e76\u539f\u4f4d\u5f62\u6210\u7684MNP\u7684\u5c3a\u5bf8\u548c\u5f62\u72b6\u9884\u671f\u7531\u4e3b\u673aMOF\u7684\u8154\u786e\u5b9a\u3002\u9897\u7c92\u5206\u5e03\u53d6\u51b3\u4e8e\u91d1\u5c5e\u524d\u4f53\u548cMOF\uff0c\u5e76\u4e14\u4e00\u4e9b\u91d1\u5c5e\u524d\u4f53\u53ef\u80fd\u88ab\u5438\u9644\u5728\u8868\u9762\u4e0a\u5e76\u4e14\u6613\u8fc1\u79fb\u3002\u7531\u4e8e\u8fd9\u4e2a\u539f\u56e0\uff0c\u901a\u8fc7\u6eb6\u6db2\u6d78\u6e0d\u5408\u6210\u7684MNP\/MOF\u590d\u5408\u6750\u6599\u5728\u67d0\u4e9b\u60c5\u51b5\u4e0b\u8868\u73b0\u51fa\u65b9\u6cd5\u63a7\u5236\u4e0d\u826f\u65f6MNP\u7684\u5e7f\u6cdb\u5206\u5e03\u3002\u589e\u5f3a\u91d1\u5c5e\u524d\u4f53\u548cMOF\u57fa\u4f53\u7684\u7a7a\u7a74\/\u901a\u9053\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u5c06\u6709\u52a9\u4e8e\u5f15\u5165\u91d1\u5c5e\u524d\u4f53\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>1 MIL-101<\/strong><strong>\u4e2d\u4e0d\u9971\u548c\u91d1\u5c5e\u4f4d\u70b9\u7684\u529f\u80fd\u5316<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-88405\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/06\/c6cs00724d-f1_hi-res.gif\" alt=\"\" width=\"700\" height=\"470\" \/><\/p>\n<p>\uff08A\uff09MIL-101\u4e2d\u4ecb\u5b54\u7b3c\u7684\u89c6\u56fe\uff1b<\/p>\n<p>\uff08B\u548cC\uff09\u5728423K\u6d3b\u531612h\u540e\uff0cMIL-101\u4ecb\u5b54\u7b3c\u4e2dCr3O\u7c07\u7684\u914d\u4f4d\u4e0d\u9971\u548c\u4f4d\u70b9\uff08CUS\uff09\u7684\u6f14\u5316\uff1b<\/p>\n<p>\uff08D\uff09\u901a\u8fc7\u5c06\u80fa\u5206\u5b50\u9009\u62e9\u6027\u63a5\u679d\u5230CUS\u4e0a\uff0c\u8131\u6c34\u7684MIL-101\u7684\u8868\u9762\u5b98\u80fd\u5316\uff1b<\/p>\n<p>\uff08E\uff09PdNPs\u9009\u62e9\u6027\u5305\u5c01\u5230\u80fa\u63a5\u679d\u7684MIL-101\u4e2d\uff0cCr\uff0cC\u548cO\u539f\u5b50\u5206\u522b\u663e\u793a\u4e3a\u9ec4\u8272\uff0c\u6d45\u7070\u8272\u548c\u7ea2\u8272\u3002CrO6\u516b\u9762\u4f53\u4ee5\u9ec4\u8272\u9634\u5f71\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>2 NiII<\/strong><strong>\u5927\u73af\u7edc\u5408\u7269\u4f5c\u4e3a\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u91d1\u5c5e\u7ed3\u6784\u5355\u5143\u6784\u5efa<\/strong><strong>MOFs<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-88406\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/06\/c6cs00724d-f2_hi-res.gif\" alt=\"\" width=\"700\" height=\"285\" \/><\/p>\n<p>\uff08a\uff09\u914d\u4f4d\u805a\u5408\u72691D\u7ed3\u6784\u7684\u89c6\u56fe\uff1b<\/p>\n<p>\uff08b\uff09\u4e09\u91cd\u8fab\u5b50\u7684\u53cc\u91cd\u7f51\u7edc\uff0c\u5176\u4e2d\u5927\u73af\u914d\u5408\u5230\u7531bpdc2-\u914d\u4f53\u4ea7\u751f\u7684\u51f9\u69fd\u4e2d\uff1b<\/p>\n<p>\uff08c\uff09\u901a\u8fc7\u5806\u53e0\u7ebf\u6027\u94fe\u4ea7\u751f\u76841D\u901a\u9053\u7684\u89c6\u56fe\u3002<\/p>\n<p>\u6b64\u5916\uff0c\u7528\u4e8e\u901a\u8fc7MOF\u7a33\u5b9a\u7684\u975e\u8d35\u91cdMNP\u7684\u8f7b\u5ea6\u5408\u6210\uff1b\u79cd\u5b50\u4ecb\u5bfc\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u5408\u6210\u975e\u8d35\u91cdMNP\u662f\u5229\u7528\u7684\u8d35\u91d1\u5c5e\u548c\u975e\u8d35\u91d1\u5c5e\u76d0\u7684\u8fd8\u539f\u7535\u4f4d\u7684\u5dee\u5f02\u3002\u5c06\u5fae\u91cf\uff08\u8d35\u91d1\u5c5e\/\u975e\u8d35\u91d1\u5c5e\u7684\u6469\u5c14\u6bd4\u4e3a1\/100-1\/200\uff09\u8d35\u91d1\u5c5e\u548c\u975e\u8d35\u91d1\u5c5e\u524d\u4f53\u5f15\u5165\u542b\u6709MOF\u7684NH<sub>3<\/sub>BH<sub>3<\/sub>\u6c34\u89e3\u4f53\u7cfb\u4e2d\u3002\u8d35\u91d1\u5c5e\u524d\u4f53\u5728MOF\u8154\u4e2d\u5feb\u901f\u8fd8\u539f\u6210NP\uff0c\u800c\u7531\u4e8e\u9ad8\u5ea6\u53ef\u8fd8\u539f\u7684\u4e2d\u95f4\u4f53M-H\u7269\u8d28\uff0c\u975e\u8d35\u91d1\u5c5e\u524d\u4f53\u968f\u540e\u88ab\u8fd8\u539f\u6210\u7531MOF\u7a33\u5b9a\u7684\u5c0fNPs\u3002\u4e0e\u4f20\u7edf\u65b9\u6cd5\u76f8\u6bd4\uff0c\u91c7\u7528\u6c27\u5316\u8fd8\u539f\u6d3b\u6027MOFs\u5f00\u53d1\u4e86\u5236\u9020MNP\u7684\u7279\u6b8a\u65b9\u6cd5\uff0c\u5bfc\u81f4MNP\u5728\u4e00\u4e2a\u7b80\u5355\u7684\u4e00\u6b65\u6cd5\u4e2d\u4ea7\u751f\uff0c\u800c\u65e0\u9700\u4f7f\u7528\u989d\u5916\u7684\u8fd8\u539f\u5242\u3002\u4f7f\u7528\u5404\u79cdNiII\u5927\u73af\u7edc\u5408\u7269\u4f5c\u4e3a\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u91d1\u5c5e\u7ed3\u6784\u5355\u5143\u6765\u6784\u5efaMOF\u3002<\/p>\n<p><strong>2.1.2\u00a0<\/strong><strong>\u53cc\u6eb6\u5242\u6cd5<\/strong><\/p>\n<p>\u6eb6\u6db2\u6d78\u6e0d\u662f\u4ea7\u751fMNP\/MOF\u590d\u5408\u6750\u6599\u7684\u7ecf\u5178\u4e14\u6709\u6548\u7684\u65b9\u6cd5\uff0c\u4f46\u662f\u96be\u4ee5\u5b9e\u73b0MNP\u76f8\u5bf9\u4e8e\u4e3b\u4f53MOF\u7684\u52a0\u8f7d\u4f4d\u7f6e\u7684\u7cbe\u786e\u63a7\u5236\u3002\u5982\u4e0a\u6240\u8ff0\uff0c\u4e00\u4e9b\u524d\u4f53\u6c89\u79ef\u5728MOF\u7684\u5916\u8868\u9762\u4e0a\u4ee5\u5f62\u6210\u805a\u96c6\u7684MNP\u3002\u4e3a\u4e86\u83b7\u5f97\u7cbe\u786e\u5305\u5c01\u5728MOF\u5b54\u5185\u7684MNP\u5e76\u9632\u6b62\u5b83\u4eec\u805a\u96c6\uff0c\u5f00\u53d1\u4e86\u53cc\u6eb6\u5242\u6cd5\uff08DSA\uff09\uff0c\u4ee5\u5408\u7406\u5730\u5c06\u91d1\u5c5e\u524d\u4f53\u5f15\u5165MOF\u5b54\u4e2d\uff0c\u7136\u540e\u8fd8\u539f\uff0c\u5f97\u5230MNPs@MOFs\u3002\u9274\u4e8e\u5728\u4e00\u4e9bMOF\u4e2d\u5177\u6709\u4eb2\u6c34\u73af\u5883\u548c\u9ad8\u5b54\u4f53\u79ef\uff0c\u7279\u522b\u662fMIL-101\uff0c\u9ad8\u5206\u6563\u5728\u5927\u4f53\u79ef\u4f4e\u6cb8\u70b9\u6709\u673a\u7269\u4e2d\u7684\u91d1\u5c5e\u524d\u4f53\u6c34\u6eb6\u6db2\u7684\u5b9a\u91cf\u4f53\u79ef\uff08\u4e0d\u5927\u4e8eMOF\u5b54\u4f53\u79ef\uff09\u6eb6\u5242\uff0c\u53ef\u4ee5\u5728\u6bdb\u7ec6\u7ba1\u529b\u548c\u4eb2\u6c34\u76f8\u4e92\u4f5c\u7528\u7684\u57fa\u7840\u4e0a\u5b8c\u5168\u7ed3\u5408\u5230MOF\u5b54\u4e2d\u3002\u6240\u5f97\u5230\u7684\u91d1\u5c5e\u524d\u4f53\u53ef\u8fdb\u4e00\u6b65\u51cf\u5c11\u4ee5\u4ea7\u751f\u9650\u5236\u5728MOF\u4e2d\u7684\u5fae\u5c0f\u7684MNP\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>3 <\/strong><strong>\u4f7f\u7528<\/strong><strong>DSA<\/strong><strong>\u7ed3\u5408\u6db2\u76f8\u6d53\u5ea6\u63a7\u5236\u7684\u8fd8\u539f\u7b56\u7565\u5c06<\/strong><strong>AuNiNPs<\/strong><strong>\u56fa\u5b9a\u5728<\/strong><strong>MIL-101<\/strong><strong>\u57fa\u8d28\u4e2d\u7684\u793a\u610f\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-88409\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/06\/c6cs00724d-f3_hi-res-1.gif\" alt=\"\" width=\"700\" height=\"367\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>4 <\/strong><strong>\u7528\u4e0d\u540c\u7a0b\u5e8f\u548c\u8fd8\u539f\u5242\u5408\u6210<\/strong><strong>Pd@Co@ MIL-101<\/strong><strong>\uff0c<\/strong><strong>Pd@Co\/MIL-101<\/strong><strong>\u548c<\/strong><strong>PdCo@MIL-101<\/strong><strong>\u50ac\u5316\u5242<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-88408\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/06\/c6cs00724d-f4_hi-res.gif\" alt=\"\" width=\"700\" height=\"390\" \/><\/p>\n<p><strong>2.1.3\u00a0\u5316<\/strong><strong>\u5b66\u6c14\u76f8\u6c89\u79ef<\/strong><\/p>\n<p>\u91c7\u7528\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\uff08CVD\uff09\u5728\u975e\u5e38\u65e9\u671f\u7684\u57fa\u7840\u4e0a\u5236\u5907MNP\/MOF\u590d\u5408\u6750\u6599\uff0c\u57fa\u4e8e\u6709\u673a\u91d1\u5c5e\u524d\u4f53\uff0c\u5373\u4f7f\u5728\u5ba4\u6e29\u4e0b\u4e5f\u662f\u9ad8\u5ea6\u6325\u53d1\u7684\uff0c\u6216\u8005\u5728\u5347\u9ad8\u7684\u6e29\u5ea6\u4e0b\u5bb9\u6613\u5347\u534e\u3002\u5728\u8be5\u5408\u6210\u7cfb\u7edf\u4e2d\uff0c\u8131\u6eb6\u7684MOF\u548c\u6325\u53d1\u6027\u91d1\u5c5e\u524d\u4f53\u901a\u5e38\u653e\u7f6e\u5728Schlenk\u7ba1\u4e2d\u7684\u4e24\u4e2a\u5206\u5f00\u7684\u73bb\u7483\u5c0f\u74f6\u4e2d\uff0c\u5e76\u5c06\u7ba1\u5bc6\u5c01\u5e76\u4fdd\u6301\u5728\u771f\u7a7a\u4e0b\u3002\u8131\u6eb6\u5242\u7684MOF\u66b4\u9732\u4e8e\u6325\u53d1\u6027\u91d1\u5c5e\u524d\u4f53\u7684\u84b8\u6c14\u4e2d\uff0c\u7136\u540e\u6839\u636e\u91d1\u5c5e\u524d\u4f53\u5728\u9759\u6001\u771f\u7a7a\u4e0b\u7684\u84b8\u6c7d\u538b\u529b\uff0c\u5728\u5408\u9002\u7684\u6e29\u5ea6\u4e0b\u5c06\u524d\u4f53\u6269\u6563\u5230MOF\u5b54\u4e2d\u3002\u56e0\u6b64\uff0c\u8be5\u65b9\u6cd5\u662f\u65e0\u6eb6\u5242\u7684\u65b9\u6cd5\uff0c\u5176\u5141\u8bb8\u52a0\u8f7d\u5927\u91cf\u7684MNP\u3002\u5f53\u91d1\u5c5e\u524d\u4f53\u6e17\u900f\u65f6\uff0cMOF\u7684\u989c\u8272\u53d1\u751f\u53d8\u5316\u3002\u7136\u540e\u5728\u7528\u70ed\/\u5316\u5b66\u8fc7\u7a0b\uff0cUV\u7167\u5c04\u6216\u53cd\u5e94\u6027\u6c14\u4f53\u5904\u7406\u4e4b\u540e\u5c06MNP\u5305\u57cb\u5728MOF\u4e2d\u3002\u5728CVD\u8fc7\u7a0b\u4e2d\u9700\u8981\u8c28\u614e\u548c\u7ecf\u9a8c\u3002\u5426\u5219\uff0c\u6240\u83b7\u5f97\u7684MNP\u53ef\u4ee5\u5177\u6709\u5bbd\u7684\u5c3a\u5bf8\u5206\u5e03\u5e76\u4e14\u5927\u4e8eMOF\u7684\u5b54\u5f84\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>5 <\/strong><strong>\u5c06<\/strong><strong>[Ru<\/strong><strong>\uff08<\/strong><strong>cod<\/strong><strong>\uff09\uff08<\/strong><strong>cot<\/strong><strong>\uff09<\/strong><strong>]<\/strong><strong>\u524d\u4f53\u63ba\u5165<\/strong><strong>MOF-5<\/strong><strong>\u7b3c\u4e2d\uff0c\u968f\u540e\u5438\u9644\u7684\u6709\u673a\u91d1\u5c5e\u524d\u4f53\u6c22\u89e3\u5f97\u5230<\/strong><strong>Ru@MOF-5<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-88410\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/06\/c6cs00724d-f5_hi-res.gif\" alt=\"\" width=\"700\" height=\"322\" \/><\/p>\n<p><strong>2.1.4\u00a0<\/strong><strong>\u56fa\u4f53\u7814\u78e8<\/strong><\/p>\n<p>\u56fa\u4f53\u7814\u78e8\u8fd8\u53ef\u4ee5\u8bf1\u5bfc\u6325\u53d1\u6027\u6709\u673a\u91d1\u5c5e\u524d\u4f53\u5f62\u6210\u6d3b\u5316\u7684MOF\uff0c\u5176\u4e2d\u56fa\u6001\u6750\u6599\u5fc5\u987b\u5145\u5206\u6df7\u5408\u3002\u5728\u7814\u78e8\u8fc7\u7a0b\u4e2d\uff0c\u6709\u673a\u91d1\u5c5e\u524d\u4f53\u7684\u5347\u534e\u84b8\u6c14\u8fc5\u901f\u6269\u6563\u5230MOF\u8154\u4e2d\u3002\u968f\u540e\uff0c\u5728\u9002\u5f53\u7684\u6e29\u5ea6\u4e0b\uff0c\u7528H<sub>2<\/sub>\u6c14\u4f53\u5904\u7406\u5d4c\u5165\u5728MOF\u4e2d\u7684\u6709\u673a\u91d1\u5c5e\u524d\u9a71\u4f53\uff0c\u5bfc\u81f4MNP\/MOF\u590d\u5408\u6750\u6599\u3002\u56fa\u4f53\u7814\u78e8\u7684\u663e\u7740\u4f18\u70b9\u5728\u4e8e\u5176\u6613\u4e8e\u64cd\u4f5c\uff0c\u5e76\u4e14\u53ef\u4ee5\u907f\u514d\u5e9f\u6eb6\u5242\u3002\u53e6\u5916\u7684\u4f18\u70b9\u662f\u6240\u6709\u5f15\u5165\u7684\u524d\u4f53\u7684\u5b8c\u5168\u52a0\u8f7d\uff0c\u56e0\u6b64\u5b83\u4eec\u7684\u52a0\u8f7d\u91cf\u53ef\u4ee5\u5bb9\u6613\u5730\u63a7\u5236\u3002\u7f3a\u70b9\u662f\u91d1\u5c5e\u524d\u4f53\u5fc5\u987b\u662f\u6325\u53d1\u6027\u7684\u5e76\u4e14\u901a\u5e38\u662f\u6602\u8d35\u7684\u3002\u5173\u4e8e\u56fa\u4f53\u7814\u78e8\u7684\u5c11\u6570\u62a5\u9053\u4ec5\u9650\u4e8eAu\/MOF\u590d\u5408\u6750\u6599\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>6 <\/strong><strong>\u901a\u8fc7\u7528<\/strong><strong>Me<sub>2<\/sub>Au<\/strong><strong>\uff08<\/strong><strong>acac<\/strong><strong>\uff09\u56fa\u4f53\u7814\u78e8<\/strong><strong>CPL-2<\/strong><strong>\uff0c\u7136\u540e\u8fdb\u884c<\/strong><strong>H<sub>2<\/sub><\/strong><strong>\u8fd8\u539f\u5408\u6210<\/strong><strong>Au\/CPL-2<\/strong><strong>\u590d\u5408\u6750\u6599<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-88411\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/06\/c6cs00724d-f6_hi-res.gif\" alt=\"\" width=\"700\" height=\"237\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>7 <\/strong><strong>\uff08<\/strong><strong>a<\/strong><strong>\uff09<\/strong><strong>Cd<sub>2<\/sub><\/strong><strong>\uff08<\/strong><strong>L<\/strong><strong>\uff09\uff08<\/strong><strong>H<sub>2<\/sub>O<\/strong><strong>\uff09\u00b7<\/strong><strong>0.5H<sub>2<\/sub>O<\/strong><strong>\u7684<\/strong><strong>3D<\/strong><strong>\u7f51\u7edc\u7684\u89c6\u56fe\uff1b\uff08<\/strong><strong>b<\/strong><strong>\uff09<\/strong><strong>Au\/Cd<sub>2<\/sub><\/strong><strong>\uff08<\/strong><strong>L<\/strong><strong>\uff09\uff08<\/strong><strong>H<sub>2<\/sub>O<\/strong><strong>\uff09\u00b7<\/strong><strong>0.5H<sub>2<\/sub>O<\/strong><strong>\u7684<\/strong><strong>AuL<sub>III<\/sub><\/strong><strong>\u8fb9\u7f18<\/strong><strong>FT-EXAFS<\/strong><strong>\u5149\u8c31<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-88412\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/06\/c6cs00724d-f7_hi-res.gif\" alt=\"\" width=\"700\" height=\"274\" \/><\/p>\n<p><strong>2.1.5\u00a0<\/strong><strong>\u70ed\u5206\u89e3<\/strong><\/p>\n<p>\u70ed\u5206\u89e3\u662f\u5408\u6210MNP@MOF\u6750\u6599\u7684\u76f8\u5bf9\u8f83\u65b0\u7684\u65b9\u6cd5\u3002\u4f18\u70b9\u662f\u5176\u6781\u7b80\u5355\uff0c\u56e0\u4e3a\u4e0d\u5f15\u5165\u53e6\u5916\u7684\u91d1\u5c5e\u524d\u4f53\u3002\u5728MOFs\u7684\u90e8\u5206\u70ed\u5206\u89e3\u8fc7\u7a0b\u4e2d\u4ea7\u751fMNP\uff0c\u5e76\u4e14\u9009\u62e9\u5408\u9002\u7684\u6e29\u5ea6\u81f3\u5173\u91cd\u8981\u3002\u6e29\u5ea6\u8fc7\u9ad8\uff0c\u5219MOF\u7ed3\u6784\u5b8c\u5168\u5d29\u6e83\uff0c\u800c\u6781\u4f4e\u6e29\u4e0d\u80fd\u4ea7\u751fMNP\u3002\u56e0\u6b64\uff0c\u57fa\u4e8e\u70ed\u5206\u89e3\u7684\u6210\u529f\u62a5\u9053\u8fdc\u4e0d\u6b62\u4e8e\u79d1\u5927-1\u548cNi-MOF-74\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>8 