{"id":90051,"date":"2017-07-07T06:30:30","date_gmt":"2017-07-06T22:30:30","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=90051"},"modified":"2017-07-05T19:52:20","modified_gmt":"2017-07-05T11:52:20","slug":"adv-funct-mater-%ef%bc%9a-%e5%a4%a7%e5%9d%97%e5%a4%b4%e8%83%b6%e8%b4%a8%e9%87%8f%e5%ad%90%e7%82%b9%e5%8a%a9%e5%8a%9b%e9%ab%98%e6%95%88%e7%a8%b3%e5%ae%9a%e9%87%8f%e5%ad%90%e7%82%b9","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=90051","title":{"rendered":"Adv. Funct. Mater.\uff1a \u201c\u5927\u5757\u5934\u201d\u80f6\u8d28\u91cf\u5b50\u70b9\u52a9\u529b\u9ad8\u6548\u7a33\u5b9a\u91cf\u5b50\u70b9\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60"},"content":{"rendered":"

\u3010<\/strong>\u5f15\u8a00\u3011<\/strong><\/p>\n

\u968f\u7740\u793e\u4f1a\u7684\u9ad8\u901f\u53d1\u5c55\u548c\u4eba\u53e3\u7684\u6025\u5267\u81a8\u80c0\uff0c\u4eba\u4eec\u5bf9\u80fd\u6e90\u7684\u9700\u6c42\u4e5f\u968f\u4e4b\u589e\u957f\u3002\u5bfb\u6c42\u9ad8\u6548\u3001\u6e05\u6d01\u7684\u53ef\u518d\u751f\u80fd\u6e90\u662f\u5168\u4e16\u754c\u5404\u56fd\u7684\u5171\u540c\u76ee\u6807\u3002\u91cf\u5b50\u70b9\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\uff08QDSCs\uff09\uff0c\u662f\u88ab\u5e7f\u6cdb\u8ba4\u4e3a\u5177\u6709\u5e7f\u9614\u5e94\u7528\u524d\u666f\u7684\u65b0\u578b\u592a\u9633\u80fd\u7535\u6c60\u4e4b\u4e00\u3002\u5176\u4e2d\uff0c\u80f6\u8d28\u91cf\u5b50\u70b9\u7531\u4e8e\u5176\u53ef\u8c03\u5e26\u9699\uff0c\u8f83\u5927\u5076\u6781\u77e9\uff0c\u7a33\u5b9a\u7684\u6eb6\u6db2\u52a0\u5de5\u5de5\u827a\u548c\u5bbd\u5149\u8c31\u8303\u56f4\u5185\u7684\u9ad8\u6d88\u5149\u7cfb\u6570\uff0c\u53ef\u4ee5\u6709\u6548\u63d0\u9ad8\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u7684\u5149\u8f6c\u5316\u6548\u7387\u3002\u4f46\u662f\uff0c\u7531\u4e8e\u5728\u91d1\u5c5e\u6c27\u5316\u7269\/\u91cf\u5b50\u70b9\/\u7535\u89e3\u6db2\u754c\u9762\u5904\u53ca\u91cf\u5b50\u70b9\u5185\u90e8\u53d1\u751f\u7684\u8f7d\u6d41\u5b50\u590d\u5408\uff0c\u4e25\u91cd\u5f71\u54cd\u4e86\u5176\u5149\u8f6c\u6362\u6548\u7387\u3002\u8fdb\u4e00\u6b65\u4f18\u5316\u6750\u6599\u7ed3\u6784\uff0c\u63d0\u5347\u91cf\u5b50\u70b9\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u5149\u7535\u8f6c\u6362\u6548\u7387\u4ecd\u662f\u79d1\u7814\u4eba\u5458\u9762\u4e34\u7684\u5de8\u5927\u6311\u6218\u3002<\/p>\n

