{"id":94045,"date":"2017-08-03T06:30:58","date_gmt":"2017-08-02T22:30:58","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=94045"},"modified":"2017-08-01T21:53:29","modified_gmt":"2017-08-01T13:53:29","slug":"%ef%bc%88%e5%b7%b2%e6%a0%a1%ef%bc%89macromolecules%ef%bc%9a-%e5%9f%ba%e4%ba%8e%e7%a1%92%e6%a1%a5%e7%9a%84%e6%9f%b1-5%e8%8a%b3%e7%83%83%e4%ba%8c%e8%81%9a%e4%bd%93%e5%92%8caie%e6%b4%bb%e6%80%a7","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=94045","title":{"rendered":"Macromolecules\uff1a \u57fa\u4e8e\u7852\u6865\u7684\u67f1-[5]\u82b3\u70c3\u4e8c\u805a\u4f53\u548cAIE\u6d3b\u6027\u56db\u82ef\u4e59\u70ef\u6784\u5efa\u7684\u5177\u6709\u53cc\u91cd\u523a\u6fc0\u54cd\u5e94\u6027\u80fd\u7684\u8367\u5149\u8d85\u5206\u5b50\u805a\u5408\u7269"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u8be5\u6587\u7ae0\u62a5\u9053\u4e86\u4e00\u79cd\u5408\u6210\u8367\u5149\u8d85\u5206\u5b50\u805a\u5408\u7269\u7684\u65b0\u65b9\u6cd5\uff0c\u901a\u8fc7\u53cc\u7852\u952e\u6865\u8054\u67f1\u4e8c\u805a\u4f53[5]\u82b3\u70c3\u548c\u542b\u6709\u4e24\u4e2a\u54aa\u5511\u672b\u7aef\u7ed3\u5408\u4f4d\u70b9\u7684AIE\u6d3b\u6027\u56db\u82ef\u57fa\u4e59\u70ef\uff08TPE\uff09\u7684\u4e3b-\u5ba2\u4f53\u76f8\u4e92\u4f5c\u7528\uff0c\u6784\u5efa\u4e86\u591a\u523a\u6fc0\u6027\u54cd\u5e94\u6027\u8367\u5149\u8d85\u5206\u5b50\u805a\u5408\u7269\u3002\u6240\u5f97\u8d85\u5206\u5b50\u805a\u5408\u7269\u5728\u4f4e\u6d53\u5ea6\u4e0b\u7684\u8367\u5149\u53d1\u5c04\u660e\u663e\u964d\u4f4e\u3002\u663e\u7136\uff0c\u5728\u8d85\u5206\u5b50\u805a\u5408\u7269\u4e2d\u5f15\u5165\u53cc\u7852\u52a8\u6001\u952e\u53ef\u5b9e\u73b0\u4f53\u7cfb\u5bf9\u6c27\u5316\u8fd8\u539f\u523a\u6fc0\u7684\u826f\u597d\u54cd\u5e94\u3002\u52a0\u5165\u8fd8\u539f\u5242\u540e\uff0c\u8d85\u5206\u5b50\u805a\u5408\u7269\u7531\u4e8e\u7cfb\u7edf\u4e2d\u5171\u4ef7\u952e\u7684\u952e\u65ad\u88c2\u800c\u89e3\u805a\uff1b\u540c\u65f6\uff0c\u4e0e\u67f1[5]\u82b3\u70c3\u5f3a\u70c8\u7ed3\u5408\u7684\u7ade\u4e89\u5ba2\u4f53\uff0c\u5982\u5df1\u4e8c\u8148\uff0c\u53ef\u4ee5\u5c06\u805a\u5408\u7269\u89e3\u805a\u6210\u4f4e\u805a\u7269\uff0c\u800c\u4e0d\u7834\