{"id":94701,"date":"2017-08-07T06:30:03","date_gmt":"2017-08-06T22:30:03","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=94701"},"modified":"2017-08-07T09:00:32","modified_gmt":"2017-08-07T01:00:32","slug":"macromolecules%e9%93%9c%e5%82%ac%e5%8c%96%e5%86%85%e7%82%94%e5%8d%95%e4%bd%93%e7%9a%84%e4%ba%b2%e7%94%b5%e6%b0%a2%e8%83%ba%e5%8c%96%e8%81%9a%e5%90%88%e5%8f%8d%e5%ba%94","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=94701","title":{"rendered":"Macromolecules\uff1a\u94dc\u50ac\u5316\u5185\u7094\u5355\u4f53\u7684\u4eb2\u7535\u6c22\u80fa\u5316\u805a\u5408\u53cd\u5e94"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u7094\u7c7b\u5355\u4f53\u7684\u6c22\u80fa\u5316\u805a\u5408\u53cd\u5e94\u662f\u5236\u5907\u542b\u6c2e\u805a\u5408\u7269\u7684\u91cd\u8981\u65b9\u6cd5\u4e4b\u4e00\u3002\u800c\u5728\u76ee\u524d\uff0c\u6240\u6709\u5df2\u7ecf\u62a5\u9053\u8fc7\u7684\u5173\u4e8e\u7094\u7c7b\u5355\u4f53\u6c22\u80fa\u5316\u805a\u5408\u7684\u53cd\u5e94\u90fd\u662f\u901a\u8fc7\u4eb2\u6838\u52a0\u6210\u6765\u5b9e\u73b0\u7684\uff1b\u6587\u732e\u4e2d\u5374\u6ca1\u6709\u62a5\u9053\u8fc7\u76f4\u63a5\u901a\u8fc7\u4eb2\u7535\u52a0\u6210\u6765\u5b9e\u73b0\u6c22\u80fa\u5316\u805a\u5408\u53cd\u5e94\u7684\u7b56\u7565\u3002\u5728\u6b64\uff0c\u7814\u7a76\u4eba\u5458\u63d0\u51fa\u4e86\u4e00\u79cd\u901a\u8fc7\u94dc\u50ac\u5316\u6765\u5b9e\u73b0\u7094\u7c7b\u5355\u4f53\u7684\u4eb2\u7535\u6c22\u80fa\u5316\u805a\u5408\u7684\u65b9\u6cd5\uff0c\u8fd9\u79cd\u65b9\u6cd5\u80fd\u591f\u5728\u6e29\u548c\u7684\u53cd\u5e94\u6761\u4ef6\u4e0b\u53ef\u9ad8\u4ea7\u7387\uff08\u9ad8\u8fbe95\uff05\uff09\u5f97\u5230\u5177\u6709\u9ad8\u91cd\u5747\u5206\u5b50\u8d28\u91cf\u7684\u53ef\u6eb6\u548c\u70ed\u7a33\u5b9a\u7684\u805a\u70ef\u80fa\u3002\u800c\u8be5\u4eb2\u7535\u6c22\u80fa\u5316\u805a\u5408\u53cd\u5e94\u7684\u533a\u57df\u9009\u62e9\u6027\u5219\u53ef\u4ee5\u901a\u8fc7\u8c03\u6574\u7094\u57fa\u76f8\u8fde\u7684\u82ef\u57fa\u4e3a\u70f7\u57fa\u6765\u5b9e\u73b0\u3002\u901a\u8fc7\u5c06\u56db\u82ef\u57fa\u4e59\u70ef\u5f15\u5165\u805a\u5408\u7269\u4e3b\u94fe\uff0c\u6240\u5f97\u805a\u5408\u7269\u8868\u73b0\u51fa\u72ec\u7279\u7684\u805a\u96c6\u8bf1\u5bfc\u53d1\u5149\u7279\u6027\uff0c\u5176\u805a\u96c6\u4f53\u53ef\u7528\u4e8e\u7206\u70b8\u7269\u7684\u7075\u654f\u68c0\u6d4b\u3002\u8fd9\u79cd\u9ad8\u6548\u7684\u805a\u5408\u53cd\u5e94\u5c06\u4e3a\u5236\u5907\u9002\u7528\u4e8e\u4e0d\u540c\u9886\u57df\u7684\u529f\u80fd\u6027\u542b\u6c2e\u805a\u5408\u7269\u63d0\u4f9b\u65b0\u5de5\u5177\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u63a2\u7d22\u65b0\u7684\u805a\u5408\u53cd\u5e94\u548c\u5f00\u53d1\u65b0\u578b\u529f\u80fd\u805a\u5408