{"id":92951,"date":"2017-07-26T06:30:28","date_gmt":"2017-07-25T22:30:28","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=92951"},"modified":"2017-07-25T16:35:28","modified_gmt":"2017-07-25T08:35:28","slug":"%e4%b8%ad%e7%a7%91%e5%a4%a7%e4%bf%9e%e4%b9%a6%e5%ae%8f%e5%9b%a2%e9%98%9fjacs-%e5%a4%a7%e9%9d%a2%e7%a7%af%e5%85%b1%e7%bb%84%e8%a3%85%e7%ba%b3%e7%b1%b3%e7%ba%bf%e7%94%a8%e4%ba%8e%e6%9f%94%e6%80%a7","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=92951","title":{"rendered":"\u4e2d\u79d1\u5927\u4fde\u4e66\u5b8f\u56e2\u961fJACS: \u5927\u9762\u79ef\u5171\u7ec4\u88c5\u7eb3\u7c73\u7ebf\u7528\u4e8e\u67d4\u6027\u900f\u660e\u667a\u80fd\u7a97\u6237"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n

\u7535\u81f4\u53d8\u8272\u5668\u4ef6\u5728\u4e0d\u540c\u504f\u538b\u4e0b\u4f1a\u8868\u73b0\u51fa\u4e0d\u540c\u7684\u5149\u5b66\u6027\u8d28\uff0c\u56e0\u800c\u5728\u667a\u80fd\u7a97\u6237\u3001\u9632\u70ab\u76ee\u540e\u89c6\u955c\u3001\u7535\u5b50\u663e\u793a\u7b49\u9886\u57df\u5177\u6709\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\u3002\u4f20\u7edf\u7684\u67d4\u6027\u7535\u81f4\u53d8\u8272\u5668\u4ef6\u4e3b\u8981\u662f\u5236\u5907\u5728\u6c27\u5316\u94df\u9521(ITO)\u7535\u6781\u4e0a\uff0c\u5b9e\u9645\u4e0a\u8fdc\u672a\u8fbe\u5230\u67d4\u6027\u7684\u6982\u5ff5\u3002\u8fd1\u5e74\u6765\uff0c\u91d1\u5c5e\u7eb3\u7c73\u7ebf(NW)\u3001\u77f3\u58a8\u70ef\u3001\u78b3\u7eb3\u7c73\u7ba1\u7f51\u683c\u6210\u4e3a\u4e86\u5236\u5907\u67d4\u6027\u900f\u660e\u7535\u6781\u7684\u70ed\u70b9\uff0c\u4f46\u78b3\u7eb3\u7c73\u7ba1\u548c\u77f3\u58a8\u70ef\u5236\u5907\u7684\u67d4\u6027\u8584\u819c\u5728\u5149\u5b66\u900f\u8fc7\u7387\u4e3a80%~90%\u65f6\uff0c\u7535\u963b\u4ec5\u4e3a100~1000\u03a9\/sq\uff0c\u5f88\u96be\u6ee1\u8db3\u5927\u591a\u6570\u7684\u5e94\u7528\u3002\u76f8\u6bd4\u800c\u8a00\uff0c\u57fa\u4e8e\u91d1\u5c5eNWs\u7684\u8584\u819c\u5177\u6709\u9ad8\u7684\u5bfc\u7535\u7387\u548c\u5149\u5b66\u900f\u8fc7\u7387\uff0c\u88ab\u5bc4\u4e88\u539a\u671b\u3002\u4e0e\u65e0\u5e8f\u7684NW\u7ed3\u6784\u76f8\u6bd4\uff0c\u901a\u8fc7\u64cd\u63a7NW\u7ec4\u88c5\u5f62\u6210\u5b8f\u89c2\u5c3a\u5ea6\u7684\u7ec4\u88c5\u4f53\u624d\u80fd\u7cbe\u786e\u5730\u8c03\u63a7\u548c\u5e73\u8861\u67d4\u6027\u900f\u660e\u7535\u6781\u7684\u5149\u5b