{"id":92333,"date":"2017-07-23T06:30:37","date_gmt":"2017-07-22T22:30:37","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=92333"},"modified":"2017-07-22T12:50:21","modified_gmt":"2017-07-22T04:50:21","slug":"%e3%80%90%e5%b7%b2%e6%a0%a1%e3%80%91%e4%b8%ad%e7%a7%91%e9%99%a2%e5%a4%a7%e5%8c%96%e6%89%80%e6%9d%a8%e7%bb%b4%e6%85%8e%e7%a0%94%e7%a9%b6%e5%91%98angew-chem-int-ed-%e4%ba%8c%e7%bb%b4%e6%9c%89","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=92333","title":{"rendered":"\u4e2d\u79d1\u9662\u5927\u8fde\u5316\u7269\u6240\u6768\u7ef4\u614e\u7814\u7a76\u5458Angew. Chem. Int. Ed.: \u4e8c\u7ef4\u6709\u673a\u91d1\u5c5e\u9aa8\u67b6\u6c14\u4f53\u5206\u79bb\u819c"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n

\u57fa\u4e8e\u819c\u7684\u6c14\u4f53\u5206\u79bb\u6280\u672f\u5177\u6709\u80fd\u8017\u4f4e\u3001\u53ef\u8fde\u7eed\u64cd\u4f5c\u3001\u6210\u672c\u4f4e\u548c\u5bf9\u73af\u5883\u53cb\u597d\u7b49\u4f18\u70b9\uff0c\u56e0\u800c\u53d7\u5230\u4e86\u5b66\u672f\u754c\u548c\u5de5\u4e1a\u754c\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u8fd1\u5e74\u6765\uff0c\u4e8c\u7ef4\u7eb3\u7c73\u7247(\u6c27\u5316\u77f3\u58a8\u70ef\u3001\u5c42\u72b6\u8fc7\u6e21\u91d1\u5c5e\u786b\u5316\u7269\u3001\u5c42\u72b6\u53cc\u6c22\u6c27\u5316\u7269\u3001\u6cb8\u77f3\u7eb3\u7c73\u7247\u7b49)\u7531\u4e8e\u5176\u539f\u5b50\u7ea7\u522b\u7684\u539a\u5ea6\u548c\u6781\u4f4e\u7684\u4f20\u8d28\u963b\u529b\uff0c\u6210\u4e3a\u4e86\u9ad8\u901a\u91cf\u6c14\u4f53\u5206\u79bb\u819c\u9886\u57df\u7814\u7a76\u7684\u70ed\u70b9\u3002\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(Metal-organic frameworks, MOFs)\u7eb3\u7c73\u7247\u5177\u6709\u4e30\u5bcc\u7684\u9aa8\u67b6\u7ed3\u6784\u548c\u5206\u5b50\u5c3a\u5ea6\u7684\u9ad8\u5bc6\u5ea6\u5b54\u9053\uff0c\u88ab\u8ba4\u4e3a\u662f\u6784\u7b51\u6c14\u4f53\u5206\u79bb\u819c\u7684\u7406\u60f3\u5355\u5143\u3002\u7136\u800c\uff0c\u5408\u6210\u7ed3\u6784\u7a33\u5b9a\u7684MOF\u7eb3\u7c73\u7247\u5de5\u827a\u590d\u6742\u3001\u6781\u5177\u6311\u6218\uff0c\u4e25\u91cd\u963b\u788d\u4e86\u5176\u540e\u7eed\u7814\u7a76\u548c\u5e94\u7528\uff0c\u662f\u4e8c\u7ef4 MOF\u7eb3\u7c73\u7247\u6c14\u4f53\u5206\u79bb\u819c\u9886\u57df\u7814\u7a76\u7684\u96be\u70b9\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/span><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u79d1\u9662\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u6768\u7ef4\u614e\u7814\u7a76\u5458<\/strong>(\u901a\u8baf\u4f5c\u8005)<\/strong>\u7b49\u4eba\u5728Angew. Chem. Int. Ed.<\/strong>\u53d1\u8868\u4e86\u9898\u4e3a\u201cTwo-Dimensional Metal\u2013Organic Framework Nanosheets for Membrane-Based Gas Separation\u201d<\/strong>\u7684\u7814\u7a76\u8bba\u6587\uff0c\u62a5\u9053\u4e86\u4e8c\u7ef4MOF\u5728\u6c14\u4f53\u5206\u79bb\u9886\u57df\u7684\u6700\u65b0\u7814\u7a76\u6210\u679c\u3002\u8be5\u56e2\u961f\u4ee5\u5168\u65b0\u7684\u4e24\u4eb2\u6027\u5c42\u72b6MOF\u524d\u9a71\u4f53Zn2<\/sub>(Bim)3<\/sub>\u4e3a\u539f\u6599\uff0c\u901a\u8fc7\u6e29\u548c\u7269\u7406\u5265\u79bb\u7684\u65b9\u6cd5\u5f97\u5230\u4e86\u53cc\u5206\u5b50\u5c42\u539a\u5ea6\u7684\u7eb3\u7c73\u7247\uff0c\u5e76\u901a\u8fc7\u81ea\u4e3b\u5f00\u53d1\u7684\u70ed\u7ec4\u88c5\u65b9\u6cd5\u5236\u5907\u4e86\u539a\u5ea6\uff1c10nm\u7684\u8d85\u8584MOF\u7eb3\u7c73\u7247\u819c\u3002\u57fa\u4e8eZn2<\/sub>(Bim)3<\/sub>\u7eb3\u7c73\u7247\u7684\u5206\u5b50\u7b5b\u819c\u5bf9H2<\/sub>\/CO2<\/sub>\u6df7\u5408\u6c14\u4f53\u8868\u73b0\u51fa\u4e86\u6781\u4e3a\u4f18\u5f02\u7684\u5206\u79bb\u6027\u80fd\uff0c\u5728\u7ef4\u6301CO2<\/sub>\u900f\u91cf\u4e0d\u53d8\u7684\u60c5\u51b5\u4e0b\uff0c\u8be5\u819c\u968f\u6d4b\u8bd5\u6e29\u5ea6\u7684\u5347\u9ad8\uff0c\u5176\u5bf9H2<\/sub>\u7684\u900f\u8fc7\u91cf\u53ef\u5347\u9ad8\u52308\u00d710-7<\/sup> mol m-2 <\/sup>s-1 <\/sup>Pa-1<\/sup>\uff0c\u5206\u79bb\u7cfb\u6570\u9ad8\u8fbe166\u3002<\/p>\n