\u7269\u6750\u6599\u662f\u805a\u5408\u7269\u79d1\u5b66\u4e2d\u6c38\u6052\u7684\u7814\u7a76\u8bfe\u9898\u3002\u4f5c\u4e3a\u4e00\u79cd\u65b0\u578b\u5148\u8fdb\u6750\u6599\uff0c\u542b\u6742\u539f\u5b50\u7684\u805a\u5408\u7269\u5f15\u8d77\u4e86\u7814\u7a76\u4eba\u5458\u7684\u6781\u5927\u5173\u6ce8\u3002\u5728\u8fc7\u53bb\u7684\u51e0\u5341\u5e74\u4e2d\uff0c\u4e3b\u94fe\u4e2d\u542b\u6709\u5176\u4ed6\u6742\u539f\u5b50\uff08\u786b\uff0c\u7845\uff0c\u6c27\uff0c\u6c2e\u548c\u78f7\uff09\u7684\u805a\u5408\u7269\u5df2\u7ecf\u88ab\u5236\u5907\u51fa\u6765\u3002\u7094\u70c3\u7684\u6c22\u80fa\u5316\u53cd\u5e94\u662f\u76f4\u63a5\u5236\u5907\u542bC-N\u952e\u5316\u5408\u7269\u6700\u4e3a\u7b80\u5355\u9ad8\u6548\u7684\u65b9\u6cd5\u4e4b\u4e00\u3002\u7136\u800c\uff0c\u7094\u7c7b\u5355\u4f53\u7684\u6c22\u80fa\u5316\u805a\u5408\u53cd\u5e94\u8fd8\u5904\u4e8e\u8d77\u6b65\u9636\u6bb5\uff0c\u53e6\u4e00\u65b9\u9762\uff0c\u7094\u7c7b\u5355\u4f53\u5177\u6709\u66f4\u52a0\u4e30\u5bcc\u7684\u5316\u5b66\u6027\u8d28\uff0c\u53ef\u5e26\u6765\u805a\u5408\u7269\u7ed3\u6784\u7684\u591a\u6837\u6027\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u51fa\u9ad8\u6548\u7684\u7094\u7c7b\u5355\u4f53\u6c22\u80fa\u5316\u805a\u5408\u53cd\u5e94\u5c06\u662f\u5236\u5907\u542b\u6c2e\u529f\u80fd\u9ad8\u5206\u5b50\u6750\u6599\u7684\u91cd\u8981\u9014\u5f84\u3002<\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u534e\u5357\u7406\u5de5\u5927\u5b66\u5510\u672c\u5fe0\u9662\u58eb<\/strong>\u3001<strong>\u79e6\u5b89\u519b\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\u5728\u8fd1\u671f\u7684<strong>Macromolecules<\/strong>\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u5173\u4e8e\u94dc\u50ac\u5316\u5185\u7094\u5355\u4f53\u7684\u4eb2\u7535\u6c22\u80fa\u5316\u805a\u5408\u53cd\u5e94\u7684\u6587\u7ae0\uff0c\u9898\u4e3a\u201c<strong>Copper-Catalyzed Electrophilic Polyhydroamination of Internal Alkynes<\/strong>\u201d\u3002\u6587\u7ae0\u4e2d\u8be6\u7ec6\u63cf\u8ff0\u4e86\u4ed6\u4eec\u5229\u7528\u5185\u7094\u548cN,N\u2019-\uff08\uff08\uff08\u5df1\u70f7-1,6-\u4e8c\u57fa\u53cc\uff08\u6c27\u57fa\uff09\uff09\u53cc\uff084,1-\u4e9a\u82ef\u57fa\uff09\uff09\u53cc\uff08\u4e9a\u7532\u57fa\uff09\uff09\u53cc\uff08O-\u82ef\u7532\u9170\u57fa-N-\u82c4\u57fa\u7f9f\u80fa\uff09\u4e3a\u5355\u4f53\uff0cCu(OAc)<sub> 2<\/sub> \u4e3a\u50ac\u5316\u5242\uff0c\u6210\u529f\u5b9e\u73b0\u4e86\u5185\u7094\u5355\u4f53\u7684\u4eb2\u7535\u6c22\u80fa\u5316\u805a\u5408\u53cd\u5e94\u3002\u6b64\u5916\uff0c\u4ed6\u4eec\u8fd8\u901a\u8fc7\u5c06\u5177\u6709\u805a\u96c6\u8bf1\u5bfc\u53d1\u5149\uff08AIE\uff09\u7279\u6027\u7684\u56db\u82ef\u57fa\u4e59\u70ef\uff08TPE\uff09\u57fa\u5143\u5f15\u5165\u805a\u5408\u7269\u94fe\u4e2d\uff0c\u5236\u5907\u4e86\u540c\u6837\u5177\u6709AIE\u7279\u6027\u7684\u805a\u5408\u7269\uff0c\u5e76\u4e14\u5176\u805a\u96c6\u4f53\u53ef\u7528\u4e8e\u7206\u70b8\u7269\u7684\u7075\u654f\u68c0\u6d4b\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe1 \u805a\u70ef\u80fa\u7684\u5236\u5907\u7b56\u7565<\/strong><\/p>\n<p><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/1.bmp\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-94704 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/1.bmp\" alt=\"\" width=\"700\" height=\"285\" \/><\/a><\/p>\n<p><strong>\u56fe2 \u94dc\u50ac\u5316\u5185\u7094\u5355\u4f53\u7684\u4eb2\u7535\u6c22\u80fa\u5316\u805a\u5408\u53cd\u5e94<\/strong><\/p>\n<p><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/2.bmp\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-94705 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/2.bmp\" alt=\"\" width=\"700\" height=\"438\" \/><\/a><\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u56fe3 \u6a21\u578b\u5316\u5408\u72694\u7684\u5408\u6210\u8def\u7ebf<\/strong><\/p>\n<p><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/3.bmp\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-94706 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/3.bmp\" alt=\"\" width=\"700\" height=\"324\" \/><\/a><\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u56fe4 \u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916\u5149\u8c31<\/strong><\/p>\n<p><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/4.bmp\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-94707 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/4.bmp\" alt=\"\" width=\"700\" height=\"627\" \/><\/a><\/p>\n<p>A\uff09\u5355\u4f531a\u7684\u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916\u5149\u8c31\uff1b<\/p>\n<p>B\uff09\u5355\u4f532 \u7684\u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916\u5149\u8c31\uff1b<\/p>\n<p>C\uff09\u6a21\u578b\u5316\u5408\u72694\u7684\u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916\u5149\u8c31\uff1b<\/p>\n<p>D\uff09\u805a\u5408\u7269PIa\u7684\u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916\u5149\u8c31\u3002<\/p>\n<p><strong>\u56fe5<sup> 1<\/sup>H\u6838\u78c1\u5171\u632f\u8c31<\/strong><\/p>\n<p><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/5.bmp\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-94708 