Ni-MOF-74<\/strong><strong>\u90e8\u5206\u70ed\u5206\u89e3<\/strong><strong>Ni@MOF<\/strong><strong>\u7684\u5408\u6210\u793a\u610f\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-88413\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/06\/c6cs00724d-f8_hi-res.gif\" alt=\"\" width=\"700\" height=\"220\" \/><\/p>\n<p><strong>2.2\u00a0<\/strong><strong>\u5f15\u5165<\/strong><strong>MNP<\/strong><strong>\u968f\u540e<\/strong><strong>MOF<\/strong><strong>\u589e\u957f<\/strong><\/p>\n<p>\u5c06\u9884\u5148\u5f62\u6210\u7684MNP\u4f5c\u4e3a\u79cd\u5b50\u6216\u6210\u6838\u4e2d\u5fc3\u5f15\u5165\u5230MOF\u8d77\u59cb\u6750\u6599\u4e2d\u662f\u8bf1\u5bfcMNP\u5468\u56f4\u7684MOF\u751f\u957f\/\u7ec4\u88c5\u7684\u5408\u7406\u7b56\u7565\uff0c\u7ed9\u51faMNP@MOF\u590d\u5408\u6750\u6599\u3002\u7b56\u7565\u4e5f\u88ab\u79f0\u4e3a\u201c\u74f6\u88c5\u8239\u201d\uff0c\u5176\u5148\u51b3\u6761\u4ef6\u662fMNP\u8868\u9762\u4e0a\u7684\u201c\u7c98\u5408\u5242\u201d\uff0c\u4ee5\u951a\u5b9aMOF\u7684\u5f02\u8d28\u751f\u957f\u5e76\u907f\u514d\u5747\u5300\u7684MOF\u6210\u6838\u3002\u8be5\u7b56\u7565\u7684\u4e24\u4e2a\u663e\u7740\u4f18\u70b9\u662f\uff1a\uff081\uff09\u590d\u5408\u6750\u6599\u4e2dMNP\u7684\u5c3a\u5bf8\uff0c\u5f62\u72b6\u548c\u7ec4\u6210\u53ef\u4ee5\u9884\u5148\u63a7\u5236\uff1b\uff082\uff09\u6838\u58f3\u7ed3\u6784\u7684MNP@MOF\u7684\u5f62\u6210\u662f\u5408\u7406\u53ef\u80fd\u7684\u3002\u56e0\u6b64\uff0c\u5e76\u975e\u6240\u6709\u7684MOF\u90fd\u9002\u7528\u4e8e\u8fd9\u79cd\u5408\u6210\u65b9\u6cd5\uff0c\u76ee\u524d\u7684\u62a5\u544a\u4e3b\u8981\u662f\u57fa\u4e8eZIF-8\u7b49MOF\u3002\u53e6\u5916\uff0cMNP\u548cMOF\u4e4b\u95f4\u7684\u7c98\u5408\u5242\uff08\u4f8b\u5982PVP\uff09\u96be\u4ee5\u5b8c\u5168\u6d17\u6389\uff0c\u5bf9\u4e8e\u6d3b\u6027\u90e8\u4f4d\u7684\u53ef\u53ca\u6027\u662f\u4e0d\u5229\u7684\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>9<\/strong> <strong>\u81ea\u7ec4\u88c5\u793a\u610f\u56fe\u8868\u793a<\/strong><strong>HKUST-1 Au NPs<\/strong><strong>\u805a\u96c6\u4f53<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-88414\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/06\/c6cs00724d-f9_hi-res.gif\" alt=\"\" width=\"700\" height=\"195\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>10 <\/strong><strong>\u663e\u793a\u4e86\u5728<\/strong><strong>ZIF-8<\/strong><strong>\u6676\u4f53\u4e2d\u53ef\u63a7\u5236\u7684\u5305\u5c01<\/strong><strong>NP<\/strong><strong>\u3002\u901a\u8fc7\u8868\u9762\u6d3b\u6027\u5242<\/strong><strong>PVP<\/strong><strong>\u7684\u8868\u9762\u6539\u6027\uff0c\u5404\u79cd\u5c3a\u5bf8\uff0c\u5f62\u72b6\u548c\u7ec4\u6210\u7684<\/strong><strong>NP<\/strong><strong>\u53ef\u4ee5\u7528\u53d7\u63a7\u7684\u7a7a\u95f4\u5206\u5e03\u5c01\u88c5\u5230<\/strong><strong>ZIF-8<\/strong><strong>\u6676\u4f53<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-88415\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/06\/c6cs00724d-f10_hi-res.gif\" alt=\"\" width=\"700\" height=\"442\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>11<\/strong><strong>\uff08<\/strong><strong>a<\/strong><strong>\uff09\u521d\u59cb\u56fa\u4f53<\/strong><strong>Pt-Ni<\/strong><strong>\u591a\u9762\u4f53\uff1b\uff08<\/strong><strong>b<\/strong><strong>\uff09<\/strong><strong>PtNi<\/strong><strong>\u6846\u67b6<\/strong><strong>@ MOF<\/strong><strong>\u4e2d\u95f4\u4f53<\/strong><strong>I<\/strong><strong>\uff1b\uff08<\/strong><strong>c<\/strong><strong>\uff09<\/strong><strong>PtNi<\/strong><strong>\u6846\u67b6<\/strong><strong>@ MOF<\/strong><strong>\u4e2d\u95f4\u4f53<\/strong><strong>II<\/strong><strong>\uff1b\uff08<\/strong><strong>d<\/strong><strong>\uff09\u6700\u7ec8\u7684<\/strong><strong>PtNi<\/strong><strong>\u6846\u67b6<\/strong><strong>@ MOF<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-88416\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/06\/c6cs00724d-f11_hi-res.gif\" alt=\"\" width=\"700\" height=\"370\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>12 <\/strong><strong>\u7eb3\u7c73\u6676\u4f53<\/strong><strong>ZIF-8<\/strong><strong>\u86cb\u9ec4<\/strong><strong>&#8211;<\/strong><strong>\u58f3\u7eb3\u7c73\u7ed3\u6784\u7684\u793a\u610f\u56fe\u751f\u957f\u8fc7\u7a0b<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-88417\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/06\/c6cs00724d-f12_hi-res.gif\" alt=\"\" width=\"700\" height=\"348\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>13 <\/strong><strong>\u663e\u793a\u4e86<\/strong><strong>Au@ZIF-8<\/strong><strong>\u7eb3\u7c73\u53cd\u5e94\u5668\u7684\u5408\u6210\u793a\u610f\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-88419\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/06\/c6cs00724d-f13_hi-res.gif\" alt=\"\" width=\"700\" height=\"220\" \/><\/p>\n<p><strong>2.3\u00a0<\/strong><strong>\u9010\u6b65\u5408\u6210<\/strong><strong>MNPs\/MOFs<\/strong><strong>\u548c<\/strong><strong>MOF\/MNP\/MOFs<\/strong><\/p>\n<p>MOF\u7684\u9884\u5408\u6210\u6216MNP\u7684\u9884\u5f62\u6210\uff0c\u968f\u540e\u5176\u5b83\u6210\u5206\u7684\u968f\u540e\u751f\u957f\uff0c\u76ee\u7684\u662f\u83b7\u5f97\u9650\u5236\u5728MOF\u9897\u7c92\u5185\u7684MNP\u3002\u53ef\u4ee5\u901a\u8fc7MOF\u548cMNP\u4e24\u8005\u7684\u9884\u5f62\u6210\u6765\u5b9e\u73b0\uff0c\u8fd9\u4e9bMOF\u548cMNP\u88ab\u6df7\u5408\u5e76\u5267\u70c8\u6405\u62cc\u6216\u8d85\u58f0\u6ce2\u4ee5\u4fbf\u57fa\u4e8e\u7269\u7406\u5438\u9644\u548c\/\u6216\u9759\u7535\u76f8\u4e92\u4f5c\u7528\u5c06\u5b83\u4eec\u7ec4\u88c5\u5728\u4e00\u8d77\uff0c\u4ece\u800c\u5f97\u5230MNP\/MOF\u3002\u6700\u8fd1\u8fdb\u4e00\u6b65\u5f00\u53d1\u4e86\u9010\u6b65\u7ec4\u88c5\u7b56\u7565\uff0c\u4ee5\u63d0\u4f9b\u7a33\u5b9a\u7684MOF\/MNP\/MOF\u590d\u5408\u6750\u6599\u3002\u4e09\u5c42MOF\/MNP\/MOF\u7684\u5408\u6210\u81f3\u5c11\u9700\u8981\u4e09\u4e2a\u6b65\u9aa4\uff0c\u4f3c\u4e4e\u590d\u6742\uff0c\u4f46\u590d\u5408\u6750\u6599\u5177\u6709\u7279\u6b8a\u7684\u4f18\u70b9\uff1aMOF\u6838\u5fc3\u4e0d\u4ec5\u4f5c\u4e3a\u4f4d\u4e8e\u4e2d\u5c42\u7684MNP\u7684\u652f\u6301\uff0c\u800c\u4e14\u8fd8\u5f15\u8d77MOF\u5916\u58f3\u7684\u540e\u7eed\u751f\u957f\uff1bMOF\u58f3\u8986\u76d6\u4e2d\u95f4\u5c42MNP\uff0c\u4ee5\u63d0\u9ad8\u590d\u5408\u6750\u6599\u7684\u7a33\u5b9a\u6027\uff0c\u5e76\u786e\u5b9a\u50ac\u5316\u5242\u7684\u5c3a\u5bf8\u9009\u62e9\u6027\u3002\u5bf9\u4e8e\u6838-\u58f3\u7ed3\u6784\u7684MNP\/MOF\u50ac\u5316\u5242\uff0c\u5f53MOF\u58f3\u7684\u539a\u5ea6\u63a7\u5236\u6784\u6210\u91cd\u5927\u6311\u6218\u65f6\uff0c\u5bf9\u4e8e\u53cd\u5e94\u6548\u7387\u81f3\u5173\u91cd\u8981\uff0c\u56e0\u4e