\u3010<\/strong>\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u7535\u5b50\u79d1\u6280\u5927\u5b66\u57fa\u7840\u4e0e\u524d\u6cbf\u7814\u7a76\u9662<\/strong>Federico Rosei<\/strong>\u6559\u6388\uff0c\u738b\u5fd7\u660e\u6559\u6388\u548c\u52a0\u62ff\u5927\u9b41\u5317\u514b\u7701\u7acb\u79d1\u5b66\u7814\u7a76\u9662\u8d75\u6d77\u5149\u535a\u58eb\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u5408\u4f5c\uff0c\u5236\u5907\u51fa\u4e86CdSe\/(CdS)x<\/sub>\u6838\u58f3\u7ed3\u6784\u91cf\u5b50\u70b9\uff08QDs\uff09\u3002\u901a\u8fc7\u8fde\u7eed\u79bb\u5b50\u5c42\u5438\u9644\u53cd\u5e94\u6cd5\u8c03\u8282\u91cf\u5b50\u70b9\u58f3\u5c42\u539a\u5ea6\uff0c\u4f18\u5316\u5176\u5149\u7535\u6027\u80fd\u3002\u5728\u6a21\u62df\u4e00\u4e2a\u592a\u9633\u7167\u5ea6AM 1.5G\uff08100 mW cm-2<\/sup>\uff09\u4e0b\uff0cCdSe\/(CdS)6<\/sub>\u91cf\u5b50\u70b9\u5177\u6709\u9ad8\u5149\u7535\u8f6c\u6362\u6548\u7387\uff083.01%\uff09\uff0c\u5927\u7535\u6d41\u5bc6\u5ea6\uff089.30 mA cm-2<\/sup>\uff09\uff0c\u9ad8\u5f00\u8def\u7535\u538b\uff080.539 V\uff09\u548c\u8f83\u5927\u586b\u5145\u56e0\u5b50\uff0860%\uff09\u3002\u4e3a\u8fdb\u4e00\u6b65\u63d0\u9ad8\u8be5\u6750\u6599\u7684\u5149\u4f0f\u6027\u80fd\uff0c\u5408\u4f5c\u56e2\u961f\u5408\u6210\u5236\u5907\u51fa\u4e86CdSe\/(CdSex<\/sub>S1\u2212x<\/sub>)4<\/sub>\/(CdS)2<\/sub> (x = 0.5) \u548cCdSe\/(CdSex<\/sub>S1\u2212x<\/sub>)5<\/sub>\/(CdS)1<\/sub> (x = 0.1\u20130.9) \u6838\u58f3\u7ed3\u6784\u91cf\u5b50\u70b9\u3002\u6d4b\u8bd5\u7ed3\u679c\u8868\u660e\uff0c\u5176\u5149\u7535\u8f6c\u6362\u6548\u7387\u5206\u522b\u9ad8\u8fbe5.12%\u548c6.86%\u3002\u8be5\u6210\u679c\u4ee5\u201cHighly Stable Colloidal \u201cGiant\u201d Quantum Dots Sensitized Solar Cells<\/strong>\u201d\u4e3a\u9898\u4e8e2017\u5e746\u670826\u65e5\u53d1\u8868\u5728\u671f\u520aAdvanced Functional Materials<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\uff1a<\/strong>QDSCs<\/strong>\u5de5\u4f5c\u539f\u7406\u56fe\u53ca<\/strong>CdSe\/(CdS)x<\/sub> (x = 0, 2, 6, 13) <\/strong>\u6838\u58f3\u7ed3\u6784<\/strong>QDs<\/strong>\u7535\u5b50\u80fd\u5e26\u5de5\u7a0b\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

CdSe\/(CdS)x (x = 0, 2, 6, 13) \u6838\u58f3\u7ed3\u6784QDs\u7535\u5b50\u80fd\u5e26\u5de5\u7a0b\uff1aCdSe\u6838\uff08\u7ea2\u8272\uff09\u4e0e\u4e0d\u65ad\u589e\u52a0\u7684\u539a\u5ea6\u7684CdS\u58f3\u5c42\uff08\u9ec4\u8272\uff09\u542b\u6709\u6216\u4e0d\u542b\u754c\u9762\u5408\u91d1\u5c42CdSex<\/sub>S1\u2212x <\/sub>(x = 0.5)\u3002R\u4e3a\u6838\u7684\u534a\u5f84\uff0c H\u4e3a\u58f3\u5c42\u539a\u5ea6\u3002<\/p>\n

\u56fe\u4e8c\uff1a\u6750\u6599\u7684\u7ed3\u6784\u8868\u5f81\u548c\u5149\u8c31\u5206\u6790<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5728CdS\u8fde\u7eed\u79bb\u5b50\u5c42\u5438\u9644\u53cd\u5e94\u5faa\u73af\u524d\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

\uff08b\uff096\u6b21CdS\u8fde\u7eed\u79bb\u5b50\u5c42\u5438\u9644\u53cd\u5e94\u5faa\u73af\u540e\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

\uff08c\uff0913\u6b21CdS\u8fde\u7eed\u79bb\u5b50\u5c42\u5438\u9644\u53cd\u5e94\u5faa\u73af\u540e\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