66\u900f\u8fc7\u7387\u548c\u5bfc\u7535\u6027\u3002\u56e0\u6b64\uff0c\u5982\u4f55\u6709\u6548\u5730\u64cd\u63a7NWs\u7684\u7ec4\u88c5\u5236\u5907\u67d4\u6027\u5668\u4ef6\u6210\u4e3a\u4e86\u8be5\u9886\u57df\u7814\u7a76\u7684\u70ed\u70b9\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/span><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u6280\u5927\u5b66\u4fde\u4e66\u5b8f\u6559\u6388<\/strong>\u548c\u5218\u5efa\u4f1f\u526f\u7814\u7a76\u5458<\/strong>(\u5171\u540c\u901a\u8baf\u4f5c\u8005)<\/strong>\u7b49\u4eba\u5728J. Am. Chem. Soc.<\/strong>\u53d1\u8868\u4e86\u9898\u4e3a\u201cLarge Area Co-Assembly of Nanowires for Flexible Transparent Smart Windows<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\uff0c\u62a5\u9053\u4e86\u5927\u9762\u79ef\u5171\u7ec4\u88c5\u7eb3\u7c73\u7ebf\u53ca\u5176\u5728\u67d4\u6027\u7535\u81f4\u53d8\u8272\u5668\u4ef6\u4e2d\u5e94\u7528\u7684\u6700\u65b0\u7814\u7a76\u6210\u679c\u3002\u7814\u7a76\u56e2\u961f\u901a\u8fc7\u6539\u8fdb\u7684Langmuir-Blodgett(LB)\u6280\u672f\u6210\u529f\u5730\u64cd\u7eb5\u4e86Ag\u548cW18<\/sub>O49<\/sub> NWs\u7684\u5927\u9762\u79ef\u7ec4\u88c5\uff0c\u5236\u5907\u4e86\u53cc\u5c42Ag\/W18<\/sub>O49<\/sub>\u7f51\u683c\u7ed3\u6784\u7684\u67d4\u6027\u900f\u660e\u5bfc\u7535\u8584\u819c\uff0c\u5177\u6709\u53ef\u8c03\u63a7\u7684\u7535\u963b(7~40\u03a9\/sq)\u548c\u5149\u5b66\u900f\u8fc7\u7387(550nm\u6ce2\u957f\u4e0b\u900f\u8fc7\u7387\u4e3a58~86%)\u3002\u5229\u7528\u8be5\u819c\u5236\u5907\u7684\u7535\u81f4\u53d8\u8272\u5668\u4ef6\u8868\u73b0\u51fa\u4e86\u975e\u5e38\u7a33\u5b9a\u7684\u7535\u81f4\u53d8\u8272\u884c\u4e3a\uff0c\u800c\u4e14\u53ef\u4ee5\u901a\u8fc7Ag\u548cW18<\/sub>O49 <\/sub>NW\u7ec4\u88c5\u7ed3\u6784\u7684\u6539\u53d8\u6765\u8c03\u63a7\u5176\u7535\u81f4\u53d8\u8272\u6027\u80fd\u3002\u4e0e\u57fa\u4e8eITO\u7684\u5668\u4ef6\u76f8\u6bd4\uff0c\u8be5\u7535\u81f4\u53d8\u8272\u819c\u5177\u6709\u975e\u5e38\u4f18\u5f02\u7684\u673a\u68b0\u7a33\u5b9a\u6027\uff0c\u5373\u4f7f\u7ecf\u8fc71000\u6b21\u4ee5\u4e0a\u5f2f\u66f2\u75b2\u52b3\u6d4b\u8bd5(r<\/em>=1.2cm)\u4ecd\u4fdd\u6301\u5f88\u9ad8\u7684\u5bfc\u7535\u7387(\u0394R\/R\u22488.3%)\u548c\u7535\u81f4\u53d8\u8272\u6027\u80fd(90%\u7684\u4fdd\u6301\u7387)\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n