u574f\u4f53\u7cfb\u4e2d\u7684\u4efb\u4f55\u5171\u4ef7\u952e\u3002\u8fd9\u4e24\u79cd\u89e3\u805a\u65b9\u6cd5\u90fd\u53ef\u4ee5\u5728\u4e00\u5b9a\u7a0b\u5ea6\u4e0a\u4f7f\u5f97\u7cfb\u7edf\u7684\u8367\u5149\u5f3a\u5ea6\u6062\u590d\uff0c\u8fd9\u5c06\u6709\u671b\u7528\u4e8e\u6784\u5efa\u5177\u6709\u4e0d\u540c\u6027\u8d28\u7684\u667a\u80fd\u8d85\u5206\u5b50\u805a\u5408\u6750\u6599\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u4e0e\u5728\u5355\u4f53\u95f4\u5f62\u6210\u5171\u4ef7\u952e\u805a\u5408\u7684\u4f20\u7edf\u805a\u5408\u65b9\u6cd5\u4e0d\u540c\uff0c\u8d85\u5206\u5b50\u805a\u5408\u7269\u662f\u5728\u805a\u5408\u4e4b\u524d\u6216\u4e4b\u540e\u901a\u8fc7\u8d85\u5206\u5b50\u4e3b-\u5ba2\u4f53\u975e\u5171\u4ef7\u76f8\u4e92\u4f5c\u7528\u5f62\u6210\u7684\u3002\u8d85\u5206\u5b50\u805a\u5408\u7269\u6750\u6599\u901a\u5e38\u8868\u73b0\u51fa\u975e\u540c\u5bfb\u5e38\u7684\u6027\u8d28\uff0c\u5982\u7279\u5f02\u6027\u8bc6\u522b\u81ea\u6108\u548c\u523a\u6fc0\u54cd\u5e94\u6027\u3002\u5c3d\u7ba1\u8fd1\u5e74\u6765\u8d8a\u6765\u8d8a\u591a\u7684\u8d85\u5206\u5b50\u805a\u5408\u7269\u5df2\u88ab\u8bbe\u8ba1\u3001\u6784\u5efa\u51fa\u6765\uff0c\u4f46\u662f\u5236\u5907\u591a\u529f\u80fd\u65b0\u578b\u8d85\u5206\u5b50\u805a\u5408\u7269\u8fdb\u800c\u5e94\u7528\u4e8e\u5404\u4e2a\u9886\u57df\u4e2d\uff0c\u4f9d\u7136\u975e\u5e38\u9700\u8981\u3002\u5728\u52a8\u6001\u7ec4\u5408\u5316\u5b66\uff08DCC\uff09\u548c\u523a\u6fc0\u54cd\u5e94\u8d85\u5206\u5b50\u7cfb\u7edf\u9886\u57df\uff0c\u52a8\u6001\u952e\u4e0e\u5176\u5728\u7279\u5b9a\u6761\u4ef6\u4e0b\u7684\u53ef\u9006\u5207\u5272\u548c\u5f62\u6210\u5df2\u7ecf\u5f15\u8d77\u4e86\u5e7f\u6cdb\u5173\u6ce8\u3002\u4e0e\u5df2\u5e7f\u6cdb\u7814\u7a76\u548c\u5e94\u7528\u7684\u542b\u786b\u5206\u5b50\u76f8\u6bd4\uff0c\u542b\u7852\u952e\u7684\u5206\u5b50\u5177\u6709\u66f4\u5feb\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u6027\u3002\u56e0\u6b64\uff0c\u5728\u8d85\u667a\u80fd\u529f\u80fd\u6750\u6599\u7684\u5236\u9020\u65b9\u9762\uff0c\u5f15\u5165\u7852\u952e\u5df2\u6210\u4e3a\u8d85\u5206\u5b50\u529f\u80fd\u4f53\u7cfb\u7684\u7814\u7a76\u70ed\u70b9\u3002<\/p>\n

