{"id":90392,"date":"2017-07-10T06:30:02","date_gmt":"2017-07-09T22:30:02","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=90392"},"modified":"2017-07-08T08:33:04","modified_gmt":"2017-07-08T00:33:04","slug":"%e4%b8%ad%e5%b1%b1%e5%a4%a7%e5%ad%a6nature%e5%ad%90%e5%88%8a%ef%bc%9a%e5%85%b7%e6%9c%89%e5%8f%af%e5%88%87%e6%8d%a2%e5%8f%91%e5%85%89%e7%9a%84%e9%87%91%e5%b1%9e%e6%9c%89%e6%9c%ba%e6%a1%86%e6%9e%b6","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=90392","title":{"rendered":"\u4e2d\u5c71\u5927\u5b66Nature\u5b50\u520a\uff1a\u5177\u6709\u53ef\u5207\u6362\u53d1\u5149\u7684\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u7528\u4e8e\u8d85\u5feb\u6c34\u4f20\u611f\u548c\u70ed\u6210\u50cf"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/span><\/strong><\/p>\n

\u8fd1\u5e74\u6765\uff0c\u91d1\u5c5e\u6709\u673a\u6846\u67b6(MOFs)\u5728\u667a\u80fd\u548c\u9ad8\u6548\u5149\u81f4\u53d1\u5149(PL)\u4f20\u611f\u548c\u6210\u50cf\u7684\u6f5c\u5728\u5e94\u7528\u5f15\u8d77\u4e86\u7814\u7a76\u8005\u4eec\u7684\u6781\u5927\u5174\u8da3\u3002MOFs\u5177\u6709\u6742\u5316\u7684\u591a\u5b54\u7ed3\u6784\uff0c\u80fd\u4e3a\u5ba2\u4f53\u5206\u5b50\u63d0\u4f9b\u65b9\u4fbf\u7684\u8fdb\u51fa\u901a\u9053\uff0c\u56e0\u6b64\u53ef\u4ee5\u7528\u4f5cPL\u4f20\u611f\u5668\u5bf9\u5ba2\u4f53\u5206\u5b50\u8fdb\u884c\u68c0\u6d4b\u3002\u4f46\u662f\u5176\u5bf9\u76ee\u6807\u5206\u5b50\u7684\u9009\u62e9\u6027\u5e38\u88ab\u4e0e\u76ee\u6807\u5206\u5b50\u76f8\u4f3c\u7684\u5206\u5b50\u6240\u5e72\u6270\uff0c\u5236\u5907\u5177\u6709\u9ad8\u9009\u62e9\u6027\u7684MOF-PL\u4f20\u611f\u5668\u4ecd\u7136\u9762\u4e34\u6311\u6218\u3002\u6c14\u4f53\u548c\u6709\u673a\u4ea7\u54c1\u4e2d\u6c34\u5206\u7684\u4f20\u611f\u548c\u68c0\u6d4b\u5728\u5316\u5de5\u8fc7\u7a0b\u3001\u73af\u5883\u76d1\u6d4b\u3001\u5236\u836f\u548c\u98df\u54c1\u68c0\u6d4b\u7b49\u9886\u57df\u5341\u5206\u91cd\u8981\uff0c\u4e0e\u4f20\u7edf\u7684Karl Fischer\u6cd5\u548c\u7535\u5316\u5b66\u6cd5\u76f8\u6bd4\uff0c\u57fa\u4e8e\u8367\u5149\u6709\u673a\u5206\u5b50\u6216MOFs\u7684PL\u6c34\u4f20\u611f\u5177\u6709\u5bb9\u6613\u5236\u5907\u3001\u65b9\u4fbf\u64cd\u4f5c\u3001\u9ad8\u7075\u654f\u5ea6\u3001\u5728\u7ebf\u548c\u65e0\u635f\u7b49\u4f18\u70b9\uff0c\u662f\u975e\u5e38\u6709\u76ca\u7684\u68c0\u6d4b\u624b\u6bb5\u3002\u56e0\u6b64\uff0c\u6709\u76ee\u7684\u5730\u8bbe\u8ba1\u5177\u6709\u4e30\u5bcc\u6c14\u5b54\u7387\u548c\u53ef\u5207\u6362\u53d1\u5149\u884c\u4e3a\u7684MOFs\u6750\u6599\u5236\u5907PL\u4f20\u611f\u5668\u7528\u4e8e\u6c34\u5206\u7684\u5feb\u901f\u