\u56fe<\/strong>1 \u7ec4\u88c5Ag\u548cW18<\/sub>O49<\/sub> NWs\u5236\u5907\u67d4\u6027\u900f\u660e\u7535\u81f4\u53d8\u8272\u819c<\/strong><\/p>\n

\"\"<\/p>\n

(a)\u67d4\u6027\u900f\u660e\u667a\u80fd\u7a97\u6237\u7684\u5236\u5907\u793a\u610f\u56fe\uff1b<\/p>\n

(b)\u5728\u805a\u5bf9\u82ef\u4e8c\u7532\u9178\u4e59\u4e8c\u9187\u916f(PET)\u57fa\u4f53\u4e0a\u5171\u7ec4\u88c5\u7684Ag\/W18<\/sub>O49<\/sub> NWs\u7f51\u683c\u7ed3\u6784\u7684SEM\u56fe\u3002\u8d28\u91cf\u6bd4(m<\/span>Ag<\/sub>:m<\/span>W18O49<\/sub>)\u4e3a14:4\uff1b<\/p>\n

(c)\u5728Ag\/W18<\/sub>O49<\/sub> NW\u819c\u4e0a\u7ec4\u88c58\u5c42W18<\/sub>O49<\/sub> NWs\u7684SEM\u56fe\uff1b<\/p>\n

(d)\u5728\u5927\u578bLB\u6c34\u69fd\u7684\u6c34-\u7a7a\u6c14\u754c\u9762\u4e0a\u7ec4\u88c5\u7684\u5355\u5c42W18<\/sub>O49 <\/sub>NW\u8584\u819c\u7684\u7167\u7247\uff1b<\/p>\n

(e)\u7531\u4e24\u5c42Ag\/W18<\/sub>O49<\/sub> NW\u7f51\u683c\u7ed3\u6784\u548c8\u5c42W18<\/sub>O49<\/sub> NWs\u7ec4\u6210\u7684\u8584\u819c\u7684\u5b9e\u7269\u7167\u7247\uff1b<\/p>\n

(f)\u56fe(e)\u4e2d\u6240\u793a\u7684\u7535\u81f4\u53d8\u8272\u819c\u4e0a6\u4e2a\u4e0d\u540c\u4f4d\u7f6e\u5904\u8584\u819c\u7684\u7535\u81f4\u53d8\u8272\u6027\u80fd\u8868\u5f81\u3002\u63d2\u56fe\u4e3a\u819c\u5728\u900f\u660e(0 V)\u548c\u7740\u8272(-1 V)\u4e24\u4e2a\u72b6\u6001\u65f6\u7684\u5178\u578b\u7167\u7247\u3002<\/p>\n

\u56fe<\/strong>2 <\/strong>\u7535\u81f4\u53d8\u8272\u819c\u7684\u673a\u68b0\u7a33\u5b9a\u6027<\/strong><\/p>\n

\"\"<\/p>\n

(a)\u67d4\u6027Ag\/W18<\/sub>O49<\/sub>\u7eb3\u7c73\u7ebf\u8584\u819c\u7684\u7535\u81f4\u53d8\u8272\u793a\u610f\u56fe\uff1b<\/p>\n

(b-c)\u9644\u7740\u5728\u70e7\u676f\u5f2f\u66f2\u5185\u8868\u9762\u7684\u7eb3\u7c73\u7ebf\u8584\u819c\u5728\u65bd\u52a0\u7535\u538b\u524d(b)\u548c\u540e(c)\u7684\u5b9e\u7269\u7167\u7247\u56fe\uff1b<\/p>\n

(d)\u7ecf\u8fc70\u3001100\u3001200\u3001300\u3001500\u548c1000\u6b21\u5f2f\u66f2\u5faa\u73af\u540e\uff0c\u67d4\u6027\u7535\u81f4\u53d8\u8272\u819c\u7684\u7535\u963b\u5728\u5f2f\u66f2\u6d4b\u8bd5\u4e2d\u539f\u4f4d\u53d8\u5316\uff1b<\/p>\n