Ogoshi\u7b49\u4eba\u7387\u5148\u4e8e2008\u5e74\u62a5\u9053\u4e86\u67f1\u82b3\u70c3\uff08pillar[n]arenes\uff08n = 5-15\uff09\uff09\uff0c\u8d85\u5206\u5b50\u5316\u5b66\u4e2d\u7684\u4e00\u7c7b\u65b0\u4e00\u4ee3\u7684\u5927\u73af\u5316\u5408\u7269\u3002\u5176\u4e2d\uff0c\u6700\u53d7\u6b22\u8fce\u7684\u4e00\u79cd\u662f\u542b\u6709\u4e94\u4e2a\u5bf9\u82ef\u4e8c\u915a\u6216\u5bf9\u82ef\u4e8c\u915a\u919a\u5355\u5143\u7684\u67f1[5]\u82b3\u70c3\uff0c\u5b83\u4eec\u57282-\u548c5-\u4f4d\u901a\u8fc7\u4e9a\u7532\u57fa\u6865\u8fde\u63a5\uff0c\u5f62\u6210\u67f1\u72b6\u201c\u4e2d\u7a7a\u201d\u7ed3\u6784\u3002\u7531\u4e8e\u67f1\u72b6\u7684\u72ec\u7279\u7279\u5f81\uff0c\u8bf8\u5982\u521a\u6027\u7ed3\u6784\uff0c\u4e0d\u540c\u5c3a\u5bf8\u7684\u7a7a\u8154\u548c\u6613\u529f\u80fd\u5316\uff0c\u8be5\u7c7b\u65b0\u578b\u5927\u73af\u5206\u5b50\u5df2\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5305\u62ec\u7eb3\u7c73\u9600\u95e8\u3001\u6709\u673a\u591a\u5b54\u6750\u6599\u5236\u5907\u3001\u6c14\u4f53\u9009\u62e9\u6027\u5438\u9644\u3001\u836f\u7269\u63a7\u5236\u91ca\u653e\u3001\u4eba\u5de5\u8de8\u819c\u901a\u9053\u3001\u8d85\u5206\u5b50\u7ec4\u88c5\u3001\u4f20\u611f\u4e0e\u68c0\u6d4b\u4ee5\u53ca\u751f\u7269\u529f\u80fd\u6750\u6599\u5728\u5185\u7684\u8bf8\u591a\u7814\u7a76\u9886\u57df\u3002\u6211\u56fd\u79d1\u5b66\u5bb6\u5728\u67f1\u72b6\u82b3\u70c3\u8d85\u5206\u5b50\u5316\u5b66\u4e0e\u6750\u6599\u9886\u57df\u505a\u51fa\u4e86\u5927\u91cf\u7a81\u51fa\u7684\u539f\u521b\u6027\u8d21\u732e\u3002<\/p>\n