\u00a0<\/strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n

\u56fe<\/strong>1 Zn2<\/sub>(Bim)3<\/sub><\/strong>\u524d\u9a71\u4f53\u7684\u7ed3\u6784<\/strong><\/p>\n

\"\"<\/p>\n

(a)Zn2<\/sub>(Bim)3<\/sub>\u524d\u9a71\u4f53\u6cbfc<\/em>\u8f74\u65b9\u5411\u76844\u5c42\u5806\u53e0\u7ed3\u6784\u793a\u610f\u56fe\u3002\u56fe\u4e2dZn-\u7eff\u8272\uff0cN-\u6a59\u8272\uff0cC-\u7070\u8272\uff0cH-\u767d\u8272\uff0cO-\u7ea2\u8272\uff1bZn\u914d\u4f4d\u591a\u9762\u4f53\u8868\u793a\u4e3a\u7eff\u8272\uff0c\u6cbfc<\/em>\u8f74\u65b9\u5411\u7684\u82ef\u5e76\u54aa\u5511\u914d\u4f53\u5c42\u8868\u793a\u4e3a\u7d2b\u8272\uff0c\u5176\u4ed6\u7684\u4e3a\u9ec4\u8272\uff1b<\/p>\n

(b)\u53cc\u5c42Zn2<\/sub>(Bim)3<\/sub>\u7ed3\u6784\u7684AB\u5f0f\u5806\u53e0\u6a21\u578b\uff1b<\/p>\n