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/5.bmp\" alt=\"\" width=\"700\" height=\"986\" \/><\/a><\/p>\n<p>A\uff09\u5355\u4f531a\u5728\u6c18\u4ee3\u4e8c\u6c2f\u7532\u70f7\u4e2d\u7684<sup>1<\/sup>H\u6838\u78c1\u5171\u632f\u8c31\uff1b<\/p>\n<p>B\uff09\u5355\u4f532\u5728\u6c18\u4ee3\u4e8c\u6c2f\u7532\u70f7\u4e2d\u7684<sup>1<\/sup>H\u6838\u78c1\u5171\u632f\u8c31\uff1b<\/p>\n<p>C\uff09\u6a21\u578b\u5316\u5408\u72694\u5728\u6c18\u4ee3\u4e8c\u6c2f\u7532\u70f7\u4e2d\u7684<sup>1<\/sup>H\u6838\u78c1\u5171\u632f\u8c31\uff1b<\/p>\n<p>D\uff09\u805a\u5408\u7269PIa\u5728\u6c18\u4ee3\u4e8c\u6c2f\u7532\u70f7\u4e2d\u7684<sup>1<\/sup>H\u6838\u78c1\u5171\u632f\u8c31\uff0c\u56fe\u4e2d\u6eb6\u5242\u548c\u6c34\u5cf0\u7528\u661f\u53f7\u6807\u8bb0\u3002<\/p>\n<p><strong>\u56fe6 \u805a\u5408\u7269PId\u548cPIa\u5728\u6c18\u4ee3\u4e8c\u6c2f\u7532\u70f7\u4e2d\u7684<sup>1<\/sup>H\u6838\u78c1\u5171\u632f\u8c31<\/strong><\/p>\n<p><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/6.bmp\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-94709 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/6.bmp\" alt=\"\" width=\"700\" height=\"522\" \/><\/a><\/p>\n<p>A\uff09PId\u7684<sup>1<\/sup>H\u6838\u78c1\u5171\u632f\u8c31\uff1b<\/p>\n<p>B\uff09PIa\u7684<sup>1<\/sup>H\u6838\u78c1\u5171\u632f\u8c31\uff0c\u56fe\u4e2d\u6eb6\u5242\u548c\u6c34\u5cf0\u7528\u661f\u53f7\u6807\u8bb0\u3002<\/p>\n<p><strong>\u56fe7 \u6a21\u578b\u5316\u5408\u72694\u4e0e\u805a\u5408\u7269PIa\u8fd8\u539f\u524d\u540e\u76841H\u6838\u78c1\u5171\u632f\u8c31<\/strong><\/p>\n<p><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/7.bmp\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-94710 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/7.bmp\" alt=\"\" width=\"700\" height=\"989\" \/><\/a><\/p>\n<p>A\uff09\u8fd8\u539f\u524d\u6a21\u578b\u5316\u5408\u72694\u5728\u6c18\u4ee3\u4e8c\u6c2f\u7532\u70f7\u4e2d\u7684<sup>1<\/sup>H\u6838\u78c1\u5171\u632f\u8c31\uff1b<\/p>\n<p>B\uff09\u8fd8\u539f\u540e\u6a21\u578b\u5316\u5408\u72694\u5728\u6c18\u4ee3\u4e8c\u6c2f\u7532\u70f7\u4e2d\u7684<sup>1<\/sup>H\u6838\u78c1\u5171\u632f\u8c31\uff1b<\/p>\n<p>C\uff09\u8fd8\u539f\u524d\u805a\u5408\u7269PIa\u5728\u6c18\u4ee3\u4e8c\u6c2f\u7532\u70f7\u4e2d\u7684<sup>1<\/sup>H\u6838\u78c1\u5171\u632f\u8c31\uff1b<\/p>\n<p>D\uff09\u8fd8\u539f\u540e\u805a\u5408\u7269PIa\u5728\u6c18\u4ee3\u4e8c\u6c2f\u7532\u70f7\u4e2d\u7684<sup>1<\/sup>H\u6838\u78c1\u5171\u632f\u8c31\uff0c\u56fe\u4e2d\u6eb6\u5242\u5cf0\u548c\u6c34\u5cf0\u7528\u661f\u53f7\u6807\u8bb0\u3002<\/p>\n<p><strong>\u56fe8 \u805a\u5408\u7269PIb\u7684\u5149\u8c31\u6d4b\u8bd5\u53ca\u5176\u7ed3\u679c<\/strong><\/p>\n<p><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/8.bmp\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-94712 