{"id":92659,"date":"2017-07-25T06:30:52","date_gmt":"2017-07-24T22:30:52","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=92659"},"modified":"2017-07-23T00:00:29","modified_gmt":"2017-07-22T16:00:29","slug":"%e4%b8%ad%e5%9b%bd%e7%a7%91%e5%ad%a6%e9%99%a2%e7%a6%8f%e5%bb%ba%e7%89%a9%e8%b4%a8%e7%bb%93%e6%9e%84%e7%a0%94%e7%a9%b6%e6%89%80%e7%ad%89%ef%bc%9a%e7%bb%8f%e6%b5%8e%e7%a8%b3%e5%ae%9a%e4%ba%a7%e6%b0%a2","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=92659","title":{"rendered":"\u4e2d\u56fd\u79d1\u5b66\u9662\u798f\u5efa\u7269\u8d28\u7ed3\u6784\u7814\u7a76\u6240\u7b49\uff1a\u7ecf\u6d4e\u7a33\u5b9a\u4ea7\u6c22\u5355\u539f\u5b50\u50ac\u5316\u5242\u7406\u8bba\u8bbe\u8ba1\u7814\u7a76\u83b7\u8fdb\u5c55"},"content":{"rendered":"<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u4e2d\u56fd\u79d1\u5b66\u9662\u798f\u5efa\u7269\u8d28\u7ed3\u6784\u7814\u7a76\u6240\u7ed3\u6784\u5316\u5b66\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u5434\u514b\u741b\u7814\u7a76\u7ec4\u5728\u526f\u7814\u7a76\u5458\u674e\u5de7\u7ea2\u4e3b\u6301\u7684\u56fd\u5bb6\u57fa\u91d1\u59d4\u9752\u5e74\u9879\u76ee\u548c\u7f8e\u56fd\u6000\u4fc4\u660e\u5927\u5b66\u5316\u5b66\u7cfb\u6559\u6388\u8303\u8302\u5b8f\u4e3b\u6301\u7684\u7f8e\u56fd\u80fd\u6e90\u90e8\u9879\u76ee\u7b49\u7684\u8d44\u52a9\u4e0b\uff0c\u79ef\u6781\u5f00\u5c55\u9762\u5411\u65b0\u80fd\u6e90\u50ac\u5316\u53cd\u5e94\u673a\u7406\u548c\u65b0\u578b\u50ac\u5316\u5242\u7684\u7406\u8bba\u7814\u7a76\u3002\u8fd1\u65e5\uff0c\u674e\u5de7\u7ea2\u4e0e\u8303\u8302\u5b8f\u5f00\u5c55\u5408\u4f5c\uff0c\u4ee5\u8d35\u91d1\u5c5e\u94c2\u7684\u9ad8\u6548\u5e94\u7528\u4e8e\u6c34\u7164\u6c14\u53cd\u5e94\u4e3a\u7814\u7a76\u80cc\u666f\uff0c\u901a\u8fc7\u4e25\u5bc6\u7684\u7406\u8bba\u8ba1\u7b97\u8bbe\u8ba1\u51fa\u4e00\u6b3e\u7a33\u5b9a\u4e14\u4f4e\u4ef7\u9ad8\u6548\u4ea7\u6c22\u7684\u65b0\u9896\u8d1f\u8f7d\u578b\u5355\u539f\u5b50Pt\u57fa\u50ac\u5316\u5242\u2014\u2014Pt@Mo<sub>2<\/sub>C\u3002\u76f8\u5173\u7814\u7a76\u7ed3\u679c\u4ee5\u201cComputation-predicted, stable, and inexpensive single-atom nanocatalyst Pt@Mo<sub>2<\/sub>C\u2013an important advanced material for H<sub>2<\/sub> production\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u671f\u520aJournal of Materials Chemistry A\u4e0a\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>1 Pt @ Mo<sub>2<\/sub>C<\/strong><strong>\uff08<\/strong><strong>001<\/strong><strong>\uff09\u8868\u9762\u4e0a\u5438\u9644\u7269\u7684\u4f18\u5148\u5438\u9644\u60c5\u51b5<\/strong><\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-92662\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/07\/4-20.jpg\" alt=\"\" width=\"600\" height=\"284\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/07\/4-20.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/07\/4-20-300x142.