(e)\u7ecf\u8fc70\u3001100\u3001200\u3001300\u3001400\u3001500\u548c1000\u6b21\u5f2f\u66f2\u5faa\u73af\u540e\uff0c\u67d4\u6027\u7535\u81f4\u53d8\u8272\u819c\u7684\u7535\u81f4\u53d8\u8272\u6027\u80fd\u3002<\/p>\n

\u8be5\u8584\u819c\u662f\u5728\u4e24\u5c42Ag\/W18<\/sub>O49<\/sub> NW \u7f51\u683c\u4e0a\u590d\u54088\u5c42W18<\/sub>O49<\/sub> NW\u83b7\u5f97\u7684\uff0cm<\/span>Ag<\/sub>:m<\/span>W18O49<\/sub> \u4e3a14:4\u3002<\/span><\/p>\n

\u56fe<\/strong>3 <\/strong>\u7535\u81f4\u53d8\u8272\u6027\u80fd\u7684\u8c03\u63a7<\/strong><\/p>\n

\"\"<\/p>\n

(a)\u5177\u6709\u53ef\u63a7\u5c42\u6570\u7684W18<\/sub>O49<\/sub> NWs\u7684\u67d4\u6027\u819c\u5668\u4ef6\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

(b-c)\u5236\u5907\u7684\u819c\u5668\u4ef6\u5728\u65bd\u52a0\u5916\u7535\u538b\u524d(b)\u3001\u540e(c)\u7684\u7167\u7247\uff1b<\/p>\n

(d-e)\u5728632.5nm\u4e0b\u76d1\u6d4b\u5230\u7684\u5177\u6709\u4e0d\u540cW18<\/sub>O49<\/sub> NWs\u5c42\u6570\u7684\u819c\u7684\u7535\u81f4\u53d8\u8272\u6027\u80fd\u3002\u5916\u52a0\u7535\u538b\u4e3a0V\u4fdd\u630120s\u540e\u5728-1V\u4fdd\u630120s\u4e3a\u4e00\u4e2a\u5faa\u73af\uff1b<\/p>\n

(f-g)\u5177\u670915\u5c42W18<\/sub>O49<\/sub> NWs\u7684NW\u819c\u5668\u4ef6\u57284000s\u5185\u7684\u7535\u81f4\u53d8\u8272\u6027\u80fd(f)\u53ca\u5176\u524d6\u4e2a\u5faa\u73af\u548c\u540e6\u4e2a\u5faa\u73af\u7684\u653e\u5927\u56fe(g)\uff1bm<\/span>Ag<\/sub>:m<\/span>W18O49<\/sub>\u4e3a14:4\u3002<\/span><\/p>\n

\u56fe<\/strong>4 <\/strong>\u7535\u81f4\u53d8\u8272\u50cf\u7d20\u70b9\u7684\u5236\u5907<\/strong><\/p>\n

\"\"<\/p>\n

(a)\u5236\u5907\u5177\u6709\u50cf\u7d20\u70b9\u548c\u201cNANO WIRE\u201d\u5b57\u6837\u7684\u7535\u81f4\u53d8\u8272\u819c\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

(b-d)\u5177\u6709\u50cf\u7d20\u70b9\u7684\u819c\u5728\u900f\u660e\u72b6\u6001(b)\u3001\u7740\u8272\u72b6\u6001(c)\u548c\u5f2f\u66f2\u72b6\u6001(d)\u65f6\u7684\u7167\u7247\uff1b<\/p>\n

(e-g)\u5177\u6709\u201cNANO WIRE\u201d\u5b57\u6837\u7684\u819c\u5728\u900f\u660e\u72b6\u6001(e)\u3001\u7740\u8272\u72b6\u6001(f)\u548c\u5f2f\u66f2\u65f6(g)\u7684\u7167\u7247\u3002<\/p>\n