\uff08d\uff094\u6b21CdSex<\/sub>S1-x<\/sub>(x = 0.5)\u548c2\u6b21 CdS\u8fde\u7eed\u79bb\u5b50\u5c42\u5438\u9644\u53cd\u5e94\u5faa\u73af\u540e\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

\uff08e\uff09d\u56fe\u7684HRTEM\u56fe\u50cf\uff1b<\/p>\n

\uff08f\uff09CdSe\/(CdS)6<\/sub> QDs \u654f\u5316\u7684TiO2<\/sub>\u8584\u819cHRTEM\u56fe\u50cf\uff1b<\/p>\n

\uff08g\uff09\u4e0d\u540c\u6b21\u6570CdS \u548cCdSex<\/sub>S1-x<\/sub>\u8fde\u7eed\u79bb\u5b50\u5c42\u5438\u9644\u53cd\u5e94\u5faa\u73af\u524d\u540eCdSe QDs\u5c3a\u5bf8\u5206\u5e03\u56fe\u50cf\uff1b<\/p>\n

\uff08h\uff09\u4e0d\u540c\u6b21\u6570CdS\u8fde\u7eed\u79bb\u5b50\u5c42\u5438\u9644\u53cd\u5e94\u5faa\u73af\u524d\u540eCdSe QDs\u5728\u7532\u82ef\u4e2d\u7684\u7d2b\u5916-\u53ef\u89c1\u5438\u6536\u5149\u8c31\u56fe\uff1b<\/p>\n

\uff08i\uff09\u5bf9\u5e94\u7684QDs\u5728\u7532\u82ef\u4e2d\u7684\u8367\u5149\u5149\u8c31\u56fe\u3002<\/p>\n

\u56fe\u4e09\uff1a\u4e0d\u540c\u58f3\u5c42\u539a\u5ea6\u5bf9\u6750\u6599\u5149\u4f0f\u6027\u80fd\u7684\u5f71\u54cd<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5728\u4e00\u4e2a\u592a\u9633\u7167\u5ea6\u4e0b\uff0cCdSe\/(CdS)x<\/sub> \u6838\u58f3\u7ed3\u6784\u91cf\u5b50\u70b9\u654f\u5316\u7535\u6c60\u7684J-V\u66f2\u7ebf\uff0c\u663e\u793a\u58f3\u539a\u5ea6\u5bf9\u5149\u4f0f\u6027\u80fd\u7684\u5f71\u54cd\uff1b<\/p>\n

\uff08b\uff09\u5f00\u8def\u7535\u538b\u8870\u53d8\u4e0e\u65f6\u95f4\u7684\u51fd\u6570\u56fe\u50cf\uff1b<\/p>\n

\uff08c\uff09\u7535\u5b50\u5bff\u547d(\u03c4 )\u4e0e\u5f00\u8def\u7535\u538b\u7684\u7684\u51fd\u6570\u56fe\u50cf\uff1b<\/p>\n

\uff08d\uff09\u590d\u5408\u7535\u963bRrec<\/sub>\u4e0e\u504f\u538bVbias<\/sub>\u7684\u51fd\u6570\u56fe\u50cf\uff1b<\/p>\n

\uff08e\uff09\u5316\u5b66\u7535\u5bb9C\u03bc<\/sub>\u4e0e\u504f\u538bVbias<\/sub>\u7684\u51fd\u6570\u56fe\u50cf\uff1b<\/p>\n

\uff08f\uff09\u7535\u5b50\u5bff\u547d(\u03c4 )\u4e0e\u504f\u538bVbias<\/sub>\u7684\u51fd\u6570\u56fe\u50cf\u3002<\/p>\n

\u56fe\u56db\uff1a\u7a33\u5b9a\u6027\u53ca\u53ef\u91cd\u590d\u6027\u6027\u80fd\u7814\u7a76<\/strong><\/p>\n

\"\"<\/p>\n

\u57fa\u4e8e\u201c\u5de8\u578b\u201d\u5408\u91d1\u6838\/\u58f3\u91cf\u5b50\u70b9\uff0cCdSe \/\uff08CdS\uff096<\/sub>\u6838\/\u58f3\u91cf\u5b50\u70b9\u548c\u88f8\u9732\u7684CdSe\u91cf\u5b50\u70b9\u7684QDSC\u7684\u529f\u80fd\u6027\u80fd\u7a33\u5b9a\u6027\u8d85\u8fc7240\u5c0f\u65f6\u3002<\/p>\n

\uff08a\uff09\u5177\u6709CdSexS1-x\u754c\u9762\u5c42\u7684\u5408\u91d1\u6838\/\u58f3QD\u5728\u4e0d\u540c\u65f6\u95f4\u4e0bJ-V\u66f2\u7ebf\uff1b<\/p>\n