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/strong><\/p>\n<p>\u62ec\u53f7\u4e2d\u7684\u503c\u662f\u5438\u9644\u80fd\u91cf\u3002\u5438\u9644\u80fd\u91cf\u4ee5eV\u7ed9\u51fa\u3002Mo\u3001Pt\u3001C\u3001O\u3001H\u539f\u5b50\u5206\u522b\u4ee5\u84dd\u8272\u3001\u6df1\u84dd\u8272\u3001\u7070\u8272\u3001\u7ea2\u8272\u548c\u767d\u8272\u7740\u8272<\/p>\n<p><strong>\u56fe<\/strong><strong>2 WGS<\/strong><strong>\u53cd\u5e94\u7684\u52bf\u80fd\u8ba1\u7b97\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-92663\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/07\/5-16.jpg\" alt=\"\" width=\"600\" height=\"273\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/07\/5-16.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/07\/5-16-300x137.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u84dd\u7ebf\uff1aPt\uff08111\uff09\u8868\u9762<\/p>\n<p>\u7eff\u7ebf\uff1aPt @ Mo<sub>2<\/sub>C\uff08001\uff09\u8868\u9762<\/p>\n<p><strong>\u3010\u7814\u7a76\u5185\u5bb9\u3011<\/strong><\/p>\n<p>\u6e05\u6d01\u80fd\u6e90\u662f\u4eba\u7c7b\u793e\u4f1a\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u57fa\u77f3\uff0c\u800c\u6c22\u662f\u4e00\u79cd\u6700\u4e3a\u7406\u60f3\u7684\u6e05\u6d01\u80fd\u6e90\u4e4b\u4e00\u3002\u6c34\u7164\u6c14\u53cd\u5e94\u662f\u4e00\u79cd\u91cd\u8981\u7684\u4ea7\u6c22\u65b9\u5f0f\uff0c\u4f46\u662f\u5173\u952e\u7684\u50ac\u5316\u5242\u53ca\u5176\u50ac\u5316\u673a\u7406\u8fd8\u7f3a\u4e4f\u6df1\u5165\u7684\u63a2\u7a76\u3002<\/p>\n<p>\u674e\u5de7\u7ea2\u4e0e\u8303\u8302\u5b8f\u5408\u4f5c\u8bbe\u8ba1\u51fa\u4e00\u6b3e\u7a33\u5b9a\u4e14\u4f4e\u4ef7\u9ad8\u6548\u4ea7\u6c22\u7684\u65b0\u9896\u8d1f\u8f7d\u578b\u5355\u539f\u5b50Pt\u57fa\u50ac\u5316\u5242\u2014\u2014Pt@Mo<sub>2<\/sub>C\u3002\u8be5\u5355\u539f\u5b50\u50ac\u5316\u5242\u80fd\u591f\u6700\u5927\u7a0b\u5ea6\u5730\u63d0\u9ad8\u8d35\u91d1\u5c5ePt\u7684\u539f\u5b50\u5229\u7528\u7387\uff0c\u4e3a\u5b9e\u7528\u4ea7\u6c22\u6750\u6599\u7684\u8bbe\u8ba1\u548c\u5e94\u7528\u63d0\u4f9b\u4e86\u91cd\u8981\u7684\u7406\u8bba\u57fa\u7840\u3002\u7814\u7a76\u7ed3\u679c\u663e\u793a\u8fc7\u6e21\u91d1\u5c5ePt\u4e0e\u8f7d\u4f53\u4e0a\u7684Mo\u539f\u5b50\u5177\u6709\u8f83\u5f3a\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u6c34\u7164\u6c14\u53cd\u5e94\u4e2d\u5438\u9644\u7269\u79cd\u6700\u7a33\u5b9a\u7684\u5438\u9644\u4f4d\u70b9\u90fd\u5728Mo\u4f4d\u70b9\u4e0a\uff1b\u4e2d\u95f4\u4f53trans-COOH\u662fPt@Mo<sub>2<\/sub>C\u50ac\u5316\u5242\u8868\u9762\u4e0a\u6700\u4e3b\u8981\u7684\u7269\u79cd\uff0c\u800cHCOO\u4e0d\u662f\u4e00\u4e2a\u6d3b\u8dc3\u7684\u53cd\u5e94\u4e2d\u95f4\u4f53\uff1b\u7814\u7a76\u521b\u65b0\u6027\u5730\u53d1\u73b0Mo\u548cPt-Mo\u4f4d\u70b9\u662f\u6c34\u7164\u6c14\u53cd\u5e94\u7684\u6d3b\u6027\u4f4d\u70b9\uff1aMo\u4f4d\u70b9\u6709\u5229\u4e8e\u6c34\u89e3\u79bb\u7684\u53d1\u751f\u5e76\u91ca\u653e\u51fa\u5927\u91cf\u6c22\uff1b\u540c\u65f6Pt-Mo\u4f4d\u70b9\u6709\u5229\u4e8eH-H\u952e\u7684\u5f62\u6210