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/8.bmp\" alt=\"\" width=\"700\" height=\"340\" \/><\/a><\/p>\n<p>A\uff09\u805a\u5408\u7269PIb\u5728\u4e0d\u540c\u6c34\u542b\u91cf\u7684THF\/\u6c34\u6df7\u5408\u6eb6\u5242\u4e2d\u7684\u8367\u5149\u5149\u8c31\uff1b<\/p>\n<p>B\uff09\u805a\u5408\u7269PIb\u7684\u76f8\u5bf9\u8367\u5149\u5f3a\u5ea6\u2014\u6c34\u542b\u91cf\u66f2\u7ebf\u3002<br \/>\n \u6eb6\u6db2\u6d53\u5ea6\uff1a10\u03bcM\uff1b\u6fc0\u53d1\u6ce2\u957f\uff1a357nm\uff1b\u63d2\u56fe\uff1a365nm UV\u7167\u5c04\u6761\u4ef6\u4e0b\uff0c\u5728THF\u6eb6\u6db2\uff08\u5de6\uff09\u548c\u542b\u6c34\u542b\u91cf\u4e3a90%\u7684THF\/\u6c34\u6df7\u5408\u6eb6\u5242\u4e2d\uff08\u53f3\uff09PIb\u7684\u8367\u5149\u7167\u7247\u3002<\/p>\n<p><strong>\u56fe9 \u52a0\u5165PA\uff08\u82e6\u5473\u9178\uff09\u540ePIb\u805a\u96c6\u4f53\u7684PL\u5149\u8c31<\/strong><\/p>\n<p><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/9.bmp\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-94714 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/9.bmp\" alt=\"\" width=\"700\" height=\"360\" \/><\/a><\/p>\n<p>A\uff09\u805a\u5408\u7269PIb\u7684THF\/\u6c34\u6df7\u5408\u6eb6\u6db2\uff08\u6c34\u542b\u91cf\u4e3a90%\uff09\u52a0\u5165\u4e0d\u540c\u91cf\u82e6\u5473\u9178\uff08PA\uff09\u7684\u8367\u5149\u5149\u8c31\uff1b\u6d53\u5ea6\uff1a10\u03bcM\uff1b\u03bbex:357nm\u3002<\/p>\n<p>B\uff09\u805a\u5408\u7269PIb\u7684\u76f8\u5bf9\u8367\u5149\u5f3a\u5ea6I<span style=\"font-size: 13.3333px;\"><sub><span style=\"line-height: 20px;\">0<\/span><\/sub><\/span>\/I-1\u2014PA\u6d53\u5ea6\u7684Stern\u2212Volmer\u56fe\uff0c\u5176\u4e2dI\u6307\u5cf0\u503c\u5f3a\u5ea6\uff0cI<sub>0<\/sub>\u8868\u793a\u7684\u662fPA\u6d53\u5ea6\u4e3a0 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\/><\/p>\n<p><strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n<p>\u534e\u5357\u7406\u5de5\u5927\u5b66\u5510\u672c\u5fe0\u9662\u58eb\u56e2\u961f\u6210\u529f\u5f00\u53d1\u51fa\u4e86\u4e00\u79cd\u9ad8\u6548\u7684\u94dc\u50ac\u5316\u7094\u7c7b\u5355\u4f53\u6c22\u80fa\u5316\u805a\u5408\u53cd\u5e94\u3002\u8be5\u53cd\u5e94\u80fd\u591f\u5728\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\u8fdb\u884c\uff0c\u5e76\u4e14\u53ef\u9ad8\u4ea7\u7387\uff08\u9ad8\u8fbe95\uff05\uff09\u5730\u5f97\u5230\u5177\u6709\u9ad8\u91cd\u5747\u5206\u5b50\u8d28\u91cf\u7684\u53ef\u6eb6\u548c\u70ed\u7a33\u5b9a\u7684\u805a\u70ef\u80fa\u3002\u800c\u8be5\u4eb2\u7535\u6c22\u80fa\u5316\u805a\u5408\u53cd\u5e94\u7684\u533a\u57df\u9009\u62e9\u6027\u5219\u53ef\u4ee5\u901a\u8fc7\u8c03\u6574\u7094\u57fa\u76f8\u8fde\u7684\u82ef\u57fa\u4e3a\u70f7\u57fa\u6765\u5b9e\u73b0\u3002\u53e6\u5916\uff0c\u5c06\u5177\u6709AIE\u6d3b\u6027\u7684TPE\u5f15\u5165\u805a\u5408\u7269PIb\u7684\u4e3b\u94fe\u4e2d\u4e5f\u4f7f\u5176\u5177\u6709AIE\u6d3b\u6027\u3002\u8fd9\u79cd\u6709\u6548\u7684\u805a\u5408\u53cd\u5e94\u5c06\u4f1a\u4e3a\u529f\u80fd\u6027\u542b\u6c2e\u805a\u5408\u7269\u7684\u5236\u5907\u5e26\u6765\u65e0\u9650\u5951\u673a\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/pubs.acs.org\/doi\/10.1021\/acs.macromol.7b00992\">Copper-Catalyzed