3a\u539a\u7684MOF\u58f3\u663e\u7740\u51cf\u7f13\u4e86\u5e95\u7269\/\u4ea7\u7269\u7684\u8fd0\u8f93\u3002\u76ee\u524d\u7684\u8bbe\u8ba1\u4f7f\u5f97\u6240\u5f97\u5230\u7684\u6838-\u58f3\u7ed3\u6784\u7684MOF\/MNP\/MOF\u50ac\u5316\u5242\u5177\u6709\u7279\u522b\u9ad8\u7684\u9009\u62e9\u6027\u548c\u9ad8\u53cd\u5e94\u6548\u7387\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>14\u00a0<\/strong><strong>\u5939\u5fc3\u72b6<\/strong><strong>MIL-101@Pt@MIL-101<\/strong><strong>\u7684\u5408\u6210\u8def\u7ebf\uff0c\u5305\u62ec\u5939\u5728<\/strong><strong>MIL-101<\/strong><strong>\u7684\u6838\u5fc3\u548c\u58f3\u4f53\u4e4b\u95f4\u7684<\/strong><strong>PtNP<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-88421\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/06\/c6cs00724d-f14_hi-res.gif\" alt=\"\" width=\"700\" height=\"394\" \/><\/p>\n<p><strong>2.4\u00a0<\/strong><strong>\u4e00\u6b65\u5408\u6210<\/strong><strong>MNPs\/MOFs<\/strong><\/p>\n<p>\u4e00\u79cd\u7b80\u5355\u6709\u6548\u7684\u4e00\u6b65\u5408\u6210\u3002\u6700\u7b80\u5355\u548c\u76f4\u63a5\u7684\u65b9\u6cd5\u662f\u5c06\u91d1\u5c5e\u524d\u4f53\u548cMOF\u7684\u539f\u6599\u6df7\u5408\u5728\u4e00\u8d77\uff0c\u7136\u540e\u8fdb\u884c\u81ea\u7ec4\u88c5\u5de5\u827a\u4ee5\u63d0\u4f9bMNP\/MOF\u590d\u5408\u6750\u6599\u3002\u5728\u53cd\u5e94\u8fc7\u7a0b\u4e2d\uff0c\u4f7f\u7528DMF\u548c\/\u6216H<sub>2<\/sub>\u4f5c\u4e3a\u91d1\u5c5e\u524d\u4f53\u7684\u6e29\u548c\u8fd8\u539f\u5242\u3002\u4e0e\u4ee5\u524d\u7684\u65b9\u6cd5\u76f8\u6bd4\uff0c\u8be5\u65b9\u6cd5\u5f88\u7b80\u5355\uff0c\u4f46\u901a\u5e38\u9700\u8981\u6709\u673a\u63a5\u5934\u4e2d\u7684\u7279\u5b9a\u539f\u5b50\u6216\u5b98\u80fd\u56e2\u6355\u83b7\u91d1\u5c5e\u524d\u4f53\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>15 <\/strong><strong>\u901a\u8fc7\uff08<\/strong><strong>a<\/strong><strong>\uff09\u901a\u8fc7\u4ec5\u901a\u8fc7\u8fd8\u539f<\/strong><strong>DMF<\/strong><strong>\u548c\uff08<\/strong><strong>b<\/strong><strong>\uff09\u52a8\u529b\u5b66\u539f\u4f4d\u4e00\u6b65\u6cd5\u7684\u539f\u4f4d\u4e00\u6b65\u7b56\u7565\u5c06<\/strong><strong>PtNP<\/strong><strong>\u7eb3\u5165<\/strong><strong>MOFs<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-88422\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/06\/c6cs00724d-f15_hi-res.gif\" alt=\"\" width=\"700\" height=\"442\" \/><\/p>\n<p><strong>3 \u8868\u5f81\u5de5\u5177<\/strong><\/p>\n<p>\u7531\u4e8eMNP\/MOF\u590d\u5408\u6750\u6599\u662f\u5177\u6709\u6709\u673a\u548c\u65e0\u673a\u7ec4\u5206\u7684\u590d\u6742\u7cfb\u7edf\uff0c\u56e0\u6b64\u4f7f\u7528\u5404\u79cd\u5206\u6790\u548c\u5149\u8c31\u5de5\u5177\u8fdb\u884c\u8868\u5f81\u3002\u4e0d\u540c\u7684\u8868\u5f81\u5de5\u5177\u7ed9\u51fa\u4e86\u5173\u4e8e\u7ed3\u6784\uff0c\u7ec4\u6210\u548c\u5b54\u6027\u8d28\u7684\u5404\u79cd\u4fe1\u606f\u3002\u901a\u8fc7\u5404\u79cd\u65b9\u6cd5\u83b7\u5f97\u7684\u7efc\u5408\u8868\u5f81\u7ed3\u679c\u80fd\u591f\u66f4\u5168\u9762\u5730\u4e86\u89e3\u590d\u5408\u6750\u6599\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u4e86\u89e3\u50ac\u5316\u5242\u5728\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u7684\u72b6\u6001\uff0c\u5728\u50ac\u5316\u53cd\u5e94\u524d\u540e\u9700\u8981\u8fdb\u884c\u8868\u5f81\u3002<\/p>\n<p><strong>3.1\u00a0<\/strong><strong>\u6210\u5206\u6d4b\u5b9a<\/strong><\/p>\n<p>\u9610\u660eMNP\/MOF\u590d\u5408\u6750\u6599\u7684\u8be6\u7ec6\u7ec4\u6210\uff0c\u5305\u62ec\u7535\u611f\u8026\u5408\u7b49\u79bb\u5b50\u4f53\uff08ICP\uff09\u5149\u8c31\uff0c\u5143\u7d20\u5206\u6790\uff0c\u7ea2\u5916\uff08IR\uff09\u5149\u8c31\uff0c\u7d2b\u5916-\u53ef\u89c1\u5149\u8c31\u548c\u6838\u78c1\u5171\u632f\uff08NMR\uff09\u5149\u8c31\u7b49\u57fa\u672c\u8868\u5f81\u5de5\u5177\u901a\u5e38\u662f\u5728\u5408\u6210\u8fc7\u7a0b\u4e2d\u4f7f\u7528\u3002<\/p>\n<p><strong>3.2\u00a0<\/strong><strong>\u7c89\u672b<\/strong><strong>X<\/strong><strong>\u5c04\u7ebf\u884d\u5c04<\/strong><\/p>\n<p>\u7c89\u672bXRD\u662f\u68c0\u6d4b\u51e0\u4e4e\u6240\u6709\u6750\u6599\u7684\u7ed3\u6676\u5ea6\u548c\u76f8\u7eaf\u5ea6\u7684\u6700\u91cd\u8981\u7684\u8868\u5f81\u6280\u672f\u4e4b\u4e00\u3002\u5bf9\u4e8eMNP\/MOF\u590d\u5408\u6750\u6599\uff0c\u7531\u4e8e\u4ee5\u4e0b\u539f\u56e0\uff0c\u7c89\u672bXRD\u662f\u81f3\u5173\u91cd\u8981\u7684\u3002\uff081\uff09\u5373\u4f7f\u5728\u590d\u5408\u6750\u6599\u7684\u5236\u5907\u8fc7\u7a0b\u4e2d\uff0c\u7279\u522b\u662f\u5728\u82db\u523b\u7684\u6761\u4ef6\u4e0b\uff0c\u5927\u591a\u6570MOF\u4e5f\u4e0d\u662f\u975e\u5e38\u575a\u56fa\u7684\uff0c\u5e76\u4e14\u5b83\u4eec\u7684\u7ed3\u6784\u5728\u50ac\u5316\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u5bb9\u6613\u584c\u9677\u3002MOFs\u7684\u7a33\u5b9a\u6027\u5728\u5176\u50ac\u5316\u5e94\u7528\u65b9\u9762\u662f\u4e00\u4e2a\u91cd\u5927\u95ee\u9898\u3002\u56e0\u6b64\uff0c\u57fa\u4e8e\u7c89\u672bXRD\u7684MOFs\u7684\u76f8\u7eaf\u5ea6\uff0c\u7ed3\u6676\u5ea6\u548c\u7ed3\u6784\u5b8c\u6574\u6027\u7684\u7814\u7a76\u51e0\u4e4e\u662f\u4e0d\u53ef\u6216\u7f3a\u7684\u3002\uff082\uff09MNP\uff0fMOF\u590d\u5408\u6750\u6599\u7684\u7c89\u672bXRD\u56fe\u8c31\u57fa\u4e8eScherrer\u65b9\u7a0b\uff1b\uff083\uff09\u7279\u522b\u662f\uff0c\u4e3a\u4e86\u8bc4\u4f30\u662f\u5426\u4fdd\u7559MOF\u7ed3\u6784\u548c\/\u6216MNP\u5c3a\u5bf8\uff0c\u5bf9\u50ac\u5316\u53cd\u5e94\u540e\u7684MNP\/MOF\u590d\u5408\u6750\u6599\u901a\u5e38\u9700\u8981\u68c0\u67e5\u7c89\u672bXRD\u56fe\u6848\u3002<\/p>\n<p><strong>3.3 N<sub>2<\/sub><\/strong><strong>\u5438\u9644<\/strong><\/p>\n<p>\u5747\u5300\u7684\u5b54\u5f84\u548c\u5927\u7684\u8868\u9762\u79ef\u662fMOFs\u7684\u91cd\u8981\u7279\u5f81\u3002N<sub>2<\/sub>\u5438\u9644\u662f\u8868\u5f81\u8d1f\u8f7dMNP\u548c\u50ac\u5316\u53cd\u5e94\u4e4b\u524d\u548c\u4e4b\u540e\u7684MOFs\u7684\u5b54\u5f84\u5206\u5e03\u548c\u5b54\u4f53\u79ef\u4ee5\u53caMOF\u7684\u8868\u9762\u79ef\u7684\u6709\u6548\u65b9\u6cd5\u3002\u6b64\u5916\uff0c\u4e3a\u4e86\u8bc4\u4f30\u5728\u50ac\u5316\u540e\u662f\u5426\u4fdd\u6301MOF\u7ed3\u6784\uff0cN<sub>2<\/sub>\u5438\u9644\u80fd\u591f\u63d0\u4f9b\u6bd4\u7c89\u672bXRD\u6570\u636e\u66f4\u9ad8\u7684\u7075\u654f\u5ea6\uff1b\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u5728\u52a0\u8f7dMNP\u4e4b\u540e\uff0cMOF\u7684\u8868\u9762\u79ef\u7684\u51cf\u5c11\u4e0d\u9002\u5408\u4f5c\u4e3a\u8bc4\u4f30MNP\u662f\u5426\u5e76\u5165MOF\u5b54\u5185\u7684\u4e2a\u4f53\u6807\u51c6\u3002<\/p>\n<p><strong>3.4 