{"id":90799,"date":"2017-07-13T06:30:40","date_gmt":"2017-07-12T22:30:40","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=90799"},"modified":"2017-07-12T09:18:27","modified_gmt":"2017-07-12T01:18:27","slug":"%e4%b8%8a%e7%a1%85%e6%89%80%e6%9d%8e%e9%a9%b0%e9%ba%9facs-nano%ef%bc%9a%e9%94%82%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0%e7%9a%84%e9%ab%98%e7%94%b5%e5%ae%b9%e9%87%8f%e8%bd%ac%e6%8d%a2%e8%b4%9f%e6%9e%81","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=90799","title":{"rendered":"\u4e0a\u7845\u6240\u674e\u9a70\u9e9fACS Nano\uff1a\u9502\u79bb\u5b50\u7535\u6c60\u7684\u9ad8\u7535\u5bb9\u91cf\u8f6c\u6362\u8d1f\u6781\u2014\u2014MoS2-C"},"content":{"rendered":"

\u3010\u5f15<\/strong> \u8a00\u3011<\/strong><\/p>\n

\u968f\u7740\u7535\u52a8\u6c7d\u8f66\u7684\u5927\u91cf\u63a8\u5e7f\uff0c\u9502\u79bb\u5b50\u7535\u6c60\u5bf9\u80fd\u91cf\u5bc6\u5ea6\u7684\u8981\u6c42\u8d8a\u6765\u8d8a\u9ad8\u3002\u6700\u65b0\u7684\u7535\u6781\u6750\u6599\u5df2\u7ecf\u5177\u5907\u8f83\u9ad8\u7684\u7535\u5bb9\u91cf\uff0c\u4f46\u662f\uff0c\u5728\u5145\u653e\u7535\u5faa\u73af\u8fc7\u7a0b\u4e2d\u4f1a\u51fa\u73b0\u76f8\u5206\u79bb\u548c\u4f53\u79ef\u81a8\u80c0\uff0c\u4ece\u800c\u5bfc\u81f4\u7535\u6781\u548c\u96c6\u6d41\u4f53\u7684\u63a5\u89e6\u4e0d\u826f\uff0c\u751a\u81f3\u51fa\u73b0\u6d3b\u6027\u7269\u8d28\u4ece\u57fa\u4f53\u7684\u8131\u843d\uff0c\u5f71\u54cd\u7535\u6c60\u6027\u80fd\u3002\u56e0\u6b64\uff0c\u9700\u8981\u4e00\u4e2a\u66f4\u597d\u7684\u7ed3\u5408\u8bbe\u8ba1\u4ee5\u7ef4\u6301\u7535\u6781\u7684\u5b8c\u6574\u6027\uff0c\u7f13\u89e3\u7535\u6c60\u5145\u653e\u7535\u5bb9\u91cf\u7684\u8870\u9000\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u4e0a\u6d77\u7845\u9178\u76d0\u7814\u7a76\u6240\u7684\u674e\u9a70\u9e9f(\u901a\u8baf\u4f5c\u8005)<\/strong>\u7b49\u4eba\u63d0\u51fa\u4e86\u4e00\u79cd\u8d85\u5e38\u8f6c\u6362\u8d1f\u6781\u7684\u6a21\u578b\uff0c\u6a21\u578b\u7531\u88ab\u8584\u78b3\u5c42\u5171\u5f62\u5c01\u88c5\u3001\u6570\u767e\u7eb3\u7c73\u5c3a\u5bf8\u7684\u6c14\u6ce1\u578b\u7279\u6b8a\u56fa\u6001MoS2<\/sub>\u7ec4\u6210\u3002\u8fd9\u79cdMoS2<\/sub>-C\u6df7\u5408\u7269\u901a\u8fc7\u591a\u91d1\u5c5e\u6c27\u9178\u76d0\uff08POM\uff09\u57fa\u87af\u5408\u7269\u7684\u540c\u65f6\u81ea\u786b\u5316\u548c\u81ea\u78b3\u5316\u83b7\u5f97\u3002\u5373\u4f7f\u662f\u8d85\u85842D\u7eb3\u7c73\u7247\uff0cMoS2<\/sub>-C\u7684\u50a8\u9502\u6027\u80fd\u4e5f\u4f18\u4e8e\u4e00\u822cMoS2<\/sub>\u57fa\u7684\u6b63\u6781\u3002\u57280.5~1A\/g\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u7ecf700\u6b21\u5faa\u73af\u540e\uff0cMoS2<\/sub>-C\u7684\u53ef\u9006\u7535\u5bb9\u91cf\u4f9d\u7136\u9ad8\u8fbe1500~2000mAh\/g\uff0c\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a10~20A\/g\u65f6\uff0c\u5176\u4e5f\u80fd\u7ef4\u6301\u57281000 mAh\/g\u5de6\u53f3\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cSupernormal Conversion Anode Consisting of High-Density MoS2<\/sub> Bubbles Wrapped in Thin Carbon Network by Self-Sulfuration of Polyoxometalate Complex\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u57282017\u5e746\u670829\u65e5\u7684ACS Nano\u671f\u520a\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1. <\/strong>MoS2<\/sub>-C<\/strong>\u590d\u5408\u6750\u6599\u7684\u5408\u6210\u7a0b\u5e8f\u793a\u610f\u56fe\u53ca\u76f8\u5e94\u6eb6\u6db2\u548c\u7c89\u672b\u7684\u7167\u7247<\/strong><\/p>\n