548c\u9ad8\u7075\u654f\u5ea6\u68c0\u6d4b\u6210\u4e3a\u4e86\u7814\u7a76\u7684\u70ed\u70b9\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/span><\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u5c71\u5927\u5b66\u5316\u5b66\u5b66\u9662\u82cf\u6210\u52c7\u6559\u6388<\/b>\u548c\u6f58\u6885\u6559\u6388<\/b>(<\/b>\u5171\u540c\u901a\u8baf\u4f5c\u8005<\/b>)<\/b>\u7b49\u4eba\u5728\u671f\u520aNature Communications<\/b>\u53d1\u8868\u4e86\u9898\u4e3a\u201cUltrafast water sensing and thermal imaging by a metal-organic framework with switchable luminescence<\/b>\u201d\u7684\u7814\u7a76\u8bba\u6587\uff0c\u62a5\u9053\u4e86MOFs\u5728\u6c34\u5206\u68c0\u6d4b\u548c\u70ed\u6210\u50cf\u9886\u57df\u7684\u6700\u65b0\u7814\u7a76\u6210\u679c\u3002\u7814\u7a76\u4eba\u5458\u5229\u7528\u5177\u6709\u6fc0\u53d1\u6001\u5206\u5b50\u5185\u8d28\u5b50\u8f6c\u79fb(ESIPT)\u7279\u6027\u548c\u53cc\u91cd\u53d1\u5149\u6027\u8d28\u7684H2<\/sub>hpi2cf(5-(2-(5-\u6c1f-2-\u7f9f\u82ef\u57fa)-4,5-\u4e8c(4-\u6c1f\u82ef\u57fa)-1H-\u54aa\u5511-1-\u57fa)\u95f4\u82ef\u4e8c\u7532\u9178)\u4f5c\u4e3a\u914d\u4f53\u6210\u529f\u7ec4\u88c5\u4e86Zn-MOF(Zn(hpi2cf)(DMF)(H2<\/sub>O))\u3002Zn-MOF\u5177\u6709\u4e24\u4eb2\u6027\u7684\u5fae\u5b54(<3\u00c5)\u7ed3\u6784\uff0c\u53ef\u4ee5\u901a\u8fc7\u7b80\u5355\u7684\u6c14\u6d41\u5439\u626b\u6216\u6e29\u548c\u52a0\u70ed(70\u2103)\u5b9e\u73b0\u7ed3\u5408\u6c34\u7684\u53ef\u9006\u53bb\u9664\uff0c\u5b8c\u6210\u5355\u6676-\u5355\u6676\u8f6c\u53d8\uff0c\u8868\u73b0\u51fa\u4e86\u975e\u5e38\u4f18\u5f02\u7684\u52a8\u6001\u53ef\u9006\u914d\u5408\u884c\u4e3a\u3002\u5176\u542b\u6c34\u76f8\u548c\u8131\u6c34\u76f8\u7684\u4e92\u76f8\u8f6c\u53d8\u53ef\u4ee5\u5f15\u8d77\u914d\u4f53ESIPT\u8fc7\u7a0b\u7684\u6253\u5f00\u548c\u5173\u95ed\uff0c\u80fd\u591f\u5b9e\u73b0\u975e\u5e38\u7075\u654f\u7684\u53cc\u8272\u5149\u81f4\u53d1\u5149\u5207\u6362\u3002\u8be5Zn-MOF\u662f\u4e00\u79cd\u975e\u5e38\u4f18\u5f02\u7684PL\u6c34\u4f20\u611f\u6750\u6599\uff0c\u5bf9\u5206\u5b50\u7ea7\u7684\u6c34\u5206\u5177\u6709\u5feb\u901f(\u79d2\u7ea7)\u548c\u9ad8\u5ea6\u7075\u654f\u7684\u54cd\u5e94\u3002\u6700\u540e\u7814\u7a76\u56e2\u961f\u5236\u5907\u4e86\u7eb8\u548cZnO\u652f\u6491\u7684Zn-MOF\u4f20\u611f\u819c\uff0c\u5e76\u8003\u5bdf\u4e86\u5176\u5728\u6e7f\u5ea6\u76d1\u6d4b(RH<1%)\u3001\u6709\u673a\u6eb6\u5242\u4e2d\u75d5\u91cf\u6c34\u63a2\u6d4b(<0.05% v\/v)\u3001\u70ed\u6210\u50cf\u548c\u6e29\u5ea6\u8ba1\u7b49\u65b9\u9762\u7684\u5e94\u7528\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/span><\/strong><\/p>\n

