{"id":96839,"date":"2017-08-20T10:00:31","date_gmt":"2017-08-20T02:00:31","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=96839"},"modified":"2017-08-20T10:50:46","modified_gmt":"2017-08-20T02:50:46","slug":"%e3%80%90%e4%bf%ae%e6%94%b9%e3%80%91%e6%b8%85%e5%8d%8e%e5%a4%a7%e5%ad%a6%e5%bc%a0%e5%bc%ba%e6%95%99%e6%8e%88adv-mater-%e7%83%ad%e5%89%a5%e7%a6%bb%e5%b1%82%e7%8a%b6mof%e5%9c%a8%e9%94%82%e7%a1%ab","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=96839","title":{"rendered":"\u6e05\u534e\u5927\u5b66\u5f20\u5f3a\u6559\u6388Adv. Mater.\uff1a\u70ed\u5265\u79bb\u5c42\u72b6MOF\u5728\u9502\u786b\u7535\u6c60\u4e2d\u7684\u5e94\u7528"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u56e0\u4e8c\u7ef4\u7eb3\u7c73\u78b3\u57fa\u6750\u6599\u5176\u8868\u9762\u53ef\u63a7\u7684\u5b54\u9699\u7ed3\u6784\u548c\u5177\u6709\u4eb2\u6c34\u6027\uff0c\u5728\u7535\u5316\u5b66\u50a8\u80fd\u7cfb\u7edf\uff08\u9502\u786b\u7535\u6c60\uff09\u5177\u6709\u5de8\u5927\u6f5c\u529b\u3002\u672c\u6587\u62a5\u9053\u4e86\u70ed\u5265\u79bb\u4e8c\u7ef4\u7ed3\u6784\u7684MOF\u6676\u4f53\u4f7f\u5176\u53d8\u6210\u591a\u5c42\u7c7b\u77f3\u58a8\u70ef\u5806\u53e0\u7ed3\u6784\u3002\u8be5\u7cfb\u5217\u5316\u5408\u7269\u662f\u7531\u9ad8\u5b54\u9699\u7684\u4e8c\u7ef4\u7247\u5c42\u7ed3\u6784\u548c\u9ad8\u6781\u6027\u7684\u5b54\u58c1\u7ec4\u6210\u3002\u57fa\u4e8e\u8be5\u79cd\u7ed3\u6784\u7684\u4f18\u52bf\uff0c\u672c\u7cfb\u5217\u5316\u5408\u7269\u7684\u4eb2\u6c34\u591a\u5c42\u7c7b\u77f3\u58a8\u70ef\u5806\u53e0\u7ed3\u6784\u53ef\u4ee5\u4f5c\u4e3a\u9502\u786b\u7535\u6c60\u7684\u6b63\u6781\u6a21\u578b\uff0c\u5e76\u63ed\u5f00\u9502\u7535\u6c60\u7684\u8868\u9762\u5316\u5b66\u95ee\u9898\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u76ee\u524d\u800c\u8a00\uff0c\u5177\u6709\u4e8c\u7ef4\u7c7b\u77f3\u58a8\u70ef\/\u6c27\u5316\u77f3\u58a8\u70ef\u7ed3\u6784\u7684\u7eb3\u7c73\u78b3\uff0c\u7531\u4e8e\u9ad8\u7eb5\u6a2a\u6bd4\u8d4b\u4e88\u5b83\u4eec\u4f18\u5f02\u7684\u7406\u5316\u7279\u5f81\uff0c\u4f7f\u5176\u5728\u7535\u5316\u5b66\u50a8\u80fd\u3001\u6c14\u4f53\u5438\u9644\u4e0e\u5206\u79bb\uff0c\u4ee5\u53ca\u50ac\u5316\u9886\u57df\u5177\u6709\u5f88\u5927\u7684\u5e94\u7528\u3002\u8fd1\u65e5\uff0c<strong>\u6e05\u534e\u5927\u5b66\u5f20\u5f3a\u6559\u6388\u5728<em>Adv. Mater<\/em><\/strong><em>.<\/em>\u4e0a\u53d1\u6587\uff0c\u9898\u540d\u201c<strong>Thermal Exfoliation of Layered Metal\u2013Organic Frameworks into Ultrahydrophilic Graphene Stacks and Their Applications in Li\u2013S Batteries\u201d<\/strong>\u3002\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u5229\u7528\u94dc\u76d04,4\u2019-\u8054\u5421\u5576MOF\u7528\u4ee5\u5f62\u6210\u4e8c\u7ef4\u5c42\u72b6\u7ed3\u6784\u3002\u4e8c\u7ef4\u7ed3\u6784\u4e2d\u901a\u8fc7\u03c0-\u03c0\u5171\u8f6d\u76f8\u4e92\u4f5c\u7528\uff0c\u5f62\u6210[Cu<sub>2<\/sub>Cl<sub>2<\/sub>C<sub>10<\/sub>H<sub>8<\/sub>N<sub>2<\/sub>]<sub>n<\/sub>\u6676\u4f53\u3002\u7531\u4e8e\u8be5\u6676\u4f53\u5f31\u7684\u8303\u5fb7\u534e\u529b\u5bb9\u6613\u88ab\u70ed\u5265\u79bb\u621010 \u03bcm\u5de6\u53f3\uff0c\u7eb3\u7c73\u5c3a\u5bf8\u539a\u5ea6\u7684\u805a\u5408\u7269\u6676\u4f53\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u00a0<\/strong><strong>\u56fe<\/strong><strong>1 MOF<\/strong><strong>\u524d\u9a71\u4f53\u7684\u8868\u5f81<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-96843 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/\u56fe\u72471-11.png\" alt=\"\" width=\"700\" height=\"569\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/\u56fe\u72471-11.