Electrophilic Polyhydroamination of Internal\u00a0Alkynes.<\/a><\/strong>\uff08Macromolecules\uff0c2017\uff0cDOI: 10.1021\/acs.macromol.7b00992\uff09<\/p>\n<p><strong>\u56e2\u961f\u4ecb\u7ecd\uff1a<\/strong><\/p>\n<p><a href=\"http:\/\/www.aiepolymer.com\/index.php?g=home&amp;m=page&amp;a=index&amp;id=1\"><strong>\u534e\u5357\u7406\u5de5\u5927\u5b66\u5510\u672c\u5fe0\u9662\u58eb\u56e2\u961f<\/strong><\/a>\u4f9d\u6258\u4e8e\u534e\u5357\u7406\u5de5\u5927\u5b66\u53d1\u5149\u6750\u6599\u4e0e\u5668\u4ef6\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u4e8e2012\u5e74\u6210\u7acb\u3002\u56e2\u961f\u73b0\u6709\u6559\u63884\u4eba\uff0c\u526f\u7814\u7a76\u54581\u4eba\uff0c\u535a\u58eb\u540e3\u4eba\uff0c\u7814\u7a76\u751f\u540c\u5b6650\u4f59\u4eba\u3002\u5176\u4e2d\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u9662\u58eb1\u4eba\uff0c\u56fd\u5bb6\u6770\u51fa\u9752\u5e74\u79d1\u5b66\u57fa\u91d1\u83b7\u5f97\u80051\u4eba\uff0c\u5e7f\u4e1c\u7701\u81ea\u7136\u79d1\u5b66\u6770\u51fa\u9752\u5e74\u79d1\u5b66\u57fa\u91d1\u83b7\u5f97\u80052\u4eba\u3002\u8fc4\u4eca\u4e3a\u6b62\uff0c\u56e2\u961f\u5df2\u57f9\u517b\u535a\u58eb\u3001\u7855\u58eb\u7814\u7a76\u751f20\u4f59\u4eba\uff0c\u53d1\u8868\u5b66\u672f\u8bba\u6587200\u4f59\u7bc7\uff0c\u6388\u6743\u548c\u7533\u8bf7\u56fd\u5bb6\u53d1\u660e\u4e13\u522920\u4f59\u4ef6\u3002\u56e2\u961f\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u5305\u62ec\uff1a\u805a\u96c6\u8bf1\u5bfc\u53d1\u5149\u673a\u7406\u7684\u63a2\u7d22\u3001\u65b0\u578b\u805a\u96c6\u8bf1\u5bfc\u53d1\u5149\u6750\u6599\u7684\u8bbe\u8ba1\u4e0e\u5236\u5907\u4ee5\u53ca\u5176\u5728\u751f\u7269\u6210\u50cf\u3001\u5316\u5b66\u4f20\u611f\u548c\u5149\u7535\u5668\u4ef6\u7b49\u9886\u57df\u7684\u5e94\u7528\uff1b\u57fa\u4e8e\u4e09\u952e\u7684\u9ad8\u5206\u5b50\u5408\u6210\u65b0\u65b9\u6cd5\u7684\u5f00\u53d1\u3001\u5177\u6709\u7279\u6b8a\u5149\u7535\u6027\u8d28\u7684\u7ebf\u5f62\u4e0e\u62d3\u6251\u7ed3\u6784\u805a\u5408\u7269\u7684\u5236\u5907\u53ca\u529f\u80fd\u5e94\u7528\u3002<\/p>\n<p><strong>\u56e2\u961f\u5728\u8be5\u9886\u57df\u5de5\u4f5c\u6c47\u603b\uff1a<\/strong><\/p>\n<p>\u5510\u672c\u5fe0\u9662\u58eb\u56e2\u961f\u957f\u671f\u81f4\u529b\u4e8e\u53d1\u5c55\u57fa\u4e8e\u4e09\u952e\u7684\u9ad8\u5206\u5b50\u5408\u6210\u65b0\u65b9\u6cd5\uff