\uff0c\u901a\u8fc7\u53cc\u91d1\u5c5e\u754c\u9762\u7684\u534f\u540c\u4f5c\u7528\uff0c\u4ece\u800c\u6709\u6548\u63d0\u9ad8\u4e86Pt@Mo<sub>2<\/sub>C\u50ac\u5316\u5242\u4ea7\u6c22\u80fd\u529b\u3002<\/p>\n<p>\u6b64\u524d\u8be5\u7814\u7a76\u7ec4\u8fd8\u5728\u4ee5\u83b7\u5f97\u6e05\u6d01\u80fd\u6e90\u4e3a\u76ee\u6807\u7684\u5149\u50ac\u5316\u5206\u89e3\u6c34\u4ea7\u6c22\u7684\u534a\u5bfc\u4f53\u6750\u6599\u80fd\u5e26\u8c03\u63a7\u7684\u7406\u8bba\u5de5\u4f5c\u4e2d\u53d6\u5f97\u8fdb\u5c55\uff08J. Mater. Chem. A 2015, 3, 8466\uff09\u3002<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1a<a href=\"http:\/\/www.cas.cn\/syky\/201707\/t20170719_4609016.shtml\" target=\"_blank\" rel=\"noopener noreferrer\">http:\/\/www.cas.cn\/syky\/201707\/t20170719_4609016.shtml<\/a>\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/pubs.rsc.org\/en\/content\/articlehtml\/2017\/ta\/c7ta03115g\" target=\"_blank\" rel=\"noopener noreferrer\">Computation-predicted, stable, and inexpensive single-atom nanocatalyst Pt@Mo<sub>2<\/sub>C \u2013 an important advanced material for H<sub>2<\/sub> production<\/a>(J. Mater. Chem. A,2017,DOI\uff1a10.1039\/C7TA03115G)<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8deer\u7f16\u8f91\uff0c<a href=\"http:\/\/www.cailiaoniu.com\/25127.html\" target=\"_blank\" rel=\"noopener noreferrer\">\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener noreferrer\">\u6d4b\u8bd5\u8c37<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u6210\u679c\u7b80\u4ecb\u3011 \u4e2d\u56fd\u79d1\u5b66\u9662\u798f\u5efa\u7269\u8d28\u7ed3\u6784\u7814\u7a76\u6240\u7ed3\u6784\u5316\u5b66\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u5434\u514b\u741b\u7814\u7a76\u7ec4\u5728\u526f\u7814\u7a76\u5458\u674e\u5de7\u7ea2\u4e3b\u6301\u7684\u56fd\u5bb6\u57fa\u91d1\u59d4\u9752\u5e74\u9879\u76ee\u548c\u7f8e\u56fd\u6000\u4fc4\u660e\u5927\u5b66\u5316\u5b66\u7cfb\u6559\u6388\u8303\u8302\u5b8f\u4e3b\u6301\u7684\u7f8e\u56fd\u80fd\u6e90\u90e8&#8230;<\/p>\n","protected":false},"author":3706,"featured_media":92661,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[116],"class_list":["post-92659","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-keji","tag-catalyst"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/92659"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/3706"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=92659"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/92659\/revisions"}],"predecessor-version":[{"id":92828,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/92659\/revisions\/92828"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/92661"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=92659"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=92659"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=92659"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}