(c)\u82ef\u5e76\u73af\u5411\u4e0a\u7684Zn2<\/sub>(Bim)3<\/sub>\u7684\u5355\u5c42\u7eb3\u7c73\u7247\u7ed3\u6784\uff0c\u56fe\u4e2d\u9ad8\u4eae\u663e\u793a\u4e86Zn\u8282\u70b9\u4e0e\u82ef\u5e76\u54aa\u5511\u914d\u4f53\u7684\u4e09\u914d\u4f4d\u7ed3\u6784\u3002\u4e3a\u4e86\u7b80\u5316\uff0c\u7701\u7565\u4e86H\u539f\u5b50\uff1bZn-\u7eff\u8272\uff0cN-\u6a59\u8272\uff0cC-\u7070\u8272\uff1b<\/p>\n

(d)Zn2<\/sub>(Bim)3<\/sub>\u524d\u9a71\u4f53\u7684PXRD(\u7c89\u672bX\u5c04\u7ebf\u884d\u5c04)\u8c31\u56fe\u3002<\/p>\n

\u56fe<\/strong>2 Zn2<\/sub>(Bim)3<\/sub><\/strong>\u524d\u9a71\u4f53\u548c\u7eb3\u7c73\u7247\u7684\u5fae\u89c2\u7ed3\u6784<\/strong><\/p>\n

\"\"<\/p>\n

(a)Zn2<\/sub>(Bim)3<\/sub>\u524d\u9a71\u4f53\u7684SEM\u56fe\u3002\u5185\u63d2\u4e3a\u56fe\u4e2d\u7ea2\u8272\u65b9\u6846\u533a\u57df\u7684\u653e\u5927\u56fe\uff0c\u6807\u5c3a\uff1a10\u03bcm\uff1b<\/p>\n

(b)Zn2<\/sub>(Bim)3<\/sub>\u7eb3\u7c73\u7247\u7684AFM\u56fe\u548c\u9ad8\u5ea6\u5256\u9762\u3002<\/p>\n

\u00a0<\/strong>\u56fe<\/strong>3 Zn2<\/sub>(Bim)3<\/sub><\/strong>\u524d\u9a71\u4f53\u7684\u5265\u79bb\u53ca\u7eb3\u7c73\u7247\u7ec4\u88c5\u8fc7\u7a0b\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

(a)\u4e0a\uff1aZn2<\/sub>(Bim)3<\/sub>\u524d\u9a71\u4f53\u6cbfc<\/em>\u8f74\u65b9\u5411\u76844\u5c42\u5806\u53e0\u793a\u610f\u56fe\uff1b\u4e0b\uff1a\u5c42\u72b6\u524d\u9a71\u4f53\u9897\u7c92\u7684SEM\u56fe\u3002\u5265\u79bb\u8fc7\u7a0b\u4e2d\u7684\u5c0f\u5206\u5b50\u4ee3\u8868\u7532\u9187\u548c\u6b63\u4e19\u9187\uff1b<\/p>\n

(b)\u4e0a\uff1aZn2<\/sub>(Bim)3<\/sub>\u7eb3\u7c73\u7247\u5206\u6563\u5728\u7532\u9187\/\u6b63\u4e19\u9187\u7684\u7b49\u4f53\u79ef\u6df7\u5408\u6db2\u4e2d\uff1b\u4e0b\uff1aZn2<\/sub>(Bim)3<\/sub>\u7eb3\u7c73\u7247\u7684TEM\u56fe\uff1b<\/p>\n

(c)\u4e0a\uff1aZn2<\/sub>(Bim)3<\/sub>\u7eb3\u7c73\u7247\u819c\u7684\u793a\u610f\u56fe\uff1b\u4e0b\uff1a200\u2103\u4e0b\u5236\u5907\u7684Zn2<\/sub>(Bim)3<\/sub>\u7eb3\u7c73\u7247\u819c\u7684\u4fef\u89c6(\u5de6\u4e0b)\u548c\u65ad\u9762(\u53f3\u4e0b)SEM\u56fe\u3002<\/p>\n

\u00a0<\/strong>\u56fe<\/strong>4 Zn2<\/sub>(Bim)3<\/sub><\/strong>\u7eb3\u7c73\u7247\u819c\u7684\u6c14\u4f53\u5206\u79bb\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