\u8be5\u8584\u819c\u662f\u5728\u4e24\u5c42Ag\/W18<\/sub>O49<\/sub> NW\u7f51\u683c\u4e0a\u590d\u54088\u5c42W18<\/sub>O49<\/sub> NW\u83b7\u5f97\u7684\uff0cm<\/span>Ag<\/sub>:m<\/span>W18O49<\/sub>\u4e3a14:4\u3002<\/span><\/p>\n

\u56fe<\/strong>5 <\/strong>\u56fa\u6001\u7535\u81f4\u53d8\u8272\u5668\u4ef6\u7684\u5236\u5907<\/strong><\/p>\n

\"\"<\/p>\n

(a)\u56fa\u6001\u7535\u81f4\u53d8\u8272\u5668\u4ef6\u7684\u7ed3\u6784\u793a\u610f\u56fe\uff1b<\/p>\n

(b-c)\u5f2f\u66f2\u65f6\uff0c\u56fa\u6001\u7535\u81f4\u53d8\u8272\u5668\u4ef6\u7684\u900f\u660e\u72b6\u6001(b)\u548c\u7740\u8272\u72b6\u6001(c)\u7684\u7167\u7247\u3002\u63d2\u56fe\u4e3a\u5668\u4ef6\u672a\u5f2f\u66f2\u65f6\u7684\u7167\u7247\uff1b<\/p>\n

(d)\u7535\u81f4\u53d8\u8272\u773c\u955c\u6a21\u578b\u7167\u7247\uff1b<\/p>\n

(e)\u7535\u81f4\u53d8\u8272\u7a97\u6237\u6a21\u578b\u7167\u7247\u3002<\/span><\/p>\n

\u56fe<\/strong>6 <\/strong>\u56fa\u6001\u7535\u81f4\u53d8\u8272\u5668\u4ef6\u7684\u7167\u7247<\/strong><\/p>\n

\"\"<\/p>\n

\u5c3a\u5bf8\u4e3a18cm\u00d715cm\u7684\u56fa\u6001\u67d4\u6027\u7535\u81f4\u53d8\u8272\u5668\u4ef6\u5b9e\u7269\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/span><\/p>\n

\u672c\u6587\u901a\u8fc7\u6539\u8fdb\u7684LB\u6280\u672f\u6210\u529f\u7ec4\u88c5\u4e86\u67d4\u6027\u7684Ag\/W18<\/sub>O49<\/sub> NW\u819c\uff0c\u5e76\u5229\u7528\u8be5\u819c\u5236\u5907\u4e86\u7535\u963b\u7387\u548c\u900f\u8fc7\u7387\u5747\u53ef\u8c03\u63a7\u7684\u7535\u81f4\u53d8\u8272\u5668\u4ef6\uff0c\u8868\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u7535\u81f4\u53d8\u8272\u6027\u80fd\u548c\u673a\u68b0\u7a33\u5b9a\u6027\uff0c\u5728\u667a\u80fd\u7a97\u6237\u3001\u592a\u9633\u80fd\u7535\u6c60\u3001\u663e\u793a\u5668\u4ef6\u548c\u5176\u4ed6\u7684\u4e0b\u4e00\u4ee3\u67d4\u6027\u5668\u4ef6\u9886\u57df\u5177\u6709\u5e7f\u9614\u7684\u5e94\u7528\u6f5c\u529b\u3002\u8be5\u7814\u7a76\u63d0\u51fa\u7684\u5927\u9762\u79ef\u5171\u7ec4\u88c5\u7eb3\u7c73\u7ebf\u7684\u65b9\u6cd5\u4e5f\u4e3a\u5176\u4ed6\u57fa\u4e8e\u7eb3\u7c73\u7ebf\u7684\u67d4\u6027\u5668\u4ef6\u7684\u8bbe\u8ba1\u548c\u5236\u5907\u63d0\u4f9b\u4e86\u5168\u65b0\u7684\u601d\u8def\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Large Area Co-Assembly of Nanowires for Flexible Transparent Smart Windows <\/a>(JACS, 2017, DOI: 10.1021\/jacs.7b03227))<\/p>\n

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\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u7eb3\u7c73\u5b66\u672f\u7ec4Roay\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

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