{"id":90981,"date":"2017-07-13T06:30:51","date_gmt":"2017-07-12T22:30:51","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=90981"},"modified":"2017-07-17T14:43:18","modified_gmt":"2017-07-17T06:43:18","slug":"%e3%80%90%e6%8a%95%e7%a8%bf%e5%be%85%e5%ae%9a%e3%80%91%e4%bb%a5%e8%89%b2%e5%88%97%e9%94%82%e7%94%b5%e5%a4%a7%e7%89%9bdoron-aurbach%e5%9b%a2%e9%98%9fjacs-%e9%94%82%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=90981","title":{"rendered":"\u4ee5\u8272\u5217\u9502\u7535\u5927\u725bDoron Aurbach\u56e2\u961fJACS: \u9502\u79bb\u5b50\u7535\u6c60\u7535\u89e3\u6db2\u4e2d\u9530\u7684\u6c27\u5316\u6001"},"content":{"rendered":"

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\n <\/span><\/strong>
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\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/span><\/strong><\/p>\n

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a) \u9530\u9178\u9502\u77f3\u58a8\u5168\u7535\u6c60\u6ee1\u7535\u6001\uff084.2v\uff09\u7ef4\u6301 6 \u5468\u7535\u5b50\u81ea\u65cb\u5171\u632f\uff08EPR\uff09\u4fe1\u53f7\u56fe\uff0c<\/p>\n

b) EPR \u4ee5\u53ca ICP \u7efc\u5408\u56fe\u3002<\/p>\n

C) 60\u2103\u9ad8\u6e29\u6761\u4ef6\u4e0b\uff0c\u7535\u6c60\u7ef4\u6301\u4e0d\u540c\u7535\u538b\uff0c\u4e0d\u540c\u65f6\u95f4\uff0c\u7535\u89e3\u6db2\u4e2d Mn3+<\/sup>\u7684\u542b\u91cf\u56fe<\/p>\n

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b)XANES \u5149\u8c31\u7684\u80fd\u91cf\u7684\u4e00\u9636\u5bfc\u6570<\/p>\n

c) \u7535\u5316\u5b66 \u6d4b\u8bd5\u540e\u5728\u7535\u89e3\u6db2\u4e2d\u6d4b\u8bd5\u540e\u5728\u7535\u89e3\u6db2\u4e2d Mn\u7684\u5e73\u5747\u6c27\u5316\u6001<\/p>\n

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\n <\/strong><\/span>
\n \u56e2\u961f\u901a\u8fc7\u4e00\u7cfb\u5217\u7684\u8868\u5f81\u8bc1\u660e\u5728\u5546\u7528\u516d\u6c1f\u78f7\u9178\u9502\u7535\u89e3\u6db2\u4f53\u7cfb\u4e2d\uff0cMn \u4e3b\u8981\u4ee5Mn3+<\/sup>\u7684\u5f62\u6001\u5b58\u5728\uff0c\u5176\u91cf\u7684\u591a\u5c11\u53d6\u51b3\u4e8e\u7535\u5316\u5b66\u6d4b\u8bd5\u6761\u4ef6\u3002Mn3+<\/sup> \u548c Mn4+<\/sup> \u5728\u7535\u89e3\u6db2\u4e2d\u76f8\u4f3c\u7684\u6eb6\u89e3\u5ea6\uff0cLMO \u662f\u5426\u4e30\u5bcc\u53ca\u5145\u7535\u72b6\u6001\u4e0d\u540c\u7b49\u56e0\u7d20\u5f71\u54cd\u4f1a\u5bfc\u81f4\u51fa\u73b0\u4e0d\u540c\u7684\u6d4b\u8bd5\u7ed3\u679c\uff0c\u4f5c\u8005\u5047\u8bbe Mn3+<\/sup>\u6bd4 Mn2+<\/sup>\u5177\u6709\u66f4\u9ad8\u7684\u6eb6\u5242\u7a33\u5b9a\u6027\uff0c\u4f7f\u5f97\u6b67\u5316\u53cd\u5e94\u901f\u7387\u7f13\u6162\uff0c\u5bfc\u81f4\u6eb6\u6db2\u4e2d Mn3+<\/sup>\u5360\u636e\u4e3b\u5bfc\u3002\u4f5c\u8005\u7684\u7ed3\u8bba\u4e0e\u4e4b\u524d\u4f20\u7edf\u7684 Mn2+<\/sup>\u5360\u4e3b\u5bfc\u7406\u8bba\u76f8\u8fdd\u80cc\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u4f5c\u8005\u53d1\u73b0\uff0c\u9530\u9178\u9502\u6b63\u6781\u4e2d\u9530\u6eb6\u51fa\u7684\u4e3b\u8981\u673a\u7406\u662f Mn3+<\/sup>\u7684\u6b67\u5316\u53cd\u5e94\uff0c\u8fd9\u4e5f\u8bb8\u540c\u6837\u9002\u7528\u4e8e\u5176\u4ed6\u5c16\u6676\u77f3\u76f8\u6b63\u6781\u6750\u6599\u3002\u00a0<\/p>\n

\u539f\u6587\u94fe\u63a5\uff1aOn the Oxidation State of Manganese Ions in Li-Ion Battery Electrolyte Solutions<\/a>\u00a0(J. Am. Chem. Soc., 2017, DOI: 10.1021\/jacs.6b10781)\u00a0<\/p>\n

\u672c\u6587\u7531\u738b\u5eb7\u6295\u7a3f\uff0c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u7ec4\u80cc\u9006\u65f6\u5149\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

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\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e<\/strong>\u6750\u6599\u4eba<\/strong><\/a>\u3001\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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