\"\"<\/p>\n

1). \u6a58\u8272\u6eb6\u6db2\u662fDTO\uff0c\u767d\u8272\u6eb6\u6db2\u662fL-\u534a\u80f1\u6c28\u9178\uff0c\u9ec4\u8272\u6eb6\u6db2\u662fPOM\uff1b<\/p>\n

2). \u9ed1\u8272\u7c89\u672b\u662fPOM-DTO\u87af\u5408\u7269\uff0c\u6df1\u84dd\u8272\u7c89\u672b\u662fPOM-L\u534a\u80f1\u6c28\u9178\u87af\u5408\u7269\uff1b<\/p>\n

3). \u5408\u6210\u8fc7\u7a0b\u5305\u62ec\u87af\u5408\u4f5c\u7528\u4e0e\u9ad8\u6e29\u5206\u89e3\u3002\u83b7\u5f97D-MoS2<\/sub>\u548cL-MoS2<\/sub>\u4e24\u79cd\u6750\u6599\uff1b<\/p>\n

4). MoS2<\/sub>-C\u590d\u5408\u6750\u6599\u5f62\u6001\u4e3a\u6c14\u6ce1\u578bMoS2<\/sub>\u56fa\u4f53\u88ab\u8584\u78b3\u5c42\u5305\u8986\uff0c\u4e0e\u4ee5\u53f6\u72b6\u9897\u7c92\u4e3a\u4e3b\u7684POM\u57fa\u590d\u5408\u4f53\u4e0d\u540c\u3002<\/p>\n

\u56fe<\/strong>2. D-MoS2<\/sub><\/strong>\u548c<\/strong>L-MoS2<\/sub><\/strong>\u7684<\/strong>XRD<\/strong>\u56fe\u6837\u53ca<\/strong>XPS<\/strong>\u5206\u6790<\/strong><\/p>\n

\"\"<\/p>\n

1). \u56fea\uff1aD-MoS2<\/sub>\u548cL- MoS2<\/sub>\u7684XRD\u56fe\u6837\u3002D-MoS2<\/sub>\u7684\uff08002\uff09\u5cf0\u503c\u8f83L- MoS2<\/sub>\u660e\u663e\uff0c\u8868\u660e\u524d\u8005\u5177\u5907S-Mo-S\u7684\u6709\u5e8f\u5806\u53e0\uff1b<\/p>\n

2). \u56fe b\u3001c\u3001d\u3001e\u3001f\u5206\u522b\u662fD-MoS2<\/sub>\u53caL- MoS2<\/sub>\u4e2dMo 3d\u3001S 2p\u3001C 1s\u3001N 1s\u3001P 2p\u7684X\u5c04\u7ebf\u5149\u7535\u5b50\u80fd\u8c31\u3002D-MoS2<\/sub>\u7684Mo 3d\u3001S 2p\u5cf0\u503c\u4f4e\u4e8eL- MoS2<\/sub>\u76f8\u5e94\u5cf0\u503c\uff0c\u8868\u660e\u524d\u8005\u6709\u8f83\u539a\u78b3\u5305\u8986\u5c42\u3002D-MoS2<\/sub>\u7684N 1s\u5cf0\u503c\u8f83L- MoS2\u9ad8\uff0c\u8868\u660e\u524d\u8005\u5177\u6709\u9ad8\u6c2e\u63ba\u6742\u91cf\u3002<\/p>\n

\u56fe<\/strong>3. D-MoS2<\/sub><\/strong>\u4e0e<\/strong>L- MoS2<\/sub><\/strong>\u7684<\/strong>SEM<\/strong>\u3001<\/strong>TEM<\/strong>\u56fe\u50cf\u53ca<\/strong>D-MoS2<\/sub><\/strong>\u7684<\/strong>STEM<\/strong>\u56fe\u50cf<\/strong><\/p>\n