\u56fe1 Zn-MOF\u7684\u5408\u6210\u8def\u5f84\u548c\u7ed3\u6784\u8f6c\u53d8<\/strong><\/p>\n

\"\"<\/p>\n

(a)\u914d\u4f53\uff1b(b)\u542b\u6c34LIFM-CL1-H2<\/sub>O(Zn(hpi2cf)(DMF)(H2<\/sub>O),\u84dd\u8272)\u548c(c)\u8131\u6c34LIFM-CL1(Zn(hpi2cf)(DMF),\u9752\u8272)\uff0c\u663e\u793aZn\u4e2d\u5fc3\u9644\u8fd1\u914d\u5408\u73af\u5883\u7684\u53d8\u5316\u3002\u4e3a\u4e86\u7b80\u5316\u7ed3\u6784\u5f0f\uff0c\u6240\u6709H\u539f\u5b50\u5747\u7701\u7565\u3002<\/p>\n

\u56fe2 Zn-MOF\u7684\u6676\u4f53\u7ed3\u6784<\/strong><\/p>\n

\"\"<\/p>\n

(a)\u542b\u6c34LIFM-CL1-H2<\/sub>O\u548c(b)\u8131\u6c34LIFM-CL1\u5c40\u90e8\u7ed3\u6784\u7684\u5bf9\u6bd4\uff0c\u663e\u793a\u968f\u7740\u7ed3\u6784\u8f6c\u53d8\u4e0e\u7f9f\u57fa(-OH)\u57fa\u56e2\u548c\u4e9a\u80fa\u57faN\u539f\u5b50\u76f8\u5173\u7684H\u952e\u53d1\u751f\u4e86\u53d8\u5316\u3002<\/p>\n

\u56fe3 \u53d1\u5149\u5207\u6362\u673a\u7406<\/strong><\/p>\n

\"\"<\/p>\n

\u57fa\u4e8e\u4e0d\u540c\u7684ESIPT\u8fc7\u7a0b\uff0c(a)\u542b\u6c34LIFM-CL1-H2<\/sub>O\u548c(b)\u8131\u6c34LIFM-CL1\u7ed3\u6784\u7684\u6c34PL\u4f20\u611f\u673a\u7406\u793a\u610f\u56fe\uff0c\u53ef\u89c1\u6fc0\u53d1\u5f15\u8d77\u7684E\u5f0f(Enol)\u548cK\u5f0f(Keto)\u4e4b\u95f4\u7684\u4e92\u53d8\u5f02\u6784\u5728LIFM-CL1-H2<\/sub>O\u4e2d\u88abH\u952e\u9501\u95ed\uff0c\u800c\u5728LIFM-CL1\u4e2d\u88ab\u6253\u5f00\u3002<\/p>\n