X<\/strong><strong>\u5c04\u7ebf\u5149\u7535\u5b50\u80fd\u8c31<\/strong><\/p>\n<p>X\u5c04\u7ebf\u5149\u7535\u5b50\u80fd\u8c31\uff08XPS\uff09\u662f\u4e86\u89e3MNP\/MOF\u590d\u5408\u6750\u6599\u7535\u5b50\u7ed3\u6784\u7684\u6709\u529b\u5de5\u5177\u3002XPS\u53ef\u4ee5\u786e\u5b9aMNP\/MOF\u590d\u5408\u6750\u6599\u4e2d\u4e0d\u540c\u7269\u79cd\u7684\u6c27\u5316\u6001\u3002<\/p>\n<p><strong>3.5\u00a0<\/strong><strong>\u7535\u5b50\u987a\u78c1\u5171\u632f<\/strong><\/p>\n<p>\u7535\u5b50\u987a\u78c1\u5171\u632f\uff08EPR\uff09\u5149\u8c31\u5bf9\u6837\u54c1\u7684\u4f53\u79ef\u7279\u6027\u654f\u611f\uff0c\u5e76\u5df2\u88ab\u7528\u4e8e\u7814\u7a76\u4f4d\u4e8eMOFs\u4e2d\u7684\u5c0fAg\u7c07\u3002Ag@MOF\u7684EPR\u5149\u8c31\u663e\u793a\u51fa\u4ee5g=2.001\u4e3a\u4e2d\u5fc3\u7684\u660e\u786e\u5b9a\u4e49\u7684\u5404\u5411\u540c\u6027\u56db\u65b9\uff0c\u8868\u660e\u5f62\u6210\u4e86Ag3\uff080\uff09\u7c07\u3002EPR\u5149\u8c31\u6cd5\u4e5f\u7528\u4e8e\u5728MNPs\/MOFs\u7684\u539f\u4f4d\u5f62\u6210\u8fc7\u7a0b\u4e2d\u9a8c\u8bc1\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u3002UiO-66-NH<sub>2<\/sub>\u66f4\u9ad8\u7684\u6d3b\u6027\uff0c\u8fd9\u53ef\u80fd\u662f\u7531\u4e8e\u5728\u524d\u4e00\u79cd\u50ac\u5316\u5242\u4e2d\u7535\u5b50\u8f6c\u79fb\u52a0\u901f\u7684\u8fc7\u7a0b\u4e2d\u5f15\u8d77\u7684\u3002<\/p>\n<p><strong>3.6\u00a0<\/strong><strong>\u5fae\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n<p>MNP\/MOF\u590d\u5408\u6750\u6599\u7684\u50ac\u5316\u6027\u80fd\u4e0e\u5176\u7ec4\u6210\u548c\u5fae\u89c2\u7ed3\u6784\u5bc6\u5207\u76f8\u5173\u3002\u56e0\u6b64\uff0c\u4e3a\u4e86\u66f4\u597d\u5730\u4e86\u89e3MNP\/MOF\u590d\u5408\u6750\u6599\u7684\u50ac\u5316\u6027\u80fd\uff0c\u6709\u5fc5\u8981\u5bf9\u6240\u6709\u50ac\u5316\u5242\u8fdb\u884c\u663e\u5fae\u7ed3\u6784\u89c2\u5bdf\u3002\u626b\u63cf\u7535\u5b50\u663e\u5fae\u955c\uff08SEM\uff09\u786e\u5b9a\u4e86MOFs\u548cMNP\/MOF\u590d\u5408\u6750\u6599\u7684\u5c3a\u5bf8\u548c\u5f62\u6001\u3002\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\uff08TEM\uff09\u786e\u5b9aMNPs\u7684\u5c3a\u5bf8\uff0c\u5206\u5e03\u548c\u5206\u6563\u3002\u7279\u522b\u5730\uff0c\u901a\u5e38\u9700\u8981\u5728\u50ac\u5316\u540e\u68c0\u67e5MNP\u76f8\u5bf9\u4e8eMOF\u9897\u7c92\u7684\u5c3a\u5bf8\u548c\u5206\u6563\u6027\uff0c\u4ee5\u786e\u5b9a\u590d\u5408\u50ac\u5316\u5242\u7684\u7a33\u5b9a\u6027\u548c\u53ef\u518d\u5faa\u73af\u6027\u3002\u4e3a\u4e86\u786e\u5b9a\u975e\u5e38\u5fae\u5c0f\u7684MNP\u7684\u5c3a\u5bf8\u548c\u5f62\u6001\uff0c\u6709\u65f6\u5019\uff0c\u5927\u89d2\u5ea6\u73af\u5f62\u6697\u573a\u6210\u50cf\u626b\u63cf\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\uff08HAADF-STEM\uff09\u66f4\u6709\u5e2e\u52a9\u3002\u9009\u62e9\u533a\u57df\u7535\u5b50\u884d\u5c04\uff08SAED\uff09\u662f\u68c0\u67e5MNP\u7684\u7ed3\u6676\u5ea6\u7684\u6709\u7528\u5de5\u5177\uff0c\u5e76\u4e14\u8fd8\u57fa\u4e8e\u6676\u683c\u8fb9\u7f18\u6765\u8bc6\u522b\u76f8\u4f4d\u3002\u5728\u6838-\u58f3\u6216\u5408\u91d1\u7ed3\u6784\u4e2d\u8bc6\u522b\u53cc\u91d1\u5c5eNP\uff0c\u7279\u522b\u662f\u5c0f\u578bNP\u3002\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e2a\u95ee\u9898\uff0c\u80fd\u91cf\u8272\u6563X\u5c04\u7ebf\u5149\u8c31\uff08EDS\uff09\uff0c\u5143\u7d20\u6620\u5c04\u548c\u7535\u5b50\u80fd\u91cf\u635f\u5931\u5149\u8c31\uff08EELS\uff09\u63d0\u4f9b\u4e86\u91cd\u8981\u7684\u4fe1\u606f\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>16 Pt-Ni<\/strong><strong>\u6846\u67b6<\/strong><strong>Ni-MOF-74<\/strong><strong>\u65ad\u5c42\u91cd\u5efa\u4e09\u7ef4\u53ef\u89c6\u5316\u7684\u516d\u4e2a\u6295\u5f71\u56fe\u50cf<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-88423\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/06\/c6cs00724d-f16_hi-res.gif\" alt=\"\" width=\"700\" height=\"625\" \/><\/p>\n<p><strong>3.7 X<\/strong><strong>\u5c04\u7ebf\u5438\u6536\u5149\u8c31<\/strong><\/p>\n<p>\u867d\u7136TEM\u89c2\u5bdf\u5bf9\u4e8e\u4e86\u89e3MNP\/MOF\u590d\u5408\u6750\u6599\u7684\u5fae\u89c2\u7ed3\u6784\u975e\u5e38\u6709\u6548\uff0c\u4f46\u5b83\u53ea\u63d0\u4f9b\u4e86\u8d85\u5c0f\u7c92\u5b50\u7684\u6709\u9650\u4fe1\u606f\u3002\u4f5c\u4e3a\u989d\u5916\u7684\u652f\u6301\uff0cX\u5c04\u7ebf\u5438\u6536\u5149\u8c31\uff08XAS\uff09\u53ef\u4ee5\u7cbe\u786e\u5730\u786e\u5b9a\u975e\u5e38\u5c0f\u7684\u91d1\u5c5e\u7c07\u6216\u751a\u81f3\u5355\u4e2a\u539f\u5b50\u7684\u5c3a\u5bf8\uff0c\u914d\u4f4d\u73af\u5883\u548c\u5316\u5b66\u5f62\u5f0f\u3002<\/p>\n<p><strong>4 \u91cd\u8981\u7684\u95ee\u9898<\/strong><\/p>\n<p>\u591a\u5e74\u6765\uff0c\u5bf9MNP\/MOF\u8fdb\u884c\u6df1\u5165\u7814\u7a76\uff0c\u53d6\u5f97\u4e86\u91cd\u5927\u8fdb\u5c55\u3002\u4e3a\u4e86\u8fdb\u4e00\u6b65\u53d1\u5c55\u8be5\u9886\u57df\u3002\u7ecf\u5178MOF-5\u548cMOF-177\u7528\u4e8e\u5728\u65e9\u671f\u9636\u6bb5\u7a33\u5b9aMNP\uff0c\u7136\u540e\u9010\u6e10\u88ab\u66f4\u7a33\u5b9a\u7684MOF\u66ff\u4ee3\uff0c\u53ef\u4fdd\u8bc1\u5927\u591a\u6570\u53cd\u5e94\u6761\u4ef6\u4e0b\u50ac\u5316\u5242\u7684\u7a33\u5b9a\u6027\u3002\u8fd1\u5e74\u6765\u5df2\u7ecf\u6709\u8d8a\u6765\u8d8a\u591a\u7684\u7a33\u5b9a\u7684MOF\u88ab\u62a5\u9053\u3002\u867d\u7136MOF\u8154\u7406\u8bba\u4e0a\u53ef\u4ee5\u9632\u6b62MNP\u7684\u8fc1\u79fb\u548c\u805a\u96c6\uff0c\u4f46\u5176\u5c3a\u5bf8\u96be\u4ee5\u63a7\u5236\uff0c\u56e0\u4e3a\u53d7\u5230\u8bb8\u591a\u56e0\u7d20\u7684\u5f71\u54cd\uff1a\uff081\uff09\u91d1\u5c5e\u524d\u4f53\u7684\u7c7b\u578b\uff1b\uff082\uff09\u91d1\u5c5e\u524d\u4f53\u7684\u6d53\u5ea6\uff1b\uff083\uff09\u6eb6\u5242\u7684\u6027\u8d28\uff1b\uff084\uff09\u91d1\u5c5e\u524d\u4f53\u7684\u8fd8\u539f\u5242\uff1b\uff085\uff09MOF\u7684\u6027\u8d28\uff0c\uff086\uff09\u751f\u4ea7MNP\/MOF\u7684\u5408\u6210\u6761\u4ef6\u3002\u4e0a\u8ff0\u51e0\u4e2a\u53c2\u6570\u901a\u5e38\u4e00\u8d77\u5de5\u4f5c\u6765\u786e\u5b9a\u6700\u7ec8\u7ed3\u679c\u3002\u6b64\u5916\uff0c\u4e0eMNP\u76f8\u4e92\u4f5c\u7528\u7684\u7279\u5b9a\u5b98\u80fd\u56e2\u6216MOF\u5b54\u9699\u73af\u5883\u663e\u7740\u5f71\u54cdMNP\u7684\u5927\u5c0f\u3002\u5173\u4e8eMNP\u76f8\u5bf9\u4e8eMOF\u9897\u7c92\u7684\u4f4d\u7f6e\u7684\u76f4\u63a5\u8bc1\u636e\uff0c\u5373MNP\u662f\u5426\u5728MOF\u5185\u6216\u5176\u5916\u8868\u9762\u4e0a\uff0c\u5728\u4e00\u4e9b\u62a5\u544a\u4e2d\u4ecd\u7136\u662f\u4e0d\u786e\u5b9a\u7684\u3002\u867d\u5df2\u7ecf\u63d0\u5230\u4e0a\u8ff0\u7684\u65ad\u5c42\u626b\u63cf\u91cd\u5efa\u5de5\u4f5c\uff0c\u4f46\u6d4b\u91cf\u662f\u8017\u65f6\u7684\uff0c\u5e76\u4e14\u5f88\u5927\u7a0b\u5ea6\u4e0a\u4f9d\u8d56\u4e8eTEM\u64cd\u4f5c\u5458\u7684\u7ecf\u9a8c\u3002\u6b64\u5916\uff0c\u76f8\u5173\u9644\u4ef6\u9644\u7740\u5230\u663e\u5fae\u955c\u662f\u5fc5\u8981\u7684\u3002\u6240\u6709\u8fd9\u4e9b\u56e0\u7d20\u4f7f\u5f97\u8fd9\u79cd\u8868\u5f81\u6280\u672f\u4e0d\u53ef\u7528\u4e8e\u8bb8\u591a\u79d1\u5b66\u5bb6\u3002\u56e0\u6b64\uff0c\u6709\u5fc5\u8981\u5f00\u53d1\u80fd\u591f\u63d0\u4f9b\u76f8\u5173\u7ed3\u6784\u4fe1\u606f\u7684\u5408\u9002\u6280\u672f\uff0c\u5e76\u4e14\u5927\u591a\u6570\u79d1\u5b66\u5bb6\u90fd\u5bb9\u6613\u83b7\u5f97\u3002\u542b\u6709\u7279\u5b9a\u5c3a\u5bf8\u548c\u5f62\u6001\u7684MNP\u7684MNP\/MOF\u590d\u5408\u6750\u6599\u7684\u5408\u6210\u662f\u975e\u5e38\u9700\u8981\u7684\u3002<\/p>\n<p><strong>5 