0c\u5e76\u91c7\u7528\u7094\u7c7b\u5355\u4f53\u6210\u529f\u5408\u6210\u4e86\u4e00\u7cfb\u5217\u529f\u80fd\u5316\u7684\u5171\u8f6d\u7094\u70c3\u805a\u5408\u7269\u3002\u5728\u7094\u7c7b\u5355\u4f53\u6c22\u80fa\u5316\u805a\u5408\u65b9\u9762\uff0c\u57fa\u4e8e\u6d3b\u5316\u5185\u7094\u5355\u4f53\uff0c\u6210\u529f\u5efa\u7acb\u4e86\u4e00\u4ef7\u94dc\u50ac\u5316\u7684\u6c28\u57fa-\u7094\u70b9\u51fb\u805a\u5408\u53cd\u5e94\uff0c\u76f8\u5173\u7ed3\u679c\u4ee5\u5c01\u9762\u8bba\u6587\u7684\u5f62\u5f0f\u53d1\u8868\u4e8ePolymer Chemistry (2016, 7, 7375-7382)\u4e0a\u3002\u8bba\u6587\u9898\u4e3a\u201c<a href=\"http:\/\/pubs.rsc.org\/en\/Content\/ArticleLanding\/2016\/PY\/C6PY01501H#!divAbstract\" target=\"_blank\" rel=\"noopener\"><strong>Cu(I)-Catalyzed amino-yne click polymerization<\/strong><\/a>\u201d\u3002<\/p>\n<p> \u968f\u540e\uff0c\u57fa\u4e8e\u6d3b\u5316\u7aef\u7094\u5355\u4f53\uff0c\u5efa\u7acb\u4e86\u5177\u6709\u533a\u57df\u548c\u7acb\u4f53\u9009\u62e9\u6027\u7684\u81ea\u53d1\u6c28\u57fa-\u7094\u70b9\u51fb\u805a\u5408\uff0c\u76f8\u5173\u7ed3\u679c\u53d1\u8868\u5728Journal of the American Chemical Society (2017, 139, 5437-5443 )\u4e0a\u3002\u8bba\u6587\u9898\u4e3a\u201c<a href=\"http:\/\/pubs.acs.org\/doi\/full\/10.1021\/jacs.7b00929\" target=\"_blank\" rel=\"noopener\"><strong>Spontaneous Amino-yne Click Polymerization: A Powerful Tool toward Regio- and Stereospecific Poly(\u03b2-aminoacrylate)s<\/strong><\/a>\u201d<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u9ad8\u5206\u5b50\u5b66\u672f\u7ec4Andy\u4f9b\u7a3f\uff0c\u5510\u672c\u5fe0\u9662\u58eb\u56e2\u961f\u5ba1\u6838\u6574\u7406\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"http:\/\/www.cailiaoniu.com\/25127.html\" target=\"_blank\" rel=\"noopener noreferrer\">\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002\u53c2\u4e0e\u9ad8\u5206\u5b50\u8bdd\u9898\u8ba8\u8bba\u6216\u4e86\u89e3\u9ad8\u5206\u5b50\u7ec4\u62db\u52df\u8be6\u60c5\uff0c\u8bf7\u52a0\u9ad8\u5206\u5b50\u4ea4\u6d41\u7fa4\uff08298064863\uff09\u3002<\/p>\n<p>\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a<strong><a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener noreferrer\">\u6d4b\u8bd5\u8c37<\/a><\/strong>\uff01<\/p>\n<p><img decoding=\"async\" class=\"aligncenter\" src=\"http:\/\/dn.cailiaoniu.com\/2017\/05\/IMG_0271-1.jpg\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u505a\u4e00\u4e2a\u7231\u5206\u4eab\u7684\u79d1\u7814\u4eba\uff0c\u8bf7\u5173\u6ce8<span style=\"color: #0000ff;\">\u5927\u5206\u5b50<\/span>\u516c\u4f17\u53f7\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 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