\"\"<\/p>\n

1). \u56fea\u3001b\u5206\u522b\u4e3aD-MoS2<\/sub>\u7684\u6574\u4f53\u7684SEM\u56fe\u50cf\u548c\u653e\u5927SEM\u56fe\u50cf\uff1b\u56fec\u3001d\u5206\u522b\u4e3aL-MoS2<\/sub>\u7684\u6574\u4f53\u7684SEM\u56fe\u50cf\u548c\u653e\u5927SEM\u56fe\u50cf\uff1b<\/p>\n

2). \u56fee\u3001f\u5206\u522b\u4e3aD-MoS2<\/sub>\u7684TEM\u56fe\u50cf\u548cHRTEM\u56fe\u50cf\uff1b\u56feg\u3001h\u5206\u522b\u4e3aL-MoS2<\/sub>\u7684TEM\u56fe\u50cf\u548cHRTEM\u56fe\u50cf\uff1b<\/p>\n

3). \u56fei\u662fD-MoS2<\/sub>\u8bd5\u6837\u7ecf\u626b\u63cf\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\u83b7\u5f97\u7684\u5143\u7d20mapping\u56fe\u3002<\/p>\n

\u56fe<\/strong>4. D-MoS2<\/sub><\/strong>\u4e0e<\/strong>L- MoS2<\/sub><\/strong>\u5728\u9502\u79bb\u5b50\u7535\u6c60\u4e2d\u7684\u6027\u80fd\u6bd4\u8f83<\/strong><\/p>\n

\"\"<\/p>\n

1). \u56fea\uff1a\u7535\u6d41\u5bc6\u5ea60.5A\/g,\u7535\u538b0.01~3V\u65f6\u5145\u653e\u7535\u5bb9\u91cf\u53ca\u5e93\u4f26\u6548\u7387\u6bd4\u8f83\uff1b<\/p>\n

2). \u56feb\uff1a\u7535\u6d41\u5bc6\u5ea6\u4ece0.5A\/g\u589e\u81f320A\/g\uff0c\u50a8\u9502\u500d\u7387\u6027\u80fd\u6bd4\u8f83\uff1b<\/p>\n

3). \u56fec\uff1a\u7535\u6d41\u5bc6\u5ea6\u4e3a1A\/g\u65f6\uff0cD-MoS2<\/sub>\u4e0eD-C\u7684\u957f\u671f\u5faa\u73af\u6027\u80fd\u6bd4\u8f83\uff1b<\/p>\n

4). \u56fed\uff1a\u7535\u6d41\u5bc6\u5ea6\u4e3a5A\/g\u65f6\uff0cL-MoS2<\/sub>\u4e0eL-C\u7684\u957f\u671f\u5faa\u73af\u6027\u80fd\u6bd4\u8f83\u3002<\/p>\n

\u56fe<\/strong>5. D-MoS2<\/sub><\/strong>\u4e0e<\/strong>L-MoS2<\/sub><\/strong>\u7684\u6052\u6d41\u5145\u653e\u7535\u66f2\u7ebf<\/strong><\/p>\n

\"\"<\/p>\n

1). \u56fea\u3001b\uff1aD-MoS2<\/sub>\u4e0eL-MoS2<\/sub>\u5206\u522b\u4f5c\u4e3a\u9502\u7535\u6c60\u8d1f\u6781\uff0c\u5728\u7535\u538b\u4e3a0.01~3V\u3001\u7535\u6d41\u5bc6\u5ea6\u4e3a0.5A\/g\u65f6\uff0c\u4e0d\u540c\u5faa\u73af\u6b21\u6570\u7684\u6052\u5b9a\u7535\u6d41\u5145\u653e\u7535\u66f2\u7ebf\u3002<\/p>\n

\u56fe<\/strong>6. D-MoS2<\/sub><\/strong>\u4e0e<\/strong>L-MoS2<\/sub><\/strong>\u7684\u4ea4\u6d41\u963b\u6297\u8c31<\/strong><\/p>\n

\"\"<\/p>\n

1). \u56fea\u3001b\uff1a\u57285A\/g\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0cLi\/D-MoS2<\/sub>\u7535\u6c60\u548cLi\/L-MoS2<\/sub>\u7535\u6c60\u5206\u522b\u5faa\u73af1\/500\/1000\u6b21\u540e\u7684\u7535\u5316\u5b66\u4ea4\u6d41\u963b\u6297\u8c31\uff1b<\/p>\n

2). \u56feC\uff1a\u5bf9\u5e94\u963b\u6297\u8c31\u62df\u5408\u7684\u7b49\u6548\u7535\u8def\u3002<\/p>\n

\u56fe<\/strong>7. D-MoS2<\/sub><\/strong>\u4e0e<\/strong>L- MoS2<\/sub><\/strong>\u5728\u94a0\u79bb\u5b50\u7535\u6c60\u4e2d\u7684\u6027\u80fd\u6bd4\u8f83<\/strong><\/p>\n