MNPs<\/strong><strong>\u548c<\/strong><strong>MOFs<\/strong><strong>\u4e4b\u95f4\u7684\u534f\u540c\u50ac\u5316<\/strong><\/p>\n<p>MNP\/MOF\u590d\u5408\u6750\u6599\u53d1\u5c55\u7684\u4e3b\u8981\u76ee\u6807\u662f\u6269\u5927\u50ac\u5316\u53cd\u5e94\u8303\u56f4\uff0c\u589e\u5f3a\u50ac\u5316\u4f5c\u7528\u3002\u6362\u53e5\u8bdd\u8bf4\uff0c\u9700\u8981\u95eeMNP\/MOF\u590d\u5408\u6750\u6599\u5982\u4f55\u80fd\u591f\u6539\u5584\u50ac\u5316\u4f5c\u7528\u3002\u901a\u8fc7\u9002\u5f53\u8bbe\u8ba1\u7684MNP\/MOF\u590d\u5408\u50ac\u5316\u5242\uff0c\u6709\u5fc5\u8981\u8ba4\u8bc6\u5230\u4e24\u79cd\u7ec4\u5206\u7684\u4f5c\u7528\u4ee5\u53ca\u5b83\u4eec\u5982\u4f55\u534f\u540c\u589e\u6548\u7684\u6027\u80fd\u3002<\/p>\n<p><strong>5.1 MNPs<\/strong><strong>\u4f5c\u4e3a\u6d3b\u8dc3\u4e2d\u5fc3\uff0c\u7531<\/strong><strong>MOFs<\/strong><strong>\u7a33\u5b9a<\/strong><\/p>\n<p>\u9274\u4e8e\u5176\u6c38\u4e45\u6027\u5b54\u9699\u5ea6\u548c\u53ef\u8c03\u5b54\u5f84\/\u73af\u5883\uff0cMOFs\u662f\u7a33\u5b9aMNP\u7684\u7406\u60f3\u5019\u9009\u7269\u3002\u5c0f\u7684MNP\u53ef\u4ee5\u901a\u8fc7MOFs\u8fdb\u884c\u9650\u5236\u6216\u7a33\u5b9a\u5316\uff0c\u663e\u793a\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6d3b\u6027\u548c\u53ef\u56de\u6536\u6027\u3002\u5728\u8fd9\u4e9b\u590d\u5408\u6750\u6599\u4e2d\uff0cMNP\u662f\u6d3b\u6027\u4e2d\u5fc3\uff0cMOFs\u8868\u73b0\u4e3aMNP\u7684\u7a33\u5b9a\u5242\uff1b\u4ee3\u8868\u4e86MNPs\u548cMOF\u4e4b\u95f4\u6700\u7b80\u5355\u7684\u534f\u540c\u4f5c\u7528\uff0c\u5e76\u5728\u8be5\u9886\u57df\u7684\u4e00\u7cfb\u5217\u91cd\u8981\u51fa\u7248\u7269\u4e2d\u5f97\u5230\u8bc1\u5b9e\u3002<\/p>\n<p><strong>5.2 MNPs<\/strong><strong>\u4f5c\u4e3a\u6d3b\u6027\u4e2d\u5fc3\uff0c<\/strong><strong>MOFs<\/strong><strong>\u7a33\u5b9a<\/strong><strong>MNP<\/strong><strong>\u5e76\u63a7\u5236\u5927\u5c0f\u9009\u62e9\u6027<\/strong><\/p>\n<p>\u968f\u7740MOF\u5c01\u88c5\u7684MNP\u7684\u5b8c\u7f8e\u63a7\u5236\uff0cMOF\u58f3\u7684\u5747\u5300\u5b54\u5f84\u5141\u8bb8\u5176\u7528\u4f5cMNP\/MOF\u590d\u5408\u6750\u6599\u7684\u5206\u5b50\u7b5b\u3002\u56e0\u6b64\uff0cMOFs\u53ef\u4ee5\u9009\u62e9\u6027\u5730\u5141\u8bb8\u5c0f\u4e8eMOF\u5b54\u7684\u5e95\u7269\/\u4ea7\u7269\u901a\u8fc7\u5e76\u63a5\u89e6MNP\uff08\u6d3b\u6027\u4f4d\u70b9\uff09\uff0c\u540c\u65f6\u963b\u6b62\u8f83\u5927\u7684\u5206\u5b50\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>17 Pt@SALEM-2<\/strong><strong>\u4e0a\u7684\u5c3a\u5bf8\u9009\u62e9\u6027\u50ac\u5316\u4f5c\u7528<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-88424\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/06\/c6cs00724d-f17_hi-res.gif\" alt=\"\" width=\"700\" height=\"423\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>18<\/strong><strong>\u8089\u6842\u919b\u5728<\/strong><strong>Pt@UiO-66-NH<sub>2<\/sub><\/strong><strong>\u4e0a\u7684\u9ad8\u5ea6\u5316\u5b66\u9009\u62e9\u6027\u6c22\u5316<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-88425\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/06\/c6cs00724d-f18_hi-res.gif\" alt=\"\" width=\"700\" height=\"411\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>19 <\/strong><strong>\u9999\u8349\u919b\u52a0\u6c22\u8131\u6c27\u53ef\u80fd\u7684\u53cd\u5e94\u9014\u5f84<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-88426\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/06\/c6cs00724d-f19_hi-res.gif\" alt=\"\" width=\"700\" height=\"484\" \/><\/p>\n<p><strong>5.3 MNPs<\/strong><strong>\u4f5c\u4e3a\u6d3b\u6027\u4e2d\u5fc3\uff0c<\/strong><strong>MOFs<\/strong><strong>\u7a33\u5b9a<\/strong><strong>MNP<\/strong><strong>\u5e76\u6d53\u7f29\u6c14\u6001\u53cd\u5e94\u7269<\/strong><\/p>\n<p>\u5728\u8bb8\u591a\u91cd\u8981\u7684\u53cd\u5e94\u4e2d\uff0c\u6d89\u53ca\u6c14\u4f53\u5206\u5b50\u3002\u4ee5\u524d\u7684\u62a5\u544a\u663e\u793a\uff0cMNP\/MOF\u53ef\u4ee5\u4e30\u5bcc\u6d3b\u6027\u4f4d\u70b9\u5468\u56f4\u7684\u6c14\u4f53\u5206\u5b50\uff0c\u4ece\u800c\u63d0\u9ad8\u50ac\u5316\u6548\u7387\u3002\u5317\u5ddd\u7ec4\u7ec7\u62a5\u9053\u4e86MOF\u5bf9Pd\u7eb3\u7c73\u7ba1\u5438\u6c22\u7684\u5f71\u54cd\u3002\u56fa\u4f532HNMR\u5149\u8c31\u8868\u660e\uff0c\u56fa\u4f53\u6eb6\u6db2\uff08Pd+H\uff09\u548c\u6c22\u5316\u7269\uff08Pd-H\uff09\u5171\u5b58\u7684Pd@HKUST-1\u4e2d\u7684\u5e73\u53f0\u72b6\u533a\u57df\u7684\u538b\u529b\u5927\u4e8ePd\u7eb3\u7c73\u7ba1\u4e2d\u7684\u538b\u529b\u3002\u5bf9\u4e8ePd@CNUST-1\uff0c\u5728Pd\u7eb3\u7c73\u7ba1\u4e2d\u7684\u6bcf\u4e2aPd\u539f\u5b50\u7684\u6c22\u6c14\u5438\u9644\u91cf\u5728\u5927\u6c14\u538b\u4e0b\u7684\u603b\u91cf\u589e\u52a0\u5230\u6bcf\u4e2aPd\u539f\u5b50\u76840.87H\u3002\u6b64\u5916\uff0cPd\u7eb3\u7c73\u7ba1\u7684\u6c22\u538b\u7ec4\u6210\u7b49\u6e29\u7ebf\u5728\u9006\u8f6c\u5de5\u827a\u65f6\u5e76\u6ca1\u6709\u5b8c\u5168\u6062\u590d\u5230\u8d77\u59cb\u70b9\uff0c\u800cPd@CUSTOR-1\u663e\u793a\u51fa\u5b8c\u5168\u53ef\u9006\u7684\u5438\u6536\/\u89e3\u5438\u54cd\u5e94\u3002\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\uff0cPd\u7eb3\u7c73\u7ba1\u4e0a\u7684\u79d1\u5927I-1\u6d82\u5c42\u53ef\u4ee5\u63d0\u9ad8\u6c22\u5bb9\u91cf\uff0c\u63d0\u9ad8\u5438\u6c22\/\u89e3\u5438\u901f\u5ea6\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>20 <\/strong><strong>\u7528\u4e8e\u7b49\u79bb\u5b50\u4f53\u9a71\u52a8\u9009\u62e9\u6027\u50ac\u5316\u70ef\u70c3\u6c22\u5316\u7684<\/strong><strong>PdNCs<\/strong><strong>\uff08\u5de6\uff09\u548c<\/strong><strong>1-<\/strong><strong>\u5df1\u70ef\u5728<\/strong><strong>PdNCs<\/strong><strong>\u6216<\/strong><strong>Pd NCsZIF-8<\/strong><strong>\u4e0a\u7684\u6c22\u5316\u4ea7\u7387\u4ee5\u53ca\u53cd\u5e94\u65f6\u95f4\uff08\u53f3\uff09<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-88428\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/06\/c6cs00724d-f20_hi-res.gif\" alt=\"\" width=\"700\" height=\"281\" \/><\/p>\n<p><strong>5.4 