(a)\u591a\u5b54Zn2<\/sub>(Bim)3<\/sub>\u7eb3\u7c73\u7247\u7684\u6c14\u4f53\u5206\u79bb\u793a\u610f\u56fe\u3002\u56fe\u4e2d\u4e3a\u4e86\u7b80\u5316\uff0c\u53ea\u663e\u793a\u4e86Zn\u539f\u5b50\uff0c\u6d45\u84dd\u8272\u7684\u5e73\u9762\u4ee3\u8868\u5ffd\u7565\u4e86\u4e24\u4eb2\u6027\u7684\u7eb3\u7c73\u7247\uff1b\u5b9e\u7ebf\u548c\u77ed\u5212\u7ebf\u4ee3\u8868H2<\/sub>(\u84dd\u8272)\u548cCO2<\/sub>(\u7ea2\u8272)\u7684\u8def\u5f84\uff1b<\/p>\n

(b)\u901a\u8fc7\u70ed\u7ec4\u88c5\u65b9\u6cd5\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u5236\u5907\u7684\u7eb3\u7c73\u7247\u819c\u5bf9\u7b49\u6469\u5c14\u6bd4H2<\/sub>\/CO2<\/sub>\u53cc\u7ec4\u4efd\u6c14\u4f53\u7684\u5206\u79bb\u6027\u80fd\uff1b<\/p>\n

(c)\u5728200\u2103\u4e0b\u5236\u5907\u7684Zn2<\/sub>(Bim)3<\/sub>\u7eb3\u7c73\u7247\u819c\u5bf9\u5355\u7ec4\u5206\u6c14\u4f53\u7684\u900f\u8fc7\u80fd\u529b\uff1b<\/p>\n

(d)\u6e29\u5ea6\u53d8\u5316\u5bf9150\u2103\u4e0b\u5236\u5907\u7684Zn2<\/sub>(Bim)3<\/sub>\u7eb3\u7c73\u7247\u819c\u7684H2<\/sub>\/CO2<\/sub>\u900f\u8fc7\u80fd\u529b\u548c\u6df7\u5408SF(\u5206\u79bb\u7cfb\u6570)\u7684\u5f71\u54cd\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/span><\/p>\n

\u672c\u6587\u901a\u8fc7\u6e29\u548c\u7269\u7406\u65b9\u6cd5\u5265\u79bb\u53cc\u4eb2\u6027\u7684\u5c42\u72b6Zn2<\/sub>(Bim)3<\/sub>\u524d\u9a71\u4f53\u6210\u529f\u83b7\u5f97\u4e86\u53cc\u5206\u5b50\u539a\u5ea6\u7684\u7eb3\u7c73\u7247\uff0c\u5e76\u901a\u8fc7\u70ed\u7ec4\u88c5\u7684\u65b9\u6cd5\u5236\u5907\u4e86\u8d85\u8584\u6c14\u4f53\u5206\u79bb\u819c\u3002\u57fa\u4e8e\u4f53\u79ef\u6392\u9664\u6548\u5e94\uff0c\u8be5\u819c\u5bf9H2<\/sub>\/CO2<\/sub>\u6df7\u5408\u6c14\u4f53\u8868\u73b0\u51fa\u4e86\u5341\u5206\u4f18\u5f02\u7684\u5206\u79bb\u6027\u80fd\uff0c\u6709\u671b\u6210\u4e3a\u65b0\u4e00\u4ee3\u7684\u8d85\u9ad8\u901a\u91cf\u6c14\u4f53\u5206\u79bb\u819c\u3002<\/p>\n

\u3010\u901a\u8baf\u4f5c\u8005\u53ca\u7814\u7a76\u56e2\u961f\u4ecb\u7ecd\u3011<\/strong><\/span><\/p>\n