\uff08b\uff09CdSe\/(CdS)6<\/sub>\u6838\u58f3\u7ed3\u6784\u5728\u4e0d\u540c\u65f6\u95f4\u4e0b\u7684J-V\u66f2\u7ebf\uff1b<\/p>\n

\uff08c\uff09\u88f8\u9732\u7684CdSe\u6838\u58f3\u7ed3\u6784\u91cf\u5b50\u70b9\u5728\u4e0d\u540c\u65f6\u95f4\u4e0b\u7684J-V\u66f2\u7ebf\uff1b<\/p>\n

\uff08d\uff09\u5bf9\u5e94\u7684QDSCs \u65f6\u95f4\u4e0e\u5f00\u8def\u7535\u538b\u51fd\u6570\u66f2\u7ebf\uff1b<\/p>\n

\uff08e\uff09\u5bf9\u5e94\u7684QDSCs \u65f6\u95f4\u4e0e\u7535\u6d41\u5bc6\u5ea6\u51fd\u6570\u66f2\u7ebf\uff1b<\/p>\n

\uff08f\uff09\u5bf9\u5e94\u7684QDSCs \u65f6\u95f4\u4e0e\u5149\u7535\u8f6c\u6362\u6548\u7387\u51fd\u6570\u66f2\u7ebf\u3002<\/p>\n

\u3010<\/strong>\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u8fd9\u9879\u5de5\u4f5c\u901a\u8fc7\u8fde\u7eed\u79bb\u5b50\u5c42\u5438\u9644\u53cd\u5e94\u6cd5\u6210\u529f\u5236\u5907\u4e86\u58f3\u5c42\u539a\u5ea6\u53ef\u8c03\u7684\u6838\u58f3\u7ed3\u6784\u91cf\u5b50\u70b9\uff0c\u8be5\u6750\u6599\u5e94\u7528\u4e8eQDSCs\uff0c\u8868\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u5149\u4f0f\u6027\u80fd\u3002\u901a\u8fc7\u8c03\u8282\u58f3\u5c42\u539a\u5ea6\uff0c\u53ef\u4ee5\u6709\u6548\u589e\u5f3a\u91cf\u5b50\u70b9\u7684\u5149\u5b66\u7269\u5316\u6027\u80fd\uff0c\u540c\u65f6\u53ef\u4ee5\u6709\u6548\u5730\u5c06\u5438\u5149\u5149\u8c31\u5411\u53ef\u89c1\u5149\u533a\u57df\u62d3\u5c55\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u7a33\u5b9a\u6027\u662fQDSCs\u80fd\u5426\u5546\u4e1a\u5316\u7684\u51b3\u5b9a\u56e0\u7d20\u4e4b\u4e00\uff0c\u800c\u8be5\u65b9\u6cd5\u4e3a\u5236\u5907\u9ad8\u6548\uff0c\u4f4e\u4ef7\uff0c\u7a33\u5b9a\u7684QDSCs\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Highly Stable Colloidal \u201cGiant\u201d Quantum Dots Sensitized Solar Cells<\/a>\u00a0(Adv. Funct. Mater., 2017, DOI: 10.1002\/adfm.201701468)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u90ed\u9759\u7f16\u8bd1\uff0c\u9ec4\u8d85\u5ba1\u6838\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u968f\u7740\u793e\u4f1a\u7684\u9ad8\u901f\u53d1\u5c55\u548c\u4eba\u53e3\u7684\u6025\u5267\u81a8\u80c0\uff0c\u4eba\u4eec\u5bf9\u80fd\u6e90\u7684\u9700\u6c42\u4e5f\u968f\u4e4b\u589e\u957f\u3002\u5bfb\u6c42\u9ad8\u6548\u3001\u6e05\u6d01\u7684\u53ef\u518d\u751f\u80fd\u6e90\u662f\u5168\u4e16\u754c\u5404\u56fd\u7684\u5171\u540c\u76ee\u6807\u3002\u91cf\u5b50\u70b9\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\uff08QDSCs\uff09\uff0c…<\/p>\n","protected":false},"author":230,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2],"tags":[78],"class_list":["post-90051","post","type-post","status-publish","format-standard","hentry","category-jiedu","category-keji","tag-photovoltaic"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/90051"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/230"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=90051"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/90051\/revisions"}],"predecessor-version":[{"id":90210,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/90051\/revisions\/90210"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=90051"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=90051"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=90051"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}