MNPs<\/strong><strong>\u4f5c\u4e3a\u6d3b\u52a8\u4e2d\u5fc3\uff0c<\/strong><strong>MOFs<\/strong><strong>\u7a33\u5b9a<\/strong><strong>MNP<\/strong><strong>\u5e76\u8c03\u8282\u5176\u7535\u5b50\u6027\u8d28<\/strong><\/p>\n<p>\u50ac\u5316\u6d3b\u6027\u4e2d\u5fc3\u7684\u6027\u8d28\u4e0e\u5176\u5468\u56f4\u7684\u5316\u5b66\u73af\u5883\u5bc6\u5207\u76f8\u5173\u3002\u9274\u4e8eMOF\u7ed3\u6784\u7684\u9ad8\u5ea6\u53ef\u8c03\u7279\u6027\uff0c\u5728\u914d\u4f53\/\u91d1\u5c5e\u7c07\u4e0a\u60ac\u6302\u7684\u5b9a\u5236\u529f\u80fd\u56e2\u53ef\u4ee5\u8c03\u8282\u539f\u5b50\u7ea7\u7684\u7535\u5b50\u7279\u6027\u3002\u5177\u6709\u4e0d\u540c\u5b98\u80fd\u56e2\u7684\u914d\u4f53\u4e0eMNP\u5177\u6709\u4e0d\u540c\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u4ece\u800c\u5bfc\u81f4MNPs\u7684\u50ac\u5316\u6d3b\u6027\u548c\u9009\u62e9\u6027\u7684\u53d8\u5316\u3002\u8fd8\u62a5\u9053\u4e86\u5728MOF\u5bbf\u4e3b\u4e2d\u7684\u91d1\u5c5e\u7c07\u4e0a\u7684\u540e\u5408\u6210\u63a5\u679d\u53e6\u5916\u7684\u57fa\u56e2\u4ee5\u63d0\u9ad8\u6d3b\u6027\u548c\u9009\u62e9\u6027\u7279\u522b\u5730\uff0c\u57fa\u4e8eMOFs\u7684\u534a\u5bfc\u4f53\u6837\u884c\u4e3a\uff0c\u5149\u7167\u5c04\u5f3a\u5ea6\u7684\u53d8\u5316\u53ef\u5f71\u54cdMOF\u548cMNP\u4e4b\u95f4\u7684\u7535\u5b50\u8f6c\u79fb\u65b9\u5411\uff0c\u4ece\u800c\u6539\u53d8MNP\u7684\u7535\u5b50\u72b6\u6001\u548c\u50ac\u5316\u6d3b\u6027\u76f8\u5173\u62a5\u544a\u867d\u7136\u975e\u5e38\u6709\u9650\uff0c\u5374\u5b8c\u5168\u4f53\u73b0\u4e86MOFs\u7684\u7ed3\u6784\u4f18\u52bf\u548c\u4f18\u5316MNPs\u50ac\u5316\u6548\u7387\u7684\u91cd\u8981\u6027\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>21 <\/strong><strong>\uff08<\/strong><strong>a<\/strong><strong>\uff09\u82ef\u7532\u919b\u548c\u4e59\u4e8c\u9187\u4e4b\u95f4\u9700\u6c27\u53cd\u5e94\u7684\u53ef\u80fd\u9014\u5f84\u548c\uff08<\/strong><strong>b<\/strong><strong>\uff09\u4f7f\u7528<\/strong><strong>Pd@UiO-66-X<\/strong><strong>\uff08<\/strong><strong>X=H<\/strong><strong>\uff0c<\/strong><strong>NH<sub>2<\/sub><\/strong><strong>\uff0c<\/strong><strong>OMe<\/strong><strong>\uff09\u50ac\u5316\u5242\u7684\u4ea7\u7269\u5206\u5e03<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-88429\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/06\/c6cs00724d-f21_hi-res.gif\" alt=\"\" width=\"575\" height=\"700\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>22 Pt<\/strong><strong>\u548c<\/strong><strong>PCN-224<\/strong><strong>\uff08<\/strong><strong>M<\/strong><strong>\uff09\u5728\u53ef\u89c1\u5149\u7167\u5c04\u4e0b<\/strong><strong>Pt<\/strong><strong>\u548c<\/strong><strong>PCN-224<\/strong><strong>\uff08<\/strong><strong>M<\/strong><strong>\uff09\u5728\u82ef\u7532\u9187\u6c27\u5316\u4e2d\u7684<\/strong><strong><sup>1<\/sup><\/strong><strong>O<sub>2<\/sub><\/strong><strong>\u548c\u7535\u5b50\u8f6c\u79fb\u7684\u673a\u7406<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-88430\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/06\/c6cs00724d-f22_hi-res.gif\" alt=\"\" width=\"700\" height=\"479\" \/><\/p>\n<p><strong>5.5\u00a0MNP<\/strong><strong>\u4f5c\u4e3a\u7535\u5b50\u53d7\u4f53\u548c\u6d3b\u6027\u4e2d\u5fc3\uff0c<\/strong><strong>MOFs<\/strong><strong>\u4f5c\u4e3a\u5149\u654f\u5242\u548c\u7a33\u5b9a\u5242<\/strong><\/p>\n<p>\u968f\u7740\u6df1\u5ea6\u9010\u6e10\u589e\u52a0\u7684\u7814\u7a76\uff0cMOF\u7684\u529f\u80fd\u4e5f\u8d8a\u6765\u8d8a\u591a\u3002\u9664\u4e86\u5e7f\u6cdb\u5173\u6ce8\u4e0a\u8ff0\u5e38\u89c1\u6709\u673a\u53cd\u5e94\u4e2d\u7684\u50ac\u5316\u4f5c\u7528\u5916\uff0cMNP\/MOF\u590d\u5408\u6750\u6599\u5728\u5149\u50ac\u5316\u7814\u7a76\u9886\u57df\u88ab\u8bc1\u660e\u662f\u91cd\u8981\u7684\u3002\u5bf9\u4e8e\u7279\u5b9a\u7684\u6709\u673a\u63a5\u89e6\u5242\uff0cMOF\u5bf9UV\u548c\u751a\u81f3\u5bbd\u8303\u56f4\u7684\u53ef\u89c1\u5149\u90fd\u6709\u54cd\u5e94\uff0c\u4f7f\u5176\u9002\u5408\u4f5c\u4e3a\u5149\u654f\u5242\u3002\u901a\u8fc7MOF\u7a33\u5b9a\u7684MNPs\u901a\u5e38\u8868\u73b0\u4e3a\u4f18\u5f02\u7684\u7535\u5b50\u53d7\u4f53\u548c\u6d3b\u6027\u4e2d\u5fc3\uff0cMOF\u548cMNP\u529f\u80fd\u7684\u6574\u5408\u53ef\u4ee5\u901a\u8fc7\u6fc0\u53d1\u7684\u7535\u5b50\u5b9e\u73b0\uff0c\u80fd\u6709\u6548\u5730\u4fc3\u8fdbMOFs\u548c\u5149\u50ac\u5316\u53cd\u5e94\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>23 <\/strong><strong>\u901a\u8fc7\u4ece\u5149\u6536\u96c6<\/strong><strong>MOF<\/strong><strong>\u6ce8\u5165\u7535\u5b50\u5230<\/strong><strong>PtNP<\/strong><strong>\u4e2d\u7684\u534f\u540c\u5149\u50ac\u5316\u6c22\u6790\u51fa<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-88431\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/06\/c6cs00724d-f23_hi-res.gif\" alt=\"\" width=\"700\" height=\"305\" \/><\/p>\n<p><strong>5.6\u00a0<\/strong><strong>\u4e24\u4e2a<\/strong><strong>MOF<\/strong><strong>\u548c<\/strong><strong>MNP<\/strong><strong>\u4f5c\u4e3a\u4e32\u8054\u50ac\u5316\u7684\u6d3b\u6027\u4f4d\u70b9<\/strong><\/p>\n<p>MNPs\u548cMOFs\u4e4b\u95f4\u7684\u529f\u80fd\u534f\u540c\u4f5c\u7528\u7684\u7814\u7a76\u4e2d\uff0c\u5c3d\u7ba1\u5f97\u5230\u7684\u50ac\u5316\u6027\u80fd\u4f18\u5f02\uff0c\u50ac\u5316\u6d3b\u6027\u51e0\u4e4e\u6765\u81eaMNP\uff0cMOF\u5f88\u5c11\u8868\u73b0\u51fa\u50ac\u5316\u6027\u80fd\uff0c\u8fd9\u663e\u7136\u662f\u53ef\u60dc\u7684\u3002\u975e\u5e38\u9700\u8981\u660e\u667a\u5730\u5c06MOF\u50ac\u5316\u548cMNP\u50ac\u5316\u6574\u5408\u5230\u4e00\u9505\u591a\u6b65\u4e32\u8054\u53cd\u5e94\u4e2d\u3002\u51e0\u9879\u7814\u7a76\u6210\u529f\u5b9e\u73b0\u4e86\u8fd9\u4e00\u4ee4\u4eba\u5174\u594b\u7684\u76ee\u6807\uff0c\u5176\u4e2dMOF\u548cMNP\u4f5c\u4e3a\u6d3b\u6027\u4f4d\u70b9\u53d1\u6325\u5404\u81ea\u7684\u529f\u80fd\uff0c\u5e76\u534f\u540c\u50ac\u5316\u7ea7\u8054\u53cd\u5e94\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>24 <\/strong><strong>\u4e32\u8054\u53cd\u5e94\uff0c\u5176\u6d89\u53ca\u7531<\/strong><strong>IRMOF-3<\/strong><strong>\u58f3\u50ac\u5316\u7684<\/strong><strong>A<\/strong><strong>\u4e0e\u4e19\u4e8c\u8148\u7684<\/strong><strong>Knoevenagel<\/strong><strong>\u7f29\u5408\uff0c\u4ee5\u53ca\u968f\u540e\u7531<\/strong><strong>PdNP<\/strong><strong>\u6838\u5fc3\u50ac\u5316\u7684\u4e2d\u95f4\u4f53<\/strong><strong>B<\/strong><strong>\u81f3<\/strong><strong>C<\/strong><strong>\u7684\u9009\u62e9\u6027\u6c22\u5316<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-88432\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/06\/c6cs00724d-f24_hi-res.gif\" alt=\"\" width=\"700\" height=\"513\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>25 <\/strong><strong>\uff08\u4e0a\uff09\u901a\u8fc7\u7ea7\u8054\u53cd\u5e94\u591a\u6b65\u5408\u6210\u4ef2\u82b3\u57fa\u80fa<\/strong><strong>;<\/strong><strong>\uff08\u4e0b\u56fe\uff09\u663e\u793a\u4e86\u901a\u8fc7\u534f\u540c\u4e09\u79cd\u7ec4\u5206\u7684\u529f\u80fd\u5b9e\u73b0<\/strong><strong>PdAg@MIL-101<\/strong><strong>\u4e0a\u7684\u4e00\u7ea7\u8054\u53cd\u5e94\u7684\u793a\u610f\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-88433\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/06\/c6cs00724d-f25_hi-res.gif\" alt=\"\" width=\"700\" height=\"623\" \/><\/p>\n<p><strong>6 