\u6768\u7ef4\u614e<\/strong>\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u9996\u5e2d\u7814\u7a76\u5458\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u56fd\u5bb6\u6770\u51fa\u9752\u5e74\u57fa\u91d1\u83b7\u5f97\u8005\uff0c\u56fd\u5bb6973\u9879\u76ee\u9996\u5e2d\u79d1\u5b66\u5bb6\u3002\u5148\u540e\u5728\u82f1\u56fdBirmingham\u5927\u5b66(1989)\u3001\u5fb7\u56fdInst. Interfacial Eng. Biotech. (1999)\u3001\u7f8e\u56fdUniv. Southern California(2001)\u7b49\u7814\u7a76\u5355\u4f4d\u53ca\u5927\u5b66\u4f5c\u8bbf\u95ee\u5b66\u8005\uff1b\u53d1\u8868\u5b66\u672f\u8bba\u6587300\u4f59\u7bc7\uff0cSCI\u5f15\u752810,000\u4f59\u6b21\uff0cH\u56e0\u5b5052\uff1b\u8457\u4f5c2\u672c\uff1b\u4e13\u5229\u6388\u674360\u4f59\u4ef6\uff0c\u5efa\u7acb\u591a\u5957\u4e07\u5428\u7ea7\u5206\u5b50\u7b5b\u819c\u5de5\u4e1a\u5e94\u7528\u88c5\u7f6e\uff1b\u83b7\u8fbd\u5b81\u7701\u81ea\u7136\u79d1\u5b66\u4e00\u7b49\u5956(\u7b2c\u4e00\u5b8c\u6210\u4eba\uff0c2006)\u4ee5\u53ca\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u4e8c\u7b49\u5956(\u7b2c\u4e00\u5b8c\u6210\u4eba\uff0c2015)\u3002<\/p>\n