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/\u56fe\u72471-11-300x244.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u56fea. MOF\u7684XRD\u4e0e\u5176\u6807\u51c6\u8c31\u56fe\u3002<\/p>\n<p>\u56feb. \u5c42\u72b6MOF\u4ee5\u53ca\u6a21\u578b\u3002<\/p>\n<p>\u56fec-e. MOF\u6750\u6599\u7684SEM\u8c31\u56fe\u3002<\/p>\n<p>\u56fef. \u673a\u68b0\u5265\u79bb\u5f97\u5230\u76842D MOF\u3002<\/p>\n<p>\u56feg. AFM\u56fe\u50cf\u4ee5\u53ca\u5176\u539a\u5ea6\u3002<\/p>\n<p><strong>\u56fe2 UHCS samples\u6750\u6599\u7684\u8868\u5f81<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-96960 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/\u56fe\u72472-14.png\" alt=\"\" width=\"634\" height=\"700\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/\u56fe\u72472-14.png 634w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/\u56fe\u72472-14-272x300.png 272w\" sizes=\"(max-width: 634px) 100vw, 634px\" \/><\/p>\n<p>\u56fea-b. UHCS\u2010500\u7684SEM\u3002<\/p>\n<p>\u56fec-d. UHCS\u2010900\u7684SEM\u3002<\/p>\n<p>\u56fee-f. UHCS\u2010900\u7684TEM\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>3 UHCS<\/strong><strong>\u6750\u6599\u7684\u5b54\u5f84\u5206\u5e03\u4ee5\u53ca\u8868\u9762\u6781\u6027\u8868\u5f81<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-96846 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/\u56fe\u72473-7.png\" alt=\"\" width=\"641\" height=\"700\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/\u56fe\u72473-7.png 641w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/\u56fe\u72473-7-275x300.png 275w\" sizes=\"(max-width: 641px) 100vw, 641px\" \/><\/p>\n<p>\u56fea. UHCS\u6750\u6599\u4e0eCVD\u77f3\u58a8\u70ef\u7684\u6c2e\u6c14\u5438\u9644\u8868\u5f81\u3002<\/p>\n<p>\u56feb. \u4eb2\u6c34\u578b\u6cb8\u77f3\uff0c\u6d3b\u6027\u70ad\uff0c\u5fae\u5b54\u78b3\u548c\u78b3\u7eb3\u7c73\u7ba1\u7684\u6c34\u84b8\u6c14\u5438\u9644\u6027\u6d4b\u8bd5\u3002<\/p>\n<p>\u56fec. \u52a8\u6001\u63a5\u89e6\u89d2\u6d4b\u8bd5\u3002<\/p>\n<p>\u56fed. \u4eb2\u6c34\u6027\u78b3\u6750\u6599\u7684\u62c9\u66fc\u5149\u8c31\u3002<\/p>\n<p>\u56fee. \u4eb2\u6c34\u6027\u78b3\u6750\u6599N 1s\u7684XPS\u5149\u8c31\u3002<\/p>\n<p><strong>\u56fe4 \u6781\u6027UHCS\u548c\u975e\u6781\u6027\u78b3\u7eb3\u7c73\u7ba1\u7684\u7535\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-96847 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/\u56fe\u72474-4.png\" alt=\"\" width=\"601\" height=\"661\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/\u56fe\u72474-4.png 601w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/08\/\u56fe\u72474-4-273x300.png 273w\" sizes=\"(max-width: 601px) 100vw, 601px\" \/><\/p>\n<p>\u56fea. UHCS\u4f5c\u4e3a\u6b63\u6781\u6750\u6599\u7684\u793a\u610f\u56fe\u3002<\/p>\n<p>\u56feb. \u5b8f\u89c2\u5438\u9644\u8bd5\u9a8c\u3002<\/p>\n<p>\u56fec. \u4ea4\u6d41\u963b\u6297\u56fe\u8c31\u3002<\/p>\n<p>\u56fed. \u4eb2\u6c34\u6027\u78b3\u7684CV\u56fe\u3002<\/p>\n<p>\u56fee. \u6052\u7535\u6d41\u5145\u653e\u7535\u56fe\u3002<\/p>\n<p>\u56fef. 