MOF<\/strong><strong>\u4e0e\u5176\u4ed6\u5ba2\u4f53\u7269\u79cd\u4e4b\u95f4\u534f\u540c\u589e\u6548\u50ac\u5316\u4f5c\u7528<\/strong><\/p>\n<p>\u529f\u80fd\u5316MOF\u4e2d\u7684\u5b54\u9699\u7a7a\u95f4\u662f\u65e0\u9650\u7684\u6f5c\u529b\uff0c\u5176\u4e2d\u53ef\u4ee5\u5b9a\u4f4d\u5404\u79cd\u5ba2\u4f53\u7269\u79cd\uff0c\u800c\u4e0d\u4ec5\u4ec5\u662fMNPs\u3002\u5df2\u7ecf\u6709\u5404\u79cd\u529f\u80fd\u7269\u8d28\u4e0eMOFs\u7ed3\u5408\u7528\u4e8e\u589e\u5f3a\u50ac\u5316\uff0c\u5305\u62ec\u91d1\u5c5e\u6c27\u5316\u7269\uff0c\u91cf\u5b50\u70b9\uff0c\u548c\u591a\u91d1\u5c5e\u6c27\u9178\u76d0\u3002\u57fa\u4e8e\u8be5\u65b9\u6cd5\u7684\u5408\u6210\u65b9\u6cd5\u548c\u6539\u8fdb\u7684\u50ac\u5316MOFs\u548c\u8fd9\u4e9b\u5ba2\u4f53\u7269\u79cd\u7684\u4e0d\u540c\u529f\u80fd\u7684\u7ec4\u5408\u7684\u534f\u540c\u6548\u5e94\u4e0e\u672c\u7efc\u8ff0\u4e2d\u63cf\u8ff0\u7684MNP\/MOF\u590d\u5408\u6750\u6599\u7684\u76f8\u4f3c\u3002\u5173\u4e8e\u5404\u79cd\u57fa\u4e8eMOF\u7684\u590d\u5408\u6750\u6599\u662fMOF\u5728\u50ac\u5316\u4e2d\u7684\u5e94\u7528\u53d1\u5c55\u4e2d\u4e0d\u53ef\u6216\u7f3a\u7684\u90e8\u5206\u3002<\/p>\n<p><strong>7 \u7ed3\u8bba\u548c\u5c55\u671b<\/strong><\/p>\n<p>MOF\u65e0\u7591\u5728\u50ac\u5316\u4e2d\u5177\u6709\u91cd\u8981\u7684\u6f5c\u529b\u548c\u4f18\u52bf\uff0c\u56e0\u6b64\uff0cMOF\u50ac\u5316\u5242\u8fd1\u5e74\u6765\u5f15\u8d77\u4e86\u4eba\u4eec\u5e7f\u6cdb\u7684\u5174\u8da3\u3002\u73b0\u5728\u5df2\u7ecf\u5f00\u53d1\u4e86\u5c06MOPs\u7eb3\u5165MOFs\u7684\u5404\u79cd\u5408\u6210\u7b56\u7565\u3002\u4e3a\u4e86\u5c06MNPs\u5f15\u5165\u9884\u5408\u6210\u7684MOF\u4e2d\uff0c\u91c7\u7528\u4e86\u4e94\u79cd\u5178\u578b\u7684\u65b9\u6cd5\uff1a\u6eb6\u6db2\u6d78\u6e0d\uff0c\u53cc\u6eb6\u5242\u6cd5\uff0c\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\u6cd5\uff0c\u56fa\u4f53\u7814\u78e8\u6cd5\u548c\u70ed\u5206\u89e3\u6cd5\u3002\u5bf9\u4e8e\u5728\u8f83\u4f4e\u6e29\u5ea6\u4e0b\u6d89\u53ca\u6c14\u4f53\u5206\u5b50\u7684\u50ac\u5316\u53cd\u5e94\uff0cMOF\u53ef\u4ee5\u5728\u4e00\u5b9a\u7a0b\u5ea6\u4e0a\u4f7f\u6d3b\u6027\u4f4d\u70b9\uff08MNPs\uff09\u5468\u56f4\u7684\u6c14\u4f53\u5206\u5b50\u5bcc\u96c6\uff0c\u4ece\u800c\u63d0\u9ad8\u50ac\u5316\u6d3b\u6027\u3002\u6b64\u5916\uff0cMNP\u7684\u6027\u80fd\u4e0e\u5176\u5468\u56f4\u7684\u5316\u5b66\u73af\u5883\u5bc6\u5207\u76f8\u5173\u3002\u6700\u8fd1\uff0cMNP\/MOF\u590d\u5408\u6750\u6599\u5728\u5149\u50ac\u5316\u4e2d\u663e\u793a\u51fa\u5de8\u5927\u7684\u6f5c\u529b\u3002\u8bb8\u591aMOF\u5bf9UV\u751a\u81f3\u5bbd\u8303\u56f4\u7684\u53ef\u89c1\u5149\u90fd\u54cd\u5e94\uff0c\u4f7f\u5f97\u5b83\u4eec\u9002\u5408\u4f5c\u4e3a\u5149\u654f\u5242\u5c06\u7535\u5b50\u8f6c\u79fb\u5230MNP\uff0c\u5bfc\u81f4\u4f18\u5f02\u7684\u5149\u50ac\u5316\u6027\u80fd\u3002\u53e6\u5916\uff0c\u8003\u8651\u5230MOF\u548cMNP\u7684\u591a\u529f\u80fd\u4f5c\u7528\uff0c\u51e0\u79cdMNP\/MOF\u50ac\u5316\u5242\u5df2\u7ecf\u8868\u73b0\u51fa\u4fc3\u8fdb\u4e00\u9505\u5f0f\u591a\u7ea7\u7ea7\u8054\u53cd\u5e94\u7684\u80fd\u529b\uff0c\u8fd9\u5c06\u8282\u7701\u5de5\u4e1a\u4e2d\u7684\u80fd\u6e90\u548c\u6210\u672c\u3002\u867d\u7136MOF\u50ac\u5316\u5242\u7684\u7814\u7a76\u53d6\u5f97\u4e86\u5de8\u5927\u8fdb\u5c55\uff0c\u4f46\u8fd9\u4e00\u9886\u57df\u76ee\u524d\u8fd8\u5904\u4e8e\u8d77\u6b65\u9636\u6bb5\uff0c\u66f4\u591a\u7684\u52aa\u529b\u5e94\u8be5\u81f4\u529b\u4e8e\u5229\u7528\u50ac\u5316\u5242\u4e2d\u7684MNP\uff0fMOFs\u7684\u7ed3\u5408\u3002\u964d\u4f4eMOF\u7684\u5927\u89c4\u6a21\u5408\u6210\u6210\u672c\u5bf9\u4e8e\u5b9e\u9645\u5e94\u7528\u4e5f\u662f\u5fc5\u9700\u7684\u3002\u968f\u7740\u7814\u7a76\u4eba\u5458\u5e94\u5bf9\u8fd9\u4e9b\u6311\u6218\u7684\u4e0d\u61c8\u52aa\u529b\uff0c\u6709\u5145\u5206\u7684\u7406\u7531\u76f8\u4fe1MNP\/MOF\u50ac\u5316\u7684\u524d\u666f\u975e\u5e38\u5149\u660e\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><a href=\"http:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2017\/cs\/c6cs00724d#!divAbstract\" target=\"_blank\" rel=\"noopener noreferrer\"> Metal\u2013organic frameworks meet metal nanoparticles: synergistic effect for enhanced catalysis<\/a>\uff08Chem.Soc.Rev., 2017, DOI: 10.1039\/C6CS00724D\uff09<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u7eb3\u7c73\u6750\u6599\u5b66\u672f\u7ec4\u575a\u6bc5\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002\u6b22\u8fce\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u7eb3\u7c73\u6750\u6599\u5b66\u672f\u4ea4\u6d41\u7fa4\uff08228686798\uff09\uff01<\/p>\n<p> \u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"http:\/\/www.cailiaoniu.com\/25127.html\" target=\"_blank\" rel=\"noopener noreferrer\">\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p> <strong>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener noreferrer\">\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>1. \u5f15\u8a00 \u91d1\u5c5e-\u6709\u673a\u9aa8\u67b6\uff08MOF\uff09\u7684\u9ad8\u8868\u9762\u79ef\uff0c\u7ed3\u6784\u591a\u6837\u6027\u548c\u5b9a\u5236\u6027\u7684\u7ed3\u6676\u591a\u5b54\u6750\u6599\uff0c\u5f15\u8d77\u4e86\u5e7f\u6cdb\u7684\u5174\u8da3\u5e76\u8868\u73b0\u51fa\u5404\u79cd\u5e94\u7528\u3002\u672c\u7efc\u8ff0\u603b\u7ed3MNP\/MOF\u6750\u6599\u5236\u5907\u548c\u8868\u5f81\u65b9\u6cd5\u53ca&#8230;<\/p>\n","protected":false},"author":3440,"featured_media":88404,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[533],"tags":[116,43,18,54,981,97,1401,245],"class_list":["post-88399","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zongshu","tag-catalyst","tag-composite","tag-xinnengyuan","tag-making","tag-test","tag-computation","tag-jianghailong","tag-mof"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/88399"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/3440"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=88399"}],"version-history":[{"count":16,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/88399\/revisions"}],"predecessor-version":[{"id":94792,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/88399\/revisions\/94792"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/88404"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=88399"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=88399"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=88399"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}