\u56fe4 \u5149\u81f4\u53d1\u5149(PL)\u5207\u6362<\/strong><\/p>\n

\"\"<\/p>\n

(a-c)\u7531\u52a0\u70ed\u3001\u6c14\u4f53\u548c\u771f\u7a7a\u8c03\u8282\u7684\u542b\u6c34LIFM-CL1-H2<\/sub>O\u548c\u8131\u6c34LIFM-CL1\u7684PL\u53d1\u5c04\u5149\u8c31\u548c\u7167\u7247\uff0c\u663e\u793a\u51faESIPT\u8fc7\u7a0b\u4e2d\u914d\u4f53H2<\/sub>hpi2cf\u5728\u84dd\u8272E\u53d1\u5c04\u548c\u9752\u8272K\u53d1\u5c04\u4e4b\u95f4\u7684PL\u5207\u6362\uff1b<\/p>\n

(d)25\u2103\u4e0b\uff0c\u771f\u7a7a\u548c1bar\u5927\u6c14\u538b(RH=45%)\u5206\u522b\u5bf9\u5e94\u7684LIFM-CL1\u548cLIFM-CL1-H2<\/sub>O\u5fae\u6676\u7684\u4f9d\u65f6PL\u5f3a\u5ea6\u7684\u5faa\u73af\u66f2\u7ebf(\u03bbex<\/sub>=365nm\uff0c\u03bbem<\/sub>=463nm)\u3002<\/p>\n

\u56fe5 \u8584\u819c\u5236\u5907<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe\u4e3a\u5728ZnO\u7eb3\u7c73\u68d2\u8584\u819c\u4e0a\u7535\u6c89\u79ef\u548c\u539f\u4f4d\u751f\u957fLIFM-CL1-H2<\/sub>O\u7684\u793a\u610f\u56fe\u3002\u4eceZnO\u524d\u9a71\u4f53\u7684SEM\u7167\u7247\u548c\u6742\u5316LIFM-CL1-H2<\/sub>O-ZnO\u819c\u7684\u8367\u5149\u663e\u5fae\u955c\u7167\u7247\u53ef\u4ee5\u770b\u51fa\u5b83\u4eec\u5206\u5c5e\u4e8e\u4e0d\u540c\u7684\u751f\u957f\u9636\u6bb5\u3002<\/p>\n

\u56fe6 \u5b9e\u9645\u5e94\u7528<\/strong><\/p>\n

\"\"<\/p>\n

(a)ZnO\u652f\u6491\u7684\u6742\u5316\u819c\u7ecf\u52a0\u70ed\u6216N2<\/sub>\u5439\u626b\u7136\u540e\u5728\u7a7a\u6c14\u4e2d\u51b7\u5374\u7684PL\u989c\u8272\u5207\u6362\u7684\u7167\u7247\uff1b<\/p>\n

(b)ZnO\u652f\u6491\u7684\u6742\u5316\u819c\u7ecf\u79fb\u52a8\u7684\u79fb\u6db2\u7ba1\u5439\u626b\u7eafN2<\/sub>\u53d1\u751fPL\u989c\u8272\u53d8\u5316\u7684\u7167\u7247(365nm\u7d2b\u5916\u8f90\u5c04)\uff1b<\/p>\n

(c-d)\u5c06ZnO\u652f\u6491\u7684(c)\u542b\u6c34\u548c(d)\u8131\u6c34\u6742\u5316\u819c\u6d78\u5165\u4e0d\u540c\u542b\u6c34\u91cf(0-0.05% v\/v)\u7684THF(\u56db\u6c22\u544b\u5583)\u6eb6\u6db2\u4e2d\u7684PL\u989c\u8272\u53d8\u5316\uff1b<\/p>\n