1C\u7535\u6d41\u4e0b\u7684\u5faa\u73af\u56fe\u3002<\/p>\n<p><strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n<p>\u8fd9\u9879\u5de5\u4f5c\u4ecb\u7ecd\u4e86\u4e00\u79cd\u7b80\u5355\u70ed\u5265\u79bbMOF\u6676\u4f53\u7684\u65b9\u6cd5\u3002\u5229\u7528\u8fd9\u79cd\u65b9\u6cd5\u5236\u5907\u51fa\u4e86\u591a\u5c42\u7c7b\u77f3\u58a8\u70ef\uff0c\u5f3a\u8868\u9762\u6781\u6027\uff0c\u591a\u7ea7\u5fae\u5b54\u548c\u5f62\u6001\u5747\u4e00\u7684\u7ed3\u6784\u3002\u5f53\u8fd9\u4e9b\u6781\u6027\u7eb3\u7c73\u78b3\u5728\u9502\u786b\u7535\u6c60\u4e2d\u4f5c\u4e3a\u6b63\u6781\u65f6\uff0c\u591a\u5b54\u6781\u6027\u53ef\u4ee5\u5438\u5f15\u591a\u786b\u5316\u7269\uff0c\u540c\u65f6\u786e\u4fdd\u7535\u5b50\u548c\u79bb\u5b50\u53ef\u4ee5\u81ea\u7531\u8f6c\u79fb\uff0c\u4ece\u800c\u4f7f\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u80fd\u591f\u53ef\u9006\u8fdb\u884c\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u6211\u4eec\u7684\u70ed\u5265\u79bb\u65b9\u6cd5\u53ef\u7528\u6765\u9ad8\u6548\u5236\u5907\u5f3a\u6781\u6027\u7eb3\u7c73\u78b3\u6750\u6599\u3002\u4e5f\u53ef\u4ee5\u63a2\u7d22\u5176\u5b83\u4e8c\u7ef4\u524d\u9a71\u6750\u6599\u7528\u4ee5\u5408\u6210\u7eb3\u7c73\u78b3\u3002<\/p>\n<p><strong>\u6587\u7ae0\u94fe\u63a5\uff1a<\/strong><u><a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/adma.201702829\/full\" target=\"_blank\" rel=\"noopener\">Thermal Exfoliation of Layered Metal\u2013Organic Frameworks into Ultrahydrophilic Graphene Stacks and Their Applications in Li\u2013S Batteries<\/a><\/u>\uff08<strong><em>Adv. Mater.<\/em><\/strong> 2017, 10.1002\/adma.201702829\uff09<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u7ec4\u5434\u6dcf\u4f9b\u7a3f\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<strong><a href=\"http:\/\/www.cailiaoniu.com\/25127.html\" target=\"_blank\" rel=\"noopener\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a><\/strong>\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com<\/p>\n<p>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<strong><a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\">\u6d4b\u8bd5\u8c37<\/a><\/strong>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u56e0\u4e8c\u7ef4\u7eb3\u7c73\u78b3\u57fa\u6750\u6599\u5176\u8868\u9762\u53ef\u63a7\u7684\u5b54\u9699\u7ed3\u6784\u548c\u5177\u6709\u4eb2\u6c34\u6027\uff0c\u5728\u7535\u5316\u5b66\u50a8\u80fd\u7cfb\u7edf\uff08\u9502\u786b\u7535\u6c60\uff09\u5177\u6709\u5de8\u5927\u6f5c\u529b\u3002\u672c\u6587\u62a5\u9053\u4e86\u70ed\u5265\u79bb\u4e8c\u7ef4\u7ed3\u6784\u7684MOF\u6676\u4f53\u4f7f\u5176\u53d8\u6210\u591a\u5c42\u7c7b\u77f3\u58a8\u70ef&#8230;<\/p>\n","protected":false},"author":3448,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-96839","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/96839"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/3448"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=96839"}],"version-history":[{"count":10,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/96839\/revisions"}],"predecessor-version":[{"id":97041,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/96839\/revisions\/97041"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=96839"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=96839"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=96839"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}