\u8fd1\u671f\uff0c\u6765\u81ea\u5409\u6797\u5927\u5b66\u7eb3\u5fae\u6784\u7b51\u5316\u5b66\u56fd\u9645\u5408\u4f5c\u8054\u5408\u5b9e\u9a8c\u5ba4<\/strong>\u7684\u6768\u82f1\u5a01\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u56e2\u961f\u5728Macromolecules<\/strong>\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u5173\u4e8e\u6784\u5efa\u8367\u5149\u548c\u53cc\u91cd\u523a\u6fc0\u54cd\u5e94\u7684\u8d85\u5206\u5b50\u805a\u5408\u7269\u4f53\u7cfb\u5408\u6210\u65b9\u6cd5\u7684\u6587\u7ae0\uff0c\u9898\u4e3a\u201cDual-Stimuli-Responsive Fluorescent Supramolecular Polymer Based on a Diselenium-Bridged Pillar[5]arene Dimer and an AIE-Active Tetraphenylethylene Guest<\/strong>\u201d\u3002\u6587\u4e2d\u4ecb\u7ecd\u4e86\u4e00\u79cd\u5408\u6210\u8d85\u5206\u5b50\u8367\u5149\u805a\u5408\u7269\u7684\u65b9\u6cd5\u53ca\u5176\u523a\u6fc0\u54cd\u5e94\u8c03\u63a7\u673a\u5236\u3002\u5728\u7ebf\u6027\u8d85\u5206\u5b50\u529f\u80fd\u6027\u805a\u5408\u7269\u7684\u5236\u9020\u4e2d\uff0c\u5408\u6210\u4e86\u7852\u952e-\u6865\u8fde\u67f1[5]\u82b3\u70c3\u4e8c\u805a\u4f53\uff0c\u5373SeSe\u2014\uff08 P5\uff09\u2014 2<\/sub>\u7528\u4f5c\u5927\u73af\u4e3b\u4f53\u5316\u5408\u7269\u3002\u7852\u7852\u53cc\u952e\u53ef\u4ee5\u4f5c\u4e3a\u8d85\u5206\u5b50\u805a\u5408\u7269\u9aa8\u67b6\u4e0a\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u6027\u7ed3\u6784\u5355\u5143\u3002\u7814\u7a76\u4eba\u5458\u8bbe\u8ba1\u5e76\u5408\u6210\u4e86\u542b\u6709\u4e2d\u6027\u5ba2\u4f53\u7684\u56db\u82ef\u57fa\u4e59\u70ef\uff08TPE\uff09\uff0c\u5176\u672b\u7aef\u4e3a\u54aa\u5511\u4f4d\u70b9\uff0c\u5373TPE\u2014\uff08 Im\uff09\u2014 2<\/sub>\u4f5c\u4e3a\u6f5c\u5728\u7684\u5ba2\u4f53\u63a5\u5934\u3002\u4f9d\u6258\u67f1[5]\u82b3\u70c3\u8154\u548c\u54aa\u5511\u90e8\u5206\u7684\u4e3b\u5ba2\u4f53\u76f8\u4e92\u4f5c\u7528\uff0cTPE\u2014\uff08 Im\uff09\u2014 2<\/sub>\u53c2\u4e0e\u5171\u805a\u8fc7\u7a0b\uff0c\u4f7f\u5f97\u6240\u5f97\u5230\u7684\u7ebf\u6027\u8d85\u5206\u5b50\u805a\u5408\u7269\u5177\u6709\u53d1\u5149\u6027\u8d28\u3002\u8fd9\u79cd\u8367\u5149\u8d85\u5206\u5b50\u805a\u5408\u7269\u7cfb\u7edf\u5728\u4e24\u79cd\u5b8c\u5168\u4e0d\u540c\u7684\u89e3\u805a\u4f5c\u7528\u4e0b\uff0c\u54cd\u5e94\u4e8e\u4e24\u79cd\u4e0d\u540c\u7684\u5916\u90e8\u89e6\u53d1\u5242\uff0c\u5373\u6c27\u5316\u8fd8\u539f\u548c\u7ade\u4e89\u6027\u7ed3\u5408\u5242\uff0c\u663e\u793a\u51fa\u8367\u5149\u589e\u5f3a\u4f5c\u7528\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1 \u57fa\u4e8e\u67f1[5]\u82b3\u70c3\u5408\u6210\u8367\u5149\u3001\u53cc\u523a\u6fc0\u54cd\u5e94\u8d85\u5206\u5b50\u805a\u5408\u4f53\u7cfb\u7684\u8bbe\u8ba1\u601d\u60f3<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe2 \u5408\u6210SeSe\u2014\uff08 P5\uff09\u2014 2<\/sub> \u3001DMP [5]\u3001\u2014\uff08 mSe\uff09\u2014 2<\/sub>\u3001TPE-Im\u548cTPE\u2014\uff08 Im\uff09\u2014 2<\/sub>\u7684\u8def\u7ebf\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe3 \u6838\u78c1\u5171\u632fH\u8c31\u56fe\uff08300 MHz\uff0cCDCl 3<\/sub>\uff0c298K\uff09<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09DMP [5]\uff082mM\uff09\uff1b<\/p>\n