(e)\u7528\u52a0\u70ed\u5230100\u2103\u7684\u5177\u6709\u201cS\u201d\u6807\u5fd7\u7684\u77f3\u5934\u5370\u7ae0(2\u00d72cm)\u5728LIFM-CL1-H2<\/sub>O\u7eb8\u819c\u4e0a\u8fdb\u884c\u70ed\u6210\u50cf\u7684\u7167\u7247\u3002<\/p>\n

\u56fe7 \u5728\u6e29\u5ea6\u8ba1\u548c\u6c34\u542b\u91cf\u6d4b\u5b9a\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n

\"\"<\/p>\n

(a)\u542b\u6c34LIFM-CL1-H2<\/sub>O\u5fae\u6676\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u53d1\u5c04\u5149\u8c31\u3002\u53ef\u4ee5\u770b\u51fa\u542b\u6c34LIFM-CL1-H2<\/sub>O\u5411\u8131\u6c34LIFM-CL1\u7684\u9010\u6b65\u8f6c\u53d8\uff0cCIE\u5750\u6807(\u8272\u5750\u6807)\u4e0e\u5404\u6e29\u5ea6\u4e0b\u7684\u53d1\u5149\u989c\u8272\u662f\u4e00\u81f4\u7684\uff1b<\/p>\n

(b)\u8131\u6c34LIFM-CL1\u5fae\u6676\u60ac\u6d6e\u5728\u4e0d\u540c\u542b\u6c34\u91cf(%\uff0cv\/v)\u7684MeOH(\u7532\u9187)\u6eb6\u6db2\u4e2d\u7684\u53d1\u5c04\u5149\u8c31\u7684\u53d8\u5316\u4ee5\u53ca\u76f8\u5e94\u53d1\u5149\u989c\u8272\u7684CIE\u5750\u6807\u3002\u6fc0\u53d1\u6ce2\u957f\u4e3a365nm\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/span><\/strong><\/p>\n

\u672c\u6587\u91c7\u7528H2<\/sub>hpi2cf\u914d\u4f53\u6210\u529f\u7ec4\u88c5\u4e86Zn-MOF\uff0c\u5e76\u7814\u7a76\u4e86\u5176\u7ed3\u6784\u548cESIPT\u8fc7\u7a0b\u4e2d\u7684PL\u7279\u6027\u3002\u5229\u7528\u5176\u53ef\u88ab\u6c34\u9a71\u52a8\u7684\u5355\u6676-\u5355\u6676\u7ed3\u6784\u8f6c\u53d8\u548cPL\u5207\u6362\u7279\u6027\u5236\u5907\u4e86\u4e00\u79cd\u8d85\u5feb(\u79d2\u7ea7)\u548c\u9ad8\u5ea6\u7075\u654f(1%RH\u62160.05% v\/v)\u7684PL\u6c34\u4f20\u611f\u5668\uff0c\u5728\u6e7f\u5ea6\u76d1\u6d4b\u3001\u6709\u673a\u6eb6\u5242\u4e2d\u75d5\u91cf\u6c34\u5206\u68c0\u6d4b\u3001\u70ed\u6210\u50cf\u548c\u6e29\u5ea6\u8ba1\u7b49\u9886\u57df\u8868\u73b0\u51fa\u4e86\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\u3002\u8be5\u7814\u7a76\u4e0d\u4ec5\u4e3aMOFs\u6750\u6599\u63d0\u4f9b\u4e00\u79cd\u8d85\u7075\u654f\u7684\u5355\u6676-\u5355\u6676\u8f6c\u53d8\u8303\u4f8b\uff0c\u800c\u4e14\u4e3a\u53d1\u5c55\u65b0\u4e00\u4ee3\u7684\u5316\u5b66\u548c\u70ed\u4f20\u611f\u5668\u63d0\u4f9b\u4e86\u65b0\u7684\u53ef\u80fd\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5<\/b>:<\/b> Ultrafast water sensing and thermal imaging by a metal-organic framework with switchable luminescence<\/a> (Nature Communications, 2017, DOI: 10.1038\/ncomms15985)<\/p>\n

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