\u6768\u7ef4\u614e\u7814\u7a76\u5458\u9886\u5bfc\u7684\u56e2\u961f\u957f\u671f\u4ece\u4e8b\u65e0\u673a\u819c\u53ca\u50ac\u5316\u65b0\u6750\u6599\u7814\u7a76\u3002\u8fd1\u5e74\u6765\uff0c\u7814\u7a76\u56e2\u961f\u5728\u900f\u6c27\u819c\u548c\u5206\u5b50\u7b5b\u819c\u7814\u7a76\u9886\u57df\u53d6\u5f97\u4e30\u7855\u6210\u679c\u3002\u5728\u900f\u6c27\u819c\u7814\u7a76\u65b9\u9762\uff0c\u53d1\u73b0\u4e86\u4f4e\u6e29\u900f\u6c27\u819c\u56e0\u786b\u6742\u8d28\u8fc1\u79fb\u8f93\u9001\u800c\u5bfc\u81f4\u7684\u6027\u80fd\u8870\u51cf\u95ee\u9898\uff0c\u521b\u65b0\u6027\u5730\u63d0\u51fa\u5728\u819c\u8868\u9762\u6d82\u8986\u591a\u5b54\u6c27\u6d3b\u5316\u5c42\u6765\u5bb9\u7eb3\u4ece\u4f53\u76f8\u6269\u6563\u6e17\u51fa\u7684\u786b\u6742\u8d28\uff0c\u89e3\u51b3\u4e86\u4f4e\u6e29\u900f\u6c27\u819c\u5173\u952e\u6027\u79d1\u5b66\u95ee\u9898(Angew. Chem. Int. Ed., 52 (2013) 3232)\uff1b\u9488\u5bf9\u819c\u6750\u6599\u4f4e\u6e29\u76f8\u53d8\u5f15\u53d1\u7684\u6027\u80fd\u8870\u51cf\u95ee\u9898\uff0c\u521b\u65b0\u6027\u5730\u63d0\u51fa\u901a\u8fc7\u9650\u5236\u91d1\u5c5e\u79bb\u5b50\u6cbf\u6676\u754c\u7684\u6269\u6563\u6765\u6291\u5236\u5f02\u76f8\u6210\u6838\u548c\u65b0\u76f8\u5f62\u6210\uff0c\u6781\u5927\u63d0\u9ad8\u4e86\u6613\u76f8\u53d8\u819c\u6750\u6599\u7684\u4f4e\u6e29\u7a33\u5b9a\u6027(Nano Letters, 15 (2015) 7678)\uff1b\u5728\u6b64\u57fa\u7840\u4e0a\uff0c\u5b9e\u73b0\u900f\u6c27\u819c\u53cd\u5e94\u5668\u4e2d\u4e00\u6b65\u540c\u65f6\u5236\u5907\u5408\u6210\u6c28\u539f\u6599\u6c14\u548cF-T\u5408\u6210\u6c14(Angew. Chem. Int. Ed., 545(2016) 8566)\u4ee5\u53ca\u6c34\u5206\u89e3\u5236\u6c22(Energ. Environ. Sci., 10 (2017) 101)\u3002\u5728\u5206\u5b50\u7b5b\u819c\u7814\u7a76\u65b9\u9762\uff0c\u5728\u56fd\u9645\u4e0a\u9996\u6b21\u6210\u529f\u5730\u5c06\u4e8c\u7ef4\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(MOF)\u6750\u6599\u5f00\u5c42\u83b7\u5f97\u5355\u5206\u5b50\u5c42\u539a\u5ea6\u7684\u5206\u5b50\u7b5b\u7eb3\u7c73\u7247\uff0c\u901a\u8fc7\u70ed\u7ec4\u88c5\u65b9\u6cd5\u5f97\u5230\u539a\u5ea6\u5c0f\u4e8e5 nm\u7684\u8d85\u8584\u5206\u5b50\u7b5b\u819c\uff0c\u5b9e\u73b0\u4e86\u5bf9\u5c3a\u5bf8\u5dee\u5f02\u4ec5\u4e3a0.04 \u7eb3\u7c73\u7684\u6c22\u6c14\u548c\u4e8c\u6c27\u5316\u78b3\u5206\u5b50\u7684\u5feb\u901f\u3001\u7cbe\u786e\u7b5b\u5206(Science, 346 (2014) 1356\uff1bAngew. Chem. Int. Ed., DOI: 10.1002\/anie.201703959)\uff1b\u9488\u5bf9MOF\u5b54\u7a97\u67d4\u6027\u95ee\u9898\uff0c\u63d0\u51fa\u4ee5\u9650\u57df\u8d1f\u8f7d\u79bb\u5b50\u6db2\u4f53\u7684\u65b9\u6cd5\u6765\u7cbe\u7ec6\u8c03\u53d8\u6750\u6599\u7684\u5b54\u9053\u4f53\u7cfb\uff0c\u6784\u5efa\u4e86\u5177\u6709\u4f18\u5f02\u6027\u80fd\u7684MOF\u819c(Angew. Chem. Int. Ed., 54 (2015) 15483)\uff1b\u7531\u4e8eMOF\u819c\u7814\u7a76\u53d7\u5230\u56fd\u9645\u5e7f\u6cdb\u5173\u6ce8\uff0c\u5e94\u9080\u5728\u5fb7\u56fd\u300a\u5148\u8fdb\u6750\u6599\u300b\u4e0a\u53d1\u8868\u8fdb\u5c55\u62a5\u544a(Adv. Mater., DOI: 10.1002\/adma.201606949)\uff1b\u5229\u7528\u7535\u5316\u5b66\u79bb\u5b50\u70ed\u5408\u6210\u65b9\u6cd5\uff0c\u539f\u4f4d\u5408\u6210\u51fa\u4e86\u9ad8\u5ea6\u9762\u5185\u53d6\u5411\u7684\u65e0\u7f3a\u9677\u5206\u5b50\u7b5b\u819c\uff0c\u6781\u5927\u514b\u670d\u4e86\u539f\u4f4d\u6676\u5316\u548c\u4e8c\u6b21\u751f\u957f\u7b49\u4f20\u7edf\u8584\u819c\u5236\u5907\u65b9\u6cd5\u819c\u7f3a\u9677\u591a\u3001\u6b65\u9aa4\u7e41\u7410\u7684\u7f3a\u70b9\uff0c\u4e3a\u5b9e\u73b0\u66f4\u591a\u5206\u5b50\u7b5b\u819c\u7684\u653e\u5927\u548c\u5de5\u4e1a\u5316\u5960\u5b9a\u4e86\u79d1\u5b66\u57fa\u7840(Angew. Chem. Int. Ed., 54 (2015) 13032)\u3002<\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Two-Dimensional Metal\u2013Organic Framework Nanosheets for Membrane-Based Gas Separation<\/a>(Angew. Chem. Int. Ed., 2017, DOI: 10.1002\/anie.201703959)<\/p>\n

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