\"\"<\/p>\n

1). \u56fea\uff1aD-MoS2<\/sub>\u4f5c\u4e3a\u94a0\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\uff0c\u5728\u7535\u538b\u4e3a0.01~3V\u3001\u7535\u6d41\u5bc6\u5ea60.1A\/g\u65f6\uff0c\u4e0d\u540c\u5faa\u73af\u9636\u6bb5\u7684\u6052\u5b9a\u7535\u6d41\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

2). \u56feb\uff1aD-MoS2<\/sub>\u5728\u94a0\u79bb\u5b50\u7535\u6c60\u4e2d\uff0c\u5145\u653e\u7535\u5bb9\u91cf\u53ca\u5e93\u4f26\u6548\u7387\u4e0e\u5faa\u73af\u6b21\u6570\u7684\u5173\u7cfb\uff1b<\/p>\n

3). \u56fec\uff1aD-MoS2<\/sub>\u4e0eL-MoS2<\/sub>\u7684\u50a8\u94a0\u500d\u7387\u6027\u80fd\u6bd4\u8f83\u3002<\/p>\n

\u3010\u5c0f<\/strong> \u7ed3\u3011<\/strong><\/p>\n

\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u79d1\u7814\u4eba\u5458\u5c06\u51e0\u767e\u7eb3\u7c73\u5927\u5c0f\u7684\u6c14\u6ce1\u578bMoS2<\/sub>\u6676\u7c92\u7528\u8584\u78b3\u5c42\u5171\u5f62\u5305\u8986\uff0c\u83b7\u5f97MoS2<\/sub>-C\u590d\u5408\u6750\u6599\uff0c\u6750\u6599\u7684\u7ed3\u6784\u5f62\u6001\u662f\u901a\u8fc7\u87af\u5408\u7269DTO-POM\uff08\u6216POM- L\u534a\u80f1\u6c28\u9178\uff09\u7684\u540c\u65f6\u81ea\u786b\u5316\u53ca\u81ea\u78b3\u5316\u5f62\u6210\u3002\u78b3\u5305\u8986\u5c42\u548c\u5468\u56f4\u66f4\u5bbd\u7684\u6c2e\u78f7\u63ba\u6742\u78b3\u57fa\u8d28\u65e0\u7f1d\u8fde\u63a5\uff0c\u6709\u6548\u907f\u514d\u4e86\u6d3b\u6027\u7269\u8d28\u7684\u5265\u843d\u4e0e\u5bfc\u7535\u7f51\u7edc\u7684\u65ad\u88c2\u3002D-MoS2<\/sub>\u5177\u6709\u8f83\u597d\u7684\u50a8\u9502\u80fd\u529b\uff0c\u5176\u57280.5A\/g\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u7ecf600\u6b21\u5faa\u73af\u540e\uff0c\u5bb9\u91cf\u4ecd\u63a5\u8fd12000 mAh\/g\uff0c\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a10~20A\/g\u65f6\uff0c\u5176\u5bb9\u91cf\u4f9d\u7136\u9ad8\u8fbe1000mAh\/g\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Supernormal Conversion Anode Consisting of High-Density MoS2 Bubbles Wrapped in Thin Carbon Network by Self-Sulfuration of Polyoxometalate Complex <\/a><\/p>\n

\uff08ACS Nano,2017;DOI:10.1021\/acsnano.7b03665\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u4eba\u7ec4\u8c22\u5143\u6797\u7f16\u8bd1\uff0c\u9ec4\u8d85\u5ba1\u6838\u3002\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\u3002<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15 \u8a00\u3011 \u968f\u7740\u7535\u52a8\u6c7d\u8f66\u7684\u5927\u91cf\u63a8\u5e7f\uff0c\u9502\u79bb\u5b50\u7535\u6c60\u5bf9\u80fd\u91cf\u5bc6\u5ea6\u7684\u8981\u6c42\u8d8a\u6765\u8d8a\u9ad8\u3002\u6700\u65b0\u7684\u7535\u6781\u6750\u6599\u5df2\u7ecf\u5177\u5907\u8f83\u9ad8\u7684\u7535\u5bb9\u91cf\uff0c\u4f46\u662f\uff0c\u5728\u5145\u653e\u7535\u5faa\u73af\u8fc7\u7a0b\u4e2d\u4f1a\u51fa\u73b0\u76f8\u5206\u79bb\u548c\u4f53\u79ef\u81a8\u80c0\uff0c\u4ece\u800c…<\/p>\n","protected":false},"author":272,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[1030],"class_list":["post-90799","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-1030"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/90799"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/272"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=90799"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/90799\/revisions"}],"predecessor-version":[{"id":91061,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/90799\/revisions\/91061"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=90799"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=90799"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=90799"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}