\uff08b\uff09TPE-Im\uff082mM\uff09\uff1b<\/p>\n

\uff08c\uff09\u5b83\u4eec\u7684\u7b49\u6469\u5c14\u6df7\u5408\u7269\uff082mM\uff09\u3002<\/p>\n

\u56fe4 TPE\u2014\uff08 Im\uff09\u2014 2<\/sub>\u548cSeSe\u2014\uff08 P5\uff09\u2014 2<\/sub>\u76841\uff1a1\u6df7\u5408\u7269\u5728CHCl 3<\/sub>\u4e2d\u7684\u76f8\u5bf9\u4e8e\u5355\u4f53\u6d53\u5ea6\u6bd4\u7c98\u5ea6\uff08298K\uff09<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe5 \u4e0d\u540c\u6d53\u5ea6\u7684TPE\u2014\uff08 Im\uff09\u2014 2<\/sub>\u548cSeSe\u2014\uff08 P5\uff09\u2014 2<\/sub>\u7684\u4e3b-\u5ba2\u4f53\u8d85\u5206\u5b50\u805a\u5408\u7269\u8367\u5149\u53d1\u5c04\u5149\u8c31<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u4e0d\u540c\u6d53\u5ea6\u7684TPE\u2014\uff08 Im\uff09\u2014 2<\/sub>\u548cSeSe\u2014\uff08 P5\uff09\u2014 2<\/sub>\u7684\u4e3b-\u5ba2\u4f53\u8d85\u5206\u5b50\u805a\u5408\u7269\u4f53\u7cfb\u5728\u7684CHCl3<\/sub>\u4e2d\u7684\u8367\u5149\u53d1\u5c04\u5149\u8c31\u3002
\n \uff08\u03bbex= 265nm; \u03bbem= 372nm;\u72ed\u7f1d\u5bbd\u5ea6\uff1aex 5 nm; 25\u2103\uff0c[TPE-\uff08Im\uff09-2<\/sub>] =10\u03bcM\uff0c\u6240\u6709\u8ff9\u7ebf\u56fa\u5b9a; \u4ece\u4e0a\u5230\u4e0b[SeSe\u2014\uff08 P5\uff09\u2014 2<\/sub> ] = 0,2,4,6,8,10,20\uff0c40\u03bcM\uff09\uff1b<\/p>\n

\uff08b\uff09 372nm\u5904\u7684\u8367\u5149\u5f3a\u5ea6\u4e0eTPE\u2014\uff08 Im\uff09\u2014 2<\/sub>\u548cSeSe\u2014\uff08 P5\uff09\u2014 2<\/sub>\u7684\u6469\u5c14\u6bd4\u7684\u66f2\u7ebf\u56fe\u3002<\/p>\n

\u56fe6 \u4e0d\u540c\u8d85\u5206\u5b50\u805a\u5408\u7269\u7684\u8367\u5149\u53d1\u5c04\u5149\u8c31\u53ca\u8367\u5149\u663e\u5fae\u955c\u56fe\u7247<\/strong><\/p>\n

\"\"<\/p>\n

\u03bbex= 265 nm;\u03bbem= 372 nm;\u72ed\u7f1d\u5bbd\u5ea6\uff1a5nm; em 5nm;\u6eb6\u5242\uff1aCHCl3<\/sub>; 25\u2103;<\/p>\n

\u9ed1\u8272\u66f2\u7ebf\uff1a10\u03bcM\u7684TPE\u2014\uff08 Im\uff09\u2014 2<\/sub>\u6eb6\u6db2\uff1b
\n \u7d2b\u8272\u66f2\u7ebf\uff1a\u7531SeSe\u2014\uff08 P5\uff09\u2014 2<\/sub>\u548cTPE\u2014\uff08 Im\uff09\u2014 2<\/sub>\u5f62\u6210\u7684\u8d85\u5206\u5b50\u805a\u5408\u7269\u6eb6\u6db2\uff0c[TPE-(Im)2<\/sub>] = [SeSe-(P5)] =10 \u03bcM\uff1b
\n \u84dd\u8272\u66f2\u7ebf\uff1a\u52a0\u51651\u5f53\u91cfDTT\u7684\u8d85\u5206\u5b50\u805a\u5408\u7269\uff1b
\n \u7ea2\u8272\u66f2\u7ebf\uff1a\u52a0\u516550\u5f53\u91cf\u5df1\u4e8c\u8148\u7684\u8d85\u5206\u5b50\u805a\u5408\u7269\u3002<\/p>\n

\u8367\u5149\u663e\u5fae\u955c\u7167\u7247\uff1a
\n \uff08a\uff09\u8d85\u5206\u5b50\u805a\u5408\u7269\u7684\u8367\u5149\u5f3a\u5ea6\uff1b<\/p>\n

\uff08b\uff09\u5728DTT\u5b58\u5728\u4e0b\u7684\u8d85\u5206\u5b50\u805a\u5408\u7269\uff1b<\/p>\n

\uff08c\uff09\u6ca1\u6709\u4efb\u4f55\u523a\u6fc0\u4e0b\u8d85\u5206\u5b50\u805a\u5408\u7269\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1a Dual-Stimuli-Responsive Fluorescent Supramolecular Polymer Based\u00a0on a Diselenium-Bridged Pillar[5]arene Dimer and an AIE-Active Tetraphenylethylene Guest<\/a><\/strong>\uff08Macromolecules \uff0c2017\uff0cDOI: 10.1021\/acs.macromol.7b01010\uff09<\/p>\n

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